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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 811 records · Page 45
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Collaborative Proposal: Improving Understanding of the Internal Structure and Dynamics of Deep Convection Using ARM Observations and Large Eddy Simulations (Final progress report)

This is the final technical report for the DOE Atmospheric System Research funded project entitled "Collaborative Proposal: Improving Understanding of the Internal Structure and Dynamics of Deep Convection Using ARM Observations and Large Eddy Simulations". This project addressed several science questions related to the structure and behavior of deep convective clouds in the atmosphere. It applied knowledge gained from this work to improve the deep cumulus convection parameterization in the Community Earth System Model (CESM). Specific outcomes related to the project include an improved understanding of: (1) how convective cloud environments regulate the size of thermals reaching the upper troposphere, and hence the shallow-to-deep convective transition; (2) the role of dynamic pressure forcing in thermal and convective cloud evolution; and (3) the role of vertical wind shear on the behavior of moist thermals and the transition from shallow to deep convection. Although the primary motivation of this project was to improve basic understanding of thermal dynamics in atmospheric convection, an important component of this work was using this improved understanding to modify the representation of entrainment and vertical velocity profiles in the Zhang-McFarlane cumulus parameterization used in CESM. This work also had a strong observational component, with analyses of Atmospheric Radiation Measurement (ARM) observations to characterize thermal characteristics and behavior. Observations collected during the ARM-supported CACTI field project were used with high-resolution simulations to explore environmental controls on deep convection initiation. Data from the ARM-supported MC3E field project were also used to evaluate the representation of updraft vertical velocities in the Zhang-McFarlane cumulus parameterization. This project directly supported the training of two post-doctoral researchers and led to 16 peer-reviewed published papers.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Morphological Heterogeneity Impact of Film Solid-State Cathode on Utilization and Fracture Dynamics

Structural heterogeneity in solid-state batteries can impact material utilization and fracture mechanisms. Crystallographically oriented lithium cobalt oxide film cathodes serve as a model electrode system for exploring how void distribution contributes to stress relief and build up during cycling. Real- and reciprocal-space operando and ex situ synchrotron based experiments are utilized to understand structural changes across multiple length scales contribute to stress generation and fracture. Nanotomography uncovers a depth-dependent porosity variation in the pristine electrode and highlights preferential fracture in regions of lower porosity during delithiation. Energy-dispersive X-ray diffraction and 3D X-ray absorption near-edge spectroscopy (XANES) reveal the underutilization of cathode material in these regions. 3D XANES also confirms preferential delithiation near the sub-grain boundaries. Chemo-mechanical modeling coupled with site-specific mechanical characterization demonstrate how stress accumulation in dense regions of the electrode leads to fracture and underutilization of active material. In conclusion, our findings reveal the importance of materials design to alleviate stress in small-volume changing cathodes.

36 MATERIALS SCIENCE↗
NASA NTRS1981

Preliminary results of the study of lightning location relative to storm structure and dynamics

Lightning is being studied relative to storm structure using a VHF space-time discharge mapping system, radar, a cloud-to-ground flash locator, acoustic reconstruction of thunder, and other instrumentation. The horizontal discharge processes within the cloud generally propagate at speeds of 10,000-100,000 m/s. Horizontal extents of lightning were found up to 90 km. In an analysis of a limited number of flashes, lightning occurred in or near regions of high cyclonic shear. Positive cloud-to-ground flashes have been observed emanating from several identifiable regions of severe storms. Lightning echoes observed with 10-cm radar generally are 10-25 dB greater than the largest precipitation echo in the storm.

Rust, W. D.↗
NASA NTRS1997

Spherical Diffusion Flames: Structure and Dynamics

The spherical geometry is the most suitable one to study fundamental issues concerning the structure and the dynamics of diffusion flames. From a theoretical point of view, it is the only geometry that permits the existence of a truly one dimensional stationary diffusion flame. A stationary planar diffusion flame with the fuel supplied upstream, at x approaches -infinity say, and the oxidant downstream, at x approaches +infinity is not possible. For a steady diffusion flame to exist, one must have nonzero fluxes of fuel and oxidant towards the flame. However, in the unlimited region behind the planar flame the only bounded solutions to the reaction-free convective-diffusive operator are constants. Hence the oxidant concentration behind the flame remains constant and there is no mechanism to generate the necessary flux towards the flame. A one-dimensional problem can be formulated if the reactants are supplied at finite locations; but the boundary conditions in this case introduce unnecessary complications and do not appropriately model the physical reality. Indeed, a planar diffusion flame can be established in the stagnation-point flow of two opposed jets but the flame in this case is stretched and the flow is essentially two-dimensional. The only stationary one-dimensional diffusion flame in an unlimited environment is therefore the spherical flame.

Matalon, Moshe↗
NASA NTRS2002

Deployment Simulation of Ultra-Lightweight Inflatable Structures

Dynamic deployment analyses of folded inflatable tubes are conducted to investigate modeling issues related to the deployment of solar sail booms. The analyses are necessary because ground tests include gravity effects and may poorly represent deployment in space. A control volume approach, available in the LS-DYNA nonlinear dynamic finite element code, and the ideal gas law are used to simulate the dynamic inflation deployment process. Three deployment issues are investigated for a tube packaged in a Z-fold configuration. The issues are the effect of the rate of inflation, the effect of residual air, and the effect of gravity. The results of the deployment analyses reveal that the time and amount of inflation gas required to achieve a full deployment are related to these issues.

Wang, John T.↗
NASA NTRS2002

Some Studies of Structure and Dynamics of Jupiter's Magnetosphere

The purpose of this investigation was to establish the relative roles of solar wind and the internal plasma processes in shaping the structure and dynamics of Jupiter's magnetosphere. We carried out several investigations to establish these roles. Three new research papers have resulted from this work. In the following we provide brief summaries of the main findings.

Khurana, Krishan K.↗
DOE OSTI2021

Toward Discovering the Structure and Dynamics of the Sun-Interstellar Medium System (Los Alamos LDRD Report)

We have taken major steps toward developing the tools necessary to explore with unprecedented resolution the plasma structure and dynamics of the Sun-interstellar medium (ISM) interaction region, known as the heliosheath. We have applied a rigorous imaging technique known as Generalized Ridge Regression (GRR) to construct statistically robust sky maps of hydrogen energetic neutral atoms (ENAs) emanating from this region and detected by the Los Alamos-led IBEX-Hi ENA imager [1] on NASA’s Interstellar Boundary Explorer (IBEX) mission [2]. Our methods go far beyond the map reconstruction process currently applied by the IBEX Science Operations Center (ISOC), opening up the possibility of new discovery science with the IBEX data set and positioning LANL for a lead science role for the upcoming Interstellar Mapping and Acceleration Probe (IMAP) mission [3] for which LANL is providing two key experiments. We have successfully demonstrated that the new maps are higher resolution and are capable of revealing structures that are not presently resolveable in standard ISOC maps

58 GEOSCIENCES↗
NASA NTRS1990

The atmospheric structure and dynamical properties of Neptune derived from ground-based and IUE spectrophotometry

A wide range of recent full-disk spectral observations is used to constrain the atmospheric structure and dynamical properties of Neptune; analytical determinations are made of the abundances of such spectrally active gas species as the deep-atmosphere CH4 molar fraction and the mean ortho/para hydrogen ratio in the visible atmosphere, as well as stratospheric and tropospheric aerosol properties. Compared to Uranus, the greater abundance and shorter lifetimes of Neptunian particulates in the stratospheric region irradiated by the solar UV flux indicate that such radiation is the darkening agent of stratospheric aerosols on both planets.

Baines, Kevin H.↗
NASA NTRS1985

Dynamic verification of very large space structures

A research program in spacecraft structures, structural dynamics, and controls verification using a relatively large, flexible beam as a focus is introduced. This research effort addresses fundamental problems applicable to the verification of large, flexible space structures and combines ground tests, flight behavior prediction, and instrumented orbital tests. The program is expected to produce quantitative results for use in improving the validity of ground tests for verifying flight performance analyses.

Hanks, B. R.↗
DOE OSTI2021

Concentration-Dependent Solvation Structure and Dynamics of Aqueous Sulfuric Acid Using Multinuclear NMR and DFT

Sulfuric acid is a ubiquitous compound for industrial processes and aqueous sulfate solutions also play a critical role in electrolytes for many prominent battery chemistries. While the thermodynamic literature for it is quite well-developed, comprehensive studies of the solvation structure, and particularly molecular-scale dynamical and transport properties, are less available. This study applies a multinuclear NMR approach to the elucidation of the solvation structure and dynamics over a wide temperature (-10 – 50?C) and concentration (0 – 18 M) range, combining 17O shift, linewidth, and T1 relaxation measurements, 33S shift and linewidth measurements, and 1H PFG-NMR measurements of the proton self-diffusivity. In conjunction, these results indicate a crossover between two regimes of solvation structure and dynamics, occurring above the concentration associated with the deep eutectic point (~ 4.5 M), with the high-concentration regime dominated by strong water-sulfate correlation. This description was borne out in detail by the activation energy trends with increasing concentration derived from the relaxation of both the H2O/H3O+ and H2SO4/HSO4-/SO42- 17O resonances and the 1H self-diffusivity. However, the 17O chemical shift difference between the H2O/H3O+ and H2SO4/HSO4-/SO42- resonances across the entire temperature range is nevertheless strikingly linear. A computational approach coupling MD simulations and DFT NMR shift calculations to reproduce this trend is presented, which will be the subject of further development. This combination of multinuclear, dynamical NMR and computational methods, and the results furnished by this study, will provide a platform for future studies on battery electrolytes where aqueous sulfate chemistry plays a central role in the solution structure.

Bazak, Jonathan D.↗
DOE OSTI2021

Effect of graphitic anode surface functionalization on the structure and dynamics of electrolytes at the interface

Surface termination on a graphitic surface and the type of electrolytes in lithium-ion batteries (LIBs) play an important part in determining the structure, composition, and thus, the quality of the emergent solid electrolyte interphase. In this paper, we analyze the structure and dynamics of electrolyte molecules in multi-component electrolyte with varying species compositions combinatorially paired with four different graphitic surfaces terminated with hydrogen, hydroxyl, carbonyl, and carboxyl to explore the interplay between surface chemistry and electrolyte dynamics at electrode/electrolyte interfaces. Addition of dimethyl carbonate and fluoroethylene carbonate brought substantial changes in the ethylene carbonate (EC) and LiPF6 surface population density for hydroxyl and carbonyl surfaces. Strong density oscillation and drastic slowing of the dynamics of the electrolyte molecules at the interface are reported for all the systems. While these observations are universal, carboxyl surfaces have the strongest local and long-range effects. Characterization of the average dipole direction at the interface shows strong orientational preferences of ethylene carbonate molecules. EC molecules are preferred to be oriented either almost parallel or perpendicular to the hydroxyl surface, are tilted between parallel and perpendicular with a higher angle of incidence of the dipole vs surface normal on the carbonyl surface than on the hydroxyl surface, and are oriented perpendicularly against the carboxyl surface. These differences highlight the significant effect of graphite surface termination on the dynamics of the electrolytes and provide insight into the complex interplays between electrolyte species and graphite anode in LIBs.

Rustam, Sabiha (ORCID:0000000224248153)↗
NASA NTRS2002

The Structure and Dynamics of the Solar Corona and Inner Heliosphere

This report covers technical progress during the fourth quarter of the second year of NASA Sun-Earth Connections Theory Program (SECTP) contract "The Structure and Dynamics of the Solar Corona and Inner Heliosphere," NAS5-99188, between NASA and Science Applications International Corporation (SAIC), and covers the period May 16, 2001 to August 15, 2001. Under this contract SAIC and the University of California, Irvine (UCI) have conducted research into theoretical modeling of active regions, the solar corona, and the inner heliosphere, using the MHD (magnetohydrodynamic) model.

Mikic, Zoran↗
NASA NTRS2001

NASA Sun-Earth Connections Theory Program: The Structure and Dynamics of the Solar Corona and Inner Heliosphere

This report covers technical progress during the fourth quarter of the second year of NASA Sun-Earth Connections Theory Program (SECTP) contract 'The Structure and Dynamics of the Solar Corona and Inner Heliosphere,' NAS5-99188, between NASA and Science Applications International Corporation, and covers the period May 16,2001 to August 15, 2001. Under this contract SAIC and the University of California, Irvine (UCI) have conducted research into theoretical modeling of active regions, the solar corona, and the inner heliosphere, using the MHD model.

Mikic, Zoran↗
NASA NTRS2001

The Structure and Dynamics of the Solar Corona and Inner Heliosphere

This report covers technical progress during the third quarter of the second year of NASA Sun-Earth Connections Theory Program (SECTP) contract 'The Structure and Dynamics of the Solar Corona and Inner Heliosphere,' NAS5-99188, between NASA and Science Applications International Corporation, and covers the period February 16, 2001 to May 15, 2001. Under this contract SAIC and the University of California, Irvine (UCI) have conducted research into theoretical modeling of active regions, the solar corona, and the inner heliosphere, using the MHD model.In this report we summarize the accomplishments made by our group during the first seven quarters of our Sun-Earth Connection Theory Program contract. The descriptions are intended to illustrate our principal results. A full account can be found in the referenced publications.

Mikic, Zoran↗