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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 811 records · Page 45

Rapid Electrochemical Diagnosis of Battery Health and Safety from Cells to Modules

Rapid electrochemical diagnosis of battery health and failure is critical for ensuring reliable battery performance and battery safety. Traditional battery health diagnostics such as capacity measurements and DC pulse tests are reliable and well-understood, however, these measurements of battery capacity and resistance do not capture all aspects of battery degradation. Other aspects of degradation, such as electrolyte decomposition, lithium-plating, and particle cracking are difficult to detect electrochemically but are crucial to measure to get a full picture of battery safety and flag out potential failures. In this work, lab- and field-aged commercial lithium-ion batteries and modules of various chemistries and formats are tested using a variety of traditional electrochemical characterization methods as well as using 2-minute pseudo-random DC pulse sequences at rest and during charge/discharge. The electrochemical measurements are compared to physical cell measurements, cell efficiency, drive cycle performance, physical and thermal heterogeneity, and qualitative safety metrics using statistical and machine-learning methods to discover if a comprehensive "battery health map" can be accurately identified using only rapid DC measurements.

ADVANCED PROPULSION SYSTEMS,ENERGY STORAGE↗

Statistical properties of the interplanetary microscale fluctuations

Results are reported for a statistical study of short-period fluctuations in the interplanetary plasma velocity and magnetic field. The data base used consists of measurements of the interplanetary plasma and magnetic field by Pioneer 6 with a time resolution of 72 sec and by Mariner 5 with a resolution of 5 min. The analysis is conducted to characterize the parent population from which all individual microscale events on these time scales are drawn. The microscale changes are grouped according to their energy densities relative to the energy density of the background magnetic field, and it is found that each grouping exhibits certain statistical properties within the limits of observational uncertainty. It is noted that these statistical properties are purely observational and independent of any physical model which may be used to interpret them. The results are discussed in the context of MHD discontinuity theory for a thermally anisotropic plasma.

Belcher, J. W.↗

Sound radiation from randomly vibrating beams of finite circular cross section

The radiation of sound from vibrating cylindrical beams is analyzed based on the frequency of the beam vibrations and the physical characteristics of the beam and its surroundings. A statistical analysis of random beam vibrations allows this result to be independent of the boundary conditions at the ends of the beam. The acoustic power radiated by the beam can be determined from a knowledge of the frequency band vibration data without a knowledge of the individual modal vibration amplitudes. A practical example of the usefulness of this technique is provided by the application of the theoretical calculations to the prediction of the octave band acoustic power output of the picking sticks of an automatic textile loom. Calculations are made of the expected octave band sound pressure levels based on measured acceleration data. These theoretical levels are subsequently compared with actual sound pressure level measurements of loom noise.

Sutterlin, M. W.↗

Unbiased estimation of oceanic mean rainfall from satellite borne radiometer measurements

The statistical properties of the radar derived rainfall obtained during the GARP Atlantic Tropical Experiment (GATE) are used to derive quantitative estimates of the spatial and temporal sampling errors associated with estimating rainfall from brightness temperature measurements such as would be obtained from a satelliteborne microwave radiometer employing a practical size antenna aperture. A basis for a method of correcting the so called beam filling problem, i.e., for the effect of nonuniformity of rainfall over the radiometer beamwidth is provided. The method presented employs the statistical properties of the observations themselves without need for physical assumptions beyond those associated with the radiative transfer model. The simulation results presented offer a validation of the estimated accuracy that can be achieved and the graphs included permit evaluation of the effect of the antenna resolution on both the temporal and spatial sampling errors.

Mittal, M. C.↗

Statistical dependency in visual scanning

A method to identify statistical dependencies in the positions of eye fixations is developed and applied to eye movement data from subjects who viewed dynamic displays of air traffic and judged future relative position of aircraft. Analysis of approximately 23,000 fixations on points of interest on the display identified statistical dependencies in scanning that were independent of the physical placement of the points of interest. Identification of these dependencies is inconsistent with random-sampling-based theories used to model visual search and information seeking.

Ellis, Stephen R.↗

Cyclotron resonant scattering in gamma-ray bursts - Further analysis of GB880205

We have extended our previous work by exploring several plane-parallel slab geometries to model the formation of cyclotron line features. We calculated the Compton temperature T(C) as a function of column density Ne for each of the new geometries. We then fit the resulting spectra to GB880205 exactly as described in Wang et al. (1989). The results show that the addition of column depth below the photon source plane leads to a modest improvement in chi-squared which, although not statistically significant, is pleasing because these geometries are more physically realistic.

Freeman, P. E.↗

A pseudo-sound constitutive relationship for the dilatational covariances in compressible turbulence: An analytical theory

The mathematical consequences of a few simple scaling assumptions about the effects of compressibility are explored using a simple singular perturbation idea and the methods of statistical fluid mechanics. Representations for the pressure-dilation and dilatational dissipation covariances appearing in single-point moment closures for compressible turbulence are obtained. While the results are expressed in the context of a second-order statistical closure they provide some interesting and very clear physical metaphors for the effects of compressibility that have not been seen using more traditional linear stability methods. In the limit of homogeneous turbulence with quasi-normal large-scales the expressions derived are - in the low turbulent Mach number limit - asymptotically exact. The expressions obtained are functions of the rate of change of the turbulence energy, its correlation length scale, and the relative time scale of the cascade rate. The expressions for the dilatational covariances contain constants which have a precise and definite physical significance; they are related to various integrals of the longitudinal velocity correlation. The pressure-dilation covariance is found to be a nonequilibrium phenomena related to the time rate of change of the internal energy and the kinetic energy of the turbulence. Also of interest is the fact that the representation for the dilatational dissipation in turbulence, with or without shear, features a dependence on the Reynolds number. This article is a documentation of an analytical investigation of the implications of a pseudo-sound theory for the effects of compressibility.

Ristorcelli, J. R.↗

Molecular abundances and low-mass star formation. 1: Si- and S-bearing species toward IRAS 16293-2422

Results from millimeter and submillimeter spectral line surveys of the protobinary source Infrared Astronomical Satellite (IRAS) 16293-2422 are presented. Here we outline the abundances of silicon- and sulfur-containing species. A combination of rotation diagram and full statistical equilibrium/radiative transfer calculations is used to constrain the physical conditions toward IRAS 16293 and to construct its beam-averaged chemical composition over a 10 to 20 sec (1600 to 3200 AU) scale. The chemical complexity as judged by species such as SiO, OCS, and H2S, is intermediate between that of dark molecular clouds such as L134N and hot molecular cloud cores such as Orion KL. From the richness of the spectra compared to other young stellar objects of similar luminosity, it is clear that molecular abundances do not scale simply with mass; rather, the chemistry is a strong function of evolutionary state, i.e., age.

Blake, Geoffrey A.↗

Improved accuracy of radar WPMM estimated rainfall upon application of objective classification criteria

Application of the window probability matching method to radar and rain gauge data that have been objectively classified into different rain types resulted in distinctly different Z(sub e)-R relationships for the various classifications. These classification parameters, in addition to the range from the radar, are (a) the horizontal radial reflectivity gradients (dB/km); (b) the cloud depth, as scaled by the effective efficiency; (c) the brightband fraction within the radar field window; and (d) the height of the freezing level. Combining physical parameters to identify the type of precipitation and statistical relations most appropriate to the precipitation types results in considerable improvement of both point and areal rainfall measurements. A limiting factor in the assessment of the improved accuracy is the inherent variance between the true rain intensity at the radar measured volume and the rain intensity at the mouth of the rain guage. Therefore, a very dense rain gauge network is required to validate most of the suggested realized improvement. A rather small sample size is required to achieve a stable Z(sub e)-R relationship (standard deviation of 15% of R for a given Z(sub e)) -- about 200 mm of rainfall accumulated in all guages combined for each classification.

Rosenfeld, Daniel↗

Recent Advances on INSAR Temporal Decorrelation: Theory and Observations Using UAVSAR

We review our recent advances in understanding the role of temporal decorrelation in SAR interferometry and polarimetric SAR interferometry. We developed a physical model of temporal decorrelation based on Gaussian-statistic motion that varies along the vertical direction in forest canopies. Temporal decorrelation depends on structural parameters such as forest height, is sensitive to polarization and affects coherence amplitude and phase. A model of temporal-volume decorrelation valid for arbitrary spatial baseline is discussed. We tested the inversion of this model to estimate forest height from model simulations supported by JPL/UAVSAR data and lidar LVIS data. We found a general good agreement between forest height estimated from radar data and forest height estimated from lidar data.

polarimetric SAR interferometry↗

A Roundtrip Journey off the Career Track: Having a Successful Career Despite Your Best Efforts

Although career tracks in science and engineering are often depicted as straight and smooth, many contain detours, side journeys and interruptions. In the end, these detours not only influence who we are, they can make us better scientists and engineers. In this presentation, Dr. Ladbury tells the tale of how his detours took him to far-flung locations from the Himalayan mountains to the African Savannah and eventually back to a rewarding career in radiation physics.

Space Radiation↗

Colloids in Microgravity

Colloidal particles are important in a broad range of applications in technology and materials processing. Due to high sensitivity to thermal fluctuations, a suspension of colloidal particles is considered as an assembly of super-atoms in condensed matter physics. This feature provides an excellent experimental model in statistical mechanics for fundamental studies of microstructural evolution and phase transformation at the individual particle level. However, using colloids to probe three-dimensional phase transitions on Earth remains a challenge as they can be influenced by the gravity force causing the particles to sediment and the solvent to flow. To suppress the undesirable gravity effects, experiments on concentrated colloids were carried out in the International Space Station (ISS) Light Microscopy Module. We will present results of these experiments.

Colloids↗

Using statistical modeling to predict and understand fusion experiments

Over 300 cryogenic layered direct-drive inertial confinement fusion implosions have been successfully executed on the OMEGA Laser System in the last decade. However, extracting sufficient understanding from these experiments to develop new designs or to identify or mitigate degradation sources remains challenging. Recently, a statistical modeling approach was developed to successfully design and predict improved implosion experiments on OMEGA. Here, we show that one-dimensional simulations can be used to predict the outcomes of systematically perturbed three-dimensional simulations and that this statistical modeling approach can be used to identify or rule out physical mechanisms for some of the degradation sources observed on the OMEGA Laser System for direct-drive cryogenic inertial confinement fusion. In this instance, we investigate the fusion yield dependencies on the ion temperature asymmetries and laser beam size observed in experiments by comparing with trends in three-dimensional synthetic simulation databases. Using the statistical model on these systematically perturbed simulations, we find that the statistically inferred dependency on the measured ion temperature asymmetries is well explained by imposed ℓ =1 modes. However, we find that the dependency on the laser beam size is only dominated by the illumination non-uniformity for some extreme cases.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Process-Structure-Property Modeling for Severe Plastic Deformation Processes Using Orientation Imaging Microscopy and Data-Driven Techniques

Machining is a severe plastic deformation process, wherein the workpiece material is subjected to high deformation rates and temperatures. During metal machining, the dynamic recrystallization mechanism causes grain refinement into the sub-micron range. In this study, we investigate the microstructure evolution of oxygen-free high conductivity copper (OFHC Cu) subject to a machining process where the cutting speed and rake angle are controlled to manipulate the process strain, strain rate, and temperatures. Microstructures of the deformed chips are quantified using orientation imaging microscopy and novel statistical descriptors that capture the morphology and local lattice misorientations generated during the several mechanistic stages of the dynamic recrystallization process. Mechanical properties of the resulting chips are quantified using spherical nanoindentation protocols. A multiple output Gaussian process regression model is used to simultaneously model the structure-property evolution, which differs from more common approaches that establish such relationships sequentially. This modeling strategy is particularly attractive since it can flexibly provide both structure and property uncertainty estimates. In addition, the statistical modeling framework allows for the inclusion of multi-fidelity data. The statistical metrics utilized serve as efficient microstructure descriptors, which retain the physics of the observed structures without having to introduce ad hoc microstructure feature definitions.

36 MATERIALS SCIENCE↗

Machine Learning Reveals the State of Intermittent Frictional Dynamics in a Sheared Granular Fault

Seismogenic plate boundaries are posited to behave in a similar manner to a densely packed granular medium, where fault and block systems rapidly rearrange the distribution of forces within themselves, as particles do in slowly sheared granular systems. Machine learning is used to show that statistical features of velocity signals from individual particles in a simulated sheared granular fault contain information regarding the instantaneous global state of intermittent frictional stick-slip dynamics. We demonstrate that combining features built from the signals of more particles can improve the accuracy of the global model and discuss the physical basis behind the decrease in error. We show that the statistical features such as median and higher moments of the signals that represent the particle displacement in the direction of shearing are among the best predictive features. We demonstrate here novel insights into the applications of machine learning in studying frictional processes occurring in geophysical systems.

58 GEOSCIENCES↗

Sulphur variations in annually layered stalagmites using benchtop micro-XRF

Variation of sulphur in annually laminated stalagmites can be used to infer the impact of past volcanic activities, anthropogenic pollution, and climate change due to increased bushfire activity. The synchrotron radiation micro-X-Ray fluorescence (SR-XRF) microprobe is a powerful tool to analyse and image sulphur recorded in stalagmites with micrometre resolution. However, access to SR-XRF beamlines can be limited, so researchers must select the most promising stalagmites for imaging. Benchtop micro-XRF is an effective tool for trace elemental analysis of speleothem samples and is a candidate for routine laboratory measurement of sulphur along stalagmite laminae and screening for SR-XRF. Here, this study describes a protocol using matrix-matched standards to measure annual variations of sulphur at trace to percent level along the laminae of two Western Australian stalagmites, one of which already having been analysed using SR-XRF. Parameters that affected quantitation include X-ray tube voltage and current, spot size of the X-ray beam and stalagmite surface roughness and porosity. The use of a 20 μm X-ray spot size provides sub-annual spatial resolution that can be completed in an overnight scan. The features in a 1000 point micro-XRF analysis of sulphur along a 20 mm transect show good consistency with SR-XRF microprobe data. Micro-XRF mapping was also performed to produce chemical images on the stalagmite and compared with Raman and X-ray diffraction (XRD) to confirm that the stalagmite is exclusively calcite, with no aragonite, and that the source of sulphur in the samples was gypsum and anhydrite. Regions of very high sulphur in the micro-XRF maps were found to be artefacts due to diffraction of the incident beam but these could be efficiently removed by using a multiple point statistics approach to produce a clean image suitable for analysis of the laminae. This work shows the potential of micro-XRF for routine analysis of sulphur in stalagmites, and to streamline sample characterisation before SR-XRF imaging.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Monitoring and prediction of porosity in laser powder bed fusion using physics-informed meltpool signatures and machine learning

In this work we accomplished the monitoring and prediction of porosity in laser powder bed fusion (LPBF) additive manufacturing process. This objective was realized by extracting physics-informed meltpool signatures from an in-situ dual-wavelength imaging pyrometer, and subsequently, analyzing these signatures via computationally tractable machine learning approaches. Porosity in LPBF occurs despite extensive optimization of processing conditions due to stochastic causes. Hence, it is essential to continually monitor the process with in-situ sensors for detecting and mitigating incipient pore formation. In this work a tall cuboid-shaped part (10 mm × 10 mm × 137 mm, material ATI 718Plus) was built with controlled porosity by varying laser power and scanning speed. This test caused various types of porosity, such as lack-of-fusion and keyhole formation, with varying degrees of severity in the part. The meltpool was continuously monitored using a dual-wavelength imaging pyrometer installed in the machine. Physically intuitive process signatures, such as meltpool length, temperature distribution, and ejecta (spatter) characteristics, were extracted from the meltpool images. Subsequently, relatively simple machine learning models, e.g., K-Nearest Neighbors, were trained to predict both the severity and type of porosity as a function of these physics-informed meltpool signatures. These models resulted in a prediction accuracy exceeding 95% (statistical F1-score). The same analysis was carried out with a complex, black-box deep learning convolutional neural network which directly used the meltpool images instead of physics-informed features. The convolutional neural network produced a comparable F1-score in the range of 89–97%. Finally, these results demonstrate that using pragmatic, physics-informed meltpool signatures within a simple machine learning model is as effective for flaw prediction in LPBF as using a complex and computationally demanding black-box deep learning model.

36 MATERIALS SCIENCE↗

On the occurrence of sympathetic flares

Random-coincidence formulas are applied to the data used in previous studies of alleged sympathetic flares to determine whether statistical evidence on the occurrence of such flares can be found for specific physically connected pairs of active regions. Only those active regions that are interconnected by magnetic loops in soft X-rays on Skylab photographs are considered to be physically connected. All pairs of flaring active regions (both interconnected and otherwise) observed on the sun during the Skylab flight are also evaluated. The only positive result is obtained with statistical confidence of 3.4 sigmas for pairs of active regions separated by no more than 30 deg. The occurrence of short time intervals between flares is shown to be increased for such active-region pairs, but the pattern of time intervals is found not to correspond with any propagation mode of a triggering agent in the solar atmosphere. It is suggested that some subphotospheric synchronization of activity in nearby plages and sunspot groups could increase the number of short time intervals between flares at different locations without any actual influence of one 'sympathetic' flare upon another, leading to the concept of 'sympathetic active regions' instead of 'sympathetic flares'.

Fritzova-Svestkova, L.↗