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At least 829 records · Page 46

Micro-fluidics and integrated optics glass sensor for in-line micro-probing of nuclear samples

We study the miniaturisation of Thermal Lens Spectrometry (TLS) towards Lab-on-chip integration in order to reduce the volume of fluid assays in nuclear process control. TLS is of great interest in this context since it combines the advantages of optical detection methods with an inherent suitability for small-scale samples. After validating the experimental principle in a classical thermal lens crossed-beam setup, we show the integration of a Young-interferometer with a microcapillary on a glass substrate, reducing the necessary sample size to 400 nl. The interferometer translates the photo-thermally induced refractive index change in the fluid to a phase shift of the fringe pattern, which can then be detected by a camera. Measurements of Co(II) in ethanol yield a detection limit of c = 5 x 10{sup -4} M for the crossed-beam setup and c = 6x10{sup -3} M for the integrated sensor. At an interaction length of 10 {mu}m, it detects a minimum absorbance of AU = 6 x 10{sup -5} in a probed volume of 10 pl. (authors)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Study of Rare Nuclear Processes with CUORE

TeO 2 bolometers have been used for many years to search for neutrinoless double beta decay in 130-Te. CUORE, a tonne-scale TeO 2 detector array, recently published the most sensitive limit on the half-life, $T_{1/2}^{0\nu} > 1.5 \times 10^{25}\,$yr, which corresponds to an upper bound of $140-400$ meV on the effective Majorana mass of the neutrino. While it makes CUORE a world-leading experiment looking for neutrinoless double beta decay, it is not the only study that CUORE will contribute to in the field of nuclear and particle physics. As already done over the years with many small-scale experiments, CUORE will investigate both rare decays (such as the two-neutrino double beta decay of 130 Te and the hypothesized electron capture in 123 Te), and rare processes (e.g., dark matter and axion interactions). This paper describes some of the achievements of past experiments that used TeO 2 bolometers, and perspectives for CUORE.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

How Galaxies Form Stars: The Connection between Local and Global Star Formation in Galaxy Simulations

Using a suite of isolated $L_\star$ galaxy simulations, we show that global depletion times and star-forming gas mass fractions in simulated galaxies exhibit systematic and well-defined trends as a function of the local star formation efficiency per freefall time, $\epsilon_{\rm ff}$, strength of stellar feedback, and star formation threshold. We demonstrate that these trends can be reproduced and explained by a simple physical model of global star formation in galaxies. Our model is based on mass conservation and the idea of gas cycling between star-forming and non-star-forming states on certain characteristic time scales under the influence of dynamical and feedback processes. Both the simulation results and our model predictions exhibit two limiting regimes with rather different dependencies of global galactic properties on the local parameters. When $\epsilon_{\rm ff}$ is small and feedback is inefficient, the total star-forming mass fraction, $f_{\rm sf}$, is independent of $\epsilon_{\rm ff}$ and the global depletion time, $\tau_{\rm dep}$, scales inversely with $\epsilon_{\rm ff}$. When $\epsilon_{\rm ff}$ is large or feedback is very efficient, these trends are reversed: $f_{\rm sf} \propto \epsilon_{\rm ff}^{-1}$ and $\tau_{\rm dep}$ is independent of $\epsilon_{\rm ff}$ but scales linearly with the feedback strength. We also compare our results with the observed depletion times and mass fractions of star-forming and molecular gas and show that they provide complementary constraints on $\epsilon_{\rm ff}$ and the feedback strength. In conclusion, we show that useful constraints on $\epsilon_{\rm ff}$ can also be obtained using measurements of the depletion time and its scatter on different spatial scales.

79 ASTRONOMY AND ASTROPHYSICS↗

A Development of Critical Components for the Modular Staged Pressurized Oxy-Combustion Power Plant

DOE's Coal FIRST (Flexible, Innovative, Resilient, Small, Transformative) Initiative was implemented to encourage the development of the coal plant of the future, which will be capable of flexible operation to meet the needs of the grid; using innovative and cutting-edge components that improve efficiency and reduce emissions; providing resilient power to Americans; being small compared to today's conventional utility-scale coal power plants; and transforming how coal power plant technologies are designed and manufactured. The modular Staged, Pressurized Oxy-Combustion (SPOC) process envisioned by and under development at Washington University in St. Louis (WUSTL) has the potential to achieve these goals. The process offers: 1) a modular plant design for improved operational flexibility; 2) fuel-staging combined with pressurized oxy-combustion, which leads to smaller plant size, higher plant efficiency, and lower cost for pollutant and greenhouse gases removal compared with traditional carbon-capture equipped coal power plants; and 3) small modular boilers and pollutant removal units that can be fabricated in shop and assembled on site, further reducing plant capital costs. Under DOE's support (DE-FE0031925), WUSTL is advancing the development of the critical components for the SPOC power plant, including the integrated combustion system and the direct contact cooler (DCC) from TRL 4 to TRL-5, which would allow them to be subsequently incorporated into a pilot plant. These units are the only two components that are not commercially available for a SPOC plant, and hence, their development is a key step toward the commercialization of SPOC. This work presents the objectives, task descriptions, and current progress of the project. So far, the fabrication of a new combustor design and the convective heat transfer boiler has been completed, and the integration of the combustor, boiler, and DCC is underway. Recent results obtained with the newly designed combustor show a stable coal/methane flame while dry-feeding PRB coal under oxy-combustion conditions.

Magalhaes, Duarte↗

Installation and operation of GeoMelt{sup R} in container vitrification in NNL Central Lab active rig hall at Sellafield - 15328

Cleanup and subsequent immobilization of wastes on the UK's NDA estate brings major challenges. With the exception of HLW where vitrification is utilized for immobilization, cement is typically used in the management and immobilization of non-heat generating wastes. However some legacy feeds such as those containing reactive metals can be incompatible with cementation technologies, and the application of engineered cement encapsulating product to raw wastes increases wasteform volume. Cementation has also been developed to be compatible with the repository concept, which provides it with a level of protection from the environment. Potential delays in repository implementation and as yet to be determined repository waste form acceptance criteria for some wastes may require the duration of above ground storage of immobilized wastes to be extended with potential effect on the integrity of the wasteform. Vitrification is a treatment option which destroys organics and hazardous inorganics such as asbestos, reduces wasteform volume, and produces a robust leach resistant wasteform. Kurion's GeoMelt{sup R} In-container Vitrification (ICV){sup TM} is a vitrification process wherein the treatment vessel can serve as an interim-storage, transport, and final long-term storage vessel - thus negating the need to pour glass into a separate container, effectively leading to a much simpler system than traditional waste melters. The inherent volume reduction from vitrification results in a dense product with self-shielding properties, and the GeoMelt treatment process has been demonstrated to homogenize elemental metals and radionuclide contaminants of concern, eliminating hot spots and mitigating criticality concerns. All of which opens up alternatives strategies for storage and disposal. GeoMelt has been proven in the commercial and US DOE waste treatment environment with over 26,000 tonnes of hazardous waste treated to date (half of this radioactive). Kurion and the UK's National Nuclear Laboratory (NNL) plan to demonstrate its application to Sellafield radioactive wastes. A small (engineering) scale demonstrator is being installed in the active rig hall at NNL's Central Laboratory at Sellafield UK with a twofold mission; 1) demonstration of the vitrification of ILW/LLW, and 2) processing of smaller volume orphan wastes that currently have no treatment path. The NNL facility will allow the handling of uranium containing materials which form a substantial component of ILW currently stored on the Sellafield site. Accurate DFs across the melter and off gas system are often difficult to obtain using inactive materials at the low concentrations present in radioactive wastes. Installation in the NNL facility will allow trace quantities of active species such as Cs-137 and Tc-99 to be processed as part of a simulant ILW stream and monitoring will allow accurate decontamination factors (DFs) to be established to support future vitrification facility design. In addition to underpinning melter operation and obtaining DFs across the system, the facility will allow the processing of radioactive waste arisings of low activity which may either be typical of larger waste volumes or may present as orphans without a disposition route. In either case the melter facility will be able to vitrify these wastes into a form that will be suitable for interim storage and disposal. Among the feeds envisaged for processing will be asbestos from power stations, contaminated soils, feeds containing uranium metals, ponds solids, sludge, and miscellaneous active laboratory wastes. The NNL Central Lab capability will be used to analyze the active product to support disposal requirements whether through letters of compliance for the Geological Disposal Facility (GDF) or waste acceptance criteria for the Low Level Waste Repository (LLWR). (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Small Business Voucher Program: Scaling-Up of Bio-Based C5 Building Block Production: Cooperative Research and Development Final Report, CRADA Number CRD-16-00611

Visolis, Inc. is an early stage industrial biotechnology company developing next generation of processes for producing building blocks for bulk polymers and fuels. The company is developing low-cost routes to the chemicals of the future in support of DOE, EERE and BETO goals to grow the U.S. bioeconomy. NREL has capabilities in scale-up of fermentation processes from bench top through pilot scales and also has expertise and technologies related to production of lignocellulosic sugars from cellulosic feedstocks. NREL's Integrated Biorefinery Research Facility (IBRF) houses multiple fermentation vessels/systems ranging in size from 0.5 to 9,000 L along with ancillary capabilities in compositional analysis, separations, and purification. NREL's role will be to scale-up the Visolis process to produce an intermediate product, mevalonic acid, from both dextrose and biomass derived sugars. The goals of the project are to: 1) transfer and reproduce one of Visolis's proprietary fermentation processes at bench top and pilot scale at NREL's IBRF using dextrose as the feedstock, 2) carry out bench-scale fermentations using Visolis's organism and cellulosic sugars, and 3) produce mevalonic acid from the bench top and pilot scale runs for catalyst lifetime testing and conversion to isoprene.

09 BIOMASS FUELS↗

Small-Scale Recycling of Irradiated Uranium and Transuranic Elements (Np, Pu) Using 3D-Printed Centrifugal Contactors

Niowave’s technology employs super-conducting linear accelerators to induce fission on low-enriched uranium targets followed by subsequent radiochemical processing to purify 99 Mo as well as a number of other fission products. Argonne’s Radiochemistry group (CFCT), in partnership with Niowave and UNLV, will be managing the TCF project to develop a closed-cycle loop for Niowave’s uranium targets. The roles of the DOE national laboratory partner will be to 1) develop a basic chemical understanding of the separations and purifications required to meet industry standards, 2) initiate the additive manufacturing (AM) of the centrifugal contactors, 3) develop a process flowsheet using Argonne computer codes.

43 PARTICLE ACCELERATORS↗

Near ground level sensing for spatial analysis of vegetation

Measured changes in vegetation indicate the dynamics of ecological processes and can identify the impacts from disturbances. Traditional methods of vegetation analysis tend to be slow because they are labor intensive; as a result, these methods are often confined to small local area measurements. Scientists need new algorithms and instruments that will allow them to efficiently study environmental dynamics across a range of different spatial scales. A new methodology that addresses this problem is presented. This methodology includes the acquisition, processing, and presentation of near ground level image data and its corresponding spatial characteristics. The systematic approach taken encompasses a feature extraction process, a supervised and unsupervised classification process, and a region labeling process yielding spatial information.

Sauer, Tom↗

Centrifugal Sieve for Gravity-Level-Independent Size Segregation of Granular Materials

Conventional size segregation or screening in batch mode, using stacked vibrated screens, is often a time-consuming process. Utilization of centrifugal force instead of gravity as the primary body force can significantly shorten the time to segregate feedstock into a set of different-sized fractions. Likewise, under reduced gravity or microgravity, a centrifugal sieve system would function as well as it does terrestrially. When vibratory and mechanical blade sieving screens designed for terrestrial conditions were tested under lunar gravity conditions, they did not function well. The centrifugal sieving design of this technology overcomes the issues that prevented sieves designed for terrestrial conditions from functioning under reduced gravity. These sieves feature a rotating outer (cylindrical or conical) screen wall, rotating fast enough for the centrifugal forces near the wall to hold granular material against the rotating screen. Conventional centrifugal sieves have a stationary screen and rapidly rotating blades that shear the granular solid near the stationary screen, and effect the sieving process assisted by the airflow inside the unit. The centrifugal sieves of this new design may (or may not) have an inner blade or blades, moving relative to the rotating wall screen. Some continuous flow embodiments would have no inner auger or blades, but achieve axial motion through vibration. In all cases, the shearing action is gentler than conventional centrifugal sieves, which have very high velocity differences between the stationary outer screen and the rapidly rotating blades. The new design does not depend on airflow in the sieving unit, so it will function just as well in vacuum as in air. One advantage of the innovation for batch sieving is that a batch-mode centrifugal sieve may accomplish the same sieving operation in much less time than a conventional stacked set of vibrated screens (which utilize gravity as the primary driving force for size separation). In continuous mode, the centrifugal sieves can provide steady streams of fine and coarse material separated from a mixed feedstock flow stream. The centrifugal sieves can be scaled to any desired size and/or mass flow rate. Thus, they could be made in sizes suitable for small robotic exploratory missions, or for semi-permanent processing of regolith for extraction of volatiles of minerals. An advantage of the continuous-mode system is that it can be made with absolutely no gravity flow components for feeding material into, or for extracting the separated size streams from, the centrifugal sieve. Thus, the system is capable of functioning in a true microgravity environment. Another advantage of the continuous-mode system is that some embodiments of the innovation have no internal blades or vanes, and thus, can be designed to handle a very wide range of feedstock sizes, including occasional very large oversized pieces, without jamming or seizing up.

Walton, Otis R.↗

An atomistically informed mesoscale model for growth and coarsening during discharge in lithium-oxygen batteries

An atomistically informed mesoscale model is developed for the deposition of a discharge product in a Li-O{sub 2} battery. This mescocale model includes particle growth and coarsening as well as a simplified nucleation model. The model involves LiO{sub 2} formation through reaction of O{sub 2}{sup −} and Li{sup +} in the electrolyte, which deposits on the cathode surface when the LiO{sub 2} concentration reaches supersaturation in the electrolyte. A reaction-diffusion (rate-equation) model is used to describe the processes occurring in the electrolyte and a phase-field model is used to capture microstructural evolution. This model predicts that coarsening, in which large particles grow and small ones disappear, has a substantial effect on the size distribution of the LiO{sub 2} particles during the discharge process. The size evolution during discharge is the result of the interplay between this coarsening process and particle growth. The growth through continued deposition of LiO{sub 2} has the effect of causing large particles to grow ever faster while delaying the dissolution of small particles. The predicted size evolution is consistent with experimental results for a previously reported cathode material based on activated carbon during discharge and when it is at rest, although kinetic factors need to be included. The approach described in this paper synergistically combines models on different length scales with experimental observations and should have applications in studying other related discharge processes, such as Li{sub 2}O{sub 2} deposition, in Li-O{sub 2} batteries and nucleation and growth in Li-S batteries.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Modeling and Characterization of Damage Processes in Metallic Materials

This paper describes a broad effort that is aimed at understanding the fundamental mechanisms of crack growth and using that understanding as a basis for designing materials and enabling predictions of fracture in materials and structures that have small characteristic dimensions. This area of research, herein referred to as Damage Science, emphasizes the length scale regimes of the nanoscale and the microscale for which analysis and characterization tools are being developed to predict the formation, propagation, and interaction of fundamental damage mechanisms. Examination of nanoscale processes requires atomistic and discrete dislocation plasticity simulations, while microscale processes can be examined using strain gradient plasticity, crystal plasticity and microstructure modeling methods. Concurrent and sequential multiscale modeling methods are being developed to analytically bridge between these length scales. Experimental methods for characterization and quantification of near-crack tip damage are also being developed. This paper focuses on several new methodologies in these areas and their application to understanding damage processes in polycrystalline metals. On-going and potential applications are also discussed.

Glaessgen, E. H.↗

Planck 2015 results: XI. CMB power spectra, likelihoods, and robustness of parameters

This study presents the Planck 2015 likelihoods, statistical descriptions of the 2-point correlationfunctions of the cosmic microwave background (CMB) temperature and polarization fluctuations that account for relevant uncertainties, both instrumental and astrophysical in nature. They are based on the same hybrid approach used for the previous release, i.e., a pixel-based likelihood at low multipoles (ℓ< 30) and a Gaussian approximation to the distribution of cross-power spectra at higher multipoles. The main improvements are the use of more and better processed data and of Planck polarization information, along with more detailed models of foregrounds and instrumental uncertainties. The increased redundancy brought by more than doubling the amount of data analysed enables further consistency checks and enhanced immunity to systematic effects. It also improves the constraining power of Planck, in particular with regard to small-scale foreground properties. Progress in the modelling of foreground emission enables the retention of a larger fraction of the sky to determine the properties of the CMB, which also contributes to the enhanced precision of the spectra. Improvements in data processing and instrumental modelling further reduce uncertainties. Extensive tests establish the robustness and accuracy of the likelihood results, from temperature alone, from polarization alone, and from their combination. For temperature, we also perform a full likelihood analysis of realistic end-to-end simulations of the instrumental response to the sky, which were fed into the actual data processing pipeline; this does not reveal biases from residual low-level instrumental systematics. Even with the increase in precision and robustness, the ΛCDM cosmological model continues to offer a very good fit to the Planck data. The slope of the primordial scalar fluctuations, n s , is confirmed smaller than unity at more than 5σ from Planck alone. We further validate the robustness of the likelihood results against specific extensions to the baseline cosmology, which are particularly sensitive to data at high multipoles. For instance, the effective number of neutrino species remains compatible with the canonical value of 3.046. For this first detailed analysis of Planck polarization spectra, we concentrate at high multipoles on the E modes, leaving the analysis of the weaker B modes to future work. At low multipoles we use temperature maps at all Planck frequencies along with a subset of polarization data. These data take advantage of Planck’s wide frequency coverage to improve the separation of CMB and foreground emission. Within the baseline ΛCDM cosmology this requires τ = 0.078 ± 0.019 for the reionization optical depth, which is significantly lower than estimates without the use of high-frequency data for explicit monitoring of dust emission. At high multipoles we detect residual systematic errors in E polarization, typically at the μK 2 level; we therefore choose to retain temperature information alone for high multipoles as the recommended baseline, in particular for testing non-minimal models. Finally and nevertheless, the high-multipole polarization spectra from Planck are already good enough to enable a separate high-precision determination of the parameters of the ΛCDM model, showing consistency with those established independently from temperature information alone.

79 ASTRONOMY AND ASTROPHYSICS↗

Exploiting nonionic surfactants to enhance fatty alcohol production in Rhodosporidium toruloides

Fatty alcohols (FOHs) are important feedstocks in the chemical industry to produce detergents, cosmetics, and lubricants. Microbial production of FOHs has become an attractive alternative to production in plants and animals due to growing energy demands and environmental concerns. However, inhibition of cell growth caused by intracellular FOH accumulation is one major issue that limits FOH titers in microbial hosts. In addition, identification of FOH-specific exporters remains a challenge and previous studies towards this end are limited. To alleviate the toxicity issue, we exploited nonionic surfactants to promote the export of FOHs in Rhodosporidium toruloides, an oleaginous yeast that is considered an attractive next-generation host for the production of fatty acid-derived chemicals. Our results showed FOH export efficiency was dramatically improved and the growth inhibition was alleviated in the presence of small amounts of tergitol and other surfactants. As a result, FOH titers increase by 4.3-fold at bench scale to 352.6 mg/L. With further process optimization in a 2-L bioreactor, the titer was further increased to 1.6 g/L. The method we show here can potentially be applied to other microbial hosts and may facilitate the commercialization of microbial FOH production.

59 BASIC BIOLOGICAL SCIENCES↗

Athermal glass work at the nanoscale: Engineered electron-beam-induced viscoplasticity for mechanical shaping of brittle amorphous silica

Amorphous silica deforms viscoplastically at elevated temperatures, which is common for brittle glasses. The key mechanism of viscoplastic deformation involves interatomic bond switching, which is thermally activated. Here, for this study, we precisely control the mechanical shaping of brittle amorphous silica at the nanoscale via engineered electron–matter interactions without heating. We observe a ductile plastic deformation of amorphous silica under a focused scanning electron beam with low acceleration voltages (few to tens of kilovolts) during in-situ compression studies, with unique dependence on the acceleration voltage and beam current. By simulating the electron–matter interaction, we show that the deformation of amorphous silica depends strongly on the volume where inelastic scattering occurs. The electron–matter interaction via e-beam irradiation alters the Si–O interatomic bonds, enabling the high-temperature deformation behavior of amorphous silica to occur athermally. Finally, by systematically controlling the electron–matter interaction volume, it is possible to mechanically shape the brittle amorphous silica on a small scale at room temperature to a level comparable to glass shaping at high temperatures. The findings can be extended to develop new fabrication processes for nano- and microscale brittle glasses.

36 MATERIALS SCIENCE↗

High resolution coherent diffractive imaging with a table-top extreme ultraviolet source

We demonstrate a resolution of 45 nm with a sample size down to 3 μm × 3 μm is achieved in a short exposure time of 2 s, from the diffraction pattern generated by a table-top high harmonic source at around 30 nm. By using a narrow-bandwidth focusing mirror, the diffraction pattern's quality is improved and the required exposure time is significantly reduced. In order to obtain a high quality of the reconstructed image, the ratio of the beam size to the sample size and the curvature of the focused beam need to be considered in the reconstruction process. This new experimental scheme is very promising for imaging sub-10 nm scale objects with a table-top source based on a small inexpensive femtosecond laser system.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A CENSUS OF OXYGEN IN STAR-FORMING GALAXIES: AN EMPIRICAL MODEL LINKING METALLICITIES, STAR FORMATION RATES, AND OUTFLOWS

In this contribution, we present the first census of oxygen in star-forming galaxies in the local universe. We examine three samples of galaxies with metallicities and star formation rates (SFRs) at z = 0.07, 0.8, and 2.26, including the Sloan Digital Sky Survey (SDSS) and DEEP2 survey. We infer the total mass of oxygen produced and mass of oxygen found in the gas-phase from our local SDSS sample. The star formation history is determined by requiring that galaxies evolve along the relation between stellar mass and SFR observed in our three samples. We show that the observed relation between stellar mass and SFR for our three samples is consistent with other samples in the literature. The mass-metallicity relation is well established for our three samples, and from this we empirically determine the chemical evolution of star-forming galaxies. Thus, we are able to simultaneously constrain the SFRs and metallicities of galaxies over cosmic time, allowing us to estimate the mass of oxygen locked up in stars. Combining this work with independent measurements reported in the literature, we conclude that the loss of oxygen from the interstellar medium of local star-forming galaxies is likely to be a ubiquitous process with the oxygen mass loss scaling (almost) linearly with stellar mass. We estimate the total baryonic mass loss and argue that only a small fraction of the baryons inferred from cosmological observations accrete onto galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

HALO EXPANSION IN COSMOLOGICAL HYDRO SIMULATIONS: TOWARD A BARYONIC SOLUTION OF THE CUSP/CORE PROBLEM IN MASSIVE SPIRALS

A clear prediction of the cold dark matter (CDM) model is the existence of cuspy dark matter halo density profiles on all mass scales. This is not in agreement with the observed rotation curves of spiral galaxies, challenging on small scales the otherwise successful CDM paradigm. In this work we employ high-resolution cosmological hydrodynamical simulations to study the effects of dissipative processes on the inner distribution of dark matter in Milky Way like objects (M Almost-Equal-To 10{sup 12} M{sub Sun }). Our simulations include supernova feedback, and the effects of the radiation pressure of massive stars before they explode as supernovae. The increased stellar feedback results in the expansion of the dark matter halo instead of contraction with respect to N-body simulations. Baryons are able to erase the dark matter cuspy distribution, creating a flat, cored, dark matter density profile in the central several kiloparsecs of a massive Milky-Way-like halo. The profile is well fit by a Burkert profile, with fitting parameters consistent with the observations. In addition, we obtain flat rotation curves as well as extended, exponential stellar disk profiles. While the stellar disk we obtain is still partially too thick to resemble the Milky Way thin disk, this pilot study shows that there is enough energy available in the baryonic component to alter the dark matter distribution even in massive disk galaxies, providing a possible solution to the long-standing problem of cusps versus cores.

79 ASTRONOMY AND ASTROPHYSICS↗

Quantitative determination of energy enhanced interlayer transport in pulsed laser deposition of SrTiO3

We present a quantitative analysis of layer-by-layer growth in pulsed laser deposition using homoepitaxy of SrTiO$_3$ as a prototype perovskite. The analysis of time-dependent coverages extracted from single shot surface x-ray diffraction transients shows that pulsed laser deposition consists of two phases that occur before and after crystallization on vastly different time scales. The non-equilibrium processes during and immediately after the arrival of the laser plume represent the primary mechanism for interlayer transport before crystallization that is completed on $\mu$s-range or faster time scales. Interlayer transport slows down dramatically after crystallization because it is driven only by sluggish thermally activated processes. The thermal interlayer transport represent a small fraction of total interlayer transport that decreases with the laser repetition rate. This analysis shows the energetic species that are present only during the plume arrival to be orders of magnitude more effective than thermal processes in promoting interlayer transport that is the key to the ability of pulsed laser deposition to produce sharp interfaces in both homo and heteroepitaxial growth of oxide films.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗