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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 811 records · Page 45

The effect of diffusion induced lattice stress on the open-circuit voltage in silicon solar cells

It is demonstrated that diffusion induced stresses in low resistivity silicon solar cells can significantly reduce both the open-circuit voltage and collection efficiency. The degradation mechanism involves stress induced changes in both the minority carrier mobility and the diffusion length. Thermal recovery characteristics indicate that the stresses are relieved at higher temperatures by divacancy flow (silicon self diffusion). The level of residual stress in as-fabricated cells was found to be negligible in the cells tested.

Weizer, V. G.↗

Piecewise-Linear Computation Of Creep

Theory of elastic and inelastic stresses and strains in isotropic materials blended with finite-element computer programs to calculate residual stresses due to creep in structures. Analogy drawn between thermal expansion and creep, enabling use of thermal-stress computational approach to calculate creep stresses and strains. Overall transient solution obtained by piecewise-linear iterations. Creep stresses in structure computed in iterative process in which cumulative creep strains treated as fictitious changes in coefficients of thermal expansion.

Jenkins, Jerald↗

Thermal Effects on the Compressive Behavior of IM7/PET15 Laminates

The effect of changing operating temperature on the compressive response of IM7/PETI5 composite laminates is investigated within this paper. The three temperatures evaluated for this study were 129 C, 21 C, and 177 C, a spectrum from cryogenic to an elevated operating temperature. Laminate compressive strength property testing was conducted using the Wyoming Combined Load Compression fixture to generate strength data at the three operating temperatures of interest for several lay-ups. A three-dimensional finite element analysis model of a [90/0]8s composite laminate subject to compressive loading is developed. The model is used to study the key attributes of the laminate that significantly influence the state of stress in the laminate. Both the resin rich layer located between lamina and the thermal residual stresses present in the laminate due to curing are included in the analysis model. For the laminate modeled, the effect of modeling temperature dependent material properties was determined to be insignificant for the operating temperatures studied. Simply using the material properties measured at the operating temperature of interest was sufficient for predicting stresses accurately in a linear analysis for the current problem. The three-dimensional analysis results revealed that the application of an applied compressive axial load in the 0-degree direction decreased the interlaminar stresses present in the laminate initially due to curing. Therefore, failure was concluded not be attributable to the interlaminar stresses in the composite laminate being studied when a compressive load is applied. The magnitude of the measured laminate compressive strength change with a change in temperature is concluded to be dominated by the change in the lamina compressive axial strength with a change in temperature.

Walker, Sandra Polesky↗

Estimation of micro-Hall-Petch coefficients for prismatic slip system in Mg-4Al as a function of grain boundary parameters

Grain size strengthening, referred to as the Hall-Petch effect, is a common strategy to improve the yield strength of magnesium (Mg) alloys. Several experimental studies have reported that the Hall-Petch slope strongly depends on the texture of the alloy. This effect arises from altering grain boundaries (GBs) resistance to different slip systems to transfer across adjacent grains. The grain boundary barrier strength of certain grain boundaries to basal slip, referred to as basal micro-Hall-Petch, was investigated in the previous work. Here in this study, the micro-Hall-Petch coefficient values for the prismatic slip $(k^{prismatic}_{μ})$ in Mg-4Al and their correlation with the grain boundary parameters were investigated. An experimental method was developed to initiate the prismatic slip band at low-stress levels. High-resolution electron backscatter diffraction (HR-EBSD) was used to measure the residual stress tensor, from which the resolved shear stress ahead of blocked prismatic slip bands was computed for seven different grain boundaries. $(k^{prismatic}_{μ})$ values for each individual GB were calculated by coupling the stress profile information with a continuum dislocation pile-up model. The $(k^{prismatic}_{μ})$ values vary from 0.138 MPa.m 1/2 to 0.685 MPa. m 1/2 which are almost three times larger than the calculated values for the basal micro-Hall-Petch. The $(k^{prismatic}_{μ})$ values were correlated with the GB parameters, and a functional relationship depending on the two most effective angles, the angle between the traces of the slip planes on the GB plane ($\phi$) and the angle between incoming and outgoing slip directions (κ), was proposed to estimate the Hall-Petch barrier for prismatic slip system. The work provides coefficients that can be supplied as input to crystal plasticity models to couple the effect of texture and grain size effectively.

36 MATERIALS SCIENCE↗

Raman spectroscopic characterization of SiO 2 phase transformation and Si substrate stress relevant to EBC performance

To accurately model the long-term durability of environmental barrier coatings (EBCs), a more complete understanding of the phase composition and transformations of the thermally grown oxide SiO 2 (TGO) is desired. For the TGO formed during thermal cycling in steam, cristobalite formation and the subsequent β- to α-cristobalite transformation has been identified as a potentially life-limiting mechanism. In this study, Raman micro-spectroscopy was used to quantify the cristobalite transformation on a polycrystalline Si coupon that was exposed to steam at 1350°C for 100 h. The phase transformation was mapped at 200–260°C on the TGO surface at different ramp rates using a heating stage and a micro-positioning stage. The stress in the Si substrate was also determined using Raman spectroscopy by measuring the stress induced peak shift. The α→β phase transformation produced a 300–500 MPa tensile stress in the Si substrate, which compared well to the stress predicted from the volumetric expansion of the cristobalite. In conclusion, quantifying the phase transformation and residual stress are critical tools in developing the next generation of high performance EBCs.

36 MATERIALS SCIENCE↗

Nonlinear laminate analysis for metal matrix fiber composites

A nonlinear laminate analysis is described for predicting the mechanical behavior (stress-strain relationships) of angleplied laminates in which the matrix is strained nonlinearly by both the residual stress and the mechanical load and in which additional nonlinearities are induced due to progressive fiber fractures and ply relative rotations. The nonlinear laminate analysis (NLA) is based on linear composite mechanics and a piece wise linear laminate analysis to handle the nonlinear responses. Results obtained by using this nonlinear analysis on boron fiber/aluminum matrix angleplied laminates agree well with experimental data. The results shown illustrate the in situ ply stress-strain behavior and synergistic strength enhancement.

Chamis, C. C.↗

Effects of Laser Etching on the Corrosion Susceptibility of SAVY 4000 and Hagan Containers

Since the late 1990’s, the Hagan container was used as the primary container for packaging of plutonium-bearing materials. The Hagan design consisted of a threaded closure, a Viton® ORing, a carbon-carbon filter, and a 304L stainless steel (SS) body. Over the years, Hagans have shown vulnerability in their design [1]. In 2008, The Department of Energy (DOE) issued DOE M 441.1-1, Nuclear Material Packaging Manual, which detailed an approach to obtain highconfidence in containers by including specific design requirements, material contents and an approach to determine life span from said contents, and surveillance techniques [2]. In response to both the vulnerability issues with the Hagan and DOE M 441.1-1, the SAVY 4000 container with its twist style closure, Viton® O-Ring, Fiberfrax-Gortex filter, and annealed 316L SS body, was designed as the replacement for Hagan containers, but only for a short term lifespan of 5 years [1]. However, both the Hagan and SAVY 4000 are being pushed to maintain a lifespan of 40 years. Therefore, proper confidence must be placed on each component of each container to last a minimum of 40 years. So far, the biggest concern found during surveillance of these containers is corrosion and the potential for failure by corrosion. One concern is that the containers fail due to stress corrosion cracking (SCC), especially around the weld between the collar and the body as welds leave residual stresses. One advantage the SAVY 4000 has is that the body is annealed, but its weld is still susceptible as it was welded after annealing [3, 4]. Moreover, 316L SS is known to have a higher pitting resistance (pits are a precursor to SCC and can also lead to extensive failure of the material), than 304L SS [4]. During recent surveillance activities, two SAVY 4000’s containing Solution Assay Instrument (SAI) solutions were opened. The SAI SAVY 4000’s contained plutonium (Pu) in 3M HCl solution in plastic volumetric flasks placed inside of polyethylene bags. Historically, a SAVY 4000 containing an SAI solution is packaged for 3 weeks, however, these particular containers were not reopened until 14 months later. When opened, brown-red corrosion product was found all over the inside of the container as shown in Figure 1.

36 MATERIALS SCIENCE↗

Stress studies in EFG

A computer code which can account for plastic deformation effects on stress generated in silicon sheet grown at high speeds is fully operative. Stress and strain rate distributions are presented for two different sheet temperature profiles. The calculations show that residual stress levels are very sensitive to details of the cooling profile in a sheet with creep. Experimental work has been started in several areas to improve understanding of ribbon temperature profiles and stress distributions associated with a 10 cm wide ribbon cartridge system.

Source record↗

A numerical simulation to verify the stress-free growth of silicon crystal ribbon

Thermal stresses developed during the growth of silicon crystal ribbon have been shown to be negligible, thus eliminating residual stresses and dislocations, if the temperature profile satisfies a second-order partial differential equation inside the ribbon. This has been numerically verified through a finite element model, an outline of which is presented here. This model shows that, for homogeneous isotropic material with temperature independent thermal expansion coefficients, thermal stresses will vanish if the temperature profile satisfies the Laplacian. A comparison of stresses due to uniform and nonuniform temperature gradients in the plane of the ribbon is also presented. The strategies employed to control the round-off error and to validate the computer model are discussed.

Ray, Sujit K.↗

Thermoelastic Stress Analysis: The Mean Stress Effect in Metallic Alloys

The primary objective of this study involved the utilization of the thermoelastic stress analysis (TSA) method to demonstrate the mean stress dependence of the thermoelastic constant. Titanium and nickel base alloys, commonly employed in aerospace gas turbines, were the materials of interest. The repeatability of the results was studied through a statistical analysis of the data. Although the mean stress dependence was well established, the ability to confidently quantify it was diminished by the experimental variations. If calibration of the thermoelastic response to mean stress can be successfully implemented, it is feasible to use the relationship to determine a structure's residual stress state.

Gyekenyesi, Andrew L.↗

Volcanoes Erupt Stressed Quartz Crystals

Volcanic eruptions are energetic events driven by the imbalance of magmatic forces. The magnitudes of these forces remain poorly constrained because they operate in regions that are inaccessible, either underground or dangerous to approach. New techniques are needed to quantify the processes that drive eruptions and to probe magma storage conditions. Here we present X-ray microdiffraction measurements of volcanic stress imparted as lattice distortions to the crystal cargo of magma from Yellowstone and Long Valley eruptions. Elevated residual stresses between 100 and 300 MPa are preserved in erupted quartz. Multiple volcanic forces could be culpable for the deformation so we analyzed crystals from pyroclastic falls, pyroclastic density currents, and effusive lavas. In conclusion, stresses are preserved in all quartz but cannot be attributed to differences in eruption style. Instead, lattice deformation likely preserves an in situ measurement of the deviatoric stresses required for the brittle failure of viscous, crystal-bearing glass during ascent.

58 GEOSCIENCES↗

Recent developments in analysis of crack propagation and fracture of practical materials

The limitations of linear elastic fracture mechanics in aircraft design and in the study of fatigue crack propagation in aircraft structures are discussed. NASA-Langley research to extend the capabilities of fracture mechanics to predict the maximum load that can be carried by a cracked part and to deal with aircraft design problems are reported. Achievements include: (1) improved stress intensity solutions for laboratory specimens; (2) fracture criterion for practical materials; (3) crack propagation predictions that account for mean stress and high maximum stress effects; (4) crack propagation predictions for variable amplitude loading; and (5) the prediction of crack growth and residual stress in built-up structural assemblies. These capabilities are incorporated into a first generation computerized analysis that allows for damage tolerance and tradeoffs with other disciplines to produce efficient designs that meet current airworthiness requirements.

Hardrath, H. F.↗

Nonlinear laminate analysis for metal matrix fiber composites

A nonlinear laminate analysis is described for predicting the mechanical behavior (stress-strain relationships) of angle-ply laminates in which the matrix is strained nonlinearly by both the residual stress and the mechanical load and in which additional nonlinearities are induced due to progressive fiber fractures and ply relative rotations. The nonlinear laminate analysis is based on linear composite mechanics and a piece-wise linear laminate analysis to handle the nonlinear responses. Results obtained by using this nonlinear analysis on boron-fiber/aluminum-matrix angle-ply laminates agree well with experimental data. The results shown illustrate the in situ ply stress-strain behavior and synergistic strength enhancement.

Chamis, C. C.↗

Thermal stress fracture of ceramic coatings

Thermal stress failures of ceramic coatings are discussed in terms of fracture mechanics concepts. The effects of transient and residual stresses on single and multiple cycle failure mechanisms are considered. A specific example of a zirconia thermal barrier coating is presented and its endurance calculated using the proposed relationships.

Andersson, C. A.↗

Monitoring Fiber Stress During Curing of Single Fiber Glass- and Graphite-Epoxy Composites

The difference in thermal expansion characteristics of epoxy matrices and graphite fibers can produce significant residual stresses in the fibers during curing of composite materials. Tests on single fiber glass-epoxy and graphite-epoxy composite specimens were conducted in which the glass and graphite fibers were preloaded in tension, and the epoxy matrix was cast around the fibers. The fiber tension was monitored while the matrix was placed around the fiber and subjected to the temperature-time curing cycle. Two mechanisms responsible for producing stress in embedded fibers were identified as matrix thermal expansion and contraction and matrix cure shrinkage. A simple analysis based on the change in fiber tension during the curing cycle was conducted to estimate the produced stresses. Experimental results on single fiber glass- and graphite-epoxy composites show that the fiber was subjected to significant tensile stresses when the temperature was raised from the first to the second dwell period. When initial fiber pretension is about 60 percent of the fiber failure load, these curing-induced stresses can cause tensile fracture of the embedded fiber.

Madhukar, Madhu S.↗

The ecology of flows and drift wave turbulence in CSDX: A model

This paper describes the ecology of drift wave turbulence and mean flows in the coupled drift-ion acoustic wave plasma of a CSDX linear device. A 1D reduced model that studies the spatiotemporal evolution of plasma mean density $\bar{n}$, and mean flows $\bar{v}$y and $\bar{v}$z, in addition to fluctuation intensity ε, is presented. Here, ε = 〈 n ~ 2 + ( ∇ ⊥ Φ ~ ) 2 + v ~ z 2 〉 is the conserved energy field. The model uses a mixing length l mix inversely proportional to both axial and azimuthal flow shear. This form of l mix closes the loop on total energy. The model self-consistently describes variations in plasma profiles, including mean flows and turbulent stresses. It investigates the energy exchange between the fluctuation intensity and mean profiles via particle flux &#9001 n ~ v ~ x 〉 and Reynolds stresses 〈 v ~ x v ~ y 〉 and 〈 v ~ x v ~ z 〉 Acoustic coupling breaks parallel symmetry and generates a parallel residual stress Π res xz . The model uses a set of equations to explain the acceleration of $\bar{v}_y$ and $\bar{v}_z$ via Π x y r e s ∝ ∇ n - and Π x y r e s ∝ ∇ n - . Flow dynamics in the parallel direction are related to those in the perpendicular direction through an empirical coupling constant σVT. This constant measures the degree of symmetry breaking in the 〈$k_mk_z$〉 correlator and determines the efficiency of ∇$\bar{n}$ in driving $\bar{v}_z$. The model also establishes a relation between ∇$\bar{v}_y$ and ∇$\bar{v}_z$, via the ratio of the stresses Π res xy and Π res xz . When parallel to perpendicular flow coupling is weak, axial Reynolds power P x z R e = - 〈 v ~ x v ~ z &#9002 ∇ v - z is less than the azimuthal Reynolds power P x y R e = - 〈 v ~ x v ~ y 〉 ∇ v - y ∇$\bar{v}_y$. The model is then reduced to a 2-field predator/prey model where $\bar{v}_z$ is parasitic to the system and fluctuations evolve self-consistently. Finally, turbulent diffusion in CSDX follows the scaling: D CSDX = D B ρ * 0.6 , where D B is the Bohm diffusion coefficient and ρ * is the ion gyroradius normalized to the density gradient | ∇ n - / n - | - 1

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Thermal dependence of stress-induced birefringence in single mode optical fibers

Measurements of the change in stress-induced birefringence with temperature in single mode optical fibers are reported. The fibers examined include those with low residual stress birefringence that have circular and elliptical cores. A section of each fiber was placed under constant load with weights and heated inside a furnace. Polarized light was coupled into and out of the fiber ends outside the furnace. Two mutually perpendicular polarization components were analyzed and detected at the fiber output end. Changes in the detected signal levels were monitored as a function of the temperature of the single mode fiber stressed under constant load. Discussion of results and applications to localized stress measurements at high temperatures are presented.

Berthold, J. W., III↗

Reduction Of Stresses In Growing Silicon Webs

New trenched lid intercepts less radiation from edges of growing silicon ribbon, giving rise to faster growth and temperature distribution resulting in lower residual stress. Cutting trench in susceptor lid allows edges of growing ribbon of silicon to cool more rapidly. Edges cool and solidify nearly same rate as center of ribbon, and thermal stress in ribbon reduced. Because of more-effective edge cooling, wider ribbon grown, and withdrawn at faster rate. Productivity of dendritic-web growth furnace increased.

Duncan, C. S.↗