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At least 829 records · Page 46

Theoretical Study of Tautomerization Reactions for the Ground and First Excited Electronic States of Adenine

Geometrical structures and energetic properties for different tautomers of adenine are calculated in this study, using multi-configurational wave functions. Both the ground and the lowest singlet excited state potential energy surfaces are studied. Four tautomeric forms are considered, and their energetic order is found to be different on the ground and the excited state potential energy surfaces. Minimum energy reaction paths are obtained for hydrogen atom transfer (tautomerization) reactions in the ground and the lowest excited electronic states. It is found that the barrier heights and the shapes of the reaction paths are different for the ground and the excited electronic states, suggesting that the probability of such tautomerization reaction is higher on the excited state potential energy surface. This tautomerization process should become possible in the presence of water or other polar solvent molecules and should play an important role in the photochemistry of adenine.

Salter, Latasha M.↗

Fully Automated Detection of Cloud and Aerosol Layers in the CALIPSO Lidar Measurements

Accurate knowledge of the vertical and horizontal extent of clouds and aerosols in the earth s atmosphere is critical in assessing the planet s radiation budget and for advancing human understanding of climate change issues. To retrieve this fundamental information from the elastic backscatter lidar data acquired during the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) mission, a selective, iterated boundary location (SIBYL) algorithm has been developed and deployed. SIBYL accomplishes its goals by integrating an adaptive context-sensitive profile scanner into an iterated multiresolution spatial averaging scheme. This paper provides an in-depth overview of the architecture and performance of the SIBYL algorithm. It begins with a brief review of the theory of target detection in noise-contaminated signals, and an enumeration of the practical constraints levied on the retrieval scheme by the design of the lidar hardware, the geometry of a space-based remote sensing platform, and the spatial variability of the measurement targets. Detailed descriptions are then provided for both the adaptive threshold algorithm used to detect features of interest within individual lidar profiles and the fully automated multiresolution averaging engine within which this profile scanner functions. The resulting fusion of profile scanner and averaging engine is specifically designed to optimize the trade-offs between the widely varying signal-to-noise ratio of the measurements and the disparate spatial resolutions of the detection targets. Throughout the paper, specific algorithm performance details are illustrated using examples drawn from the existing CALIPSO dataset. Overall performance is established by comparisons to existing layer height distributions obtained by other airborne and space-based lidars.

Vaughan, Mark A.↗

Energy and Momentum in Mechanical Impact Testing

The ASTM G86 method is used to determine the ignition sensitivity of materials to mechanical impact in oxygen. It has long been known that different systems built to the standard produce different results. Given the current push towards direct comparison of numerical results from different systems rather than just material rankings, it is desirable to normalize the systems to some performance-based metric. Normalization is complicated by the fact that the energy and momentum of a particular impact scale differently with plummet mass and drop height, and therefore adjusting the mass and height to account for system differences would result in a different impact. The standard uses dent blocks to assess impacts. However, it was unknown if the differences in momentum could be identified during dent block impacts. To determine this, dent blocks were impacted with constant energy and different momentums, using instrumented and non-instrumented plummets. The dent blocks showed statistically significant differences in the penetration function when subjected to impacts with the same energy but different momentum. Further, the instrumented plummet showed drastic differences in the power delivery with different momentums. System configuration was also shown to have an effect on the response of the penetration function to different momentums.

Energy↗

Energy and Momentum in Mechanical Impact Testing

The ASTM G86 method is used to determine the ignition sensitivity of materials to mechanical impact in oxygen. It has long been known that different systems built to the standard produce different results. Given the current push towards direct comparison of numerical results from different systems rather than just material rankings, it is desirable to normalize the systems to some performance-based metric. Normalization is complicated by the fact that the energy and momentum of a particular impact scale differently with plummet mass and drop height, and therefore adjusting the mass and height to account for system differences would result in a different impact. The standard uses dent blocks to assess impacts. However, it was unknown if the differences in momentum could be identified during dent block impacts. To determine this, dent blocks were impacted with constant energy and different momentums, using instrumented and non-instrumented plummets. The dent blocks showed statistically significant differences in the penetration function when subjected to impacts with the same energy but different momentum. Further, the instrumented plummet showed drastic differences in the power delivery with different momentums. System configuration was also shown to have an effect on the response of the penetration function to different momentums.

Energy↗

Gain degradation and efficiencies of spiral electron multipliers

The characteristics of spiral electron multipliers as functions of accumulated counts were investigated. The mean gain of the multipliers showed a steady decline from about 100 million when new, to about one million after 100 billion events when biased in a saturation mode. For prolonged use in a space environment, improved life expectancy might be obtained with a varying bias voltage adjusted to maintain the gain comfortably above a given discrimination level. Pulse-height distributions at various stages of the lifetime and variations of efficiency with energy of detected electrons are presented.

Judge, R. J. R.↗

Effect of marine stratocumulus in TOMS ozone

The algorithm used to correct total O3 from the total ozone mapping spectrometer (TOMS) for cloud effects is based on the measured reflectivity, a climatological cloud top height, and an assumed tropospheric O3 column amount below clouds. In regions of persistent subtropical marine stratocumulus it is assumed that this introduces a positive error into total O3 because these clouds are lower than the assumed mean cloud height used in the algorithm. This appears to be confirmed by high correlation between Nimbus 7 TOMS total O3 and reflectivity data for typical regimes of persistent stratus, as identified by the international satellite cloud climatology project (ISCCP) observations. The TOMS total O3 overestimate has been computed using Nimbus 7/solar backscattered ultraviolet total O3 derived using temperature humidity infrared radiometer (THIR) data for years 1979-1984. A functional relationship between the THIR/non-THIR total O3 difference and reflectivity is used with TOMS reflectivity to modify Nimbus 7 TOMS O3 data for selected regions and periods. The correction diminishes or eliminates a number of apparent O3 maxima, with reductions of up to 20 Dobson units (DU) in total O3 on daily maps and approximately 5 DU on monthly mean O3 maps. Significant correlation between corrected TOMS O3 and reflectivity data remains because low-altitude O3 is retrieved more efficiently over a high-albedo surface. It is also possible that dynamical influences leading to stratocumulus formation bring O3-enriched air into the area. These results imply that although good arguments can be made for the use of TOMS total O3 as a proxy for tropospheric O3 in the tropics, caution must be exercised in the use of daily and even monthly O3 maps in the vicinity of clouds. Further research into the TOMS algorithm in cloudy regions is required to derive reliable estimates of tropospheric O3.

Thompson, A. M.↗

Dynamics of the Antarctic Circumpolar Current. Evidence for Topographic Effects from Altimeter Data and Numerical Model Output

Geosat altimeter data and numerical model output are used to examine the circulation and dynamics of the Antarctic Circumpolar Current (ACC). The mean sea surface height across the ACC has been reconstructed from height variability measured by the altimeter, without assuming prior knowledge of the geoid. The results indicate locations for the Subantarctic and Polar Fronts which are consistent with in situ observations and indicate that the fronts are substantially steered by bathymetry. Detailed examination of spatial and temporal variability indicates a spatial decorrelation scale of 85 km and a temporal e-folding scale of 34 days. Empirical Orthogonal Function analysis suggests that the scales of motion are relatively short, occuring on 1000 km length-scales rather than basin or global scales. The momentum balance of the ACC has been investigated using output from the high resolution primitive equation model in combination with altimeter data. In the Semtner-Chervin quarter-degree general circulation model topographic form stress is the dominant process balancing the surface wind forcing. In stream coordinates, the dominant effect transporting momentum across the ACC is bibarmonic friction. Potential vorticity is considered on Montgomery streamlines in the model output and along surface streamlines in model and altimeter data. (AN)

Gille, Sarah T.↗

In-Space Radiator Shape Optimization using Genetic Algorithms

Future space exploration missions will require the development of more advanced in-space radiators. These radiators should be highly efficient and lightweight, deployable heat rejection systems. Typical radiators for in-space heat mitigation commonly comprise a substantial portion of the total vehicle mass. A small mass savings of even 5-10% can greatly improve vehicle performance. The objective of this paper is to present the development of detailed tools for the analysis and design of in-space radiators using evolutionary computation techniques. The optimality criterion is defined as a two-dimensional radiator with a shape demonstrating the smallest mass for the greatest overall heat transfer, thus the end result is a set of highly functional radiator designs. This cross-disciplinary work combines topology optimization and thermal analysis design by means of a genetic algorithm The proposed design tool consists of the following steps; design parameterization based on the exterior boundary of the radiator, objective function definition (mass minimization and heat loss maximization), objective function evaluation via finite element analysis (thermal radiation analysis) and optimization based on evolutionary algorithms. The radiator design problem is defined as follows: the input force is a driving temperature and the output reaction is heat loss. Appropriate modeling of the space environment is added to capture its effect on the radiator. The design parameters chosen for this radiator shape optimization problem fall into two classes, variable height along the width of the radiator and a spline curve defining the -material boundary of the radiator. The implementation of multiple design parameter schemes allows the user to have more confidence in the radiator optimization tool upon demonstration of convergence between the two design parameter schemes. This tool easily allows the user to manipulate the driving temperature regions thus permitting detailed design of in-space radiators for unique situations. Preliminary results indicate an optimized shape following that of the temperature distribution regions in the "cooler" portions of the radiator. The results closely follow the expected radiator shape.

Hull, Patrick V.↗

Atmospheric pressure, density, temperature and wind variations between 50 and 200 km

Data on atmospheric pressure, density, temperature and winds between 50 and 200 km were collected from sources including Meteorological Rocket Network data, ROBIN falling sphere data, grenade release and pitot tube data, meteor winds, chemical release winds, satellite data, and others. These data were analyzed by a daily difference method and results on the distribution statistics, magnitude, and spatial structure of the irregular atmospheric variations are presented. Time structures of the irregular variations were determined by the analysis of residuals from harmonic analysis of time series data. The observed height variations of irregular winds and densities are found to be in accord with a theoretical relation between these two quantities. The latitude variations (at 50 - 60 km height) show an increasing trend with latitude. A possible explanation of the unusually large irregular wind magnitudes of the White Sands MRN data is given in terms of mountain wave generation by the Sierra Nevada range about 1000 km west of White Sands. An analytical method is developed which, based on an analogy of the irregular motion field with axisymmetric turbulence, allows measured or model correlation or structure functions to be used to evaluate the effective frequency spectra of scalar and vector quantities of a spacecraft moving at any speed and at any trajectory elevation angle.

Justus, C. G.↗

Intensive probing of a clear air convective field by radar and instrumental drone aircraft.

An instrumented drone aircraft was used in conjunction with ultrasensitive radar to study the development of a convective field in the clear air. Radar data are presented which show an initial constant growth rate in the height of the convective field of 3.8 m/min, followed by a short period marked by condensation and rapid growth at a rate in excess of 6.1 m/min. Drone aircraft soundings show general features of a convective field including progressive lifting of the inversion at the top of the convection and a cooling of the air at the top of the field. Calculations of vertical heat flux as a function of time and altitude during the early stages of convection show a linear decrease in heat flux with altitude to near the top of the convective field and a negative heat flux at the top. Evidence is presented which supports previous observations that convective cells overshoot their neutral buoyancy level into a region where they are cool and moist compared to their surroundings. Furthermore, only that portion of the convective cell that has overshot its neutral buoyancy level is generally visible to the radar.

Rowland, J. R.↗

Supersonic Stall Flutter of High Speed Fans

An analytical model is developed for predicting the onset of supersonic stall bending flutter in axial flow compressors. The analysis is based on a modified two dimensional, compressible, unsteady actuator disk theory. It is applied to a rotor blade row by considering a cascade of airfoils whose geometry and dynamic response coincide with those of a rotor blade element at 85 percent of the span height (measured from the hub). The rotor blades are assumed to be unshrouded (i.e., free standing) and to vibrate in their first flexural mode. The effects of shock waves and flow separation are included in the model through quasi-steady, empirical, rotor total-pressure-loss and deviation-angle correlations. The actuator disk model predicts the unsteady aerodynamic force acting on the cascade blading as a function of the steady flow field entering the cascade and the geometry and dynamic response of the cascade. Calculations show that the present model predicts the existence of a bending flutter mode at supersonic inlet Mach numbers. This flutter mode is suppressed by increasing the reduced frequency of the system or by reducing the steady state aerodynamic loading on the cascade. The validity of the model for predicting flutter is demonstrated by correlating the measured flutter boundary of a high speed fan stage with its predicted boundary. This correlation uses a level of damping for the blade row (i.e., the log decrement of the rotor system) that is estimated from the experimental flutter data. The predicted flutter boundary is shown to be in good agreement with the measured boundary.

Adamczyk, J. J.↗

High-Spatial-Resolution OH PLIF Visualization in a Cavity-Stabilized Ethylene-Air Turbulent Flame

High-spatial-resolution OH planar laser-induced fluorescence was measured for a premixed ethylene-air turbulent flame in an electrically-heated Mach 2 continuous-flow facility (University of Virginia Supersonic Combustion Facility, Configuration E.) The facility comprised a Mach 2 nozzle, an isolator with flush-wall fuel injectors, a combustor with optical access, and an extender. The flame was anchored at a cavity flameholder with a backward-facing step of height 9 mm. The temperature-insensitive Q1(8) transition of OH was excited using laser light of wavelength 283.55 nm. A spatial filter was used to create a laser sheet approximately 25 microns thick based on full-width at half maximum (FWHM). Extension tubes increased the magnification of an intensified camera system, achieving in-plane resolution of 40 microns based on a 50% modulation transfer function (MTF). The facility was tested with total temperature 1200 K, total pressure 300 kPa, local fuel/air equivalence ratios of approximately 0.4, and local Mach number of approximately 0.73 in the combustor. A test case with reduced total temperature and another with reduced equivalence ratio were also tested. PLIF images were acquired along a streamwise plane bisecting the cavity flameholder, from the backward facing step to 120 mm downstream of the step. The smallest observed features in the flow had width of approximately 110 microns. Flame surface density was calculated for OH PLIF images.

Geipel, Clayton M.↗

Modeling Demographic-Driven Vegetation Dynamics and Ecosystem Biogeochemical Cycling in NASA GISS’s Earth System Model (ModelE-BiomeE v.1.0)

We developed a demographic vegetation model, BiomeE, to improve the modeling of vegetation dynamics and ecosystem biogeochemical cycles in the NASA Goddard Institute of Space Studies' ModelE Earth system model. This model includes the processes of plant growth, mortality, reproduction, vegetation structural dynamics, and soil carbon and nitrogen storage and transformations. The model combines the plant physiological processes of ModelE's original vegetation model, Ent, with the plant demographic and ecosystem nitrogen processes that have been represented in the Geophysical Fluid Dynamics Laboratory's LM3-PPA. We used nine plant functional types to represent global natural vegetation functional diversity, including trees, shrubs, and grasses, and a new phenology model to simulate vegetation seasonal changes with temperature and precipitation fluctuations. Competition for light and soil resources is individual based, which makes the modeling of transient compositional dynamics and vegetation succession possible. Overall, the BiomeE model simulates, with fidelity comparable to other models, the dynamics of vegetation and soil biogeochemistry, including leaf area index, vegetation structure (e.g., height, tree density, size distribution, and crown organization), and ecosystem carbon and nitrogen storage and fluxes. This model allows ModelE to simulate transient and long-term biogeophysical and biogeochemical feedbacks between the climate system and land ecosystems. Furthermore, BiomeE also allows for the eco-evolutionary modeling of community assemblage in response to past and future climate changes with its individual-based competition and demographic processes.

Biogeochemical cycles↗

Ground testing at MSFC

The large-scale field collection of acoustic data and their analysis are described in this review. The entire sound-field program has the purpose of solving complex problems of excessive noise propagation associated with the static test firing of large space-booster powerplants. The site of data collection has been Mississippi Test Facility (MTF), where far-field sound-propagation and correlated meteorological measurements were initiated in 1962. The statistical evaluation of sound-measurement data shows that the polar distribution of sound in the springtime (at MTF) is determined mainly by the temperature field of the atmosphere. Greater deformation of sound-intensity polar distribution occurs in the autumn as a result of the influence of the wind field. The data on sound attenuation as a function of distance from its source revealed attenuation in excess of the expected magnitude. The excess was mainly between 1 and 10 kilometers from the source, with maximum attenuation (17 to 18 decibels) near 6 kilometers. Excess sound attenuation was compared with calculated sound dispersion. For all sound frequencies in all seasons the deviation between reference and empirical attenuation values formed a bell-shaped distribution on a semilogarithmic plot. The physical causes for the sound- attenuation behavior are considered to be atmospheric diffraction and scattering effects. Statistical analysis of sod-intensity extremes indicated amplification of the sound signals by focusing which could be expected along selected azimuths. Empirical amplification values showed the maximum occurring in winter (50 decibels at 22 kilometers). For the analysis of correlation between empirical sound data and local atmospheric sound- propagation conditions, #e concept of analytical classification of sound-velocity profiles has been developed. Examination of over a quarter-million individual sound-velocity profiles indicates that 33 profile types for heights up to 3 kilometers constitute the empirical possibilities of sound-propagation conditions in southeastern United States. Since the focusing qualities of each sound- velocity profile can be determined as a class characteristic, the overall probabilities of focusing occurrence can he obtained. The severity of focusing, as based upon lateral spread of focusing areas, has been determined. The data for MTF indicate focusing is most severe in winter, with the direction toward east being most affected. Sound propagation is a fluctuating phenomenon because atmospheric conditions vary continuously. A measuring system for analyzing the nonstationary sound-propagation phenomena has been established. The analysis of the acoustic fluctuation data is sup- posed to provide "dynamic” perturbation functions of sound, which are to be superimposed on the related characteristic sound-velocity-profile type. The ultimate result of the program will be the establishment of reliable contingency tables showing the relationship between atmospheric parameters and far-field sound intensities. These data will be the basis for more accurate sound-propagation forecasting for static firing tests.

STATIC TESTING↗

A representation of Jacchia's thermospheric models in spherical harmonic functions

The Jacchia models are represented in terms of spherical harmonic functions. This representation has the advantage of ease of comparison with other global theoretical and empirical models that use this mathematical form. Furthermore, it is analytic, continuous, and has continuous derivatives all over the globe. The representation of the exospheric temperatures shows clearly the amplitudes of the various periodic terms and uses relatively few constants. An example of a similar representation for the total mass density at a particular height and level of solar activity is given as well.

Blum, P.↗

Processing parameters associated with scale-up of balloon film production

A method is set forth for assessing strain-rate profiles that can be used to develop a scale-up theory for blown-film extrusion. Strain rates are evaluated by placing four ink dots on the stalk of an extruded bubble to follow the displacements of the dots as a function of time. The instantaneous Hencky strain is obtained with the displacement data and plotted for analysis. Specific attention is given to potential sources of error in the distance measurements and corrections for these complex bubble geometries. The method is shown to be effective for deriving strain-rate data related to different processing parameters for the production of balloon film. The strain rates can be compared to frostline height, blow-up ratio, and take-up ratio to optimize these processing variables.

Simpson, D. M.↗

Junction-to-Case Thermal Resistance of a Silicon Carbide Bipolar Junction Transistor Measured

Junction temperature of a prototype SiC-based bipolar junction transistor (BJT) was estimated by using the base-emitter voltage (V(sub BE)) characteristic for thermometry. The V(sub BE) was measured as a function of the base current (I(sub B)) at selected temperatures (T), all at a fixed collector current (I(sub C)) and under very low duty cycle pulse conditions. Under such conditions, the average temperature of the chip was taken to be the same as that of the temperature-controlled case. At increased duty cycle such as to substantially heat the chip, but same I(sub C) pulse height, the chip temperature was identified by matching the V(sub BE) to the thermometry curves. From the measured average power, the chip-to-case thermal resistance could be estimated, giving a reasonable value. A tentative explanation for an observed bunching with increasing temperature of the calibration curves may relate to an increasing dopant atom ionization. A first-cut analysis, however, does not support this.

Niedra, Janis M.↗

Suit Port Aft Bulkhead Mockup Test Results and Lessons Learned

The Small Pressurized Rover (SPR) is currently being carried as an integral part of the current Lunar Surface Architectures under consideration in the Constellation program. One element of the SPR is the suit port, the means by which the crew performs Extravehicular Activities (EVAs). Two suit port deliverables were produced in fiscal year 2008: an aft bulkhead mockup for functional integrated testing with the 1-G SPR mockup and a functional and pressurizable engineering unit. This paper focuses on the test results and lessons learned on the aft bulkhead mockup. The suit port aft bulkhead mockup was integrated with the mockup of the SPR cabin and chassis. It is located on the aft bulkhead of the SPR cabin structure and includes hatches, a locking mechanism, seals, interior and exterior suit don/doff aids, and exterior platforms to accommodate different crewmember heights. A lightweight mockup of the Mark III suit was tested with the suit port aft bulkhead mockup. There are several limitations to the suit port and mockup suits, and results of the suit port evaluation are presented and interpreted within the context of the limitations.

Romig, Barbara A.↗