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At least 811 records · Page 45

Powder agglomeration in a microgravity environment

This is the final report for NASA Grant NAG3-755 entitled 'Powder Agglomeration in a Microgravity Environment.' The research program included both two types of numerical models and two types of experiments. The numerical modeling included the use of Monte Carlo type simulations of agglomerate growth including hydrodynamic screening and molecular dynamics type simulations of the rearrangement of particles within an agglomerate under a gravitational field. Experiments included direct observation of the agglomeration of submicron alumina and indirect observation, using small angle light scattering, of the agglomeration of colloidal silica and aluminum monohydroxide. In the former class of experiments, the powders were constrained to move on a two-dimensional surface oriented to minimize the effect of gravity. In the latter, some experiments involved mixture of suspensions containing particles of opposite charge which resulted in agglomeration on a very short time scale relative to settling under gravity.

Cawley, James D.↗

Structure and stability of hydrous minerals at high pressure

The presence of even small amounts of hydrogen in the Earth's deep interior may have profound effects on mantle melting, rheology, and electrical conductivity. The recent discovery of a large class of high-pressure H-bearing silicates further underscores the potentially important role for hydrous minerals in the Earth's mantle. Hydrogen may also be a significant component of the Earth's core, as has been recently documented by studies of iron hydride at high pressure. In this study, we explore the role of H in crystal structures at high pressure through detailed Raman spectroscopic and x ray diffraction studies of hydrous minerals compressed in diamond anvil cells. Brucite, Mg(OH)2, has a simple structure and serves as an analogue for the more complex hydrous silicates. Over the past five years, this material has been studied at high pressure using shock-compression, powder x ray diffraction, infrared spectroscopy, Raman spectroscopy, and neutron diffraction. In addition, we have recently carried out single-crystal synchrotron x-ray diffraction on Mg(OH)2 and Raman spectroscopy on Mg(OD)2 at elevated pressure. From all these studies, an interesting picture of the crystal chemical behavior of this material at high pressure is beginning to emerge. Some of the primary conclusions are as follows: First, hydrogen bonding is enhanced by the application of pressure. Second, layered minerals which are elastically anisotropic at low pressure may not be so at high pressure. Furthermore, the brucite data place constraints on the effect of hydrogen on seismic velocities and density at very high pressure. Third, the stability of hydrous minerals may be enhanced at high P by subtle structural rearrangements that are difficult to detect using traditional probes and require detailed spectroscopic analyses. Finally, brucite appears to be unique in that it undergoes pressure-induced disordering that is confined solely to the H-containing layers of the structure.

Duffy, T. S.↗

Mutagenesis in human cells with accelerated H and Fe ions

The overall goals of this research were to determine the risks of mutation induction and the spectra of mutations induced by energetic protons and iron ions at two loci in human lymphoid cells. During the three year grant period the research has focused in three major areas: (1) the acquisition of sufficient statistics for human TK6 cell mutation experiments using Fe ions (400 MeV/amu), Fe ions (600 MeV/amu) and protons (250 MeV/amu); (2) collection of thymidine kinase- deficient (tk) mutants or hypoxanthine phosphoribosyltransferase deficient (hprt) mutants induced by either Fe 400 MeV/amu, Fe 600 MeV/amu, or H 250 MeV/amu for subsequent molecular analysis; and (3) molecular characterization of mutants isolated after exposure to Fe ions (600 MeV/amu). As a result of the shutdown of the BEVALAC heavy ion accelerator in December 1992, efforts were rearranged somewhat in time to complete our dose-response studies and to complete mutant collections in particular for the Fe ion beams prior to the shutdown. These goals have been achieved. A major effort was placed on collection, re-screening, and archiving of 3 different series of mutants for the various particle beam exposures: tk-ng mutants, tk-sg mutants, and hprt-deficient mutants. Where possible, groups of mutants were isolated for several particle fluences. Comparative analysis of mutation spectra has occured with characterization of the mutation spectrum for hprt-deficient mutants obtained after exposure of TK6 cells to Fe ions (600 MeV/amu) and a series of spontaneous mutants.

Kronenberg, Amy↗

Tidal disruption and the appearance of periodic comet Shoemaker-Levy 9

A unified model is formulated to interpret quantitatively the observed characteristics of the nuclear train, the two dust trails, and the tail region of P/Shoemaker-Levy 9 in terms of a collisionally modified rotation velocity distribution of the comet's debris. Since there is no evidence for the comet's out-gassing, the model does not assume activity. The discruption of the parent comet was due primarily to tidal stesses during its extremely close approach to Juptier in July 1992. The original nucleus is found to have been most probably approximately 5 km in radius or, equivalently, approximately 10(exp 17) g in mass. The dynamical separation of the debris occurred apparently approximately 2.2 hr after the perijove passage, even though the actual fragmentation of the original mass is likely to have begun before closest approach. Physical breakp was accompanied by ubiquitous low-velocity collisions among the particulates, resulting in a rearrangement of the initial rotaional velocities into a rapidly 'thermalized' distribution, characterized by a long tail of relatively high velocities for the debris that populates the dust trails far from the nuclear train. Compelling evidence is presented for secondary fragmentation events, indicative of the comet's continuing disintegration. Secondary fragmentation may be caused by rotational bursting of the massive fragments that had been cracked but unbroken during the tidal disruption. Impact conditions and possible interactions of the comet's debris with the jovian system during the encounter in July 1994 are described.

Sekanina, Z.↗

Microstructural and strength stability of a developmental CVD SiC fiber

The effects of thermal exposure on the room temperature tensile strength and microstructure of a developmental 50 micron CVD SiC fiber have been studied. The fibers were heat treated between 600 and 2000 C in 0.1 MPa argon and air environments for up to 100 hr. In the as-fabricated condition, the fibers showed approximately 6 GPa tensile strength. After argon treatment, the fibers showed strength degradation after 1 hr exposure beyond 1000 C, but those exposed between 1600 and 2000 C retained approximately 2 GPa strength. TEM results showed microstructural changes both in the surface coating and SiC sheath. Flaws created by the rearrangement of carbon in the surface coating and growth of equiaxed SiC grain zone in the SiC sheath are the suggested mechanisms of strength degradation. After air treatment, fibers showed strength degradation after only 2 min exposure at 600 C. Strength retention after 2 min at 1500 C was approximately 2 GPa. Oxidation of the surface coating is the primary reason for strength degradation.

Bhatt, Ramakrishna T.↗

Architecture and performance analysis of DIRSMIN: A fault-tolerant switch using dilated reduced-stage MIN

We develop and analyze a dilated high performance fault tolerant fast packet multistage interconnection network (MIN) in this paper. In this new design, the links at the input and the output stages of a dilated banyan-based MIN are rearranged to create multiple routes for each source-destination pair in the network after removing one stage in the network. These multiple paths are link- and node-disjoint. Fault tolerance at low latency is achieved by sending multiple copies of each input packet simultaneously using different routes and different priorities. This guarantees that high throughput is maintained even in the presence of faults. Throughput is analyzed using simulation and analysis and we show that the new design has considerably higher performance in the presence of a faulty switching element (SE) or link in comparison to dilated networks. We also analyze the reliability and show that the new design has superior reliability in comparison to competing proposals.

Somani, Arun K.↗

Flight control augmentation for AFT CG launch vehicles

The Space Shuttle was only the first step in achieving routine access to space. Recently, the NASA Marshall Space Flight Center (MSFC) has been studying a whole spectrum of new launch vehicles (L/V's) for space transportation. Some of these could transport components of the Space Station to orbit, and some could take us to Mars and beyond to boldly expand our frontiers of knowledge. In all our future launch vehicle (L/V) designs, decreasing the structural weight will always be of great concern. This is tantamount to increased payload capability, which in turn means reduced cost-per-pound to orbit. One very significant increase in payload capability has been defined. In a L/V recently studied at MSFC it has been shown that a sizable weight savings can be realized by a rearrangement of the internal propellant tanks. Studies have been conducted both at MSFC and at Martin Marietta Corporation, maker of the Space Shuttle External Tank (ET) which show that a very substantial weight can be saved by inverting the relative positions of the liquid hydrogen (LH2) and the liquid oxygen (LOX) propellant tanks in a particular L/V studied. As the vehicle sits on the launch pad, in the conventional configuration the heavier LOX tank is located on top of the lighter LH2. This requires a heavy structural member between the two tanks to prevent the lighter LH2 tank from being crushed. This configuration also requires large, long, and even drag producing LOX feed lines running the length of the vehicle on the exterior fuselage. If the relative position of the propellant tanks is inverted, both the heavy structural separation member and the long LOX feed lines could be deleted. While the structures community at MSFC was elated with this finding, the LOX tank aft configuration gave the vehicle an aft center-of-gravity (cg) location which surfaced controllability concerns. In the conventional configuration the L/V is controlled in the ascent trajectory by the gimballing of its rocket engines. Studies have been conducted at MSFC which showed that the resulting aft cg configured L/V would not be adequately controllable with the engine gimballing alone.

Barret, Chris↗

A Theoretical Investigation of Longitudinal Stability of Airplanes with Free Controls Including Effect of Friction in Control System

The relation between the elevator hinge moment parameters and the control forces for changes in forward speed and in maneuvers is shown for several values of static stability and elevator mass balance. The stability of the short period oscillations is shown as a series of boundaries giving the limits of the stable regions in terms of the elevator hinge moment parameters. The effects of static stability, elevator moment of inertia, elevator mass unbalance, and airplane density are also considered. Dynamic instability is likely to occur if there is mass unbalance of the elevator control system combined with a small restoring tendency (high aerodynamic balance). This instability can be prevented by a rearrangement of the unbalancing weights which, however, involves an increase of the amount of weight necessary. It can also be prevented by the addition of viscous friction to the elevator control system provided the airplane center of gravity is not behind a certain critical position. For high values of the density parameter, which correspond to high altitudes of flight, the addition of moderate amounts of viscous friction may be destabilizing even when the airplane is statically stable. In this case, increasing the viscous friction makes the oscillation stable again. The condition in which viscous friction causes dynamic instability of a statically stable airplane is limited to a definite range of hinge moment parameters. It is shown that, when viscous friction causes increasing oscillations, solid friction will produce steady oscillations having an amplitude proportional to the amount of friction.

Greenberg, Harry↗

A Science Strategy for Space Physics

This report by the Committee on Solar and Space Physics and the Committee on Solar-Terrestrial Research recommends the major directions for scientific research in space physics for the coming decade. As a field of science, space physics has passed through the stage of simply looking to see what is out beyond Earth's atmosphere. It has become a 'hard' science, focusing on understanding the fundamental interactions between charged particles, electromagnetic fields, and gases in the natural laboratory consisting of the galaxy, the Sun, the heliosphere, and planetary magnetospheres, ionospheres, and upper atmospheres. The motivation for space physics research goes far beyond basic physics and intellectual curiosity, however, because long-term variations in the brightness of the Sun virtually affect the habitability of the Earth, while sudden rearrangements of magnetic fields above the solar surface can have profound effects on the delicate balance of the forces that shape our environment in space and on the human technology that is sensitive to that balance. The several subfields of space physics share the following objectives: to understand the fundamental laws or processes of nature as they apply to space plasmas and rarefied gases both on the microscale and in the larger complex systems that constitute the domain of space physics; to understand the links between changes in the Sun and the resulting effects at the Earth, with the eventual goal of predicting the significant effects on the terrestrial environment; and to continue the exploration and description of the plasmas and rarefied gases in the solar system.

Source record↗

The Melting of Aqueous Foams

Diffusing-wave spectroscopy measurements show that ordinarily solid aqueous foams flow by a series of stick-slip avalanche-like rearrangements of neighboring bubbles from one tight packing configuration to another. Contrary to a recent prediction, the distribution of avalanche sizes do not obey a power-law distribution characteristic of self-organized criticality. This can be understood from a simple model of foam mechanics based on bubble-bubble interactions.

Durian, Douglas J.↗

Hydrodynamics of Relativistic Fireballs

Many models of gamma-ray bursts involve a fireball, which is an optically thick concentration of radiation energy with a high ratio of energy density to rest mass. We examine analytically and numerically the evolution of a relativistic fireball. We show that, after an early rearrangement phase, most of the matter and energy in the fireball is concentrated within a narrow shell. The shell propagates at nearly the speed of light, with a frozen radial profile, and according to a simple set of scaling laws. The spectrum of the escaping radiation is harder at early times and softer later on. Depending on the initial energy-to-mass ratio, the final outcome of a fireball is either photons with roughly the initial temperature or ultrarelativistic baryons. In the latter case, the energy could be converted back to gamma-rays via interaction with surrounding material.

Piran, Tsvi↗

An Exact Separation of the Spin-Free and Spin-Dependent Terms of the Dirac-Coulomb-Breit Hamiltonian

The Dirac Hamiltonian is transformed by extracting the operator (sigma x p)/2mc from the small component of the wave function and applying it to the operators of the original Hamiltonian. The resultant operators contain products of Paull matrices that can be rearranged to give spin-free and spin-dependent operators. These operators are the ones encountered in the Breit-Pauli Hamiltonian, as well as some of higher order in alpha(sup 2). However, since the transformation of the original Dirac Hamiltonian is exact, the new Hamiltonian can be used in variational calculations, with or without the spin-dependent terms. The new small component functions have the same symmetry properties as the large component. Use of only the spin-free terms of the new Hamiltonian permits the same factorization over spin variables as in nonrelativistic theory, and therefore all the post-Self-Consistent Field (SCF) machinery of nonrelativistic calculations can be applied. However, the single-particle functions are two-component orbitals having a large and small component, and the SCF methods must be modified accordingly. Numerical examples are presented, and comparisons are made with the spin-free second-order Douglas-Kroll transformed Hamiltonian of Hess.

Dyall, Kenneth G.↗

Multiple Concurrent Visual-Motor Mappings: Implications for Models of Adaptation

Previous research on adaptation to visual-motor rearrangement suggests that the central nervous system represents accurately only 1 visual-motor mapping at a time. This idea was examined in 3 experiments where subjects tracked a moving target under repeated alternations between 2 initially interfering mappings (the 'normal' mapping characteristic of computer input devices and a 108' rotation of the normal mapping). Alternation between the 2 mappings led to significant reduction in error under the rotated mapping and significant reduction in the adaptation aftereffect ordinarily caused by switching between mappings. Color as a discriminative cue, interference versus decay in adaptation aftereffect, and intermanual transfer were also examined. The results reveal a capacity for multiple concurrent visual-motor mappings, possibly controlled by a parametric process near the motor output stage of processing.

Cunningham, H. A.↗

Southern Hemisphere In Situ Observations of OH, HO2, CIO and BrO from the ER-2 Aircraft for the 1994 ASHOE Mission

A summary of the first order scientific conclusions that emerged from the research done under this grant are as follows: (1) For the first time, the concentration of the key hydrogen and halogen radicals OH, H02, ClO and BrO were determined on a global scale extending from the arctic circle to the antarctic circle, over the altitude domain of the ER-2. That domain extends from 15-20 km altitude, covering a critical part of the lower stratosphere; (2) Simultaneous, in situ measurements of the concentrations of OH, H02, ClO, BrO, NO and NO2 demonstrate the predominance of odd-hydrogen and halogen free radical catalysis in determining the rate of removal of ozone in the lower stratosphere over the complete ASHOE mission. This extends to the global scale the "first look" data obtained during the NASA Stratospheric Photochemistry and Dynamics Experiment (SPADE), executed out of Ames Research Center in June 1993. This represents a major rearrangement of our understanding with respect to the hierarchy of dominant catalytic cycles controlling ozone loss in the lower stratosphere. For the past twenty years, it has been assumed that nitrogen radicals dominate the destruction rate of ozone in the lower stratosphere; (3) Throughout the altitude and latitude range covered by ASHOE, it was determined that a single catalytic cycle, HO2 + O3 yields OH + 2O2, accounted for one half of the total O3 removal in this region of the atmosphere. Halogen radical catalytic cycles were found to account for one third of the ozone loss, and nitrogen radicals were found to account for 20% of the loss; (4) Simultaneous observations of the full complement of radicals, tracers, ozone, and water vapor during ASHOE demonstrated quantitatively the coupling that exists between the rate limiting radicals and other reactive species in the photochemical reaction network. Specifically, the concentrations of ClO and HO2 are inversely correlated with the concentration of NOx. This carries the implication that the NOx effluent from the proposed High Speed Civil Transport may be less destructive to stratospheric ozone than had previously been thought. ASHOE brought this conclusion forward for the first time on a global basis; and (5) The density of BrO was measured on a global scale during ASHOE in the lower stratosphere. It was found that bromine is responsible for 55-65% of the local rate of catalytic destruction of ozone by reactions involving bromine and chlorine. Normalizing calculated loss rates to total available inorganic bromine and chlorine explicitly demonstrates that bromine is 60-80 times more efficient than chlorine in removing ozone in the lower stratosphere. An inferred value of total inorganic bromine is in excellent agreement with measurements of their source species, organic bromine compounds in the troposphere.

Anderson, James G.↗

Microgravity Foam Structure and Rheology

To exploit rheological and multiple-light scattering techniques, and ultimately microgravity conditions, in order to quantify and elucidate the unusual elastic character of foams in terms of their underlying microscopic structure and dynamics. Special interest is in determining how this elastic character vanishes, i.e. how the foam melts into a simple viscous liquid, as a function of both increasing liquid content and shear strain rate. The unusual elastic character of foams will be quantified macroscopically by measurement of the shear stress as a function of static shear strain, shear strain rate, and time following a step strain; such data will be analyzed in terms of a yield stress, a static shear modulus, and dynamical time scales. Microscopic information about bubble packing and rearrangement dynamics, from which these macroscopic non-Newtonian properties presumably arise, will be obtained non-invasively by novel multiple-light scattering diagnostics such as Diffusing-Wave Spectroscopy (DWS). Quantitative trends with materials parameters, such as average bubble size, and liquid content, will be sought in order to elucidate the fundamental connection between the microscopic structure and dynamics and the macroscopic rheology.

Durian, Douglas J.↗

Characterization of the Minimum Energy Path for the Reaction of Singlet Methylene with N2: The Role of Singlet Methylene in Prompt NO

We report calculations of the minimum energy pathways connecting CH2 + N2 to diazomethane and diazirine, for the rearrangement of diazirine to diazomethane, for the dissociation of diazirine to HCN2+H, and of diazomethane to CH2N+N. The calculations use Complete Active Space Self-Consistent Field (CASSCF) derivative methods to characterize the stationary points and Internally Contracted Configuration Interaction (ICCI) to determine the energetics. The calculations suggest a potential new source of prompt NO from the reaction CH2 with N2 to give diazirine, and subsequent reaction of diazirine with hydrogen abstracters to form doublet HCN2, which leads to HCN+N(S-4) on the previously studied CH+N2 surface. The calculations also predict accurate 0 K heats of formation of 77.7 kcal/mol and 68.0 kcal/mol for diazirine and diazomethane, respectively.

Walch, Stephen P.↗

Characterization of the Minimum Energy Path for the Reaction of Singlet Methylene with N2: The Role of Singlet Methylene in Prompt NO

We report calculations of the minimum energy pathways connecting (1)CH2+N2 to diazomethane and diazirine, for the rearrangement of diazirine to diazomethane, for the dissociation of diazirine to HCN2+H, and of diazomethane to CH2N+N. The calculations use complete active space self-consistent field (CASSCF) derivative methods to characterize the stationary points and internally contracted configuration interaction (ICCI) to determine the energetics. The calculations suggest a potential new source of prompt NO from the reaction of (1)CH2 with N2 to give diazirine, and subsequent reaction of diazirine with hydrogen abstracters to form doublet HCN2, which leads to HCN+N(S-4) on the previously studied CH+N2 Surface. The calculations also predict accurate 0 K heats of formation of 77.7 kcal/mol and 68.0 kcal/mol for diazirine and diazomethane, respectively.

Walch, Stephen P.↗

Fast Reconnection of Weak Magnetic Fields

Fast magnetic reconnection refers to annihilation or topological rearrangement of magnetic fields on a timescale that is independent (or nearly independent) of the plasma resistivity. The resistivity of astrophysical plasmas is so low that reconnection is of little practical interest unless it is fast. Yet, the theory of fast magnetic reconnection is on uncertain ground, as models must avoid the tendency of magnetic fields to pile up at the reconnection layer, slowing down the flow. In this paper it is shown that these problems can be avoided to some extent if the flow is three dimensional. On the other hand, it is shown that in the limited but important case of incompressible stagnation point flows, every flow will amplify most magnetic fields. Although examples of fast magnetic reconnection abound, a weak, disordered magnetic field embedded in stagnation point flow will in general be amplified, and should eventually modify the flow. These results support recent arguments against the operation of turbulent resistivity in highly conducting fluids.

Zweibel, Ellen G.↗