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At least 811 records · Page 45

Forecasting Coronal Mass Ejections from Vector Magnetograms

Identification of active regions from which Earthward halo Coronal Mass Ejections (CMEs) are likely to originate is important both for understanding how CMEs are produced and for prediction of hazardous space weather. In previous work, from a set of 17 MSFC (Marshall Space Flight Center) vector magnetograms of 12 bipolar active regions situated within +/- 2 days of rotation from central meridian, we have evaluated four different measures of the global nonpotentiality of the magnetic field of each active region, and have found that the nonpotentiality of these active regions is strongly correlated with their CME productivity during the time interval of +/- 2 days centered on the day of the magnetogram: strongly nonpotential bipolar active regions are much more likely to produce a CME during this interval that are weakly nonpotential bipolar active regions. To further establish the use of active-region nonpotentiality for forecasting CMEs, we have expanded the sample to 19 additional bipolar active regions, with vector magnetograms taken with the upgraded MSFC vector magnetograph from September 2000 through June 2001 with support from our LWS grant (M. J. Hagyard, PI). The four global measures of nonpotentiality are the length of strong-shear, strong-field main neutral line, the net current, and two other measures of the overall twist in the magnetic field of the active-region bipole. We find: 1) The statistical significance of the correlation of the nonpotentiality of active regions with their CME productivity within +/- 2 days of the day of the magnetogram is greater than 99%. 2) 67% of the strongly nonpotential active regions produced CMEs within the +/- 2 day window, while only 17% of the weakly nonpotential ones did. 3) The statistical significance of the correlation of the nonpotentiality of active regions with their CME productivity during 0-2 days after the day of the magnetogram is about 97%. 4) 42% of the strongly nonpotential active regions produced CMEs within the 0-2 day window, while only 10% of the weakly nonpotential ones did. 5) The four different measures of an active region's nonpotentiality agree most of the time in their classification of the nonpotentiality as strong or weak (75%-90% depending on the pair of measurements). Additional information is included in the original extended abstract.

Moore, R. L.↗

Properties of Subsurface Soil Cores from Four Geologic Provinces Surrounding Mars Desert Research Station, Utah: Characterizing Analog Martian Soil in a Human Exploration Scenario

The DOMEX program is a NASA-MMAMA funded project featuring simulations of human crews on Mars focused on science activities that involve collecting samples from the subsurface using both manual and robotic equipment methods and analyzing them in the field and post mission. A crew simulating a human mission to Mars performed activities focused on subsurface science for 2 weeks in November 2009 at Mars Desert Research Station near Hanksville, Utah --an important chemical and morphological Mars analog site. Activities performed included 1) survey of the area to identify geologic provinces, 2) obtaining soil and rock samples from each province and characterizing their mineralogy, chemistry, and biology; 3) site selection and reconnaissance for a future drilling mission; 4) deployment and testing of Mars Underground Mole, a percussive robotic soil sampling device; and 5) recording and analyzing how crew time was used to accomplish these tasks. This paper summarizes results from analysis of soil cores

Stoker, C. R.↗

Neutron activation analysis of stoney spherules from a marine sediment sample

The identification of extraterrestrial material in samples collected at the surface of the Earth is discussed. Criteria were established for black magnetic spherules which involve the presence of: Fe, Ni, and Co in iron meteoritic ratios, wustite, and Fe-Ni metal while reliable criteria for stoney spherules are not well established. Neutron activation analysis was performed on eight stony spherules separated from the same marine sediment used by Millard and Finkelman. The 22 elements were determined by Compton suppression and triple coincidence gamma counting. It is found that Fe, Mg, Al, Ni, Cr, Co, Ir, and Sc are the best discriminators between chondritic and terrestrial compositions. Three of the spherules have compositions very close to chondrites and of these, two contain 0.5 and 0.25 ppm Ir. The other five spherules contain much less than chondritic concentrations of Ni but this element may be segregated and lost during ablation of the parent meteorite. One of these five low Ni spherules contains 2.9 ppm Ir while the other four contain less than 0.05 ppm Ir.

Millar, H. T., Jr.↗

Pathways towards Valid Data: Assessment of Optimized Packaging Strategies for Core Components - 18158

Every company that runs nuclear power plants needs a strategy for disposal of the radioactive waste and for decommissioning and dismantling of its nuclear reactors. The dismantling progress of several German NPPs is already in an advanced stage. Hence, particularly highly activated core components have to be disposed of as radioactive waste. Nevertheless, this is also an issue during the operating phase due to necessary replacements of highly activated core components such as PWR control elements or RPV heads. The conditioning of waste packages for final disposal in the German repository Konrad requires the core components to be dismantled, packaged and dried. Therefore, a qualified packaging strategy is needed to ensure a reliable compliance with the protection objectives of the repository and an optimized utilization of prescribed contingents. Exemplified by PWR control elements a pathway is drawn how to perform an optimized packaging strategy in compliance with the protection objectives of the repository based on only few relevant radionuclides derived from activation calculations. For these calculations, particularly the influence of trace impurities in the materials has to be considered and their amounts have to be verified or analyzed by sampling. Furthermore, low nuclide activities from contamination cannot simply be neglected because some of them are obliged to be declared or their radiological relevance has not been sufficiently determined. Due to various influence factors, qualified sampling strategies need carefully considered concepts. Therefore, detailed planning facilitates the qualification and approval process and reduces the costs for analyses and the number of containers. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

NOvA Dual-Baseline Search for Active-to-Sterile Neutrino Oscillations using Neutrino- and Antineutrino-Enriched Samples

We report a search for neutrino oscillations to sterile neutrinos in the NOvA detectors under a model with three active and one sterile neutrinos. This search simultaneously fits data in the two NOvA detectors and is the first from NOvA to use both neutrino- and antineutrino-mode beams, with exposures of $26.61\times10^{20}$ and $12.50\times10^{20}$ protons on target, respectively. There is no evidence for sterile neutrinos in the data and we are able to exclude regions of parameter space that were allowed by previous experiments, including most of the allowed region reported by IceCube.

Abubakar, S. [Erciyes U.]↗

DISSECTING PHOTOMETRIC REDSHIFT FOR ACTIVE GALACTIC NUCLEUS USING XMM- AND CHANDRA-COSMOS SAMPLES

In this paper, we release accurate photometric redshifts for 1692 counterparts to Chandra sources in the central square degree of the Cosmic Evolution Survey (COSMOS) field. The availability of a large training set of spectroscopic redshifts that extends to faint magnitudes enabled photometric redshifts comparable to the highest quality results presently available for normal galaxies. We demonstrate that morphologically extended, faint X-ray sources without optical variability are more accurately described by a library of normal galaxies (corrected for emission lines) than by active galactic nucleus (AGN) dominated templates, even if these sources have AGN-like X-ray luminosities. Preselecting the library on the bases of the source properties allowed us to reach an accuracy {sigma}{sub {Delta}z/(1+z{sub s{sub p{sub e{sub c)}}}}}{approx}0.015 with a fraction of outliers of 5.8% for the entire Chandra-COSMOS sample. In addition, we release revised photometric redshifts for the 1735 optical counterparts of the XMM-detected sources over the entire 2 deg{sup 2} of COSMOS. For 248 sources, our updated photometric redshift differs from the previous release by {Delta}z > 0.2. These changes are predominantly due to the inclusion of newly available deep H-band photometry (H{sub AB} = 24 mag). We illustrate once again the importance of a spectroscopic training sample and how an assumption about the nature of a source together, with the number and the depth of the available bands, influences the accuracy of the photometric redshifts determined for AGN. These considerations should be kept in mind when defining the observational strategies of upcoming large surveys targeting AGNs, such as eROSITA at X-ray energies and the Australian Square Kilometre Array Pathfinder Evolutionary Map of the Universe in the radio band.

79 ASTRONOMY AND ASTROPHYSICS↗

Eco-friendly and effective strategy to synthesize ZnO/Ag{sub 2}O heterostructures and its excellent photocatalytic property under visible light

Highlights: • ZnO/Ag{sub 2}O photocatalysts with heterostructures were synthesized via a facile mechanochemical method. • The synthetic process does not involve any organic solvents and the reaction matrix can be recycled easily. • The synthetic method is gram-scale, and we can easily and routinely scale up this process to produce grams of the heterostructure nanomaterials. • The as-prepared samples without post-calcination show a high degree of crystallinity. - Abstract: ZnO/Ag{sub 2}O photocatalysts with heterostructure were synthesized by a green and effective mechanochemical method. The preparation process was taken in solid state at room temperature with a short grinding time. The as-made products showed a high degree of crystallinity without post-calcination treatment. Such synthetic method does not involve any organic solvents and the reaction matrix can be recycled. The as-prepared ZnO/Ag{sub 2}O samples show excellent photocatalytic activity and photostability for degradation of different organic dyes under visible light. The content of Ag{sub 2}O plays an important role in the photocatalytic activity, which can be tuned by the precursor AgNO{sub 3}. The photodegradation rate constant (k) of the optimal ZnO/Ag{sub 2}O sample under visible light is nearly 0.1004 min{sup −1} for methylene blue (MB), 0.063 min{sup −1} for rhodamine B (RHB) and 0.07 min{sup −1} for methyl orange (MO), which are much better than the pure ZnO (0.0075 min{sup −1}). The enhancement of the visible light photocatalytic activity could be attributed to the heterojunction interfaces induced by the match of crystal lattice and energy band between the Ag{sub 2}O and ZnO. The Ag{sub 2}O generates the excited-state electrons under visible light irradiation. The excited electrons on Ag{sub 2}O could directly transfer to the conduction band (CB) of ZnO, making ZnO/Ag{sub 2}O present remarkable visible light photocatalytic activity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Far-infrared and accretion luminosities of the present-day active galactic nuclei

We investigate the relation between star formation (SF) and black hole accretion luminosities, using a sample of 492 type-2 active galactic nuclei (AGNs) at z<0.22, which are detected in the far-infrared (FIR) surveys with AKARI and Herschel. We adopt FIR luminosities at 90 and 100 μm as SF luminosities, assuming the proposed linear proportionality of star formation rate with FIR luminosities. By estimating AGN luminosities from [O iii]λ5007 and [O i]λ6300 emission lines, we find a positive linear trend between FIR and AGN luminosities over a wide dynamical range. This result appears to be inconsistent with the recent reports that low-luminosity AGNs show essentially no correlation between FIR and X-ray luminosities, while the discrepancy is likely due to the Malmquist and sample selection biases. By analyzing the spectral energy distribution, we find that pure-AGN candidates, of which FIR radiation is thought to be AGN-dominated, show significantly low-SF activities. These AGNs hosted by low-SF galaxies are rare in our sample (∼1%). However, the low fraction of low-SF AGNs is possibly due to observational limitations since the recent FIR surveys are insufficient to examine the population of high-luminosity AGNs hosted by low-SF galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

Enhanced Photocatalytic Property of Cu Doped Sodium Niobate

Here, we investigate the photocatalytic activity of Cu doped NaNbO 3 powder sample prepared by the modified polymer complex method. The photocatalytic activity of hydrogen evolution from methanol aqueous solution was improved by Cu 2.6 at% doping. The photocatalytic degradation of rhodamine B (RhB) under visible light irradiation was enhanced in comparison with pristine NaNbO 3 . Cu introduction improved the adsorption property of NaNbO 3 , judging from the Fourier transform infrared spectra. Moreover, the ultraviolet light excitation in Cu doped sample would accelerate the mineralized process.

36 MATERIALS SCIENCE↗

Machine-Learning Methods Enable Exhaustive Searches for Active Bimetallic Facets and Reveal Active Site Motifs for CO 2 Reduction

Bimetallic catalysts are promising for the most difficult thermal and electrochemical reactions, but modeling the many diverse active sites on polycrystalline samples is an open challenge. Here, we present a general framework for addressing this complexity in a systematic and predictive fashion. Active sites for every stable low-index facet of a bimetallic crystal are enumerated and cataloged, yielding hundreds of possible active sites. The activity of these sites is explored in parallel using a neural-network-based surrogate model to share information between the many density functional theory (DFT) relaxations, resulting in activity estimates with an order of magnitude fewer explicit DFT calculations. Sites with interesting activity were found and provide targets for follow-up calculations. This process was applied to the electrochemical reduction of CO 2 on nickel gallium bimetallics and indicated that most facets had similar activity to Ni surfaces, but a few exposed Ni sites with a very favorable on-top CO configuration. This motif emerged naturally from the predictive modeling and represents a class of intermetallic CO 2 reduction catalysts. These sites rationalize recent experimental reports of nickel gallium activity and why previous materials screens missed this exciting material. Most importantly these methods suggest that bimetallic catalysts will be discovered by studying facet reactivity and diversity of active sites more systematically.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Mars Technology Rover with Arm-Mounted Percussive Coring Tool, Microimager, and Sample-Handling Encapsulation Containerization Subsystem

A report describes the PLuto (programmable logic) Mars Technology Rover, a mid-sized FIDO (field integrated design and operations) class rover with six fully drivable and steerable cleated wheels, a rocker-bogey suspension, a pan-tilt mast with panorama and navigation stereo camera pairs, forward and rear stereo hazcam pairs, internal avionics with motor drivers and CPU, and a 5-degrees-of-freedom robotic arm. The technology rover was integrated with an arm-mounted percussive coring tool, microimager, and sample handling encapsulation containerization subsystem (SHEC). The turret of the arm contains a percussive coring drill and microimager. The SHEC sample caching system mounted to the rover body contains coring bits, sample tubes, and sample plugs. The coring activities performed in the field provide valuable data on drilling conditions for NASA tasks developing and studying coring technology. Caching of samples using the SHEC system provide insight to NASA tasks investigating techniques to store core samples in the future.

Younse, Paulo J.↗

X-Ray Emission of Ultraviolet Variable Active Galactic Nucleus Candidates

We analyze the X-ray properties of a sample of 23 high-probability active galactic nucleus (AGN) candidates with ultraviolet variability identified in Wasleske et al. Using data from the Chandra X-ray Observatory and XMM-Newton Observatory, we that find 11/23 nuclei are X-ray detected. We use spectral energy distribution modeling to compute star formation rates and show that the X-ray luminosities are typically in excess of the X-ray emission expected from star formation by at least an order of magnitude. Interestingly, this sample shows a diversity of optical spectroscopic properties. We explore possible reasons for why some objects lack optical spectroscopic signatures of black hole activity while still being UV-variable and X-ray bright. We find that host galaxy stellar emission and obscuration from gas and dust are potential factors. We study where this sample falls on relationships such as α OX - L 2500 and L X - L IR and find that some of the sample falls outside the typical scatter for these relations, indicating that they differ from the standard quasar population. With the diversity of optical spectroscopic signatures and varying impacts of dust and stellar emissions on our sample, these results emphasize the strength of variability in selecting the most complete set of AGN, regardless of other host galaxy properties.

79 ASTRONOMY AND ASTROPHYSICS↗

Automated Radioanalytical System Incorporating Microwave-Assisted Sample Preparation, Chemical Separation, and Online Radiometric Detection for the Monitoring of Total 99Tc in Nuclear Waste Processing Streams

An automated fluidic instrument is described that rapidly determines the total 99Tc content of aged nuclear waste samples, where the matrix is chemically and radiologically complex and the existing speciation of the 99Tc is variable. The monitor links microwave-assisted sample preparation with an automated anion exchange column separation and detection using a flow-through solid scintillator detector. The sample preparation steps acidify the sample, decompose organics, and convert all Tc species to the pertechnetate anion. The column-based anion exchange procedure separates the pertechnetate from the complex sample matrix, so that radiometric detection can provide accurate measurement of 99Tc. We developed a preprogrammed spike addition procedure to automatically determine matrix-matched calibration. The overall measurement efficiency that is determined simultaneously provides a self-diagnostic parameter for the radiochemical separation and overall instrument function. Continuous, automated operation was demonstrated over the course of 54 h, which resulted in the analysis of 215 samples plus 54 hly spike-addition samples, with consistent overall measurement efficiency for the operation of the monitor. A sample can be processed and measured automatically in just 12.5 min with a detection limit of 23.5 Bq/mL of 99Tc in low activity waste (0.495 mL sample volume), with better than 10% RSD precision at concentrations above the quantification limit. This rapid automated analysis method was developed to support nuclear waste processing operations planned for the Hanford nuclear site.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A Measure from Line-of-Sight Magnetograms for Prediction of Coronal Mass Ejections

From a sample of 17 vector magnetograms of 12 bipolar active regions, we have recently found (1) that a measure of the overall nonpotentiality (the overall twist and shear in the magnetic field) of an active region is given by the strong-shear length L(sub SS), the length of the portion of the main neutral line on which the observed transverse fields is strong (greater than 150 G) and strongly sheared (shear angle greater than 45 deg), and (2) that L(sub SS) is well correlated with the CME productivity of the active regions during the +/- 2-day time window centered on the day of the magnetogram. In the present paper, from the same sample of 17 vector magnetograms, we show that there is a viable proxy for L(sub SS) that can be measured from a line-of-sight magnetogram. This proxy is the strong-gradient length L(sub SG), the length of the portion of the main neutral line on which the potential transverse field is strong (greater than 150 G) and the gradient of the line-of-sight field is sufficiently steep (greater than or approximately 50 G/Mm). In our sample of active regions, L(sub SG) is statistically significantly correlated with L(sub SS) (correlation confidence level greater than 95%), and L(sub SG) is as strongly correlated with active-region CME productivity as is L(sub SS)(correlation confidence level approximately 99.7%). Because L(sub SG) can be measured from line-of-sight magnetograms obtained from conventional magnetographs, such as the magnetograph mode of the Michelson Doppler Imager (MDI) on board the Solar and Heliospheric Observatory (SOHO), it is a dependable substitute for L(sub SS) for use in operational CME forecasting. In addition, via measurement of L(sub SG), the years-long, nearly continuous sequence of 1.5-hour-cadence full-disk line-of-sight magnetograms from MDI can be used to track the growth and decay of the large-scale nonpotentiality in active regions and to examine the role of this evolution in active-region CME productivity.

Falconer, D. A.↗

STELLAR POPULATIONS OF ULTRAVIOLET-SELECTED ACTIVE GALACTIC NUCLEI HOST GALAXIES AT z {approx} 2-3

We use stellar population synthesis modeling to analyze the host-galaxy properties of a sample of 33 UV-selected, narrow-lined active galactic nuclei (AGNs) at z {approx} 2-3. In order to quantify the contribution of AGN emission to host galaxy broadband spectral energy distributions (SEDs), we use the subsample of 11 AGNs with photometric coverage spanning from rest-frame UV through near-IR wavelengths. Modeling the SEDs of these objects with a linear combination of stellar population and AGN templates, we infer the effect of the AGN on derived stellar population parameters. We also estimate the typical bias in derived stellar populations for AGNs lacking rest-frame near-IR wavelength coverage, and develop a method for inferring the true host-galaxy properties. We compare AGN host-galaxy properties to those of a sample of UV-selected, star-forming non-AGNs in the same redshift range, including a subsample carefully matched in stellar mass. Although the AGNs have higher masses and star-formation rates than the full non-active sample, their stellar population properties are consistent with those of the mass-selected sample, suggesting that the presence of an AGN is not connected with the cessation of star formation activity in star-forming galaxies at z {approx} 2-3. We suggest that a correlation between M {sub BH} and galaxy stellar mass is already in place at this epoch. Assuming a roughly constant Eddington ratio for AGNs at all stellar masses, we are unable to detect the AGNs in low-mass galaxies because they are simply too faint.

79 ASTRONOMY AND ASTROPHYSICS↗

Influence of crystalline phase and defects in the ZrO{sub 2} nanoparticles synthesized by thermal plasma route on its photocatalytic properties

Graphical abstract: Thermal plasma synthesized nanophase zirconia showing the blue shift in the band gap of monoclinic phase as found from the photoabsorption spectroscopy was found to be the dominant parameter for the enhancement in its photocatalytic activity. The existence of different defect states and their concentration in as synthesized samples also inferred from the photoabsorption measurements were also found to be responsible for the enhanced photocatalytic activity of the samples. Highlights: ► Phase controlled structural formation of nanophase ZrO{sub 2} by thermal plasma route. ► Enhanced photocatalytic degradation rate of methylene blue dye. ► The blue shift in the band gap of monoclinic phase of nanocrystalline ZrO{sub 2}. ► Existence of different defect states in the as synthesized nano phase ZrO{sub 2}. ► Several competing processes which controls the photocatalytic degradation rate. -- Abstract: The photocatalytic activity of pure ZrO{sub 2} samples, prepared by a thermal plasma route, and characterized by X-ray diffraction technique was tested for the degradation of methylene blue, which is known to be a hazardous dye. Although, all these samples synthesized at different operating pressures of the thermal plasma reactor showed the photocatalytic activity; the sample synthesized at 1.33 bar of operating pressure showed the highest photocatalytic activity. The blue shift in the band gap of monoclinic phase, as observed from the photo-absorption spectroscopy, may be attributed to the enhanced photocatalytic activity. The existence of different defect states and their concentration as, inferred from the photo-absorption measurements were also found to be responsible for the enhanced photocatalytic activity of the as synthesized samples.

36 MATERIALS SCIENCE↗

STELLAR EVIDENCE THAT THE SOLAR DYNAMO MAY BE IN TRANSITION

Precise photometry from the Kepler space telescope allows not only the measurement of rotation in solar-type field stars, but also the determination of reliable masses and ages from asteroseismology. These critical data have recently provided the first opportunity to calibrate rotation–age relations for stars older than the Sun. The evolutionary picture that emerges is surprising: beyond middle-age the efficiency of magnetic braking is dramatically reduced, implying a fundamental change in angular momentum loss beyond a critical Rossby number (Ro ∼ 2). We compile published chromospheric activity measurements for the sample of Kepler asteroseismic targets that were used to establish the new rotation–age relations. We use these data along with a sample of well-characterized solar analogs from the Mount Wilson HK survey to develop a qualitative scenario connecting the evolution of chromospheric activity to a fundamental shift in the character of differential rotation. We conclude that the Sun may be in a transitional evolutionary phase, and that its magnetic cycle might represent a special case of stellar dynamo theory.

79 ASTRONOMY AND ASTROPHYSICS↗

Osteoblast fibronectin mRNA, protein synthesis, and matrix are unchanged after exposure to microgravity

The well-defined osteoblast line, MC3T3-E1 was used to examine fibronectin (FN) mRNA levels, protein synthesis, and extracellular FN matrix accumulation after growth activation in spaceflight. These osteoblasts produce FN extracellular matrix (ECM) known to regulate adhesion, differentiation, and function in adherent cells. Changes in bone ECM and osteoblast cell shape occur in spaceflight. To determine whether altered FN matrix is a factor in causing these changes in spaceflight, quiescent osteoblasts were launched into microgravity and were then sera activated with and without a 1-gravity field. Synthesis of FN mRNA, protein, and matrix were measured after activation in microgravity. FN mRNA synthesis is significantly reduced in microgravity (0-G) when compared to ground (GR) osteoblasts flown in a centrifuge simulating earth's gravity (1-G) field 2.5 h after activation. However, 27.5 h after activation there were no significant differences in mRNA synthesis. A small but significant reduction of FN protein was found in the 0-G samples 2.5 h after activation. Total FN protein 27.5 h after activation showed no significant difference between any of the gravity conditions, however, there was a fourfold increase in absolute amount of protein synthesized during the incubation. Using immunofluorescence, we found no significant differences in the amount or in the orientation of the FN matrix after 27.5 h in microgravity. These results demonstrate that FN is made by sera-activated osteoblasts even during exposure to microgravity. These data also suggest that after a total period of 43 h of spaceflight FN transcription, translation, or altered matrix assembly is not responsible for the altered cell shape or altered matrix formation of osteoblasts.

Flight Experiment↗