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At least 829 records · Page 46

Soil type and texture impacts on soil organic carbon accumulation in a sub-tropical agro-ecosystem

Soil organic carbon (C) plays a fundamental role in tropical and subtropical soil fertility, agronomic productivity, and soil health. As a tool for understand ecosystems dynamics, mathematical models such as Century have been used to assess soil's capacity to store C in different environments. However, as Century was initially developed for temperate ecosystems, several authors have hypothesized that C storage may be underestimated by Century in Oxisols. We tested the hypothesis that Century model can be parameterized for tropical soils and used to reliably estimate soil organic carbon (SOC) storage. The aim of this study was to investigate SOC storage under two soil types and three textural classes and quantify the sources and magnitude of uncertainty using the Century model. The simulation for SOC storage was efficient and the mean residue was 10 Mg C ha -1 (13%) for n = 91. However, a different simulation bias was observed for soil with <600 g kg -1 of clay was 16.3 Mg C ha -1 (18%) for n = 30, and at >600 g kg -1 of clay, was 4 Mg C ha -1 (5%) for n = 50, respectively. The results suggest a non-linear effect of clay and silt contents on C storage in Oxisols. All types of soil contain nearly 70% of Fe and Al oxides in the clay fraction and a regression analysis showed an increase in model bias with increase in oxides content. Consequently, inclusion of mineralogical control of SOC stabilization by Fe and Al (hydro) oxides may improve results of Century model simulations in soils with high oxides contents

Century model↗

Combined effects of temperature and precipitation on soil organic carbon changes in the uplands of eastern China

Temperature and precipitation simultaneously influence soil organic carbon (SOC) in agroecosystems. While their individual impacts have been extensively studied, their combined effects remain poorly understood at a regional scale. This study quantified the combined influence of temperature and precipitation on SOC in upland-crop fields of northern Jiangsu Province in eastern China. We used the DeNitrification-DeComposition (DNDC, version 9.5) model with the currently most detailed upland soil database in China. This 1:50,000 soil database contains 17,024 upland soil polygons that were generated using 983 upland soil profiles. Model simulations indicated that under a combined scenario of rising air temperature (T) of 2 °C and a simultaneous decrease (or increase) in precipitation (P) by 20%, the 3.93 Mha of upland soils in the study region sequestered 39.10 (or 37.39) Tg C from 2010-2039. The C sequestration from the combined effects of T and P on SOC was 2.40 (or 2.12) Tg C less, relative to the sum of the amount produced from the individual effect. Moreover, if the increase in T changed from 2 °C to 4 °C, with P still decreasing (or increasing) by 20%, the C sequestration further decreased by 1.2 (or 1.68) Tg C. Our analysis of the combined effects of T and P on SOC changes suggests that future warming and P change in this region may have a negative influence on SOC sequestration, despite the upland agroecosystems serve as a long-term sink for atmospheric CO2. Furthermore, SOC changes in different upland soil groups and administrative areas varied widely due to the heterogeneity in soil properties and fertilizer applications. This emphasizes the importance of detailed soil datasets and the need to adopt on-farm management practices to different soil groups and administrative areas under future climate change.

Zhang, Liming↗

Techno-economic analysis and life cycle assessment for electrochemical ammonia production using proton conducting membrane

Green ammonia production is facing increasing interest on a global scale as a hydrogen carrier for power generation as well as fertilizer for food production. The conventional Haber-Bosch method for ammonia synthesis is energy demanding, requires high purity hydrogen, and is based on fossil fuels. A preliminary techno-economic model for electrochemical ammonia synthesis at near ambient pressure using feed rates of 32 metric ton/day for hydrogen and 135 metric ton/day for nitrogen is presented in this study. Various pathways using different methods for nitrogen generation and hydrogen production were investigated to gain insight into added energy savings per metric ton of ammonia. Electrochemical synthesis using electrolysis for hydrogen and cryogenic nitrogen was found to be a potentially viable pathway for green ammonia. The profitability metrics including discounted cash flow rate of return, net present value and discounted payback period were estimated to be 8%, $40 MM, and 4–6 years respectively for this pathway. The cost of electricity, conversion rate, and conversion efficiency dominate the tonnage cost of ammonia and were used to assess the feasibility of the model. A life cycle assessment was also conducted to assess the environmental impact of a well to product ammonia process.

08 HYDROGEN↗

Persistent DNA Damage in Spermatogonial Stem Cells After Fractionated Low-Dose Irradiation of Testicular Tissue

Purpose: Testicular spermatogenesis is extremely sensitive to radiation-induced damage, and even low scattered doses to testis from radiation therapy may pose reproductive risks with potential treatment-related infertility. Radiation-induced DNA double-strand breaks (DSBs) represent the greatest threat to the genomic integrity of spermatogonial stem cells (SSCs), which are essential to maintain spermatogenesis and prevent reproduction failure. Methods and Materials: During daily low-dose radiation with 100 mGy or 10 mGy, radiation-induced DSBs were monitored in mouse testis by quantifying 53 binding protein 1 (53BP-1) foci in SSCs within their stem cell niche. The accumulation of DSBs was correlated with proliferation, differentiation, and apoptosis of testicular germ cell populations. Results: Even very low doses of ionizing radiation arrested spermatogenesis, primarily by inducing apoptosis in spermatogonia. Eventual recovery of spermatogenesis depended on the survival of SSCs and their functional ability to proliferate and differentiate to provide adequate numbers of differentiating spermatogonia. Importantly, apoptosis-resistant SSCs resulted in increased 53BP-1 foci levels during, and even several months after, fractionated low-dose radiation, suggesting that surviving SSCs have accumulated an increased load of DNA damage. Conclusions: SSCs revealed elevated levels of DSBs for weeks after radiation, and if these DSBs persist through differentiation to spermatozoa, this may have severe consequences for the genomic integrity of the fertilizing sperm.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Facile All-Optical Method for In Situ Detection of Low Amounts of Ammonia

As a key precursor for nitrogenous compounds and fertilizer, ammonia affects our lives in numerous ways. Rapid and sensitive detection of ammonia is essential, both in environmental monitoring and in process control for industrial production. Here we report a novel and nonperturbative method that allows rapid detection of ammonia at low concentrations, based on the all-optical detection of surface-enhanced Raman signals. We show that this simple and affordable approach enables ammonia probing at selected regions of interest with high spatial resolution, making in situ and operando observations possible.

09 BIOMASS FUELS↗

Best practices in catalysis: A perspective

Catalysis, from its roots in petrochemical refining and conversion, has emerged as a transdisciplinary field that now encompasses synthesis of materials and molecules that enable applications in energy conversion and storage, environmental remediation, medicine, plastics, and fertilizer production, among numerous others. A handful of disciplines can claim relevance and success over such an extended period of time and continue to claim a preeminent role in defining the state-of-the-art in science and technology. Syncretic and rapid advancements in formulation and spectroscopic characterization of materials and molecules useful as catalysts, high-level density functional and molecular orbital theory calculations, and a strong foundation in concepts of physical chemistry, thermodynamics, and chemical kinetics offer new and abundant opportunities at the present day for addressing the grand challenge of controlling chemical transformations using catalysis. Here, we examine what we have learned of concepts that underpin heterogeneous catalysis but more importantly, how we learned to archive our knowledge in context of a set of best practices and standards that have emerged in the course of our learnings—ones we seek to highlight herein. Our perspective emphasizes concepts in synthesis, characterization, kinetics, and theory, because these four elements combined enable description of molecular acts that happen on surfaces and how fast they occur. In revisiting best practices in heterogeneous catalysis in these sub-fields and in authorship and peer review we aspire to augment clarity, reproducibility, and rigor in the science and practice of catalysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Yearlong semi-continuous operation of thermophilic two-stage anaerobic digesters amended with biochar for enhanced biomethane production

This study aimed to scale up an integrated waste-to-energy system for producing pipelinequality biomethane from shake flasks experiments to two-stage digester systems with semicontinuous operation. The yearlong operation was successfully conducted to compare the performance of thermophilic anaerobic digestion (AD) of sewage sludge amended with corn stover biochar (CSBC) and pine biochar (PBC) to the control under various conditions. Both CSBC and PBC promoted the substrate utilization, methane productivity, and process stability of AD, while CSBC showed superior potential. CSBC enhanced methane content in biogas (CH 4 %) and methane production rate (P CH$_4$ ) by up to 25% and 37% respectively in comparison to the control, with maximum CH 4 % of 95% and CH 4 yield of 0.34 L/g volatile solid (VS)-added being achieved at steady state. The biochar supplementation also led to a substantial increase of the macro- and micro-nutrients (P, K, Ca, Mg, Fe) by up to 33 times in the digestate, increasing its fertilizer value. Finally, microbial community structure and dynamics were also investigated and compared, and in particular, CSBC promoted the abundance of Clostridia and Methanosarcina. Collectively, this study proves that pyro-biochar as an effective additive material enhances AD performance with continuous operation and that CSBC shows greater potential.

54 ENVIRONMENTAL SCIENCES↗

A multi-product landscape life-cycle assessment approach for evaluating local climate mitigation potential

Increasing demand for land-based climate mitigation requires more efficient management of agricultural landscapes for competing objectives. Here we develop methods for assessing trade-offs and synergies between intensification and carbon-sequestering conservation measures in annual crop production landscapes using the DayCent ecosystem model and the Greenhouse Gases, Regulated Emissions, and Energy Use in Technologies (GREET) life-cycle assessment (LCA) model. We compiled county-scaled crop yields, fertilizer application rates, and tillage intensity for a corn–soybean farming case study landscape in the US state of Iowa. Using DayCent, we estimated a baseline soil organic carbon (SOC) accrual rate of 0.29 Mg C ha -1 y -1 driven by historical increases in crop productivity and reductions in tillage intensity. We then simulated the effects of management interventions targeted toward intensification (stover removal) and SOC sequestration (tillage intensity reduction and winter cover crop addition) individually and in combination. We propose a new multi-product landscape–LCA approach that analyzes marginal changes in corn grain, corn stover, and soybean production from the landscape in terms of their value for biofuel production (corn ethanol, soy biodiesel, and cellulosic ethanol from stover) and associated net displacement of conventional fossil-derived fuel use. This enables us to evaluate both intensification and sequestration effects in common CO 2 -equivalent mitigation units. We also used DayCent-simulated yields under the different land management scenarios to estimate farm-level costs and revenues. Our results show that intensification via collecting 30% of corn stover for biofuel production would increase the total greenhouse gas (GHG) mitigation potential of this landscape by 0.93 Mg CO 2 e ha -1 y -1 and provide $49 ha -1 y -1 of additional net revenue from biomass sales, but would reduce the baseline SOC accumulation rate by approximately 40%. In contrast, integrated approaches that include co-adoption of winter cover cropping and/or tillage intensity reduction would result in increased rates of SOC accumulation above the baseline, achieving simultaneous improvements in both farm profits and the overall GHG mitigation potential of the landscape.

54 ENVIRONMENTAL SCIENCES↗

Estimation of abatement potentials and costs of air pollution emissions in China

Understanding the air pollution emission abatement potential and associated control cost is a prerequisite to design cost ef?cient control policies. In this study, a linear programming algorithm model, International Control Cost Estimate Tool, was updated with cost data for applications of 56 types of end-of-pipe technologies and ?ve types of renewable energy in 10 major sectors namely power generation, industry combustion, cement pro-duction, iron and steel production, other industry processes, domestic combustion, transportation, solvent use, livestock rearing, and fertilizer use. The updated model was implemented to estimate the abatement potential and marginal cost of multiple pollutants in China. The total maximum abatement potentials of sulfur dioxide (SO2), nitrogen oxides (NOx), primary particulate matter (PM2.5), non-volatile organic compounds (NMVOCs), and ammonia (NH3) in China were estimated to be 19.2, 20.8, 9.1, 17.2 and 8.6 Mt, respectively, which accounted for 89.7%, 89.9%, 94.6%, 74.0%, and 80.2% of their total emissions in 2014, respectively. The associated control cost of such reductions was estimated as 92.5, 469.7, 75.7, 449.0, and 361.8 billion CNY in SO2, NOx, primary PM2.5, NMVOCs and NH3, respectively. Shandong, Jiangsu, Henan, Zhejiang, and Guangdong provinces exhibited large abatement potentials for all pollutants. Provincial disparity analysis shows that high GDP regions tend to have higher reduction potential and total abatement costs. End-of-pipe technologies tended be a cost-ef?cient way to control pollution in industries processes (i.e., cement plants, iron and steel plants, lime production, building ceramic production, glass and brick production), whereas such technologies were less cost- effective in fossil fuel-related sectors (i.e., power plants, industry combustion, domestic combustion, and transportation) compared with renewable energy. The abatement potentials and marginal abatement cost curves developed in this study can further be used as a crucial component in an integrated model to design optimized cost-ef?cient control policies.

Zhang, Fenfen↗

Effects of residue removal and tillage on greenhouse gas emissions in continuous corn systems as simulated with RZWQM2

Agricultural production is a major source of carbon dioxide (CO 2 ) and nitrous oxide (N 2 O) globally. The effects of conservation practices on soil CO 2 and N 2 O emissions remain a high degree of uncertainty. In this study, soil CO 2 and N 2 O emissions under different residue and tillage practices in an irrigated, continuous corn system, were investigated using the Root Zone Water Quality Model (RZWQM2). Combinations of no/high stover removal (NR and HR, respectively) and no-till/conventional tillage (NT and CT, respectively) field experiments were tested over the four crop-years (Apr. 2011–Apr. 2015). The model was calibrated using the NRCT, and validated with other treatments. The simulation results showed that soil volumetric water content (VWC) in the NR treatments (i.e., NRCT and NRNT) was 1.3%–1.9% higher than that in the HR treatments (i.e., HRCT and HRNT) averaged across the four years. A higher amount of CO 2 and N 2 O emissions were simulated in the NRCT across the four years (annual average: 7034 kg C/ha/yr for CO 2 and 3.8 kg N/ha/yr for N 2 O), and lower emissions were in the HRNT (annual average: 6329 kg C/ha/yr and 3.7 kg N/ha/yr for N 2 O). A long-term simulation (2001–2015) suggested that the CO 2 and N 2 O emissions were closely correlated with the stover removal degree (SRD), tillage, VWC, soil temperature (ST), years in management (Y), and fertilizer application. Stover and tillage practices had cumulative effects on CO 2 emissions. The simulated annual CO 2 emissions in 1st year from NRCT, NRNT, and HRCT were 7.8%, 0.0%, and 7.7% higher than that from HRNT, respectively; then the emissions in 15th year were 63.6%, 47.7%, and 29.1% higher, respectively. Meanwhile, there were no cumulative effects on N 2 O emissions. Furthermore, the results also demonstrated that the RZWQM2 is a promising tool for evaluating the long-term effects of CO 2 and N 2 O emissions on different conservation practices.

54 ENVIRONMENTAL SCIENCES↗

Electrochemical sulfate production from sulfide-containing wastewaters and integration with electrochemical nitrogen recovery

Electrochemical methods can help manage sulfide in wastewater, which poses environmental and health concerns due to its toxicity, malodor, and corrosiveness. In addition, sulfur could be recovered as fertilizer and commodity chemicals from sulfide-containing wastewaters. Wastewater characteristics vary widely among wastewaters; however, it remains unclear how these characteristics affect electrochemical sulfate production. Here, in this study, we evaluated how four characteristics of influent wastewaters (electrolyte pH, composition, sulfide concentration, and buffer strength) affect sulfide removal (sulfide removal rate, sulfide removal efficiency) and sulfate production metrics (sulfate production rate, sulfate production selectivity). We identified that electrolyte pH (3 × difference, i.e., 25.1 to 84.9 μM h –1 in average removal rate within the studied pH range) and sulfide concentration (16 × difference, i.e., 82.1 to 1347.2 μM h –1 in average removal rate) were the most influential factors for electrochemical sulfide removal. Sulfate production was most sensitive to buffer strength (6 × difference, i.e., 4.4 to 27.4 μM h –1 in average production rate) and insensitive to electrolyte composition. Together, these results provide recommendations for the design of wastewater treatment trains and the feasibility of applying electrochemical methods to varying sulfide-containing wastewaters. In addition, we investigated a simultaneous multi-nutrient (sulfur and nitrogen) process that leverages electrochemical stripping to further enhance the versatility and compatibility of electrochemical nutrient recovery.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Predicting the climate change impacts on water-carbon coupling cycles for a loess hilly-gully watershed

Understanding the climate change impacts on water and carbon cycles is of great importance for comprehensive watershed management. Although many studies have been conducted on the future climate change impacts on either water cycle or carbon cycle, the potential impacts on water-carbon coupling cycles are still poorly understood. Here we used an integrated hydro-biochemical model (SWAT-DayCent) to quantitatively investigate the climate change impacts on water-carbon coupling cycles with a case study of typical loess hilly-gully watershed-the Jinghe River Basin (JRB) on the Loess Plateau. We used climate scenarios data derived under the three Representative Concentration Pathways (RCPs2.6, 4.5 and 8.5) by five downscaled Global Circulation Models (GCMs) and set two future periods of 2020–2049 (near future, NF) and 2070–2099 (far future, FF). It was projected that the annual precipitation would generally decrease slightly during the NF period but increase by 4–11% during the FF period, while the maximum/minimum air temperatures would increase significantly. The average annual streamflow would decrease (with up to 20.1% under RCP8.5) and evapotranspiration (ET) would remain almost unchanged during the NF period; however, both of them would increase during the FF period. The net primary production (NPP) would be generally higher due to the CO2 fertilization, whereas the soil organic carbon would decrease across all scenarios due to the warmer climate. The NPP-ET was projected to be closely coupled across all scenarios, and this coupling was mainly controlled by the inter-annual variability (IAV) of precipitation. Moreover, the precipitation IAV combined with NPP-ET coupling could also jointly control the NPP variability in the JRB. These projections in water-carbon coupling cycles can be useful to make better-informed decisions for future water resources and ecosystem management of the loess hilly-gully regions.

climate change↗

Draft Genome Sequence of Mentha longifolia and Development of Resources for Mint Cultivar Improvement

The genus Mentha encompasses species cultivated for their essential oils, which are formulated into a vast array of consumer products. Desirable oil characteristics and resistance to the fungal disease Verticillium wilt are top priorities for the mint industry. However, cultivated mints have complex polyploid genomes and are sterile. Breeding efforts, therefore, require the development of genomic resources for fertile mint species. Here, we present draft de novo genome and plastome assemblies for a wilt-resistant South African accession of Mentha longifolia (L.) Huds., a diploid species ancestral to cultivated peppermint and spearmint. The 353 Mb contained 35,597 predicted protein-coding genes, including 292 disease resistance gene homologs, and nine genes determining essential oil characteristics. A genetic linkage map ordered 1,397 genome scaffolds on 12 pseudochromosomes. Over two million simple sequence repeats were identified, which will aid molecular marker development. The M. longifolia genome is a valuable resource for both metabolic engineering and molecular breeding. This is exemplified by employing the genome sequence to clone and functionally characterize promoters in a peppermint cultivar, and demonstrating the utility of a glandular trichome-specific promoter to increase expression of a biosynthetic gene, thereby modulating essential oil composition.

Aromatic Plant, Essential Oil, Genome, Mint, Verti↗

Metal-organic framework-derived nitrogen-doped highly disordered carbon for electrochemical ammonia synthesis using N 2 and H 2 O in alkaline electrolytes

Ammonia (NH 3 ) is considered an important chemical for both agriculture fertilizer and renewable energy. The conventional Haber-Bosh process to produce NH 3 is energy intensive and leads to significant CO 2 emission. Alternatively, electrochemical synthesis of ammonia (ESA) through the nitrogen reduction reaction (NRR) by using renewable electricity has recently attracted significant attention. Herein, we report a metal-organic framework-derived nitrogen-doped nanoporous carbon as an electrocatalyst for the NRR. It exhibits a remarkable production rate of NH 3 up to 3.4 ×10 –6 mol cm –2 h –1 with a Faradaic efficiency (FE) of 10.2% at –0.3 V vs . RHE under room temperature and ambient pressure using aqueous 0.1 M KOH electrolyte. Increasing the temperature to 60 °C further improves production rates to 7.3 × 10 –6 mol cm –2 h –1 . The stability of the nitrogen-doped carbon electrocatalyst was demonstrated during an 18-h continuous test with constant production rates. First principles calculations were used to elucidate the possible active sites and reaction pathway. The moiety, which consists of three pyridinic N atoms (N 3 ) adjacent with one carbon vacancy embedded in a carbon layer, is able to strongly adsorb N 2 and further realize N≡N triple bond dissociation for the subsequent protonation process. The rate-determining step of the NRR is predicted to be the adsorption and bond activation of N 2 molecule. Increasing overpotentials is favorable for the protonation process during NH 3 generation. Further doping Fe into the nitrogen-doped carbon likely blocks the N 3 active sites and facilitates the hydrogen evolution reaction, a strong competitor to the NRR, thus yielding negative effect on ammonia production. Furthermore, this work provides a new insight into the rational design and synthesis of nitrogen-doped and defect-rich carbon as efficient NRR catalysts for NH 3 synthesis at ambient conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

High-throughput screening to predict highly active dual-atom catalysts for electrocatalytic reduction of nitrate to ammonia

Ammonia is an essential chemical owing to its importance in fertilizer production and other industrial applications. Electrocatalytic nitrate reduction to ammonia (NO 3 RR) holds great promise for low-temperature ammonia production while simultaneously addressing nitrate-based environmental concerns. To provide the mechanistic understanding needed to design an effective electrocatalyst, we systematically investigated the catalytic performance of metal-based dual-atom catalysts (DACs) anchored on two-dimensional (2D) expanded phthalocyanine (Pc) for NO 3 RR. We found that NO 3 RR can efficiently produce ammonia on Cr 2 -Pc, V 2 -Pc, Ti 2 -Pc, and Mn 2 -Pc surfaces with low limiting potentials of – 0.02, – 0.25, – 0.34, and – 0.41 V RHE , respectively. Moreover, using the free energy difference of *NO 3 - and *H as a descriptor, we found that the hydrogen evolution reaction is significantly suppressed on the DAC surface due to an ensemble effect in which the two metal atoms cooperate to selectively form ammonia. We performed high-throughput screening to develop an efficient metal-based DAC for NO 3 - reduction, followed by a mechanistic study to elucidate the NO3RR pathway on the DAC. Finally, this work provides design information for advancing sustainable ammonia synthesis under ambient conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Sensitivity of the active neutron coincidence collar response during simulated and experimental fresh fuel assay

Verification of the fissile (and fertile) content in fresh nuclear fuel assemblies is conducted by the IAEA to enforce the Nuclear Non-Proliferation Treaty using the UNCL (Uranium Neutron Collar — Light Water Reactor Fuel). The UNCL uses an uncorrelated AmLi neutron source to interrogate the fuel, producing a signal of coincident fission neutrons (Doubles rate) used to assay 235 U content of the fuel. The cost of producing calibration assemblies and limited availability of diverse commercial assemblies at any one time historically restricted the ability to explore the full parameter space experimentally. Monte Carlo simulations can overcome this, but introduce additional sources of uncertainty. In this work, the sensitivity of simulations and measurements to various parameters is assessed for a reference 1616 PWR assembly of uniform 3.2% enrichment. Uncertainty contributions in this evaluation include: simulated AmLi neutron source spectrum, AmLi neutron emission rate, AmLi anisotropicity, high density polyethylene (HDPE) density, the precise position of the fuel assembly within the detector, and experimentally the statistical uncertainty. The overall total systematic uncertainty estimate for the simulation of the absolute/relative Doubles rates responses are estimated to be approximately 2.0%/1.5%, and for experimental measurements systematic uncertainty reduces to 1.1%. This analysis supports further work using the relative Doubles rates in place of measurements for updating and extending the UNCL analysis methodology as systematic uncertainty is reasonably small.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Antinuclei in heavy-ion collisions

Here, we review progress in the study of antinuclei, starting from Dirac's equation and the discovery of the positron in cosmic-ray events. The development of proton accelerators led to the discovery of antiprotons, followed by the first antideuterons, demonstrating that antinucleons bind into antinuclei. With the development of heavy-ion programs at the Brookhaven AGS and CERN SPS, it was demonstrated that central collisions of heavy nuclei offer a fertile ground for research and discoveries in the area of antinuclei. In this review, we emphasize recent observations at Brookhaven's Relativistic Heavy Ion Collider and at CERN's Large Hadron Collider, namely, the antihypertriton and the antihelium- 4, as well as measurements of the mass difference between light nuclei and antinuclei, and the interaction between antiprotons. Physics implications of the new observations and different production mechanisms are discussed. We also consider implications for related fields, such as hypernuclear physics and spacebased cosmic-ray experiments.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Novel ammonia recovery from anaerobic digestion by integrating biogas stripping and gypsum absorption

Recovering ammonia from anaerobic digestion (AD) effluent offers the opportunity to produce a renewablefertilizer and reduce environmental impact. A novel process developed for such an application was evaluatedduring this study. The feature of the process is integrating biogas stripping and gypsum (CaSO 4 •2H 2 O) absorption. The result revealed that the lower CO 2 content and the absorption temperature contributed the higherefficiency of ammonia recovery. The gypsum solution recovered around 95% of the stripped ammonia when thestripping gas contained 10% CO 2 and it rose to 100% when the gas contained more than 30% CO 2 . Furthermore,a statistical model and genetic algorithm were applied to estimate the total ammonia recovery and optimize theoperating parameters. The experimental and modeling results indicated that integrating biogas stripping withgypsum absorption can effectively harvest ammonia nitrogen and reduce CO 2 emissions while producing(NH 4 ) 2 SO 4 fertilizer from AD effluent.

59 BASIC BIOLOGICAL SCIENCES↗