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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 811 records · Page 45
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Life cycle assessment of co-firing biomass at coal-fired power plants with carbon capture and storage toward net-zero emissions

Co-firing biomass with carbon capture and storage (BECCS) offers a technological option to decarbonize coal-fired power plants toward net-zero emissions. This study estimates the life cycle emissions of co-firing biomass at coal-fired power plants with CCS and quantifies its variability and uncertainty. Deployment of co-firing BECCS at coal-fired power plants can significantly reduce the life cycle emissions toward the net-zero target but lower the power plant performance, which vary with numerous factors, including coal type, biomass type, co-firing level, and CO 2 capture rate. The breakeven co-firing levels required for biomass at coal-fired power plants with 90 % CO 2 capture to reach net-zero emissions fall with a range roughly from 15 % to 25 % on an energy basis, depending on coal and biomass types. Increasing the CO 2 capture rate from 90 % to 95 % can lower the breakeven co-firing levels by about 5 to 8 percentage points for the biomass resources of interest, which can lower reliance on biomass resources and facilitate large-scale deployment of co-firing BECCS in fossil-rich regions but with limited biomass resources. Furthermore, findings improve the understanding of the techno-environmental performance of co-firing BECCS and inform strategic planning decisions on net-zero emissions in the coal-fired power sector.

Breakeven co-firing level↗
DOE OSTI2021

Water heating energy use reductions from EPA WaterSense lavatory plumbing fittings

Hot water savings from water-efficient lavatory fittings lead to reductions in water heating energy consumption, and ultimately to decreases in carbon emissions. This paper characterizes existing and proposed approaches used to estimate hot water savings and carbon emissions reductions stemming from the U.S. Environmental Protection Agency's WaterSense program. Also described are refinements that improve the accuracy of residential hot water use percentage estimates of lavatory fittings. The authors conclude that (1) hot water percentages for showers and faucets calculated using up-to-date, publicly available national data are consistent with those found by regional studies and household-level models of water use; (2) the accuracy of heating energy savings estimates attributable to WaterSense-labeled lavatory products, as well as associated emissions reductions, can be refined by modifying the existing energy factor/uniform energy factor (EF/UEF)-based estimation approach with available data. The refined approach accounts for more nuanced conditions than the EF/UED-based approach but depends on data not always available; and (3) the approaches described and intermediate outputs can be generalized for other water conservation programs or estimating purposes.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2025

Glacial‐Interglacial and Millennial‐Scale Changes in Nitrous Oxide Emissions Pathways and Source Regions

During the transition from the Last Glacial Maximum (LGM) to the Holocene, the atmospheric N 2 O mole fraction increased by 80 nmol mol −1 . Using ice core measurements of N 2 O isotopomer ratios, we show that this increase was driven by increases in both nitrification and denitrification, with the relative partitioning between both production pathways depending on the assumed isotopic end-member source signatures. Similarly, we also attribute a 35 nmol mol −1 N 2 O mole fraction increase during the Heinrich Stadial 4/Dansgaard Oeschger 8 (HS4/DO8) millennial-scale event to increases in both N 2 O production pathways. In contrast, the 25 nmol mol −1 N 2 O mole fraction decrease during the Younger Dryas was driven almost exclusively by a decrease in nitrification. The deglacial and HS4/DO8 increases in N 2 O production occurred in both marine and terrestrial environments, with the terrestrial source responding faster to warming by about two centuries. Constraints on changes in nitrification and denitrification emissions are robust and consistent with previous studies showing the sensitivity of N 2 O emissions to abrupt Northern Hemisphere warming. This study demonstrates for the first time the importance of both denitrification and nitrification pathways in driving source changes. Absolute emissions are more uncertain due to uncertainty about source isotopomer signatures. For instance, the contribution of denitrification to emissions at the LGM shifts from (65 ± 10) % to (91 ± 6) % when factoring in isotope enrichment due to partial reduction of N 2 O to N 2 during denitrification. Reducing uncertainty in source signatures will increase the power of ice core N 2 O isotope records in deducing environmental change.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Steric effects in light-induced solvent proton abstraction

The significance of solvent structural factors in the excited-state proton transfer (ESPT) reactions of Schiff bases with alcohols is reported here. In this work, we use the super photobase FR0-SB and a series of primary, secondary, and tertiary alcohol solvents to illustrate the steric issues associated with solvent to photobase proton transfer. Steady-state and time-resolved fluorescence data show that ESPT occurs readily for primary alcohols, with a probability proportional to the relative –OH concentration. For secondary alcohols, ESPT is greatly diminished, consistent with the barrier heights obtained using quantum chemistry calculations. ESPT is not observed in the tertiary alcohol. We explain ESPT using a model involving an intermediate hydrogen-bonded complex where the proton is “shared” by the Schiff base and the alcohol. The formation of this complex depends on the ability of the alcohol solvent to achieve spatial proximity to and alignment with the FR0-SB* imine lone pair stabilized by the solvent environment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Anaerobic respiration pathways and response to increased substrate availability of Arctic wetland soils

The availability of labile carbon (C) compounds in Arctic wetland soils is expected to increase due to thawing permafrost and increased fermentation as a result of decomposition of organic matter with warming. How microbial communities respond to this change will affect the balance of CO 2 and CH 4 emitted during anaerobic organic matter decomposition, and ultimately the net radiative forcing of greenhouse gas emissions from these soils. While soil water content limits aerobic respiration, the factors controlling methanogenesis and anaerobic respiration are poorly defined in suboxic Arctic soils. In this study, we conducted incubation experiments on two tundra soils from field sites on the Seward Peninsula, Alaska, with contrasting pH and geochemistry to determine the pathways of anaerobic microbial respiration and changes with increasing substrate availability upon warming. In incubation of soils from the circumneutral Teller site, the ratio of CO 2 to CH 4 dropped from 10 to <2 after 60 days, indicating rapid depletion of alternative terminal electron acceptors (TEAs). Addition of acetate stimulated production of CO 2 and CH 4 in a nearly 1:1 ratio, consistent with methanogenesis, and the composition of the microbial community shifted to favor clades capable of utilizing the added acetate such as the Fe(III)-reducing Geobacter and the methanogenic archaea Methanosarcina. In contrast, both CO 2 and CH 4 production declined with acetate addition during incubation of soils from the more acidic Council site, and fermentative microorganisms increased in abundance despite the high availability of fermentation products. These results demonstrate that the degree to which increasing substrate availability stimulates greenhouse gas production in tundra wetlands will vary widely depending on soil pH and geochemistry.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

MUSEQuBES: calibrating the redshifts of Ly α emitters using stacked circumgalactic medium absorption profiles

ABSTRACT Ly α emission lines are typically found to be redshifted with respect to the systemic redshifts of galaxies, likely due to resonant scattering of Ly α photons. Here, we measure the average velocity offset for a sample of 96 z ≈ 3.3 Ly α emitters (LAEs) with a median Ly α flux (luminosity) of ${\approx}10^{-17}~\rm erg~cm^{-2}~s^{-1}$ (${\approx}10^{42}~\rm erg~s^{-1}$) and a median star formation rate (SFR) of ≈1.3 $\rm M_{\odot }~yr^{-1}$ (not corrected for possible dust extinction), detected by the Multi-Unit Spectroscopic Explorer as part of our MUSEQuBES circumgalactic medium (CGM) survey. By postulating that the stacked CGM absorption profiles of these LAEs, probed by eight background quasars, must be centred on the systemic redshift, we measure an average velocity offset, Voffset = 171\pm 8 km s−1, between the Ly α emission peak and the systemic redshift. The observed Voffset is lower by factors of ≈1.4 and ≈2.6 compared to the velocity offsets measured for narrow-band-selected LAEs and Lyman break galaxies, respectively, which probe galaxies with higher masses and SFRs. Consistent with earlier studies based on direct measurements for individual objects, we find that the Voffset is correlated with the full width at half-maximum of the red peak of the Ly α line, and anticorrelated with the rest-frame equivalent width. Moreover, we find that Voffset is correlated with SFR with a sub-linear scaling relation, $V_{\rm offset}\propto \rm SFR^{0.16\pm 0.03}$. Adopting the mass scaling for main-sequence galaxies, such a relation suggests that Voffset scales with the circular velocity of the dark matter haloes hosting the LAEs.

Muzahid, Sowgat↗
DOE OSTI2021

Retaining Geochemical Signatures during Aragonite-Calcite Transformation at Hydrothermal Conditions

Transformation of aragonite, a mineral phase metastable at Earth’s surface, to calcite widely occurs in both sedimentary and metamorphic systems with the presence of an aqueous phase. The transformation process can affect geochemical signatures of aragonite (a protolith). This study focused on quantification of the retention of Mg/Ca and Sr/Ca ratios, and δ18O during the transformation process as well as evaluation of the transformation rate. To investigate the effect of transformation from aragonite to calcite on elemental and stable isotope ratios, we conducted a series of experiments in NaCl solutions at temperatures between 120 and 184 °C. Two additional experiments at 250 °C were conducted to estimate the transformation rate of aragonite to calcite. Protolith materials consist of (1) synthetic (Mg; Sr-bearing or non-Mg; Sr bearing) needle-shaped microcrystals of aragonite (<5 µm in size) and (2) larger chips (>100 µm in size) of natural aragonite. X-ray diffraction (XRD) showed that microcrystals successfully transformed to calcite within 30 h and scanning electron microscopy (SEM) yielded a change in the crystal size to >10 µm in rhombohedral shape. Electron backscatter diffraction (EBSD) of the larger aragonite chips showed that transformation to randomly oriented calcite occurred at the rims and along the cracks while the core retained an aragonite crystal structure. Isotope-ratio mass spectrometry (IRMS) analyses showed that calcite δ18O was controlled by temperature and δ18O of the solution. The obtained calibration curve of isotope fractionation factor versus temperature is consistent with other studies. Inductively coupled plasma optical emission spectroscopy (ICP-OES) analyses showed that calcite partially or completely retained Mg/Ca and Sr/Ca ratios through the transformation.

58 GEOSCIENCES↗
NASA NTRS1978

HEAO-1 observations of Her X-1 at energies above 13 keV

Results from preliminary analysis of HEAO-1 pointing observations of Her X-1 on three days in February 1978 are presented. Pulsed flux is detected up to approximately 70 keV with a clear indication of emission at approximately 60 deV which is above the continuum spectrum extrapolated from lower energies. If this excess emission is interpreted as a spectral line, its intensity varies from (1.2 plus or minus 0.2) x (10 to the minus 3 power) to (0.2 plus or minus 0.2) x (10 to the minus 3 power) ph/sq cm-sec with a time scale of one day. A factor 2 decrease in the low energy continuum is associated with the decrease in the excess emission.

Matteson, J. L.↗
NASA NTRS1979

A small helium-cooled infrared telescope for Spacelab 2

A helium cooled telescope of 15 cm aperture is being designed and constructed jointly by the University of Arizona, the Smithsonian Astrophysical Observatory and the Marshall Space Flight Center for high sensitivity infrared astronomical observations from Spacelab 2. A focal plane array of ten detectors provide a total field of view of 3 deg and cover the wavelength regions 4.5-8.5, 6-7, 9-16, 18-30 and 80-120 microns. A highly redundant all sky survey will be conducted by repeated scanning of the sky during many orbits of the spacecraft. High redundancy will allow discrimination among variable and constant celestial sources and several types of variable nearby sources. The principal astronomical result of the survey will be the absolute flux measurement of low surface brightness, large scale celestial infrared emissions but it will also extend existing IR sky surveys by a factor of 10 in point source sensitivity. The experiment will also make significant engineering measurements of contaminants in the Shuttle environment, test the technology of storage and utilization of large quantities of superfluid helium in space and test mechanical designs for future infrared telescopes for the Space Shuttle.

Gautier, T. N., III↗
NASA NTRS1981

The Mg 2 h and k lines in a sample of dMe and dM stars

Both Mg II h and k line fluxes are presented for a sample of 4 dMe and 3 dM stars obtained with the IUE satellite in the long wavelength, low dispersion mode. The observed fluxes are converted to stellar surface flux units and the importance of chromospheric non radiative heating in this sample of M dwarf stars is intercompared. In addition, the net chromospheric radiative losses due to the Ca II H and K lines in those stars in the sample for which calibrated Ca II H and K line data exist are compared. Active region filling factors which likely give rise to the observed optical and ultraviolet chromospheric emission are estimated. The implications of the results for homogeneous, single component stellar model chromospheres analyses are discussed.

Giampapa, M. S.↗
NASA NTRS1981

The variability of the sun's ultraviolet radiation

Solar UV intensity variations determined by direct irradiance measurements and by measurements of the plage/quiet sun contrast are reviewed. Typical values for the solar UV variability over a solar cycle are: less than 1% at wavelengths longer than 2100 A, 8% at 2080 A (continuum), 20% at 1900 A (continuum), 70% at H Ly alpha, 200% in certain emission lines in the 1200-1800 A range, and more than a factor of 4 in coronal lines at less than 1000 A.

Brueckner, G. E.↗
NASA NTRS1981

Magnetic fields on the Sun

Synoptic observations of solar magnetic fields are discussed. Seen in long-term averages, the magnetic fields of the Sun show distinctive behavior. The active-region latitudes are characterized by magnetic fields of preceding polarity. The flow of following polarity fields to make up the polar fields is episodic, not continuous. This field motion is a directed poleward flow and is not due to diffusion. The total magnetic flux on the solar surface, which is related linearly to the calcium emission in integrated sunlight, varies from activity minimum to maximum by a factor of 2 or 3. Nearly all this flux is seen at active-region latitudes-only about 1% is at the poles. The total flux of the Sun disappears from the surface at a very rapid rate and is replaced by new flux. All the field and flux patterns that we see originate in active-region latitudes. The polar magnetic fields of the Sun were observed to change polarity recently. The variations of the full-disk solar flux are shown to lead to the proper rotation rate of the Sun, but the phase of the variations is constant for only a year or two at most.

Howard, R.↗
NASA NTRS1984

Radio emission from the outer parts of stellar atmospheres (mantles) at centimeter wavelengths and the winds of early-type stars

It is noted that when magnetic lines of force are present in the mantle of an early-type star, gyroresonance radiation at radio wavelengths may occur at detectable levels in addition to bremsstrahlung. An expression is derived for the effective value of the ratio of the emissivity in gyroresonance radiation to that in bremsstrahlung, and some numerical values are estimated using values of the parameters which may be typical for conditions in the mantles of early-type stars. The volume emissivity in gyroresonance radiation may exceed that for bremsstrahlung by a large factor. The implications of this result for the interpretation of the radio fluxes from early-type stars are discussed. It is shown that the radio-frequency radiation emerging from a hot star probably consists of gyroresonance radiation from an array of magnetic loops as well as bremsstrahlung from a low-density wind. It is argued that it is probable that the estimates of rate of mass loss made ignoring the possibility of gyroresonance radiation may be too large by a factor of at least 10.

Underhill, A. B.↗
NASA NTRS1984

Sensitivity of thermal inertia calculations to variations in environmental factors

The sensitivity of thermal inertia (TI) calculations to errors in the measurement or parameterization of a number of environmental factors is considered here. The factors include effects of radiative transfer in the atmosphere, surface albedo and emissivity, variations in surface turbulent heat flux density, cloud cover, vegetative cover, and topography. The error analysis is based upon data from the Heat Capacity Mapping Mission (HCMM) satellite for July 1978 at three separate test sites in the deserts of the western United States. Results show that typical errors in atmospheric radiative transfer, cloud cover, and vegetative cover can individually cause root-mean-square (RMS) errors of about 10 percent (with atmospheric effects sometimes as large as 30-40 percent) in HCMM-derived thermal inertia images of 20,000-200,000 pixels.

Kahle, A. B.↗
NASA NTRS1985

The unexpected ultraviolet variability of Herbig-Haro object 1

The line fluxes of the C IV 1550 A and semiforbidden C III 1909 A emission lines in HH 1 are noted to have monotonically decreased by factors of 4-6 between 1979 and 1983, despite a lack of indications of optical range changes. The thickness of the shocked layers and preshock density can be estimated on the basis of these rapid changes, with results suggesting a clumpy medium that leads to truncated shock waves with column densities insufficient for the development of complete recombination zones.

Brugel, E. W.↗
NASA NTRS1986

Passive microwave soil moisture research

During the four years of the AgRISTARS Program, significant progress was made in quantifying the capabilities of microwave sensors for the remote sensing of soil moisture. In this paper, a discussion is provided of the results of numerous field and aircraft experiments, analysis of spacecraft data, and modeling activities which examined the various noise factors such as roughness and vegetation that affect the interpretability of microwave emission measurements. While determining that a 21-cm wavelength radiometer was the best single sensor for soil moisture research, these studies demonstrated that a multisensor approach will provide more accurate soil moisture information for a wider range of naturally occurring conditions.

Schmugge, T.↗
NASA NTRS1986

Radio observations of galactic bulge and globular cluster X-ray sources

A program of VLA observations of luminous X-ray sources in the Galactic bulge and globular clusters has been undertaken. Faint radio sources have been found as the counterparts of several Galactic bulge X-ray sources. Discovery of a relatively bright radio counterpart for GX 13 + 1 has allowed a much more precise source position to be obtianed and a likely IR identification to be made. The results suggest that the radio emission may be nonthermal. Comparison of the results with those of Geldzahler (1983) shows that the radio emission from Galactic bulge X-ray sources is highly variable by factors of at least three. Extended ratio monitoring could yield the long-sought binary periods for these objects.

Grindlay, Jonathan E.↗