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At least 847 records · Page 47

Capturing O2 Desorption Through Isoconversional Kinetics for CFD Application

The present work examines desorption mechanisms and kinetics of the calcium-doped strontium perovskite at 25% calcium content (i.e., Sr_0.75 Ca_0.25 FeO_(3-δ)). Laboratory-scale, low inventory, fixed bed redox cycle experiments were developed and conducted in both dry and steam-based environments for three isothermal temperatures, 450, 500 and 550C. The temporal evolution of the conversion extent of the material sample over the redox cycles were obtained through the analysis of the gaseous products of the redox reactions. Using subsequently isoconversional differential methods, it was found that the activation energy exhibits a strong dependence on the extent of conversion during the desorption of this perovskite. In addition, the reconstruction of the reaction model showed that the desorption kinetics are controlled by a three-step mechanism. A successful a priori verification of the isoconversional desorption kinetics against the dry and steam-based environment desorption experimental data are shown.

Konan, Ndri A.↗

FY24 Status of Engineered Barrier Systems Research

This report describes research and development (R&D) activities conducted during Fiscal Year 2024 (FY24) specifically related to the Engineered Barrier System (EBS) R&D Work Package in the Spent Fuel and High-Level Waste Disposition Campaign supported by the United States (U.S.) Department of Energy (DOE). The R&D activities focus on understanding EBS component evolution and interactions within the EBS, as well as interactions between the host media and the EBS. The R&D team represented in this report consists of individuals from Sandia National Laboratories, Lawrence Berkeley National Laboratory (LBNL), Los Alamos National Laboratory (LANL), and Vanderbilt University. EBS R&D work also leverages international collaborations to ensure that the DOE program is active and abreast of the latest advances in nuclear waste disposal.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Neutronics analyses for the conceptual design of the SNS Second Target Station

The Spallation Neutron Source, in operation at the Oak Ridge National Laboratory since 2006, was designed to allow the addition of a second target station and an upgrade of the accelerator proton power. Both upgrades are now underway. Here we describe the evolution of the design of the target of the second target station with the emphasis on the effects of the proton beam footprint on the energy deposition in the target, stresses induced by the pulsed operation, and the importance of the residual heat. The moderator configurations and their optimization are discussed. With the utilization of pure parahydrogen moderators, small neutron beam cross-sections, and the specific optimization, neutron beams of the second target station will achieve exceptionally high peak brightness and time-averaged brightness.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Exobiology experiment concepts for space station

The exobiology discipline uses ground based and space flight resources to conduct a multidiscipline research effort dedicated to understanding fundamental questions about the origin, evolution, and distribution of life and life related molecules throughout the universe. Achievement of this understanding requires a methodical research strategy which traces the history of the biogenic elements from their origins in stellar formation processes through the chemical evolution of molecules essential for life to the origin and evolution of primitive and, ultimately, complex living species. Implementation of this strategy requires the collection and integration of data from solar system exploration spacecraft and ground based and orbiting observatories and laboratories. The Science Lab Module (SLM) of the Space Station orbiting complex may provide an ideal setting in which to perform certain classes of experiments which form the cornerstone of exobiology research. These experiments could demonstrate the pathways and processes by which biomolecules are synthesized under conditions that simulate the primitive Earth, planetary atmospheres, cometary ices, and interstellar dust grains. Exobiology experiments proposed for the Space Station generally fall into four classes: interactions among gases and grains (nucleation, accretion, gas-grain reactions), high energy chemistry for the production of biomolecules, physical and chemical processes occurring on an artificial comet, and tests of the theory of panspermia.

Griffiths, L. D.↗

Exobiology experiment concepts for Space Station

The exobiology discipline uses ground based and space flight resources to conduct a multidiscipline research effort dedicated to understanding fundamental questions about the origin, evolution, and distribution of life and life related molecules throughout the universe. Achievement of this understanding requires a methodical research strategy which traces the history of the biogenic elements from their origins in stellar formation processes through the chemical evolution of molecules essential for life to the origin and evolution of primitive and, ultimately, complex living species. Implementation of this strategy requires the collection and integration of data from solar system exploration spacecraft and ground based and orbiting observatories and laboratories. The Science Lab Module (SLM) of the Space Station orbiting complex may provide an ideal setting in which to perform certain classes of experiments which form the cornerstone of exobiology research. These experiments could demonstrate the pathways and processes by which biomolecules are synthesized under conditions that stimulate the primitive earth, planetary atmospheres, cometary ices, and interstellar dust grains. Exobiology experiments proposed for the Space Station generally fall into four classes: interactions among gases and grains (nucleation, accretion, gas-grain reactions), high energy chemistry for the production of biomolecules, physical and chemical processes occurring on an artificial comet, and tests of the theory of panspermia.

Griffiths, Lynn D.↗

Windows on the axion

Peccei-Quinn symmetry with attendant axion is a most compelling, and perhaps the most minimal, extension of the standard model, as it provides a very elegant solution to the nagging strong CP-problem associated with the theta vacuum structure of QCD. However, particle physics gives little guidance as to the axion mass; a priori, the plausible values span the range: 10(-12)eV is approx. less than m(a) which is approx. less than 10(6)eV, some 18 orders-of-magnitude. Laboratory experiments have excluded masses greater than 10(4)eV, leaving unprobed some 16 orders-of-magnitude. Axions have a host of interesting astrophysical and cosmological effects, including, modifying the evolution of stars of all types (our sun, red giants, white dwarfs, and neutron stars), contributing significantly to the mass density of the Universe today, and producting detectable line radiation through the decays of relic axions. Consideration of these effects has probed 14 orders-of-magnitude in axion mass, and has left open only two windows for further exploration: 10(-6)eV is approx. less than m(a) is approx. less than 10(-3)eV and 1eV is approx. less than m(a) is approx. less than 5eV (hadronic axions only). Both these windows are accessible to experiment, and a variety of very interesting experiments, all of which involve heavenly axions, are being planned or are underway.

Turner, Michael S.↗

A proven approach for more effective software development and maintenance

Modern space flight mission operations and associated ground data systems are increasingly dependent upon reliable, quality software. Critical functions such as command load preparation, health and status monitoring, communications link scheduling and conflict resolution, and transparent gateway protocol conversion are routinely performed by software. Given budget constraints and the ever increasing capabilities of processor technology, the next generation of control centers and data systems will be even more dependent upon software across all aspects of performance. A key challenge now is to implement improved engineering, management, and assurance processes for the development and maintenance of that software; processes that cost less, yield higher quality products, and that self-correct for continual improvement evolution. The NASA Goddard Space Flight Center has a unique experience base that can be readily tapped to help solve the software challenge. Over the past eighteen years, the Software Engineering Laboratory within the code 500 Flight Dynamics Division has evolved a software development and maintenance methodology that accommodates the unique characteristics of an organization while optimizing and continually improving the organization's software capabilities. This methodology relies upon measurement, analysis, and feedback much analogous to that of control loop systems. It is an approach with a time-tested track record proven through repeated applications across a broad range of operational software development and maintenance projects. This paper describes the software improvement methodology employed by the Software Engineering Laboratory, and how it has been exploited within the Flight Dynamics Division with GSFC Code 500. Examples of specific improvement in the software itself and its processes are presented to illustrate the effectiveness of the methodology. Finally, the initial findings are given when this methodology was applied across the mission operations and ground data systems software domains throughout Code 500.

Pajerski, Rose↗

The AstroBiology Explorer (ABE) MIDEX Mission Concept: Identifying Organic Molecules in Space

The Astrobiology Explorer (ABE) is a MIDEX mission concept, currently under Concept Phase A study at NASA's Ames Research Center in collaboration with Ball Aerospace & Technologies, Corp., and managed by NASA's Jet Propulsion Laboratory. ABE will conduct infrared spectroscopic observations to address important problems in astrobiology, astrochemistry, and astrophysics. The core observational program would make fundamental scientific progress in understanding the distribution, identity, and evolution of ices and organic matter in dense molecular clouds, young forming stellar systems, stellar outflows, the general diffuse ISM, HII regions, Solar System bodies, and external galaxies. The ABE instrument concept includes a 0.6 m aperture Ritchey-Chretien telescope and three moderate resolution (R = 2000-3000) spectrometers together covering the 2.5-20 micron spectral region. Large format (1024 x 1024 pixel) IR detector arrays will allow each spectrometer to cover an entire octave of spectral range per exposure without any moving parts. The telescope will be cooled below 50 K by a cryogenic dewar shielded by a sunshade. The detectors will be cooled to approx. 7.5 K by a solid hydrogen cryostat. The optimum orbital configuration for achieving the scientific objectives of the ABE mission is a low background, 1 AU Earth driftaway orbit requiring a Delta II launch vehicle. This configuration provides a low thermal background and allows adequate communications bandwidth and good access to the entire sky over the approx. 1.5 year mission lifetime.

Ennico, Kimberly↗

Continuing Evolution of Mars Sample Return

This paper addresses the continued evolution of the Groundbreaking MSR concept over the last year. One of the tenets of the low-cost approach is to use substantial heritage from an earlier mission, Mars Science Laboratory (MSL). Recently, the MSL project developed and switched to a revolutionary landing approach, coined 'sky-crane' where the MSL, which is a rover, is lowered gently to the Martian surface from a hovering vehicle. MSR has adopted this approach, again continuing to capitalize on the heritage for a significant portion of the new lander. In parallel, a MSR Technology Board was formed to reexamine MSR technology needs and participate in a continuing refinement of architectural trades. While the focused technology program continues to be definitized through the remainder of this year, the current assessment of what technology development is required, is discussed in this paper. In addition, the results of new trade studies and considerations will be discussed.

Mars Sample Return (MSR)↗

Nature of Reduced Carbon in Martian Meteorites

Martian meteorites provide important information on the nature of reduced carbon components present on Mars throughout its history. The first in situ analyses for carbon on the surface of Mars by the Viking landers yielded disappointing results. With the recognition of Martian meteorites on Earth, investigations have shown carbon-bearing phases exist on Mars. Studies have yielded presence of reduced carbon, carbonates and inferred graphitic carbon phases. Samples ranging in age from the first approximately 4 Ga of Mars history [e.g. ALH84001] to nakhlites with a crystallization age of 1.3 Ga [e.g. Nakhla] with aqueous alteration processes occurring 0.5-0.7 Ga after crystallizaton. Shergottites demonstrate formation ages around 165-500 Ma with younger aqueous alterations events. Only a limited number of the Martian meteorites do not show evidence of significance terrestrial alterations. Selected areas within ALH84001, Nakhla, Yamato 000593 and possibly Tissint are suitable for study of their indigenous reduced carbon bearing phases. Nakhla possesses discrete, well-defined carbonaceous phases present within iddingsite alteration zones. Based upon both isotopic measurements and analysis of Nakhla's organic phases the presence of pre-terrestrial organics is now recognized. The reduced carbon-bearing phases appear to have been deposited during preterrestrial aqueous alteration events that produced clays. In addition, the microcrystalline layers of Nakhla's iddingsite have discrete units of salt crystals suggestive of evaporation processes. While we can only speculate on the origin of these unique carbonaceous structures, we note that the significance of such observations is that it may allow us to understand the role of Martian carbon as seen in the Martian meteorites with obvious implications for astrobiology and the pre-biotic evolution of Mars. In any case, our observations strongly suggest that reduced organic carbon exists as micrometer- size, discrete structures on Mars associated with clay and salt minerals. The Mars Science Laboratory s investigators should be aware of reduced organic carbon components within clay-bearing phases.

Gibson, Everett K., Jr.↗

Laser Communications Relay Demonstration (LCRD) Update and the Path Towards Optical Relay Operations

This paper provides a concept for an evolution of NASA's optical communications near Earth relay architecture. NASA's Laser Communications Relay Demonstration (LCRD), a joint project between NASA's Goddard Space Flight Center (GSFC), the Jet Propulsion Laboratory - California Institute of Technology (JPL), and the Massachusetts Institute of Technology Lincoln Laboratory (MIT LL). LCRD will provide a minimum of two years of high data rate optical communications service experiments in geosynchronous orbit (GEO), following launch in 2019. This paper will provide an update of the LCRD mission status and planned capabilities and experiments, followed by a discussion of the path from LCRD to operational network capabilities.

Space Communications↗

American Made Energy Infrastructure - Evolution of Federal Incentives and Requirements

This presentation, "Evolution of Federal Incentives and Requirements," explores the development and impact of federal cybersecurity regulations, tax credits, and domestic content requirements on the energy sector. It covers key legislation such as the ARRA of 2009, IIJA, and IRA, and their implications for grid modernization, manufacturing, and deployment of energy technologies. The presentation also addresses definitions and restrictions related to Foreign Entities of Concern (FEOC) and their impact on federal procurement. Additionally, it introduces the DOE's cybersecurity framework for energy supply chains and practical actions for compliance planning.

25 - ENERGY STORAGE↗

The physical foundation of the reconnection electric field

Magnetic reconnection is a key charged particle transport and energy conversion process in environments ranging from astrophysical systems to laboratory plasmas [Yamada et al., Rev. Mod. Phys. 82, 603–664 (2010)]. Magnetic reconnection facilitates plasma transport by establishing new connections of magnetic flux tubes, and it converts, often explosively, energy stored in the magnetic field to kinetic energy of charged particles [J. L. Burch and J. F. Drake, Am. Sci. 97, 392–299 (2009)]. The intensity of the magnetic reconnection process is measured by the reconnection electric field, which regulates the rate of flux tube connectivity changes. The change of magnetic connectivity occurs in the current layer of the diffusion zone, where the plasma transport is decoupled from the transport of magnetic flux. Here we report on computer simulations and analytic theory to provide a self-consistent understanding of the role of the reconnection electric field, which extends substantially beyond the simple change of magnetic connections. Rather, we find that the reconnection electric field is essential to maintain the current density in the diffusion region, which would otherwise be dissipated by a set of processes. Natural candidates for current dissipation are the average convection of current carriers away from the reconnection region by the outflow of accelerated particles, or the average rotation of the current density by the magnetic field reversal in the vicinity. Instead, we show here that the current dissipation is the result of thermal effects, underlying the statistical interaction of current-carrying particles with the adjacent magnetic field. We find that this interaction serves to redirect the directed acceleration of the reconnection electric field to thermal motion. This thermalization manifests itself in form of quasi-viscous terms in the thermal energy balance of the current layer. This collisionless viscosity, found in the pressure evolution equation, dominates near the x-line. These quasi-viscous terms act to increase the average thermal energy. Our predictions regarding current and thermal energy balance are readily amenable to exploration in the laboratory or by satellite missions, in particular, by NASA's Magnetospheric Multiscale mission.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Enhancing Oxygen Evolution Reaction and Stability in Proton-Conducting Solid Oxide Electrolysis Cells (p-SOECs) via a Porous Gadolinium-Doped Ceria Interlayer

Proton-conducting solid oxide electrolysis cells (p-SOECs) offer a promising pathway for intermediate temperature (400-600 °C) hydrogen production. However, they still face critical challenges related to sluggish oxygen evolution reaction (OER) kinetics and low Faradaic efficiencies. Here, in this work, we demonstrate that introducing a thin (~0.8 µm) porous Gd 0.1 Ce 0.9 O 1.95 (GDC) interlayer between a BaCo 0.8 Zr 0.1 Zn 0.1 O 3-δ (BCZZ) oxygen electrode and electrolyte significantly enhances p-SOEC performance. The GDC interlayer reduces polarization resistance by 48% (0.54 to 0.28 O cm 2 ) and increases Faradaic efficiency from 63% to 81% at -0.8 A/cm 2 and 600 °C. GDC interlayer p-SOECs display elevated effective H 2 current densities compared to control p-SOECs and reach up to -1.22 A/cm 2 at 1.3 V. Mechanistic studies on the interactions between GDC and BCZZ reveal that GDC intrinsically promotes OER kinetics by significantly reducing the polarization activation energy (Ea p ), dropping from 1.45 to 1.22 eV for full p-SOECs and 0.98 to 0.76 eV for symmetric cells. This promotional effect is localized in the electrochemically active region near the electrolyte interface. Durability testing for over 1500 hours under 50% H 2 O conditions indicates that the GDC interlayer also improves long-term stability, with a degradation rate 53% lower than control p-SOECs. By pinpointing the interfacial region where GDC exerts its promotional effect, highlighting its role in enhancing OER kinetics, and establishing interlayer engineering as a powerful technique, this work provides a unified pathway to simultaneously improve p-SOEC activity, Faradaic efficiency, and durability.

08 - HYDROGEN↗

Final Report for Large Scale Laboratory Experiments on Kinetic Magnetic Reconnection

Magnetic reconnection plays a fundamental role in nearly all magnetized plasmas as it enables magnetic energy to be converted into high speed flows, and thermal energy. It allows the magnetic field lines to change topology in collisionless plasmas, and it thereby controls the spatial and temporal evolution of explosive phenomena such as solar flares, coronal mass ejections, and internal disruptions in fusion devices. Because of its strong impact on the plasma dynamics, understanding the physics of magnetic reconnection is one of the most important topics in plasma physics. New frontiers have now emerged in reconnection research with an emphasis on particle energization, reconnection with multiple X-lines in large systems, and the role of kinetic effects in collisionless reconnection. These research topics are closely linked and large scale computer simulations show that 3D effects are likely important to explain the detailed observations of reconnection in solar, interplanetary and magnetospheric plasmas. For experiments to remain relevant in this maturing field of research and help push forward the new frontiers, new devices are needed which access the regimes of large system size and low normalized collisionallity. To address this need, the project the new Terrestrial Reconnection EXperiment (TREX), which is spatially the largest dedicated reconnection experiment constructed to date. With the use of the 3m diameter spherical vacuum vessel of the Madison Plasma Dynamo Experiment (MPDX), the TREX is highly leveraged by earlier NSF investments. MPDX was constructed with funds from NSF's MRI program and is now being operated as a multi-investigator facility, which we name the Wisconsin Plasma Physics Laboratory (WiPPL). The project was carried out mainly by two UW-Madison graduate students, for reconnection in parameter regimes and configurations in TREX not attainable by previous experiments. The implementation of TREX within WiPPL renders the upgraded facility unique in its capabilities to extend the frontiers of experimental reconnection research, including access to reconnection in the collisionless regime at large system sizes and compatible with three-dimensional configurations. The theoretical teams in reconnection research have been given full access to the experimental results. Our experimental results havel allowed us to test existing theoretical models, provide resolution to controversy, and stimulate new understanding of magnetic reconnection. The WiPPAL, with its large basic plasma physics device, is largely operated by graduate and undergraduate students. It has proven an ideal facility for students to become immersed in state of the art research while learning the fundamental principles of plasma physics. The program has also proven effective in attracting new outstanding students into plasma physics and providing them with exciting learning experiences. While our research program and experimental results successfully compete with those of professional scientists at national labs, the most important legacy of our research is, perhaps, the broad training in experimental plasma physics of the large number of students affiliated with our program.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

High-Mach number, laser-driven magnetized collisionless shocks

Collisionless shocks are ubiquitous in space and astrophysical systems, and the class of supercritical shocks is of particular importance due to their role in accelerating particles to high energies. While these shocks have been traditionally studied by spacecraft and remote sensing observations, laboratory experiments can provide reproducible and multi-dimensional datasets that provide complementary understanding of the underlying microphysics. We present experiments undertaken on the OMEGA and OMEGA EP laser facilities that show the formation and evolution of high-Mach number collisionless shocks created through the interaction of a laser-driven magnetic piston and magnetized ambient plasma. Through time-resolved, 2-D imaging we observe large density and magnetic compressions that propagate at super-Alfvenic speeds and that occur over ion kinetic length scales. Electron density and temperature of the initial ambient plasma are characterized using optical Thomson scattering. Measurements of the piston laser-plasma are modeled with 2-D radiation-hydrodynamic simulations, which are used to initialize 2-D particle-in-cell simulations of the interaction between the piston and ambient plasmas. The numerical results show the formation of collisionless shocks, including the separate dynamics of the carbon and hydrogen ions that constitute the ambient plasma and their effect on the shock structure. Furthermore, the simulations also show the shock separating from the piston, which we observe in the data at late experimental times.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Synthesis of rhenium coatings on 316 stainless steel and their electrochemical behavior towards water oxidation in saline environments

The production of electrolytic hydrogen or Green Hydrogen has attracted the attention of scientists as a potential enabler of sustainable energy production. The cleavage of the water molecule requires high energy, in order to produce hydrogen and oxygen through their corresponding half reactions, the hydrogen evolution and oxygen evolution reactions. Further, this latter reaction has been studied in more detail, since its slow kinetics make the water electrolysis less efficient, and, for instance, delay the formation of hydrogen in the counter compartment of the electrolytic cell. In this work, a study of the oxygen evolution reaction is presented. For this, a series of rhenium catalysts deposited onto stainless steel 316 are studied with the aim of analyzing the effect of the pure metal (Re) and the metal with heteroatoms (Re-C, Re-B, and Re-O). As one of the problems worldwide is the scarcity of freshwater, the study focuses on the performance of this series of catalysts in highly saline environments, representative of seawater. The synthesis and electrochemical performance is shown, giving high expectations that these electrocatalysts could be potential electrocatalysts in marine environments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A near-explicit mechanistic evaluation of Isoprene photochemical seecondary organic aerosol formation and evolution: simulations of multiple chamber experiments with and without added NOx

Experimentally determined yields of secondary organic aerosol (SOA) from the photochemical oxidation of isoprene in the absence of aqueous acidic aerosol vary substantially, both within a given experiment and across different environmental chamber conditions. The underlying mechanisms driving this variation remain poorly evaluated, leading to significant uncertainty in how to extrapolate laboratory chamber results to the atmosphere. Herein, we compare SOA predictions from a near-explicit gas-phase chemical mechanism of isoprene oxidation by the hydroxyl radical (OH) in the presence and absence of nitrogen oxide radicals (NOx), to multiple chamber experiments on non-aqueous isoprene photochemical SOA (ipSOA) conducted by different groups in different chambers. SOA is predicted by volatility-driven gas-particle partitioning of hundreds of individual reaction products. The mechanism includes simplified descriptions of particle-phase organic chemistry, including organic hydroperoxide photolysis, and organic nitrate hydrolysis and accretion reactions. The model has good skill (mean normalized bias typically within 25%) at predicting the observed formation and evolution of ipSOA across a range of chambers and conditions at low NOx. The model has much less skill at describing the observed non-linear response of ipSOA to elevated NOx. Organic nitrate hydrolysis is unable to explain significant ipSOA at high NOx, whereas particle-phase accretion reactions of tertiary nitrates may play a role. Uncertainties in the chamber radical environment and fate of key organic peroxy radicals (RO2) remain as or even more important than vapor losses to chamber walls in determining how best to extrapolate chamber-based yields to the atmosphere. Implications for likely atmospheric yields of ipSOA and recommendations for future chamber experiments are discussed.

Thornton, Joel A.↗