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At least 829 records · Page 46

Preliminary Two-Phase Terry Turbine Nozzle Models for RCIC Off-Design Operation Conditions

This report presents the effort to extend the single-phase analytical Terry turbine model to cover two-phase off-design conditions. The work includes: (1) adding well-established two-phase choking models – the Isentropic Homogenous Equilibrium Model (IHEM) and Moody’s model, and (2) theoretical development and implementation of a two-phase nozzle expansion model. The two choking models provide bounding cases for the two-phase choking mass flow rate. The new two-phase Terry turbine model uses the choking models to calculate the mass flow rate, the critical pressure at the nozzle throat, and steam quality. In the divergent stage, we only consider the vapor phase with a similar model for the single-phase case by assuming that the liquid phase would slip along the wall with a much slower speed and will not contribute the impulse on the rotor. We also modify the stagnation conditions according to two-phase choking conditions at the throat and the cross-section areas for steam flow at the nozzle throat and at the nozzle exit. The new two-phase Terry turbine model was benchmarked with the same steam nozzle test as for the single-phase model. Better agreement with the experimental data is observed than from the single-phase model. We also repeated the Terry turbine nozzle benchmark work against the Sandia CFD simulation results with the two-phase model for the pure steam inlet nozzle case. The RCIC start-up tests were simulated and compared with the single-phase model. Similar results are obtained. Finally, we designed a new RCIC system test case to simulate the self-regulated Terry turbine behavior observed in Fukushima accidents. In this test, a period inlet condition for the steam quality varying from 1 to 0 is applied. For the high quality inlet period, the RCIC system behaves just like the normal operation condition with a high pump injection flow rate and a nominal steam release rate through the turbine, with the net addition of water to the primary system; for the low quality inlet period, the RCIC turbine shaft work dramatically decreases and results in a much reduced pump injection flow rate, and the mixture flow rate through the turbine increases due to the high liquid phase flow rate. The net effect for this period is net removal of coolant from the primary loop. With the periodic addition and removal of coolant to the primary loop, the self-regulation mode of the RCIC system can be maintained for a quite long time. Both the IHEM and Moody’s models generate similar phenomena; however noticeable differences can be observed.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Predictive LES Modeling and Validation of High-Pressure Turbulent Flames and Flashback in Hydrogen-enriched Gas Turbines

The overall objective of this project is to make advances in large-eddy simulation modeling of swirl-flame flashback at elevated pressure, where the reactants can be premixed or stratified, and composed of methane enriched with hydrogen. The modeling effort was conducted with a companion experimental validation effort that focused on high-speed measurements of flashback in a model swirl-flame combustor. The modeling effort focused on the development of manifold-based combustion model for flashback simulations. The main complexity in this configuration comes from the flames’ propagation through a stratified fuel-air mixture along with heat loss near the walls. For this purpose, a non-adiabatic flamelet model was developed and tested using canonical flow configurations. Further, extensive validation in premixed configurations is used to establish the model’s accuracy in capturing heat loss and flame propagation. Finally, the model was tested using the UT flame flashback experiment, and was shown to accurately capture the flame flashback process. The end products from this work are a) a full validated flameout-based approach for modeling flame flashback; b) a complete implementation of the model in the open source OpenFOAM framework, which has been made available to both industry and academia; c) an extensive suite of validation studies performed using the OpenFOAM solver. In addition, new techniques for flame modeling, subfilter modeling of scalars, and simulation of low Mach number flows were developed and tested. In the experimental validation effort, flashback was studied in a premixed and stratified swirl flame by using high-speed imaging diagnostics. Fuels tested included CH 4 enriched with H 2 , with H 2 enrichment up to 84% by volume. These flashback experiments are conducted at pressures ranging from 1 to 5 atm. A swirler-based fuel-injection system was used to create the fuel-air stratification in the radial direction. For the high-pressure measurements, an optically accessible elevated pressure chamber was used. The spatial distribution of the equivalence ratio under non-reacting conditions was characterized using planar laser-induced fluorescence with acetone as the fuel tracer. It was observed that fuel-air pockets were distributed across the mixing tube width, although in an average sense, the fuel-air mixture was radially stratified. The global behavior of upstream flame propagation was investigated for different levels of hydrogen-enrichment. For stratified hydrogen-rich flashback, the propagation path of the flame changed from the inner wall to outer wall, which was induced by the faster chemistry of stoichiometric mixtures that are frequently present near the outer wall. This behavior of hydrogen-rich flashback persists even at elevated pressures up to 5 atm, although the propagation of the flame occurs as a wide flame tongue as opposed to the acute-tipped flame structures present in the atmospheric cases. The end product of the experimental effort is greatly improved knowledge of flashback physics and a unique database that can be used for model validation.

08 HYDROGEN↗

A Qualitative Strategy for Fusion of Physics into Empirical Models for Process Anomaly Detection

To facilitate the automated online monitoring of power plants, a systematic and qualitative strategy for anomaly detection is presented. This strategy is essential to provide credible reasoning on why and when an empirical versus hybrid (i.e., physics-supported) approach should be used and to determine the ideal mix of these two approaches for a defined anomaly detection scope. Empirical methods are usually based on pattern, statistical, and causal inference. Hybrid methods include the use of physics models to train and test data methods, reduce data dimensionality, reduce data-model complexity, augment data, and reduce empirical uncertainty; hybrid methods also include the use of data to tune physics models. The presented strategy is driven by key decision points related to data relevance, simple modeling feasibility, data inference, physics-modeling value, data dimensionality, physics knowledge, method of validation, performance, data availability, and suitability for training and testing, cause-effect, entropy inference, and model fitting. The strategy is demonstrated through a pilot use case for the application of anomaly detection to capture a valve packing leak at the high-pressure coolant injection system of a nuclear power plant.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Quarterly Research Performance Progress Report (Q8)

As part of Task 1, we have started by testing our modeling capabilities by reproducing isothermal DFIT simulations presented in the literature. Once satisfied with the results we have started by targeting the modeling of the DFITs at conducted at well 58-32. We have a identified a specific test (cycle 4 in zone 2) as the most interesting to be model with GEOS hydraulic fracturing module. Thus, we have first produced results with an isothermal model and adjusted model parameters to get a satisfying match with field pressure data. The, we have added thermal effects and compared the modeling results with and without thermal effects to estimate how thermal effects may influence test interpretation. Models seem to suggest that, for small volumes of fluid, thermal effects are moderate. In Task 2, we have adapted GEOS phase-field formulation to be able to simulate near-wellbore hydraulic fracture nucleation and propagation. We have devised a novel formulation that, compared to other existing ones, incorporates rock strengths. We have submitted a journal publication about our work. We are currently employing this phase-field formulation to model the experiments taking place at U Pitt and help us understand the effect of various parameters. In Task 3, we have built a model of the region surround well 16A and have started modeling stage 3 stimulation because of its simpler planar geometry. After calibrating simulation parameters using known analytical solutions, we have simulated the stage 3 stimulation using our isothermal hydraulic fracturing module, varying the permeability field, the stress conditions including different physics to get a better understanding of the numerical challenges and of the effects of varying these parameters on the simulation results. In Task 4 laboratory experimentation, a set of specialized drilling and injection tools has been customized and constructed to accommodate an inclined well with an orientation of up to 30 degrees relative to material anisotropy or principal stress axes. These inclined samples have also undergone thermal stress and hydraulic fracturing at a temperature of 190 degrees Celsius. Furthermore, both vertical and deviated sampling testing setups enable an extended analysis of post-peak pressure behaviors, facilitating post-test pressure analyses such as the G-function, step rate, and fracture reopening measurements. Thus, the key components of in-situ stress estimation can be extracted and validated through our experiment, providing a solid foundation for validating existing in-situ stress estimation theories or proposing new ones. Simultaneously, we are integrating computer vision techniques with traditional experimental fracture observation methods such as multi-overcore/slicing and water-penetration fracture observation. This combination will prove beneficial in populating the hydraulic fracture patterns database, generated under challenging EGS conditions. This approach aims to deepen our understanding of the complexities in EGS reservoirs and pave the way for future data-driven investigations. Additionally, PITT has also equipped the ELE International compression machine, which is now prepared for conducting indirect tensile and fracture toughness tests. These tests will aid in characterizing how rock fabrics influence the resulting fracture patterns. Additionally, we have completed the required personnel training and gained access to Scanning Electron Microscopy (SEM) and Energy Dispersive Spectroscopy (EDS) for conducting more detailed characterization and analysis of rock fabrics, as well as the examination of thermal and hydraulically induced fracture patterns. Thus, the PITT team has effectively demonstrated the capabilities of our experimental apparatuses in exploring the thermal effects, well deviation angles, material anisotropy, and operational choices (such as circulation rate, injection fluid viscosity, and injection rate) and their impact on pressure responses and fracture trajectories under the Utah FORGE conditions.

15 GEOTHERMAL ENERGY↗

Advancing local helicity injection for non-solenoidal tokamak startup

Experiments on the A ~ 1 PEGASUS ST are advancing the physics and technology basis of Local Helicity Injection (LHI). LHI injects helicity with relatively intense electron current sources in the plasma edge. It creates high toroidal current, toroidally-averaged tokamak-like plasmas that have been efficiently transitioned to Ohmically driven tokamak plasmas. Tradeoffs between physics and engineering goals are tested with LHI systems on the low-field-side and the high-field-side of PEGASUS, producing plasmas predominantly driven by non-solenoidal induction and DC helicity drive, respectively. An extensive LHI source development campaign comparing active arc sources, passive and gas-effused electrode sources lead to the selection of active arc sources for present and next-step LHI deployments. LHI plasmas with net toroidal current I p =0.225 MA, T e >100 eV, and n e ~ 10 19 m -3 are attained to date. A predictive 0D power-balance model describes experimental I p (t) and partitions the active current drive sources. High-frequency MHD activity is found to be present during LHI current drive, in addition to n=1 modes previously found in NIMROD simulation and experiment. A new system of reduced MHD activity was detected where n=1 activity is suppressed, LHI CD efficiency improves, and long-pulse plasmas are sustained with V IND ~ 0.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Technology Enablers for Advanced Gasoline Compression Ignition Engines

To meet current emission regulations and increasingly demanding global fleet CO2 standards on fuel economy and future trends towards life cycle GHG emissions, advanced combustion engines remain significant in the passenger vehicle sector to achieve high efficiency and low emissions over the full operating range. Lean burn gasoline compression ignition (GCI) technology has shown to have the most potential in reaching these goals, although it faces challenges in the operating range. In this study, an advanced GCI engine is considered with the capability to operate under two combustion modes, namely low temperature combustion (LTC) and GCI. They are enabled with the use of two Hyundai in-house developed technologies; an advanced valve control mechanism known as continuously variable valve duration (CVVD) and a high-pressure gasoline injection system. At low load, the engine utilizes dual CVVD and dual CVVT (continuously variable valve timing) mechanisms for both intake and exhaust valvetrains to enable NVO (negative valve overlap) to trap hot residuals. The hot residuals enable low load auto-ignition, and the phasing control of that auto-ignition is achieved by varying the degrees of NVO, and in turn, the amount of hot residuals. This is done in real time with respect to the changes in engine loads or operating conditions, significantly improving cylinder-phasing control in LTC mode, and subsequently is able to realize a fuel economy gain and reduced emission benefits. Early direct injection during NVO or intake stroke is used to form homogenous or quasi-homogenous air-fuel mixture for LTC. At mid to high loads, late direct injection of gasoline or GCI mode is employed to take advantage of the high volatility and high resistance to auto-ignition of gasoline fuel, so that diesel-engine like high combustion efficiency can be achieved with lower soot emissions for the same NOx level as diesel combustion. In this paper, the key control and fueling technologies that enable this multiple mode combustion are introduced, and the resultant analysis on engine test and CFD simulation at LTC and GCI operating conditions are presented in detail.

Gasoline compression ignition, low temperature com↗

Development of Hydrogen Burner for FT4000® Aeroderivative Engine - Final Report

This report details an effort to develop a retrofittable fuel/air injector for the FT4000® aeroderivative gas turbine that enables use of hydrogen as a carbon-free fuel for efficient power generation. The FT4000 engine’s low-NOx combustor was developed by Pratt & Whitney and RTX Technology Research Center with core technology from the Pratt & Whitney PW4000 turbofan aircraft engine. The current FT4000 production engine operates on either natural gas or No. 2 fuel oil with water injection to achieve high thermal efficiency and low emissions. This engine is fielded by Mitsubishi Power Aero and delivers 70 MW of power with a simple-cycle efficiency of over 41% when operating with wet compression. The work reported here advances the technology readiness level of the FT4000 combustor for operation with hydrogen, starting with an experimental assessment of the current production hardware with increasing hydrogen content mixed with natural gas and ending with improved nozzle concepts for fully robust operation with 100% hydrogen. High-pressure single-sector combustor rig tests have been completed, demonstrating the ability for the dual fuel nozzle to operate an FT4000 combustor on 100% hydrogen with low nitrogen oxide (NOx) emissions. Metal temperature measurements and video images of the flame structure from zero to 100% hydrogen highlight opportunities to improve the fuel nozzle robustness for high hydrogen conditions. The design of new fuel/air mixer concepts to improve durability and operability with high hydrogen levels was also completed. A total of eleven new concepts were developed and analyzed, ranging from modifications to the bill-of-materials nozzle to fully clean sheet designs. The concepts were evaluated with non-reacting and reacting flow evaluations to assess the performance of the new hardware designs. Non-reacting tests included Phase Doppler Particle Analysis (PDPA) for droplet size and velocity, mechanical patternation for liquid water flux, and planar laser induced fluorescence (PLIF) with acetone-seeding for gaseous fuel/air mixing characterization. Five scaled candidate fuel nozzle designs, in addition to a scaled bill-of-materials nozzle, were then successfully evaluated in an atmospheric pressure burner rig. The nozzles were evaluated for performance with natural gas, hydrogen/natural gas blends, and pure hydrogen. For 100% hydrogen, the nozzles were evaluated with and without water injection. Optical and infrared imaging of the flame and fuel nozzle was captured. NOx emissions were sampled from fixed emissions probes. The results show measurable differences between the various designs, and the data was used to down-select the two most promising designs to advance to future full pressure rig testing. Results from this study have cleared the current production FT4000 engines with dual fuel nozzles to operate at baseload power on blends of hydrogen mixed with natural gas and water. Two promising nozzle designs have been developed to enable fully robust operation with up to 100% hydrogen. These nozzles require validation at full baseload operating conditions before they can be introduced to the field.

03 NATURAL GAS↗

Assessment of calcium addition on the removal of U(VI) in the alkaline conditions created by NH3 gas

Remediation of uranium (U) contamination in the deep vadose zone (VZ) sediments abundant in calcite mineral is a challenging task considering the formation of highly stable and mobile uranyl complexes with carbonate and calcium in pore water composition. There is a concern that uranium contamination in the VZ can serve as a continued source for groundwater pollution, creating a risk to human health and the environment through the groundwater pathway. This requires in-situ remediation of the radionuclide-contaminated VZ to convert soluble U species to low solubility precipitates that are stable in the natural environment. Injection of reactive gasses (e.g., NH3) is a promising technology to decrease U mobility in the unsaturated zone without the addition of liquid amendments. The NH3 injection creates alkaline conditions that can alter the sediment pore water composition due to a release of elements from minerals (via desorption and dissolution) that are present in the sediment. However, it is not known how VZ pore water constituents (Si, Al3+, HCO3 -, and Ca2 +) would affect U(VI) removal/precipitation in alkaline conditions. This study quantified the role of major pore water constituents typically present in the arid and semi-arid environments of the western regions of the U.S and identified solid uranium-bearing phases that could potentially precipitate from solutions approximating pore water compositions after pH manipulations via ammonia gas injections. Triplicate samples were prepared using six Si (5, 50 100, 150, 200, and 250 mM), six HCO3 - (0, 3, 25, 50, 75, and 100 mM), and two Ca2+ (5 and 10 mM) concentrations. The concentration of aluminum and uranium was kept constant at 5mM and 0.0084 mM, respectively, in all synthetic formulations tested. Results showed that the percentage of U(VI) removal was controlled by the Si/Al molar ratios and Ca2+ concentrations. Regardless of the bicarbonate concentration tested, the percentage of U(VI) removed increased as the Si/Al ratios were increased. However, higher Ca concentrations correlated with higher U(VI) removal, ranging between 96% and 99%, at low Si/Al ratios. The SEM images of dried precipitates displayed dense amorphous regions high in silica content, where EDS elemental analysis unveiled higher U atomic percentages. The formation of uranyl silicate and carbonate minerals was also predicted by the speciation modeling. XRD analysis revealed the presence of uranyl carbonate mineral phases (andersonite, grimselite); however, uranyl silicates predicted (Naboltwoodite) were not identified experimentally, possibly due to the amorphous nature of the silica solid phases observed in our experiments.

Katsenovich, Yelena↗

Ramalin, an antioxidant compound derived from Antarctic lichen, prevents progression of liver fibrosis induced by dimethylnitrosamine (DNM) in rats

Highlights: • New chemical substance, “Ramalin”, derived from Antarctic lichen, acts as a powerful antioxidant and ROS scavenger. • Ramalin significantly reduces hepatic stellet cell activation, while also reducing malondialdehyde (MDA), and hydroxyproline (HP). • Ramalin offers hepatoprotection effect by ameliorating DMN-induced oxidative stress and hepatotoxicity. Hepatic fibrosis is characterized by the excessive accumulation of extracellular matrix (ECM), primarily collagen, within the liver. Because reactive oxygen species (ROS) has been implicated in its pathogenesis, the use of antioxidants as a potential treatment has been broadly explored. Here, we investigated the hepatoprotective properties of ramalin (RM), a compound extracted from the Antarctic lichen Ramalina terebrata, against hepatic fibrosis in vitro and in vivo. RM suppressed hepatic stellate cell (HSC) activation in vitro without any significant signs of adverse effects on the cells tested, and the accumulation of ECM was dramatically reduced in the liver tissue. Oral administration of RM in rats noticeably improved the gross appearance of the liver with increased body and liver weight relative to the DMN injected rats, and all of the serum biochemical markers returned to the normal range. RM treatment have ameliorated hepatic fibrosis in rats induced by DMN by repressing α-smooth muscle actin (α-SMA) and upregulating heme oxygenase-1 (HO-1). In addition, RM significantly reduced collagen accumulation, and levels of malondialdehyde (MDA) and hydroxyproline (HP) in the liver tissue of DMN injected rats. The efficacy exerted by RM was through erythroid 2–related factor 2 (Nrf2) mediated antioxidant response proteins such as HO-1 and NAD(P)H quinone dehydrogenase 1 (NQO-1). Our results show the beneficial effect of RM against the progression of hepatic fibrosis.

60 APPLIED LIFE SCIENCES↗

First feedback-controlled divertor detachment in W7-X: Experience from TDU operation and prospects for operation with actively cooled divertor

In the last experimental campaign (OP1.2b) of the stellarator Wendelstein 7-X (W7-X), boronisation as a mean for first wall conditioning was applied for the first time which led to strongly reduced impurity fluxes from plasma-facing components. Thermal detachment at the uncooled target plates of the test divertor unit (TDU) was reached at higher plasma densities and was accompanied by high recycling of neutrals at the target plate. A feedback control system was established in W7-X to actively control the gas injection (actuator) for plasma fuelling and impurity seeding [3] through the divertors. It allowed very successful stabilisation of the detached plasma condition state as well as mitigation of thermal overloads to some baffle tiles. Different routinely available diagnostic signals were used as input parameters (sensors). We describe the setup of the feedback control system, its performance and provide some example results with the main focus on the development of the control scheme which led to the detachment stabilisation over the entire longest (30 s) high-power discharge at W7-X so far. In view of the achieved very successful detachment stabilisation and the necessity to include simultaneous optimisation of the core performance in the future, the feedback control system is being upgraded for the upcoming campaign (OP2.1) in which the water cooled and hereby inherently steady-state capable divertor has been currently installed. The prospects and some experiment ideas for active detachment control are discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Time-Based CAN IDS Paper Results Code

Modern vehicles are complex cyber-physical systems made of hundreds of electronic control units (ECUs) that communicate over controller area networks (CANs). This inherited complexity has expanded the CAN attack surface which is vulnerable to message injection attacks. These injections change the overall timing characteristics of messages on the bus, and thus, to detect these malicious messages, time-based intrusion detection systems (IDSs) have been proposed. However, time-based IDSs are usually trained and tested on low-fidelity datasets with unrealistic, labeled attacks. This makes difficult the task of evaluating, comparing, and validating IDSs. Here we detail and benchmark four time-based IDSs against the newly published ROAD dataset, the first open CAN IDS dataset with real (non-simulated) stealthy attacks with physically verified effects. We found that methods that perform hypothesis testing by explicitly estimating message timing distributions have lower performance than methods that seek anomalies in a distribution related statistic. In particular, these “distribution-agnostic” based methods outperform “distribution-based” methods by at least 55% in area under the precision-recall curve (AUC-PR). Our results expand the body of knowledge of CAN time-based IDSs by providing details of these methods and reporting their results when tested on datasets with real advanced attacks. Finally, we develop an after-market plug-in detector using lightweight hardware, which can be used to deploy the best performing IDS method on nearly any vehicle.

Moriano, Pablo [Oak Ridge National Lab. (ORNL), Oa↗

In Situ Plasma Processing of Superconducting Cavities at JLab

Jefferson Lab has an ongoing R&D program in plasma processing which is close to going into production pro-cessing in the CEBAF accelerator. Plasma processing is a common technique for removing hydrocarbons from surfaces, which increases the work function and reduces the secondary emission coefficient[1]. The initial focus of the effort is processing C100 cavities by injecting RF power into the HOM coupler ports. The goal will be to improve the operational gradients and the energy margin of the CEBAF linacs by processing cryomodules in situ. Results from processing cryomodule in the cryomodule test bunker as well as vertical test results will be present-ed. This work will describe the systems and methods used at JLAB for processing cavities using an argon oxygen gas mixture. Before and after plasma processing results will also be presented.

Powers, T.↗

AGGREGATE: dAta-driven modelinG preservinG contRollable dEr for outaGe mAnagemenT and rEsiliency (Report for Task 10: Controllability and Observability Analysis (Deliverable D7))

It is common to have less than full observability for distribution systems, as the number of available measurements are not sufficient. Considering increasing penetration of distributed energy resources (DERs), it is imperative to understand and control distribution systems better. Developed for the transmission system, the original numerical observability analysis methods were based on the canonical DC Power Flow (DC-PF) model. However, the DC-PF model is ill-suited for the distribution system in which line resistance to reactance (R/X) ratios can be near unity. In this report, we apply the non-iterative Observability Test (OT) and Observable Island Identification Procedure (OIIP) in to the gain matrix from the distribution system state estimator. Because sensors are few in distribution systems, pseudo-measurements based on historical load profiles and zero-injection virtual measurements are often employed to ensure observability. However, both the observability and the accuracy of the state estimates are uncertain when historical data is limited/unavailable.

42 ENGINEERING↗

Kinematic Evidence for an Embedded Planet in the IM Lupi Disk

Abstract We test the hypothesis that an embedded giant planet in the IM Lupi protostellar disk can produce velocity kinks seen in CO line observations as well as the spiral arms seen in scattered light and continuum emission. We inject planets into 3D hydrodynamics simulations of IM Lupi, generating synthetic observations using Monte Carlo radiative transfer. We find that an embedded planet of 2–3 M Jup can reproduce non-Keplerian velocity perturbations, or “kinks”, in the 12 CO J = 2–1 channel maps. Such a planet can also explain the spiral arms seen in 1.25 mm dust continuum emission and 1.6 μ m scattered-light images. We show that the wake of the planet can be traced in the observed peak velocity map, which appears to closely follow the morphology expected from our simulations and from analytic models of planet–disk interaction.

79 ASTRONOMY AND ASTROPHYSICS↗

Optimal Coordinated EV Charging with Reactive Power Support in Constrained Distribution Grids

Electric vehicle (EV) charging/discharging can take place in any P-Q quadrants, which means EVs could support reactive power to the grid while charging the battery. In controlled charging schemes, distribution system operator (DSO) coordinates with the charging of EV fleets to ensure grid’s operating constraints are not violated. In fact, this refers to DSO setting upper bounds on power limits for EV charging. In this work, we demonstrate that if EVs inject reactive power into the grid while charging, DSO could issue higher upper bounds on the active power limits for the EVs for the same set of grid constraints. We demonstrate the concept in an 33-node test feeder with 1,500 EVs. Case studies show that in constrained distribution grids in coordinated charging, average costs of EV charging could be reduced if the charging takes place in the fourth P-Q quadrant compared to charging with unity power factor.

24 POWER TRANSMISSION AND DISTRIBUTION↗

A multi-species powder dropper for magnetic fusion applications

Here, we present a device for controlled injection of a variety of materials in powder form. The system implements four independent feeder units, arranged to share a single vertical drop tube. Each unit consists of a 80 ml reservoir, coupled to a horizontal linear trough, where a layer of powder is advanced by piezo-electric agitation at a speed proportional to the applied voltage, until it falls into a drop tube. The dropper has been tested with a number of impurities of low (B, BN, C), intermediate (Si, SiC), and high Z (Sn) and a variety of microscopic structures (flakes, spheres, rocks) and sizes (5-200 μm). For low Z materials, drop rates ~2-200 mg/s have been obtained showing good repeatability and uniformity. A calibrated light-emitting diode (LED)-based flowmeter allows measuring and monitoring the drop rate during operation. The fast time-response of the four feeders allows combination of steady and pulsed injections, providing a flexible tool for controlled-dose, real-time impurity injection in fusion plasmas.

47 OTHER INSTRUMENTATION↗

Liquefaction of Forest Biomass to "Drop-in" Hydrocarbon Biofuels

The overall goal of the project was to demonstrate solvent liquefaction as a viable path to stable intermediates for subsequent upgrading to fuel blendstocks. Iowa State University (ISU) utilized technology developed by Chevron to produce “green crude” via continuous biomass liquefaction to bio-oil without catalyst or reducing gas, then upgraded the crude to drop-in hydrocarbon liquid transportation fuels. Original benchmarks for the project included conversion of biomass to bio-oil at a yield of 50% or more, produce bio-oil with oxygen content below 20 wt%, and recycle a portion of the bio-oil product for use as solvent, displacing initial hydrocarbon solvent. Initial testing and technology development was completed by Chevron using a custom Small Continuous Liquefaction Unit (SCLU) operated in “once-through” mode. In this system, liquid product and solid residual/char was collected together and required both off-line solids removal and product separation. This unit was disassembled and major components incorporated into a redesigned solvent liquefaction system at ISU capable of processing biomass at rates up to 1 kg/h. Online, continuous solids separation and bio-oil recovery/separation systems were successfully implemented. Online solids removal using an acetone injection to aid in separation achieved over 99% solids removal efficiency, and acetone recovery of greater than 97% was achieved. The gas stripping system developed for the separation of medium wood oil (MWO) for the recycle stream from the heavy wood oil (HWO) product stream was also successful in recovering approximately 93 wt% of the initial solvent from the biomass-derived products. Due to the generation of fine particulate and the high molecular weight of the HWO which both negatively affect the ability to separate the product oil, solvent recycle was not fully implemented in the system. The biomass used in this project is loblolly pine forest residue. The solvent was a blend of two hydrocarbon liquids. The majority of the solvent was comprised of commercially available naphthalene-depleted heavy aromatic solvent. The hydrogen donor solvent was a proprietary cut of light cycle oil (LCO) that was hydrotreated. As much as 25 wt% of the solvent mixture was comprised of the hydrotreated LCO. Higher blend ratios were limited by the economics of providing hydrogen to the process in this manner. Two cases were evaluated for technical feasibility on the SCLU. These are 1. Simulated phenolic solvent recycle and 2. Hydrocarbon-rich solvent processing. The simulated phenolic solvent recycle case was based on an idealistic solvent mixture where only 5% makeup or hydrogen donor solvent entered the system. The resulting solvent mixture at steady state was estimated to be 75 wt% depleted hydrogen donor, 20 wt% biomass derived phenolic monomers, and 5 wt% HLCO. This case resulted in the highest bio-oil organic yield observed in the project of 66.7 wt% on a solvent-less, dry biomass basis and relatively low oxygen content of 12%. Additionally, these conditions deconstructed the biomass so well, that extremely fine particulate was generated such that 5 micron barrier filters were unable to remove the material. Offline addition of acetone, centrifugation and acetone removal were required in order to remove the particulate prior to fractionation with the stripping column. The resulting HWO had a high molecular weight and was therefore very viscous in nature, remaining solid at room temperature. Additionally, the column was unable to sustainably strip enough MWO to close the recycle loop balance while maintaining flowability of product oil exiting the column. It was determined that additional HLCO would be required at the front of the process to decrease product viscosity both by dilution and additional hydrogen transfer into the HWO product oil. The hydrocarbon rich mixture was the preferred mixture for a majority of the project and featured a 25% donor or HLCO content and 75% depleted hydrogen donor mix. A series of three tests were conducted using this mixture and serve as the basis for a paper detailing the system. While the online acetone injection system for high pressure solids removal was demonstrated early on using this mixture, difficulty controlling process flows led to the use of an atmospheric stirred tank filtration system. At these high donor solvent levels, the product stream easily partitioned with sufficient MWO to close the recycle loop balance. Additionally, this mixture produced HWO product oil at just over 55% yield, <5% oxygen content, and a reasonable viscosity at room temperature. A 56 hour campaign was conducted with the ISU pilot to produce a large enough batch of HWO product oil to conduct upgrading experiments at Chevron’s Richmond, CA facility. Benchtop hydrotreating units were used to conduct long-duration hydrogenation/hydrogenolysis reactions in order to provide yield data and help validate assumptions made in the TEA model. Resulting products featured an oxygen content of <1%, near the detectability limit. Hydrocracking simulations were also performed, and a distribution of heavy wood oil to refinery products was determined. These distributions are based on a database of commercial and pilot plant operation used by Chevron to estimate product yield from novel inputs based on the input physical and chemical characteristics. While multi-week benchtop hydrotreating tests were successfully conducted without fouling, analysis and testing of the heavy wood oil suggest it may be better suited for hydrocracking. Metals content in the heavy wood oil would likely create catalyst fouling over time and reduce lifetime of hydrotreating catalysts. Yields and product partitioning were also more favorable from hydrocracking compared to those from hydrotreating.

09 BIOMASS FUELS↗

Muon Borehole Detector Design for Use in 4-D Density Overburden Monitoring

The increase of atmospheric CO2 concentrations has initiated research into carbon sequestration methods. One possibility is to store CO2 in subsurface porous reservoirs. The monitoring of the injected CO2 plume is vital because escaping CO2 poses health and environmental risks. Typically, seismic reflection methods are used to determine the change in density due to the replacement of brine by CO2 in the reservoir, but this is expensive and not continuous. A potential alternative is to use cosmic muon tomography to measure density changes in the reservoir as a function of time. This paper describes the development of a muon detector that will be capable of being deployed in boreholes. The detector has the required dimensions, an angular resolution of approximately 2 degrees, and is robust. The design is based on alternating layers of scintillating rods, which can provide 4-D tomographic data to detect small changes in density at depths up to approximately 2 km. Geant4, a Monte Carlo simulation code, is being used to develop models to guide the design of the physical configuration. Preliminary testing and measurements have been performed to validate the simulation predictions and optimize the performance of the system. The simulation and preliminary experimental results are presented here.

Borehole Detector, CO¬2 Sequestration, Geant4, Muo↗