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DOE OSTI2019

Surface, Interface, and Temperature Effects on the Phase Separation and Nanoparticle Self Assembly of Bi-Metallic Ni0.5Ag0.5: A Molecular Dynamics Study

Classical molecular dynamics (MD) simulations were used to investigate how free surfaces, as well as supporting substrates, affect phase separation in a NiAg alloy. Bulk samples, droplets, and droplets deposited on a graphene substrate were investigated at temperatures that spanned regions of interest in the bulk NiAg phase diagram, i.e., miscible and immiscible liquid, liquid-crystal, and crystal-crystal regions. Using MD simulations to cool down a bulk sample from 3000 K to 800 K, it was found that phase separation below 2400 K takes place in agreement with the phase diagram. When free surface effects were introduced, phase separation was accompanied by a core-shell transformation: spherical droplets created from the bulk samples became core-shell nanoparticles with a shell made mostly of Ag atoms and a core made of Ni atoms. When such droplets were deposited on a graphene substrate, the phase separation was accompanied by Ni layering at the graphene interface and Ag at the vacuum interface. Thus, it should be possible to create NiAg core-shell and layer-like nanostructures by quenching liquid NiAg samples on tailored substrates. Furthermore, interesting bimetallic nanoparticle morphologies might be tuned via control of the surface and interface energies and chemical instabilities of the system.

core-shell nanoparticles↗

NASA NTRS1997

Complex Permittivities of Candidate Radome Materials at W-band

This report presents the results of w-band complex permittivity measurements performed in NASA Langley's Electromagnetics Research Branch. The test articles included in the permittivity study were flat panels of materials which are under consideration for use in a radome for the Passive Millimeter Wave Camera (PMMWC) flight experiment. This experiment is scheduled to fly on the Air Force's 'Speckled Trout' aircraft in late 1997. The radome design is very important because the PMMWC can tolerate only a small amount of electromagnetic loss through the radome. A free space measurement system was used to obtain complex reflection and transmission coefficients of the samples. The frequency of interest was 89 GHz, so measurements were performed over a range of 79 to 99 GHz. The transmission and reflection coefficients were used, along with the measured sample thickness, to calculate complex permittivity over the frequency range. The material samples measured in this study can be divided into four categories: skin materials, core materials, coating materials, and layered samples.

Cravey, Robin↗

DOE OSTI2015

Prestellar core formation, evolution, and accretion from gravitational fragmentation in turbulent converging flows

We investigate prestellar core formation and accretion based on three-dimensional hydrodynamic simulations. Our simulations represent local ∼1 pc regions within giant molecular clouds where a supersonic turbulent flow converges, triggering star formation in the post-shock layer. We include turbulence and self-gravity, applying sink particle techniques, and explore a range of inflow Mach numbers M=2−16. Two sets of cores are identified and compared: t{sub 1} cores are identified from a time snapshot in each simulation and represent dense structures in a single cloud map; t{sub coll} cores are identified at their individual time of collapse and represent the initial mass reservoir for accretion. We find that cores and filaments form and evolve at the same time. At the stage of core collapse, there is a well-defined, converged characteristic mass for isothermal fragmentation that is comparable to the critical Bonnor–Ebert mass at the post-shock pressure. The core mass functions (CMFs) of t{sub coll} cores show a deficit of high-mass cores (≳7 M{sub ⊙}) compared to the observed stellar initial mass function (IMF). However, the CMFs of t{sub 1} cores are similar to the observed CMFs and include many low-mass cores that are gravitationally stable. The difference between t{sub 1} cores and t{sub coll} cores suggests that the full sample from observed CMFs may not evolve into protostars. Individual sink particles accrete at a roughly constant rate throughout the simulations, gaining one core mass per freefall time even after the initial mass reservoir is accreted. High-mass sinks gain proportionally more mass at later times than low-mass sinks. There are outbursts in accretion rates, resulting from clumpy density structures falling into the sinks.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2017

Class II 6.7 GHz Methanol Maser Association with Young Massive Cores Revealed by ALMA

We explored the implication of the association (or lack of it) of 6.7 GHz class II methanol (CH{sub 3}OH) masers with massive dense cores (MDCs) detected (within a sample of ATLASGAL selected infrared quiet massive clumps) at 0.9 mm with Atacama Large Millimeter/submillimeter array. We found 42 out of the 112 cores (37.5%) detected with the Atacama Compact Array (ACA) to be associated with 6.7 GHz CH{sub 3}OH masers. The lowest mass core with CH{sub 3}OH maser association is ∼12 M{sub ⊙}. The angular offsets of the ACA cores from the 6.7 GHz CH{sub 3}OH maser peak positions range from 0.″17 to 4.″79, with a median value of 2.″19. We found a weak correlation between the 0.9 mm continuum (MDCs) peak fluxes and the peak fluxes of their associated methanol multibeam (MMB) 6.7 GHz CH{sub 3}OH masers. About 90% of the cores associated with 6.7 GHz CH{sub 3}OH masers have masses of >40 M {sub ⊙}. The CH{sub 3}OH maser containing cores are candidates for embedded high-mass protostellar objects in their earliest evolutionary stages. With our ACA 0.9 continuum data compared with the MMB 6.7 GHz CH{sub 3}OH maser survey, we have constrained the cores already housing massive protostars based on their association with the radiatively pumped 6.7 GHz CH{sub 3}OH masers.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS2003

Soil Sampling Techniques For Alabama Grain Fields

Characterizing the spatial variability of nutrients facilitates precision soil sampling. Questions exist regarding the best technique for directed soil sampling based on a priori knowledge of soil and crop patterns. The objective of this study was to evaluate zone delineation techniques for Alabama grain fields to determine which method best minimized the soil test variability. Site one (25.8 ha) and site three (20.0 ha) were located in the Tennessee Valley region, and site two (24.2 ha) was located in the Coastal Plain region of Alabama. Tennessee Valley soils ranged from well drained Rhodic and Typic Paleudults to somewhat poorly drained Aquic Paleudults and Fluventic Dystrudepts. Coastal Plain s o i l s ranged from coarse-loamy Rhodic Kandiudults to loamy Arenic Kandiudults. Soils were sampled by grid soil sampling methods (grid sizes of 0.40 ha and 1 ha) consisting of: 1) twenty composited cores collected randomly throughout each grid (grid-cell sampling) and, 2) six composited cores collected randomly from a -3x3 m area at the center of each grid (grid-point sampling). Zones were established from 1) an Order 1 Soil Survey, 2) corn (Zea mays L.) yield maps, and 3) airborne remote sensing images. All soil properties were moderately to strongly spatially dependent as per semivariogram analyses. Differences in grid-point and grid-cell soil test values suggested grid-point sampling does not accurately represent grid values. Zones created by soil survey, yield data, and remote sensing images displayed lower coefficient of variations (8CV) for soil test values than overall field values, suggesting these techniques group soil test variability. However, few differences were observed between the three zone delineation techniques. Results suggest directed sampling using zone delineation techniques outlined in this paper would result in more efficient soil sampling for these Alabama grain fields.

Thompson, A. N.↗

DOE OSTI2017

Occurrence of Radio Minihalos in a Mass-limited Sample of Galaxy Clusters

We investigate the occurrence of radio minihalos—diffuse radio sources of unknown origin observed in the cores of some galaxy clusters—in a statistical sample of 58 clusters drawn from the Planck Sunyaev–Zel’dovich cluster catalog using a mass cut ( M {sub 500} > 6 × 10{sup 14} M {sub ⊙}). We supplement our statistical sample with a similarly sized nonstatistical sample mostly consisting of clusters in the ACCEPT X-ray catalog with suitable X-ray and radio data, which includes lower-mass clusters. Where necessary (for nine clusters), we reanalyzed the Very Large Array archival radio data to determine whether a minihalo is present. Our total sample includes all 28 currently known and recently discovered radio minihalos, including six candidates. We classify clusters as cool-core or non-cool-core according to the value of the specific entropy floor in the cluster center, rederived or newly derived from the Chandra X-ray density and temperature profiles where necessary (for 27 clusters). Contrary to the common wisdom that minihalos are rare, we find that almost all cool cores—at least 12 out of 15 (80%)—in our complete sample of massive clusters exhibit minihalos. The supplementary sample shows that the occurrence of minihalos may be lower in lower-mass cool-core clusters. No minihalos are found in non-cool cores or “warm cores.” These findings will help test theories of the origin of minihalos and provide information on the physical processes and energetics of the cluster cores.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRSDate not supplied

Curation protocol of Phobos sample returned by the Martian Moon Exploration (MMX)

The Martian Moons Exploration (MMX) aims to return the regolith samples from the Martian moon, Phobos. After the topographic and spectroscopic observation, the spacecraft will land on the surface of Phobos to conduct the sampling operation[1–2]. Pneumatic and coring samplers will collect ≥10 g Phobos grains from two different sites. The collected samples will be retrieved from the capsule and transferred to the curation facility in 2029.

R Fukai↗

DOE OSTI2015

Mock-Up activities for the extraction of samples from a salt-stone disposal unit - 15502

Mock-up testing with respect to the core-drilling of simulant salt-stone grout was conducted to support the future retrieval of field-emplaced salt-stone samples from salt-stone Disposal Unit (SDU) Cell 2A. The primary objectives of extracting samples from SDU Cell 2A are to enable measurement of field-emplaced samples with respect to properties that influence long-term performance, such as saturated hydraulic conductivity, and to compare the measured properties for field-emplaced and comparable samples prepared in the laboratory. Initial mock-up activities (Phases 1 and 2) were conducted in Fiscal Years (FY) 2013 and 2014 in order to demonstrate the viability of standard core-drilling techniques that are typically employed for sampling concrete structures. The primary requirement for the core-drilling technique was that it should minimize the potential of physical or chemical sample changes that would artificially degrade key grout properties. Mock-up activities were aimed at optimizing the techniques for core-drilling, and subsequent sample extraction, using a set-up that mimicked, to the extent practical, both the physical characteristics, and operational complexities, of core-drilling salt-stone grout from the roof of the SDU. Samples extracted from the grout monolith were subsequently characterized with respect to saturated hydraulic conductivity and compressive strength, and compared to data for cast samples prepared using the same simulant salt-stone material. The comparison of these properties for the two sample types was expected to highlight potential flaws (e.g., micro-cracking) introduced by the core-drilling process. While the data for saturated hydraulic conductivity were virtually identical (approximately 2 E-09 cm/sec), the compressive strength of the core-drilled samples (approximately 3.5 MPa (500 psi)) was on average half that measured for the cast samples. It was suspected that increased water saturation and surface scoring of the core-drilled samples might account for the disparate compressive Strength data. During Phases 1 and 2 it was determined that cores could be successfully drilled and extracted to a depth of approximately 0.9 meters (3 feet) below the grout surface. Phase 3 (FY 2105) has been initiated and is primarily directed at demonstrating the ability to core-drill through approximately 1.8 meters (6 feet) of overlying grout to retrieve the desired sample from the SDU. The original drill depth of 0.6 - 0.9 meters (2-3 feet) was based on an SDU fill height of 5.6 meters (18.5 feet) and sample location of approximately 4.9 meters (16 feet); recently the allowable fill height in the SDUs has been increased to 6.5 meters (21.25 feet); hence the increased depth of overlying grout above the samples to be retrieved. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2014

Electronic study of Al substituted La{sub 0.7}Ca{sub 0.3}MnO{sub 3} using photoemission spectroscopy

Polycrystalline samples of La{sub 0.7}Ca{sub 0.3}Mn{sub 1−X}Al{sub X}O{sub 3} (X=0, 0.05, 0.15) are prepared using solid state reaction route. Photoemission spectroscopy measurements were performed on these samples to investigate their electronic properties. Al shows 3+ oxidation state in both Al doped samples while no effect of Al doping is found on the core level spectrum of La 4d and Ca 2p orbitals and they were found in 3{sup +} and 2{sup +} oxidation state respectively in all the samples . Mn 2p core level photoemission measurements indicates that for 5% Al doped sample (lower doping) Al ions replaces the Mn{sup 3+} ions while they substitute Mn{sup 4+} in 15 % Al doped sample ((higher doping)

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2016

Sampling for Soil Carbon Stock Assessment in Rocky Agricultural Soils

Coring methods commonly employed in soil organic C (SOC) stock assessment may not accurately capture soil rock fragment (RF) content or soil bulk density (rho (sub b)) in rocky agricultural soils, potentially biasing SOC stock estimates. Quantitative pits are considered less biased than coring methods but are invasive and often cost-prohibitive. We compared fixed-depth and mass-based estimates of SOC stocks (0.3-meters depth) for hammer, hydraulic push, and rotary coring methods relative to quantitative pits at four agricultural sites ranging in RF content from less than 0.01 to 0.24 cubic meters per cubic meter. Sampling costs were also compared. Coring methods significantly underestimated RF content at all rocky sites, but significant differences (p is less than 0.05) in SOC stocks between pits and corers were only found with the hammer method using the fixed-depth approach at the less than 0.01 cubic meters per cubic meter RF site (pit, 5.80 kilograms C per square meter; hammer, 4.74 kilograms C per square meter) and at the 0.14 cubic meters per cubic meter RF site (pit, 8.81 kilograms C per square meter; hammer, 6.71 kilograms C per square meter). The hammer corer also underestimated rho (sub b) at all sites as did the hydraulic push corer at the 0.21 cubic meters per cubic meter RF site. No significant differences in mass-based SOC stock estimates were observed between pits and corers. Our results indicate that (i) calculating SOC stocks on a mass basis can overcome biases in RF and rho (sub b) estimates introduced by sampling equipment and (ii) a quantitative pit is the optimal sampling method for establishing reference soil masses, followed by rotary and then hydraulic push corers.

hammer method↗

NASA NTRS1988

Search for the Tunguska event in the Antarctic snow

The Tunguska explosion in 1908 is supposed to have been produced by the impact of a small celestial body. The absence of any identifiable crater together with the huge energy released by the event suggest that the impactor exploded in midair and that its material was widely spread over the Earth. The short term contribution of such exceptional events to the total accretion rate of extraterrestrial material by the Earth could be significant. Samples were chosen in a core electromechanically drilled in 1984 near South Pole Station. There, the low temperatures, preventing melting all year long, and the nearly regular snow fall rate provide good conditions for a reliable continuous record of any infalling material. In many samples Ir was below the detection limit of the instrumentation. The iridium infall averaged over 45 samples is given. In a few samples the iridium content is significantly higher than the average: the frequency and amplitude of such fluctuations can be explained by the presence on some filters of finite size cosmic particles. No significant systematic increase above the average level is observed in the part of the core corresponding to the Tunguska event. The two major results of this study are: (1) The presence of Tunguska explosion debris in the Antarctic snow is not confirmed; and (2) The estimate of the average iridium infall, is an order of magnitude lower than the Ganapathy's background but is close to the values measured in Antarctic snow and atmospheric samples by Takahashi et al. The results are also consistent with the flux of micrometeoroids deduced from optical and radar observations or derived from the study of Greenland cosmic dust collection but are lower than the flux at mid-latitude measured in paleocene-oligocene sediments from the central part of the Pacific Ocean.

Rocchia, R.↗

DOE OSTI2013

Asteroseismological study of massive ZZ Ceti stars with fully evolutionary models

We present the first asteroseismological study for 42 massive ZZ Ceti stars based on a large set of fully evolutionary carbon-oxygen core DA white dwarf models characterized by a detailed and consistent chemical inner profile for the core and the envelope. Our sample comprises all of the ZZ Ceti stars with spectroscopic stellar masses between 0.72 and 1.05 M {sub ☉} known to date. The asteroseismological analysis of a set of 42 stars enables study of the ensemble properties of the massive, pulsating white dwarf stars with carbon-oxygen cores, in particular the thickness of the hydrogen envelope and the stellar mass. A significant fraction of stars in our sample have stellar mass that is high enough to crystallize at the effective temperatures of the ZZ Ceti instability strip, which enables us to study the effects of crystallization on the pulsation properties of these stars. Our results show that the phase diagram presented in Horowitz et al. seems to be a good representation of the crystallization process inside white dwarf stars, in agreement with the results from white dwarf luminosity function in globular clusters.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS2019

Broadband Characterization of Stress Induced Anisotropy in Nanocomposite Co74.6Fe2.7Mn2.7Nb4Si2B14

We report on the broadband characterization of Co74:6Fe2:7Mn2:7Nb4Si2B14 (at%) melt-spun, soft magnetic alloy ribbons after various secondary processing treatments. Ribbons were investigated in the as-cast (melt-spun) condition, after annealing under stress at 50 - 200 MPa, and after transverse magnetic field (TMF) annealing. The magnetization dynamics of these materials have been studied from 10 - 60 GHz using ferromagnetic resonance (FMR). The in-plane uniaxial anisotropy was determined from the FMR data and permeability extracted for each condition. The permeability determined from broadband FMR was in good agreement with independently determined values using vibrating sample magnetometry and impedance spectrometry of toroidal cores. The effective damping parameter (α (sub ϱff)) of all the samples was close to 0.015 except for the TMF sample, which showed higher damping, possibly due to two magnon scattering.

Abhishek Srivastava↗

DOE OSTI2022

Atomic-Scale STEM Analysis Shows Structural Changes of Au–Pd Nanoparticles in Various Gaseous Environments

We report dynamical restructuring effects in free-standing Au 0.75 Pd 0.25 nanoparticles occurring in gaseous environments at elevated temperatures. The freshly prepared sample was found to have a core–shell structure with a Pd-rich phase on the surface. The evolution of sample composition and morphology under exposure to 1 bar of pure gases, namely O 2 , H 2 , air, CO, and CO 2 , at different temperatures was studied using in situ scanning transmission electron microscopy (STEM) and energy-dispersive X-ray spectroscopy (EDS). We observed sharper facets on the surface of the particles under O 2 or air at 400 °C. Small islands of Pd were present on the surface, although some Pd was redistributed inside the bulk when the temperature was increased under O 2 . Subtle changes in surface roughness were noted when O 2 was substituted with H 2 at 400 °C, an observation correlated to density functional theory (DFT) calculations. The particles lost clean surface facets when CO was introduced at room temperature and at 200 °C. No substantial changes could be observed after exposure to CO 2 at 250 °C. The adsorption of CO molecules on the surface modifies the surface of the particles and decreases the facet prevalence. Furthermore, these in situ observations show how gases can induce subtle modification of the surface of nanocatalysts, potentially impacting their chemical properties.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

Opening-mode fracturing and cementation during hydrocarbon generation in shale: An example from the Barnett Shale, Delaware Basin, West Texas

Relative timing of fracturing is a key input for predictive fracture models, but timing information for fractures is commonly difficult to obtain. In this study, we used crosscutting relations and fluid inclusion assemblage temperatures from fracture cements from a few well-documented sampled fractures, combined with a one-dimensional burial history model, to establish timing for three generations of opening-mode fractures in a Barnett Shale core from the southern part of the Delaware Basin, Pecos County, West Texas. A burial history model is presented for the cored well and matched to measured vitrinite reflectance in samples from the core, and bottomhole temperature in the well. Here, the earliest fractures (group 1) likely formed due to early fluid-expulsion events (ca. 300 Ma) and were folded during host-rock compaction. Later group 2 fractures are sealed with fibrous barite containing primary, liquid hydrocarbon inclusions (mean homogenization temperature [T h ] = –9°C) and aqueous fluid inclusions (mean T h = 108.1°C). Group 2 fractures likely formed in response to fluid overpressure associated with cracking of type II kerogen to oil. Group 3 vertical fractures are up to 2 m in height with kinematic apertures ranging from less than 0.05 to 1.4 mm, partly open, and strike dominantly 010°–020°. Sequentially trapped aqueous fluid inclusions in fracture-spanning quartz cement bridges (mean T h = 110°C in crack-seal texture and 128°C in post-crack-seal fracture cement) record fracture opening under increasing temperature, inferred to reflect increasing burial, with continued overpressuring during the Triassic to Late Cretaceous. Some group 3 fractures may have continued to fill during Cenozoic uplift.

02 PETROLEUM↗

NASA NTRS1976

Petrographic and ferromagnetic resonance studies of the Apollo 15 deep drill core

Detailed petrographic grain size, and ferromagnetic resonance studies were performed on a representative suite of samples from the Apollo 15 deep drill core. Petrographic analyses of the 90-150 micron size fraction show a subtle upward increase in the ratio of mare to highland components. The agglutinate content at the FMR intensity normalized to FeO show that the soils in the core are generally immature to submature. The most striking feature shown by the maturity indices is a systematic decrease in maturity from the lunar surface to a depth of about 40 cm. Although other mechanisms are possible, the downward decrease in maturity can be attributed to in situ reworking over a time span of 400 m.y. at a 50% probability.

Heiken, G. H.↗

DOE OSTI2020

ZPPR-15 Small Reactivity Worth Experiments

In addition to measuring the worth of sodium voiding and the worth of simulated control rods, the ZPPR staff measured the Doppler worth of four standard samples, the worth of axial expansion and the worth of radial bowing in ZPPR-15. Doppler sample worths were measured in ZPPR-15A, ZPPR-15B and ZPPR-15D. The Doppler samples were natural UO 2 , depleted uranium metal, depleted U-10Zr alloy and 33% enriched UO 2 . These samples were placed in a sample capsule in the inner core of ZPPR-15 and heated to various temperatures between 300 K and 1100 K. The resulting changes in reactivity relative to the reference configuration were measured to determine the Doppler worths of the samples. Special segmented drawers were constructed to measure the worth of axial expansion in ZPPR15. The segments were connected to each other, and the back segment was connected to a spring-loaded cable. Pulling the cable introduced small gaps between drawer segments to simulate axial expansion, and releasing the cable eliminated those gaps. The worth of this simulated axial expansion was measured in ZPPR-15A, ZPPR-15B and ZPPR-15D. The worth of radial bowing was measured in ZPPR-15, but the experimenters regarded the result as unsatisfactory. Radial bowing was measured by two methods in ZPPR-17A, so the ZPPR-17A bowing measurements were analyzed in place of the unpublished ZPPR-15 radial bowing measurement. The first ZPPR-17A measurement consisted of rearranging the plates in 96 core drawers at the core-radial blanket boundary to simulate outward motion of the fuel during bowing. The second ZPPR-17A measurement used a new bowing oscillator to move the core plates a small distance vertically in a special drawer. The published uncertainties for the Doppler worth, axial expansion worth and radial bowing worth measurements are the statistical uncertainties in the measurements. In reality, the published uncertainty for each of these measurements is just one component of the total uncertainty. There are additional uncertainties specific to each measurement and a common uncertainty related to conversion from the natural measurement units, cents, to pcm for calculations. A full uncertainty analysis was performed for each measurement. The significant uncertainties were quantified, and a total uncertainty was determined for each measurement. The ZPPR-15 and ZPPR-17A experimental records were used to create detailed as-built Monte Carlo models of the Doppler worth, axial expansion and radial bowing measurement configurations.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2022

The impact of freeze-thaw history on soil carbon response to experimental freeze-thaw cycles

This dataset contains data used for the paper "The impact of freeze-thaw history on soil carbon response to experimental freeze-thaw cycles". The Related References field will be updated with a full citation when available.Freeze-thaw is a disturbance process in cold regions where permafrost soils are becoming vulnerable to temperature fluctuations above 0˚C. Freeze-thaw alters soil physical and biogeochemical properties with implications for carbon persistence and emissions in Arctic landscapes. We examined whether different freeze-thaw histories in two soil systems led to contrasting biogeochemical responses under a laboratory-controlled freeze-thaw incubation. We investigated controls on soil organic matter (SOM) composition through Fourier-transform ion cyclotron resonance mass spectroscopy (FT-ICR-MS) to identify nominal carbon oxidation states and relative abundances of aliphatic-type carbon molecules in both surface and subsurface soils. Soil cores (~ 60 cm-depth) were sampled from two sites in Alaskan permafrost landscapes with different in situ freeze-thaw characteristics: Healy (>40 freeze-thaw cycles annually) and Toolik (<150 freeze-thaw cycles annually). FT-ICR-MS was coupled with in situ temperature data and soil properties (i.e., soil texture, mineralogy) to assess (1) differences in SOM composition associated with previous freeze-thaw history and (2) sensitivity to experimental freeze-thaw in the extracted cores. Control (freeze-only) samples showed greater carbon oxidation in Healy soils compared with Toolik, even in lower mineral horizons where freeze-thaw history was comparable across both sites. Healy showed the most loss of carbon compounds following experimental freeze-thaw in the lower mineral depths, including a decrease in aliphatics. Toolik soils responded more slowly to freeze-thaw as shown by intermediary carbon oxidation distributed across multiple carbon compound classes. Variations in the response of permafrost carbon chemistry to freeze-thaw is an important factor for predicting changes in soil function as permafrost thaws in high northern latitudes.This dataset contains a compressed (.zip) archive of the data and R scripts used for this manuscript. The dataset includes files in .csv format, which can be accessed and processed using MS Excel or R. This archive can also be accessed on GitHub at https://github.com/Erin-Rooney/FTC-FTICR (DOI 10.5281/zenodo.6533064).

54 ENVIRONMENTAL SCIENCES↗