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The sun and interplanetary magnetic field

The interplanetary magnetic field (IMF) serves as a link between the sun, the response of the earth to solar activity and variations in galactic cosmic radiation. The IMF originates as a solar-coronal magnetic field that is transported into space by the solar wind. The close connection between solar magnetic fields and the origin and structure of the solar wind is described. The solar wind forms the heliosphere, a cavity containing the magnetized solar plasma from which the interstellar plasma and field are excluded. The entry of galactic cosmic rays into the heliosphere and their strong interaction with the IMF are discussed, this topic being of primary importance to the production and temporal variations of radiogenic elements. The profound influence of the IMF on geomagnetic activity and the aurora is discussed within the context of merging or reconnection with the planetary field. The physical connection is thus established between solar magnetic fields, magnetic storms and aurora. The state of the solar wind and IMF during the Maunder minimum is considered and an explanation for the (relative) absence of sunspots and aurora is proposed. The mechanism is an interruption of the oscillatory solar dynamo, a consequent reduction in the heating of the corona, a cessation of the supersonic solar wind and a weakening or absence of southward-directed magnetic fields in the vicinity of the earth.

Smith, Edward J.↗

Bias properties of extragalactic distance indicators. 3: Analysis of Tully-Fisher distances for the Mathewson-Ford-Buchhorn sample of 1355 galaxies

The observational selection bias properties of the large Mathewson-Ford-Buchhorn (MFB) sample of axies are demonstrated by showing that the apparent Hubble constant incorrectly increases outward when determined using Tully-Fisher (TF) photometric distances that are uncorreted for bias. It is further shown that the value of H(sub 0) so determined is also multivlaued at a given redshift when it is calculated by the TF method using galaxies with differenct line widths. The method of removing this unphysical contradiction is developed following the model of the bias set out in Paper II. The model developed further here shows that the appropriate TF magnitude of a galaxy that is drawn from a flux-limited catalog not only is a function of line width but, even in the most idealistic cases, requires a triple-entry correction depending on line width, apparent magnitude, and catalog limit. Using the distance-limited subset of the data, it is shown that the mean intrinsic dispersion of a bias-free TF relation is high. The dispersion depends on line width, decreasing from sigma(M) = 0.7 mag for galaxies with rotational velocities less than 100 km s(exp-1) to sigma(M) = 0.4 mag for galaxies with rotational velocities greater than 250 km s(exp-1). These dispersions are so large that the random errors of the bias-free TF distances are too gross to detect any peculiar motions of individual galaxies, but taken together the data show again the offset of 500 km s(exp-1) fond both by Dressler & Faber and by MFB for galaxies in the direction of the putative Great Attractor but described now in a different way. The maximum amplitude of the bulk streaming motion at the Local Group is approximately 500 km s(exp-1) but the perturbation dies out, approaching the Machian frame defined by the CMB at a distance of approximately 80 Mpc (v is approximately 4000 km s(exp -1)). This decay to zero perturbation at v is approximately 4000 km s(exp -1) argues against existing models with a single attraction at approximately 4500 km s(exp -1) (the Great Attactor model) pulling the local region. Rather, the cause of the perturbation appears to be the well-known clumpy mass distribution within 4000 km s(exp -1) in the busy directions of Hydra, Centaurus, Antila and Dorado, as postulated earlier (Tammann & Sandage 1985).

Federspiel, Martin↗

Fall, Recovery and Characterization of the Novato L6 Chondrite Breccia

The Novato L6 chondrite fragmental breccia fell in California on 17 October 2012, and was recovered after the Cameras for Allsky Meteor Surveillance (CAMS) project determined the meteor's trajectory between 95 and 45 km altitude. The final fragmentation at 33 1 km altitude was exceptionally well documented by digital photographs. The first sample was recovered before rain hit the area. First results from a consortium study of the meteorite's characterization, cosmogenic and radiogenic nuclides, origin and conditions of the fall are presented. Some meteorites did not retain fusion crust and show evidence of spallation. Before entry, the meteoroid was 35+/-5 cm in diameter (mass 80+/-35 kg) with a cosmic ray exposure age of 9+/-1 Ma, if it had a one-stage exposure history. However, based on the cosmogenic nuclide inventory, a two-stage exposure history is more likely, with lower shielding in the last few Ma. Thermoluminescence data suggest a collision event within the last approx. 0.1 Ma. Novato likely belonged to the class of shocked L chondrites that have a common shock age of 470 Ma, based on the U,Th-He age of 460+/-220 Ma. The measured orbits of Novato, Jesenice and Innisfree are consistent with a proposed origin of these shocked L chondrites in the Gefion asteroid family, but leave open the possibility that they came to us directly from the 5:2 mean motion resonance with Jupiter. Novato experienced a stronger compaction than did other L6 chondrites of shock-stage S4. Despite this, a freshly broken surface shows a wide range of organic compounds.

meteorites↗

DSMC Simulations of Ballute Aerothermodynamics Under Hypersonic Rarefied Conditions

This paper presents computational results obtained with the direct simulation Monte Carlo (DSMC) method for towed ballute applications. A ballute is an inflatable drag device that can be used to create a large amount of drag at high altitudes. Consequently, ballutes provide a potential technology for achieving aerocapture when the primary spacecraft velocity reduction (ΔV) is achieved at much higher altitudes than with the conventional rigid aeroshell. Since the ΔV is achieved at relatively high altitudes, rarefaction can be significant and is the motivation for the current study with the DSMC method. Computed surface and flow-field results are presented for a toroidal ballute, isolated tethers when exposed to free-stream flow conditions, and the flow interactions resulting from a toroidal ballute when towed by a six meter diameter Mars Pathfinder shaped (without tethers) spacecraft. All results presented are for Earth entry at velocities of 14 to 7 km/s (primary focus is at 8.55 km/s, same as some previous Titan aerocapture studies) and altitudes of 200 to 100 km. Variations of drag and heating coefficients as a function of rarefaction are presented. A description of the flow structure is provided and also an explanation of how it is affected by shock interactions produced solely by the ballute and those resulting from the two body combination of towed ballute and spacecraft is also given.

James N Moss↗

Galileo Preparing for Jupiter Arrival

The most critical events of the Galileo mission occur on Jupiter arrival day, December 7, 1995. In chronological order, these one-time events are: a 1000 km flyby of the innermost Galilean satellite Io, the 75-minute Atmospheric Entry Probe mission, and the Orbiter's Jupiter Orbit Insertion (JOI) maneuver. In addition, extensive, unique Orbiter science observations are planned because this is the only time Galileo will encounter Io, fly through the Io torus, and will be so close to Jupiter -- three times closer than at any of the perijove passes in the orbital mission. All of these events occur in what will be by far the most intense radiation environment Galileo will ever see. The focus of this paper is the extraordinary preparations being made to maximize the reliability of the most critical events in order to ensure a successful probe mission and Orbiter Insertion while also gathering unique arrival day Orbiter science. The paper also provides a mission status report including the return of the asteroid Ida data and the Galileo direct line-of-sight observations of Comet Shoemaker-Levy fragments impacting Jupiter in July 1994.

Galileo↗

Case Study of Meteoroid Fluence on a Mars Sample Return Mission

The Mars Sample Return Campaign must satisfy a Back Planetary Protection requirement that limits the risk of biological contamination of the Earth by Martian microbes. The Earth Re-turn Orbiter (ERO), being developed by the European Space Agency (ESA), will carry a Capture, Containment and Return System (CCRS), which is being developed by NASA to retrieve orbiting samples (OS) from Mars orbit, surround them with two containment layers to create a Contained OS (COS), and transfer the COS to the Earth Entry System (EES), which will be re-leased by ERO to carry the samples through entry, descent and landing at the Utah Test and Training Range. Micrometeoroid impact damage to the Thermal Protection System (TPS) of the EES, which may occur at any time in the ERO mission, is recognized as a potential risk driver for loss of sample containment that needs to be rigorously assessed. A Micrometeoroid Protection System (MMPS) will be implemented to limit that risk. The MMPS consists of a shield covering the TPS called the Micrometeoroid Garage (MMG) and a system of cameras to inspect the TPS. An extensive study was performed by the CCRS Project in collaboration with the NASA Engineering and Safety Center (NESC)to assess the probability of damage to the MMG and TPS by meteoroids over the entire ERO mission. This included the computation of the meteoroid fluence on the MMG and directly on the TPS after EES separation, and assessment of damage to the MMG and TPS via hypervelocity impact tests, hydrocode simulations, and empirical damage prediction and ballistic limit equations (BLEs). The focus of this paper is the meteoroid fluence on the MMG.

Micrometeoroid↗

Case Study of Meteoroid Fluence on a Mars Sample Return Mission

The Mars Sample Return Campaign must satisfy a Back Planetary Protection requirement that limits the risk of biological contamination of the Earth by Martian microbes. The Earth Re-turn Orbiter (ERO), being developed by the European Space Agency (ESA), will carry a Capture, Containment and Return System (CCRS), which is being developed by NASA to retrieve orbiting samples (OS) from Mars orbit, surround them with two containment layers to create a Contained OS (COS), and transfer the COS to the Earth Entry System (EES), which will be re-leased by ERO to carry the samples through entry, descent and landing at the Utah Test and Training Range. Micrometeoroid impact damage to the Thermal Protection System (TPS) of the EES, which may occur at any time in the ERO mission, is recognized as a potential risk driver for loss of sample containment that needs to be rigorously assessed. A Micrometeoroid Protection System (MMPS) will be implemented to limit that risk. The MMPS consists of a shield covering the TPS called the Micrometeoroid Garage (MMG) and a system of cameras to inspect the TPS. An extensive study was performed by the CCRS Project in collaboration with the NASA Engineering and Safety Center (NESC)to assess the probability of damage to the MMG and TPS by meteoroids over the entire ERO mission. This included the computation of the meteoroid fluence on the MMG and directly on the TPS after EES separation, and assessment of damage to the MMG and TPS via hypervelocity impact tests, hydrocode simulations, and empirical damage prediction and ballistic limit equations (BLEs). The focus of this paper is the meteoroid fluence on the MMG.

micrometeoroid↗

Stabilization of Residual Contamination with Alternative Materials - 19404

Since 2015, Savannah River National Laboratory (SRNL) in conjunction with Florida International University (FIU) have been investigating the applicability of intumescent coatings as radiological contamination fixatives for stabilization of residual materials after decontamination efforts have concluded. Intumescent coatings are designed to prevent heat transfer to a protected substrate and are typically used in both the aerospace industry to protect components from thermal shock and in building design to protect building joints that may fail in the event of a fire. For this work, these materials are examined for their ability to reduce worker risk by fixating residual contamination and lower the impact of a release in a scenario that breaches containment of a contaminated building and subsequently induces a large-scale fire by crediting their fire-retardant attributes. Initial studies of intumescent coatings and commercial fixatives included performance in direct flame, varied environmental conditions (20-110 F or -6.67 C, 10-95% relative humidity), adhesion studies to stainless steel after curing in varied environmental conditions, and radiological exposure. Of all the materials tested, many were found to be inadequate in one or more of these areas. These materials failed in one or more of three characteristic ways: 1) through delamination at reduced temperatures (≤40 F or 4.44 C) or from even moderate handling, 2) melting off the substrate at elevated temperatures (≥90 F or 32.22 C), 3) proving to be flammable and promote smoke propagation. Failure in these ways results in the potential for a subsequent release of the fixated contamination in the event of water presence/absence or direct flame. Using these results as a platform for the best in class identified material that did not experience failure in any of these tests, SRNL and FIU targeted the plutonium-238 contaminated hot cells within Savannah River Site (SRS) Building 235-F as a characteristic test bed to benchmark an intumescent coating used as a contaminant fixative. Through discussion with the SRS 235-F Risk Reduction personnel, appropriate hazards and performance metrics were discussed and a cold demonstration was performed in a hot cell mockup located at SRS. The application methods were proven functional in the cold mock up, and these intumescent coatings were subsequently utilized in the Savannah River Site Building 235-F's Plutonium Fuel Form (PuFF) Facility to aid in stabilization of plutonium-238 in both a contaminated hot cell and Entry Hood in September 2018. Presented in this work is the overview of the application process, associated working considerations for introduction of equipment and materials into the facility, lessons learned, and lifetime monitoring data to date. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Selection and Assessment of Predictions of the Mars Pathfinder Landing Site

The successful landing of the Mars Pathfinder spacecraft on Mars allows the review of the process of selecting the landing site and assessing predictions made for the site based on Viking and Earth-based data. Selection of the landing site for Mars Pathfinder was a two-phase process. The first phase took place from October 1993 to June 1994 and involved: initial identification of engineering constraints, definition of environmental conditions at the site for spacecraft design, and evaluation of the scientific potential of different landing sites. This phase culminated with the first "Mars Pathfinder Landing Site Workshop", held at the Lunar and Planetary Institute in Houston, Texas on April 18-19, 1994, in which suggested approaches and landing sites were solicited from the entire scientific community. A preliminary site was selected by the project for design purposes in June 1994. The second phase took place from July 1994 to March 1996 and involved: developing criteria for evaluating site safety using images and remote sensing data, testing of the spacecraft and landing subsystems (with design improvements) to establish quantitative engineering constraints on landing site characteristics, evaluating all potential landing sites on Mars, and certification of the site by the project. This phase included a second open workshop, "Mars Pathfinder Landing Site Workshop II: Characteristics of the Ares Vallis Region and Field Trips in the Channeled Scabland, Washington" held in Spokane and Moses Lake September 24-30, 1995 and formal acceptance of the site by NASA Headquarters. Engineering constraints on Pathfinder landing sites were developed from the initial design of the spacecraft and the entry, descent and landing scenario. The site must be within 5 degrees of the subsolar latitude at the time of landing (15N for maximum solar power and flexible communications with Earth. It also must be below 0 km elevation to enable enough time for the parachute to bring the lander to the proper terminal velocity for landing. The entire landing ellipse, which is 70 km by 200 km due to navigational, ephemeris and atmospheric uncertainties, must be free of steep slopes, scarps and obvious hazards in Viking orbiter images, have acceptable radar reflectivity, moderate rock abundances and have little or no dust. Scientific considerations of the Mars Pathfinder payload and mission indicate that analyses of "grab bag" samples at the mouths of outflow channels can offer a first order assessment of a variety of rock types on Mars. Highland sites offer the advantage of in situ analysis of ancient rocks on Mars that record crustal differentiation and the nature of the early environment. Dark gray sites offer the potential of analyzing unweathered and unoxidized materials. Following a general assessment of the safety of different sites, a preliminary selection of a "grab bag" site was made. This site, Ares Vallis, is near the mouth of an outflow channel that may contain ancient Noachian terrain, Hesperian ridged plains, and reworked channel materials. All potential landing sites on Mars that met basic safety criteria were analyzed in detail. Sites (100 by 200 km target ellipses) were considered safe if they were below 0 km elevation, were free of obvious hazards (high relief surface features) in high-resolution (< 50 m/pixel) Viking orbiter images and had acceptable reflectivity and roughness at radar wavelengths, high thermal inertia, moderate rock abundance, low red to violet ratio, and low albedo. Only 4 sites on Mars met all the above criteria, which included 1995 opposition 3.5 cm delay-Doppler radar data. Complete data were evaluated for 7 sites and the Viking landing sites for comparison for all the above criteria as well as crater abundance, hill and mesa abundance, slopes over meter to kilometer scales, low altitude winds (from global circulation models and slopes), the size-frequency distribution of large rocks, as well as rover trafficability and science potential. Discussion of potential hazards at Ares Vallis using a variety of data sets (including radar) at a second open workshop, indicated this site cannot be shown to be any more hazardous than the Viking landing sites. Field trips to the Channeled Scabland and the Ephrata Fan, analogs for Ares Vallis and the landing site, respectively, provided valuable insight into possible geologic processes and potential surface characteristics. Three sites met all the data requirements and safety criteria for landing Pathfinder. Ares Vallis was selected by the project because it appeared acceptably safe (although it appeared to have greater rock abundances than other sites, its elevation was likely the best known) and offered the prospect of analyzing a variety of rock types expected to be deposited by catastrophic floods, which would enable addressing first-order scientific questions such as differentiation of the crust, the development of weathering products, and the nature of the early martian environment and its subsequent evolution. The selection was reviewed by an external board at a number of meetings and accepted, and the site was approved by NASA Headquarters. Data gathered by the Pathfinder lander' and rover provides the opportunity to test the predictions made for the site in the selection process based on remote observations from Earth, orbit, and the surface. The discussion below is taken from Golombek et al. to which the reader is referred for a more complete discussion and a complete list of references, which are omitted here for brevity. Many characteristics of the landing site are consistent with its being shaped and deposited by the Ares and Tiu catastrophic floods. The rocky surface is consistent a depositional plain comprising semi-rounded pebbles, cobbles and tabular boulders (some of which appear imbricated and/or inclined in the direction of flow) that appear similar to depositional plains in terrestrial catastrophic floods. The Twin Peaks appear to be streamlined hills in lander images, which is consistent with interpretations of larger hills in Viking orbiter images of the region that suggest the lander is on the flank of a broad, gentle ridge trending northeast from Twin Peaks. This ridge, which is the rise to the north of the lander, is aligned in the downstream direction from the Ares and Tiu Valles floods, and may be a debris tail deposited in the wake of the Twin Peaks. Channels visible throughout the scene may be a result of late stage drainage. As predicted by delay-Doppler radar measurements and tracking results, the average elevation of the center of the site was about the same as Viking Lander I relative to the 6.1 mbar geoid. The Doppler tracking and two-way ranging estimate for the elevation of the spacecraft is only 45 in lower than the Viking I Lander and within 100 in of that expected, which is within the uncertainties of the measurements. After landing, surface pressures and winds (5-10 m/s) were found to be similar to expectations based on Viking data, although temperatures were about 10 K warmer. The temperature profile below 50 km was also roughly 20 K warmer. As a result, predicted densities were 5% higher near the surface and up to 40% lower at 50 km but within the entry, descent and landing design margins. The populations of craters and small hills and the slopes of the hills measured in high-resolution (38 m/pixel) Viking orbiter images and the radar derived slopes of the landing site are all consistent with observations of these properties in the lander images. A rocky surface was expected from Viking Infra-Red Thermal Mapper (IRTM) observations and comparisons with the Viking landing sites. The observed cumulative fraction of area covered by rocks with diameters greater than 3 cm and heights greater than 0.5 in (potentially hazardous to landing) at Ares is similar to that predicted by IRTM observations and models of Viking lander and Earth analog rock size-frequency distributions. The IRTM prediction postulated an effective thermal inertia of 30 (10(exp -3) cgs units - cal/cubic cm/s(exp 0.5)/K) for the rock population, but we obtain a slightly different effective thermal inertia for the actual rock population. The validity of interpretations of radar echoes prior to landing are supported by a simple radar echo model, an estimate of the reflectivity of the soil from its bulk density, and the fraction of area covered by rocks. In the calculations, the soil produces the quasi-specular echo and the rocks produce the diffuse echo. The derived quasispecular cross section is comparable to the cross-sections and reflectivities reported for 3.5-cm wavelength observations. The model yields a diffuse echo that is modestly larger than the polarized diffuse echo reported for 3.5-cm wavelength observations. At 12.5-cm wavelength, similar rock populations at Ares and the Viking I site were expected because the diffuse echoes are comparable, but the large normal reflectivities suggests that bulk densities of the soils at depth are greater than those at the surface. We also obtain a fine-component inertia near 8.4 which agrees with the fine-component inertia of 8.7 (in 10(exp -3) cgs units) estimated from thermal observations from orbit by the IRTM; for this estimate, we used a bulk thermal inertia of 10.4 for the landing site, an effective thermal inertia near 40 (10(exp -3) cgs units) for the rock population, and a graphical representation of Kieffer's model. Color and albedo data for Ares suggested surfaces of materials at Ares Vallis would be relatively dust free or unweathered prior to landing compared with the materials at the Viking landing sites. This suggestion is supported by the abundance of relatively dark-gray rocks at Ares and their relative rarity at the Viking landing sites, where rocks are commonly coated with bright red dust. Finally, the 40 km long Ephrata Fan of the Channeled Scabland in Washington state, which was deposited where c

Golombek, M. P.↗

The Planetary Protection Strategy of the Earth Return Orbiter–Capture, Containment & Return System in the Context of the Mars Sample Return Campaign

The Mars Sample Return Campaign aims at bringing back to Earth the rock and atmospheric samples that the rover Perseverance has started to collect on the surface of Mars with the goal of analyzing them in a facility built specifically for this purpose to answer questions about the habitability of Mars. The Campaign consists of several missions, including the Earth Return Orbiter–Capture, Containment & Return System (ERO-CCRS), which will capture the samples previously put in Martian orbit, contain them in redundant containers to ensure that no unsterilized particles are released, and return them to Earth through a parachute-less entry vehicle. Both NASA and ESA policies address the United Nations’ Outer Space Treaty by addressing potential harm from material returned from solar system bodies beyond the Earth-Moon system. In the conduct of Mars Sample Return, the two agencies have agreed to apply approaches consistent with their own standards to campaign elements each provides. This work presents the overall strategy for both forward and backward planetary protection for the ERO-CCRS mission. Specifically, for forward planetary protection, CCRS is not required to meet specific bioburden requirements as a Category III mission provided the ERO (1) meets orbital lifetime requirements during orbiter operations and (2) any elements jettisoned at Mars meet orbital lifetime requirements. CCRS is required to be built in ISO-8 or better cleanrooms and, by agreement with ERO, be compatible with direct bioburden verification methods. For backward planetary protection, the overall approach includes building robust, highly reliable systems to prevent inadvertent release of unsterilized Mars material through redundant containment vessels and particle transport analyses. Ongoing work to define verification approaches and quantify containment assurance levels for specific sample return systems will also be discussed, along with how those data will inform launch approval for ERO-CCRS.

Giuseppe Cataldo↗

Refinery Perspective on Decarbonizing with Marine Biofuels

This work seeks to understand what biofuel production pathways a refinery might prefer to produce very low sulfur fuel oil (VLSFO) for marine applications. A comprehensive refinery optimization model was modified to allow for (1) direct blending of soy biodiesel, renewable diesel, Fischer-Tropsch diesel, and several pyrolysis oils and (2) indirect blending of all pyrolysis oils via co-processing in a fluidized catalytic cracker (FCC) and diesel hydrotreater into the marine fuel pool. Results showed that preferred pathways to bio-VLSFO production included co-processing low-quality pyrolysis oil in a FCC to blend the resulting biogenic light cycle oil, directly blending soy biodiesel, and directly blending small quantities of pyrolysis oil. Bio-VLSFO production costs were compared to those of fossil VLSFO subject to different marine fuel demands, benchmark crude oil prices, and biogenic fractions in the finished product. Given benchmark crude oil prices over 60 $/bbl, bio-VLSFO production appeared to be significantly cheaper than fossil VLSFO. Corresponding marginal abatement costs of CO 2 mostly ranging from -300 to 350 $/ton of CO 2 were also determined using a simplified but novel approach to allow for a comparison to other decarbonization strategies. In conclusion, this work indicates that low-sulfur contents in biofuels, relatively relaxed specifications for marine fuels, and current difficulties in meeting VLSFO specifications with crude oils can combine to make bio-VLSFO production cost-effective. Moreover, marine fuels appear to be a good entry point for refiners to start decarbonizing with biofuel pathways that could eventually be extended to other product pools.

09 BIOMASS FUELS↗

Trehalose Degradation by Cellvibrio japonicus Exhibits No Functional Redundancy and Is Solely Dependent on the Tre37A Enzyme

The α-diglucoside trehalose has historically been known as a component of the bacterial stress response, though it more recently has been studied for its relevance in human gut health and biotechnology development. The utilization of trehalose as a nutrient source by bacteria relies on carbohydrate-active enzymes, specifically those of the glycoside hydrolase family 37 (GH37), to degrade the disaccharide into substituent glucose moieties for entry into metabolism. Environmental bacteria using oligosaccharides for nutrients often possess multiple carbohydrate-active enzymes predicted to have the same biochemical activity and therefore are thought to be functionally redundant. In this study, we characterized trehalose degradation by the biotechnologically important saprophytic bacterium Cellvibrio japonicus This bacterium possesses two predicted α-α-trehalase genes, tre37A and tre37B, and our investigation using mutational analysis found that only the former is essential for trehalose utilization by C. japonicus Heterologous expression experiments found that only the expression of the C. japonicus tre37A gene in an Escherichia coli treA mutant strain allowed for full utilization of trehalose. Biochemical characterization of C. japonicus GH37 activity determined that the tre37A gene product is solely responsible for cleaving trehalose and is an acidic α-α-trehalase. Bioinformatic and mutational analyses indicate that Tre37A directly cleaves trehalose to glucose in the periplasm, as C. japonicus does not possess a phosphotransferase system. This study facilitates the development of a comprehensive metabolic model for α-linked disaccharides in C. japonicus and more broadly expands our understanding of the strategies that saprophytic bacteria employ to capture diverse carbohydrates from the environment. The metabolism of trehalose is becoming increasingly important due to the inclusion of this α-diglucoside in a number of foods and its prevalence in the environment. Bacteria able to utilize trehalose in the human gut possess a competitive advantage, as do saprophytic microbes in terrestrial environments. While the biochemical mechanism of trehalose degradation is well understood, what is less clear is how bacteria acquire this metabolite from the environment. The significance of this report is that by using the model saprophyte Cellvibrio japonicus, we were able to functionally characterize the two predicted trehalase enzymes that the bacterium possesses and determined that the two enzymes are not equivalent and are not functionally redundant. Here, the results and approaches used to understand the complex physiology of α-diglucoside metabolism from this study can be applied broadly to other polysaccharide-degrading bacteria.

59 BASIC BIOLOGICAL SCIENCES↗

Opportunities for Catalytic Reactions and Materials in Buildings

Residential and commercial buildings are responsible for over 30% of global final energy consumption and accounts for ~40% of annual direct and indirect greenhouse gas emissions. Energy efficient and sustainable technologies are necessary to not only lower the energy footprint but also lower the environmental burden. Many proven and emerging technologies are being pursued to meet the ever-increasing energy demand. Catalytic science has a significant new role to play in helping address sustainable energy challenges, particularly in buildings, compared to transportation and industrial sectors. Thermally driven heat pumps, dehumidification, cogeneration, thermal energy storage, carbon capture and utilization, emissions suppression, waste-to-energy conversion, and corrosion prevention technologies can tap into the advantages of catalytic science in realizing the full potential of such approaches, quickly, efficiently, and reliably. Catalysts can help increase energy conversion efficiency in building related technologies but must utilize low cost, easily available and easy-to-manufacture materials for large scale deployment. This entry presents a comprehensive overview of the impact of each building technology area on energy demand and environmental burden, state-of-the-art of catalytic solutions, research, and development opportunities for catalysis in building technologies, while identifying requirements, opportunities, and challenges.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Low-Density Aerodynamics of the Stardust Sample Return Capsule

The aerodynamics of the Stardust Sample Return Capsule are analyzed in the low- density, transitional flow regime using free-molecular, Direct Simulation Monte Carlo, Navier-Stokes, and Newtonian methods to provide inputs for constructing a transitional flow bridging relation. The accuracy of this bridging relation in reconstructing the aero- dynamic coefficients given by the more exact methods is presented for a range of flight conditions and vehicle attitudes. There is good agreement between the various prediction methods, and a simple sine-squared bridging relation is shown to provide a reasonably good description of the axial force, normal force, and pitching moment over a range of Knudsen numbers from 0.001 to 10. The predictions show a static instability of the Star- dust capsule in the free-molecular regime that persists well into the transitional flow. The addition of a thin disk to the base of the capsule is shown to remove this static instability. However, the extremely high entry velocity of 12.6 km/s for the proposed trajectory introduces difficult design issues for incorporating this disk caused by the high aerothermal loads that occur even under relatively rarefied conditions.

Wilmoth, Richard G.↗

Should We Believe Atmospheric Temperatures Measured by Entry Accelerometers Traveling at "Slow" Near-Sonic Speeds?

Mars Pathfinder's Accelerometer instrument measured an unexpected and large temperature inversion between 10 and 20 kilometer altitude. Other instruments have failed to detect similar temperature inversions. I test whether this inversion is real or not by examining what changes have to be made to the assumptions in the accelerometer data processing to obtain a more "expected" temperature profile. Changes in derived temperature of up to 30K, or 15%, are necessary, which correspond to changes in derived density of up to 25% and changes in derived pressure of up to 10%. If the drag coefficient is changed to satisfy this, then instead of decreasing from 1.6 to 1.4 from 20 kilometers to 10 kilometers, the drag coefficient must increase from 1.6 to 1.8 instead. If winds are invoked, then speeds of 60 meters per second are necessary, four times greater than those predicted. Refinements to the equation of hydrostatic equilibrium modify the temperature profile by an order of magnitude less than the desired amount. Unrealistically large instrument drifts of 0.5-1.0 meters per square second are needed to adjust the temperature profile as desired. However, rotational contributions to the accelerations may have the necessary magnitude and direction to make this correction. Determining whether this hypothesis is true will require further study of the rigid body equations of motion, with detailed knowledge of the positions of all six accelerometers. The paradox concerning this inversion is not yet resolved. It is important to resolve it because the paradox has some startling implications. At one extreme, are temperature profiles derived from accelerometers inherently inaccurate by 20K or more? At the other extreme, are RS temperature profiles inaccurate by this same amount?

Withers, Paul↗

Format reference for the Atlas of Neutron Resonances electronic files

The Atlas of Neutron Resonances is the direct successor to the vaunted BNL-325 series of references. The current Atlas is the culmination of the lifelong work of Said Mughabghab and within it Dr. Mughabghab strove to compile all known neutron resonances and related data. The current version of the Atlas is distributed in two volumes, covering isotopes with Z=1-60 in volume I and Z=61-104 in volume II. The Atlas is organized into two parts, a general reference for all things related to neutron resonance physics and listings of parameters for each element and/or isotope. The general reference is repeated in each volume. The individual elements and/or isotope listings contain a list of thermal cross section data, resonance properties, lists of resonance parameters for each isotope (and occasionally for elements in the event that resonances could not be attributed to individual isotopes) and an extensive bibliography. The entries of the Atlas are derived from two sets of files: txsrp files: these files contain listings of thermal properties, resonance properties, bibliographic references and coding that defines the columns in the corresponding cftma file. cfmta files: these files contain a list of compiled resonance parameters. There is one txsrp and one cfmta file for each element.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

NASA Pioneer: Venus reverse playback telemetry program TR 78-2

During the entry of the Pioneer Venus Atmospheric Probes into the Venus atmosphere, there were several events (RF blackout and data rate changes) which caused the ground receiving equipment to lose lock on the signal. This caused periods of data loss immediately following each one of these disturbing events which lasted until all the ground receiving units (receiver, subcarrier demodulator, symbol synchronizer, and sequential decoder) acquired lock once more. A scheme to recover these data by off-line data processing was implemented. This scheme consisted of receiving the S band signals from the probes with an open loop reciever (requiring no lock up on the signal) in parallel with the closed loop receivers of the real time receiving equipment, down converting the signals to baseband, and recording them on an analog recorder. The off-line processing consisted of playing the analog recording in the reverse direction (starting with the end of the tape) up, converting the signal to S-band, feeding the signal into the "real time" receiving system and recording on digital tape, the soft decisions from the symbol synchronizer.

Modestino, J. W.↗

Galileo Probe Measurements of Thermal and Solar Radiation Fluxes in the Jovian Atmosphere

The Galileo probe net flux radiometer (NFR) measured radiation fluxes in Jupiter's atmosphere from about 0.44 to 14 bars, using five spectral channels to separate solar and thermal components. Onboard calibration results confirm that the NFR responded to radiation approximately as expected. NFR channels also responded to a superimposed thermal perturbation, which can be approximately removed using blind channel measurements and physical constraints. Evidence for the expected NH3 cloud was seen in the spectral character of spin-induced modulations of the direct solar beam signals. These results are consistent with an overlying cloud of small NH3 ice particles (0.5-0.75 microns in radius) of optical depth 1.5-2 at 0.5 microns. Such a cloud would have so little effect on thermal fluxes that NFR thermal channels provide no additional constraints on its properties. However, evidence for heating near 0.45 bar in the NFR thermal channels would seem to require either an additional opacity source beyond this small-particle cloud, implying a heterogeneous cloud structure to avoid conflicts with solar modulation results, or a change in temperature lapse rate just above the probe measurements. The large thermal flux levels imply water vapor mixing ratios that are only 6% of solar at 10 bars, but possibly increasing with depth, and significantly subsaturated ammonia at pressures less than 3 bars. If deep NH3 mixing ratios at the probe entry site are 3-4 times ground-based inferences, as suggested by probe radio signal attenuation, then only half as much water is needed to match NFR observations. No evidence of a water cloud was seen near the 5-bar level. The 5-microns thermal channel detected the presumed NH4SH cloud base near 1.35 bars. Effects of this cloud were also seen in the solar channel upflux measurements but not in the solar net fluxes, implying that the cloud is a conservative scatterer of sunlight. The minor thermal signature of this cloud is compatible with particle radii near 3 gm, but it cannot rule out smaller particles. Deeper than about 3 bars, solar channels indicate unexpectedly large absorption of sunlight at wavelengths longer than 0.6 microns, which might be due to unaccounted-for absorption by NH3 between 0.65 and 1.5 microns.

Sromovsky, L. A.↗