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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 829 records · Page 46
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

Mechanical confinement for improved energy storage density in BNT-BT-KNN lead-free ceramic capacitors

With the advent of modern power electronics, embedded circuits and non-conventional energy harvesting, the need for high performance capacitors is bound to become indispensible. The current state-of-art employs ferroelectric ceramics and linear dielectrics for solid state capacitance. However, lead-free ferroelectric ceramics propose to offer significant improvement in the field of electrical energy storage owing to their high discharge efficiency and energy storage density. In this regards, the authors have investigated the effects of compressive stress as a means of improving the energy storage density of lead-free ferroelectric ceramics. The energy storage density of 0.91(Bi{sub 0.5}Na{sub 0.5})TiO{sub 3}-0.07BaTiO{sub 3}-0.02(K{sub 0.5}Na{sub 0.5})NbO{sub 3} ferroelectric bulk ceramic was analyzed as a function of varying levels of compressive stress and operational temperature .It was observed that a peak energy density of 387 mJ.cm{sup -3} was obtained at 100 MPa applied stress (25{sup o}C). While a maximum energy density of 568 mJ.cm{sup -3} was obtained for the same stress at 80{sup o}C. These values are indicative of a significant, 25% and 84%, improvement in the value of stored energy compared to an unloaded material. Additionally, material's discharge efficiency has also been discussed as a function of operational parameters. The observed phenomenon has been explained on the basis of field induced structural transition and competitive domain switching theory.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Maximal absorption in ultrathin TiN films for microbolometer applications

Ultrathin light absorbers present a viable route toward improving the specific detectivity and response time of microbolometers. However, for an ultrathin film to absorb light efficiently, the dielectric function of the film and its thickness must satisfy strict requirements. Here we experimentally demonstrate an average absorptance of 48% ± 2.5% in the 8–13 μm (769–1250 cm -1 ) spectral range for 10 nm thick titanium nitride (TiN), a value bordering on the 50% fundamental absorptance limit for a suspended thin film. The heat capacity per unit area of this absorber is only 1.2 × 10 -6 J/K/cm 2 , which is beneficial for improving the response time of a microfabricated bolometer. We also show that a sufficient condition for reaching maximal absorption in an ultrathin film is that ε" $\gg$ |ε'|.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Effect of pressure cycling and compression rate on the bcc-hcp transition in an FeNi alloy

Here, we investigate the body-centered cubic (bcc) to hexagonal close-packed (hcp) phase transition in Fe-10wt. %Ni alloy, combining pressure cycling and fast compression with time-resolved synchrotron x-ray diffraction in a dynamic diamond anvil cell. Three pressure cycles were conducted with compression rates ranging from 0.1 to nearly 10 3 GPa/s. During the first cycle with the slowest compression, the observed orientations in the bcc and hcp phases are consistent with the Burgers mechanism, followed by c-axis rotation of the hcp phase consistent with {$10$ $\bar{1}2$} twinning. During the following cycles with fast compression at 10 2 –10 3 GPa/s, the hcp phase exhibits negligible c-axis rotation with a nearly constant c/a ratio of ∼1.61 up to ∼30 GPa, indicating suppression of plastic deformation (especially, twinning) due to sample confinement from the gasket. Notably, the onset pressure of the transition decreases with additional pressure cycling and faster compression, which normally leads to over-pressurization. This suggests that defects or shear induced from the pressure cycling reduces the transition kinetics even during fast compression. These insights into the deformation and transition behavior in an FeNi alloy under multiple dynamic loading cycles can offer guidance for future design of advanced structural alloys and improve our understanding of planetary core processes.

FeNi alloy↗
DOE OSTI2011

SPINNING DUST EMISSION: EFFECTS OF IRREGULAR GRAIN SHAPE, TRANSIENT HEATING, AND COMPARISON WITH WILKINSON MICROWAVE ANISOTROPY PROBE RESULTS

Planck is expected to answer crucial questions on the early universe, but it also provides further understanding on anomalous microwave emission. Electric dipole emission from spinning dust grains continues to be the favored interpretation of anomalous microwave emission. In this paper, we present a method to calculate the rotational emission from small grains of irregular shape with moments of inertia I{sub 1} {>=} I{sub 2} {>=} I{sub 3}. We show that a torque-free rotating irregular grain with a given angular momentum radiates at multiple frequency modes. The resulting spinning dust spectrum has peak frequency and emissivity increasing with the degree of grain shape irregularity, which is defined by I{sub 1}:I{sub 2}:I{sub 3}. We discuss how the orientation of the dipole moment {mu} in body coordinates affects the spinning dust spectrum for different regimes of internal thermal fluctuations. We show that the spinning dust emissivity for the case of strong thermal fluctuations is less sensitive to the orientation of {mu} than in the case of weak thermal fluctuations. We calculate spinning dust spectra for a range of gas density and dipole moment. The effect of compressible turbulence on spinning dust emission is investigated. We show that the emission in a turbulent medium increases by a factor from 1.2 to 1.4 relative to that in a uniform medium, as the sonic Mach number M{sub s} increases from 2 to 7. Finally, spinning dust parameters are constrained by fitting our improved model to five-year Wilkinson Microwave Anisotropy Probe cross-correlation foreground spectra, for both the H{alpha}-correlated and 100-{mu}m-correlated emission spectra.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Effect of low-temperature compression on superconductivity and crystal structure in strontium metal

The superconducting and structural properties of elemental strontium metal were investigated under pressures up to 60 GPa while maintaining cryogenic conditions during pressure application. Applying pressure at low temperatures reveals differences in superconducting and structural phases compared to previous reports obtained at room temperatures. Notably, the superconducting critical temperature exhibits a twofold increase under compression after cryogenic cooling within the pressure range of 35–42 GPa, compared to cryogenic cooling after room-temperature compression. Subsequently, the transition width becomes significantly sharper above 42 GPa. Low-temperature x-ray diffraction measurements under pressure reveal that this change corresponds to the Sr-III to Sr-IV transition, with no evidence of any metastable structure. Furthermore, the monoclinic Sr-IV structure was observed to remain stable to much higher pressures—at least up to 60 GPa, without the appearance of the incommensurate Sr-V phase present at room temperature. As a result, this implies that thermal activation energy plays an important role in overcoming the presence of a kinetic barrier to the Sr-V phase at room temperature.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

A mechanical reduced order model for elastomeric 3D printed architectures

Direct ink writing of silicone elastomers enables printing with precise control of porosity and mechanical properties of ordered cellular solids, suitable for shock absorption and stress mitigation applications. With the ability to manipulate structure and feedstock stiffness, the design space becomes challenging to parse to obtain a solution producing a desired mechanical response. We derive an analytical design approach for a specific architecture. Results from finite element simulations and quasi-static mechanical tests of two different parallel strand architectures were analyzed to understand the structure-property relationships under uniaxial compression. Combining effective stiffness-density scaling with least squares optimization of the stress responses yielded general response curves parameterized by resin modulus and strand spacing. An analytical expression of these curves serves as a reduced order model, which, when optimized, provides a rapid design capability for filament-based 3D printed structures. Finally, as a demonstration, the optimal design of a face-centered tetragonal architecture is computed that satisfies prescribed minimum and maximum load constraints.

36 MATERIALS SCIENCE↗
DOE OSTI2015

A Framework of Hyperspectral Image Compression using Neural Networks

Hyperspectral image analysis has gained considerable attention due to its wide range of applications. Hyperspectral images provide a vast amount of information about underlying objects in an image by using a large range of the electromagnetic spectrum for each pixel. However, since the same image is taken multiple times using distinct electromagnetic bands, the size of such images tend to be significant, which leads to greater processing requirements. The aim of this paper is to present a proposed framework for image compression and to study the possible effects of spatial compression on quality of unmixing results. Image compression allows us to reduce the dimensionality of an image while still preserving most of the original information, which could lead to faster image processing. This paper presents preliminary results of different training techniques used in Artificial Neural Network (ANN) based compression algorithm.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2013

Characterization and Computer Modeling for Brunelleschi's Dome of Santa Maria del Fiore in Florence

In 1420 Brunelleschi began construction on the enormous dome of Santa Maria del Fiore church in Florence Italy. Of special interest was the fact that his design did not require temporary supports from below (the distance from the ground level to the dome was too high to build such scaffolding/centering). Instead he made use of the stabilizing effect of compressive hoop stresses. As the dome went up, it was always in balance since no part extended beyond the other. Thus, the compressive forces were distributed both radially from the apex of the dome, and circumferentially about the center of the dome providing a stable configuration.

Accelerator Design, Technology, and Operations↗
DOE OSTI2014

Development of A High Performance Cold Climate Heat Pump

The primary goals of the proposed project were to develop, test, and evaluate a high performance and cost-effective vapor compression air-source heat pump for use in cold climate regions. Vapor compression heat pumps are a proven technology, and have been used for many years to meet heating requirements for buildings in residential, commercial, and industrial applications. However, in climate regions that experience very low outdoor ambient temperatures both the heating capacity and coefficient of performance (COP) of traditional air-source vapor compression heat pumps drops dramatically with a decrease in the outdoor air temperature. The efficiency of heat pumping equipment has improved substantially over the past 20 years; however, the efficiencies of the highest rated equipment on the market are approaching practical limits that cannot be surpassed without modifications to the basic cycle and possibly the use of additional hardware. In this report, three technologies to improve the efficiency of vapor compression systems are described. These are a) vapor injected compression, b) oil flooded compression and c) hybrid flow control of the evaporator. Compressor prototypes for both, oil flooded and vapor injected compression were developed by Emerson Climate Technologies. For the oil flooded compressor, the oil injection port location was optimized and an internal oil separator was added using several design iterations. After initial testing at Emerson Climate Technologies, further testing was done at Purdue University, and compressor models were developed. These models were then integrated into a system model to determine the achievable improvement of seasonal energy efficiency (SEER) for Minneapolis (Minnesota) climate. For the oil flooded compression, a 34% improvement in seasonal energy efficiency was found while a 21% improvement in seasonal energy efficiency ratio was found for the vapor injected compression. It was found that one benefit of both tested compression technologies is a lower discharge temperature, which allows for continued operation at lower ambient temperatures. A bin analysis of the vapor injected prototype cold climate heat pump predicts a 6% improvement in HSPF for Minneapolis. This improvement is mainly a result of the increased capacity of the system for active vapor injection. For the oil flooded system, a slightly larger performance improvement is predicted, in this case mostly caused by an increase in heating COP. Based on an economic analysis of these results, the maximum additional cost of the system changes, for the Minneapolis location, are $\$430$ for the vapor injected system and $\$391$ for the oil flooded system. These estimates assume that a 3-year simple payback period is accepted by the customer. For the hybrid flow control of evaporators, a new type of balancing valve was developed together with Emerson Climate technologies to reduce the cost of the control scheme. In contrast to conventional stepper motor valves, this valve requires less cables and can be driven by a cheaper output circuit on the control board. The correct valve size was determined in a dedicated test stand in several design iterations. The performance benefits of the hybrid control of the evaporator coil were determined for clean coil conditions as well as with partial blockage of the air inlet grille and under frosting conditions. For clean coil conditions, the benefits in terms of COP and capacity are negligible. However, significant benefits were noted for severely air-maldistributed operating conditions. For the H2-test, the maximum COP improvement of 17% along with a capacity improvement of nearly 40% was observed. Overall, the hybrid control scheme leads to a significant amount of performance improvement, if the air inlet conditions to the evaporator are maldistributed.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2016

HEATING AND ACCELERATION OF THE FAST SOLAR WIND BY ALFVÉN WAVE TURBULENCE

We present numerical simulations of reduced magnetohydrodynamic (RMHD) turbulence in a magnetic flux tube at the center of a polar coronal hole. The model for the background atmosphere is a solution of the momentum equation and includes the effects of wave pressure on the solar wind outflow. Alfvén waves are launched at the coronal base and reflect at various heights owing to variations in Alfvén speed and outflow velocity. The turbulence is driven by nonlinear interactions between the counterpropagating Alfvén waves. Results are presented for two models of the background atmosphere. In the first model the plasma density and Alfvén speed vary smoothly with height, resulting in minimal wave reflections and low-energy dissipation rates. We find that the dissipation rate is insufficient to maintain the temperature of the background atmosphere. The standard phenomenological formula for the dissipation rate significantly overestimates the rate derived from our RMHD simulations, and a revised formula is proposed. In the second model we introduce additional density variations along the flux tube with a correlation length of 0.04 R {sub ⊙} and with relative amplitude of 10%. These density variations simulate the effects of compressive MHD waves on the Alfvén waves. We find that such variations significantly enhance the wave reflection and thereby the turbulent dissipation rates, producing enough heat to maintain the background atmosphere. We conclude that interactions between Alfvén and compressive waves may play an important role in the turbulent heating of the fast solar wind.

79 ASTRONOMY AND ASTROPHYSICS↗