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At least 847 records · Page 47

Magnetic phase diagram and electronic structure of UPt 2 Si 2 at high magnetic fields: A possible field-induced Lifshitz transition

We have measured Hall effect, magnetotransport and magnetostriction on the field induced phases of single crystalline UPt2Si2 in magnetic fields up to 60T at temperatures down to 50mK, this way firmly establishing the phase diagram for magnetic fields Bka and c axes. Moreover, for Bkc axis we observe strong changes in the Hall effect at the phase boundaries. From a comparison to band structure calculations utilizing the concept of a dual nature of the uranium 5f electrons, we propose that these represent field induced topological changes of the Fermi surface due to at least one Lifshitz transition. Furthermore, we find a unique history dependence of the magnetotransport and magnetostriction data, indicating that the proposed Lifshitz type transition is of a discontinuous nature, as predicted for interacting electron systems.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Proton deflectometry analysis in magnetized plasmas: Magnetic field reconstruction in one dimension

Proton deflectometry is used in magnetized high-energy-density plasmas to observe electromagnetic fields. Here we describe a reconstruction algorithm to recover the electromagnetic fields from proton fluence data in 1-D. The algorithm is verified against analytic solutions and applied to example data. Next, we study the role of source fluence uncertainty for 1-D reconstructions. We show that reconstruction boundary conditions can be used to constrain the source fluence profile and use this to develop a reconstruction using a specified pair of boundary conditions on the magnetic field. From these considerations, we experimentally demonstrate a hybrid mesh-fluence reconstruction technique where fields are reconstructed from fluence data in an interior region with boundary conditions supplied by direct mesh measurements at the boundary.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Conversion of Magnetic Energy to Plasma Kinetic Energy During Guide Field Magnetic Reconnection in the Laboratory

Here, we present laboratory measurements showing the two-dimensional (2D) structure of energy conversion during magnetic reconnection with a guide field over the electron and ion diffusion regions, resolving the separate energy deposition on electrons and ions. We find that the electrons are energized by the parallel electric field at two locations, at the X line and around the separatrices. On the other hand, the ions are energized ballistically by the perpendicular electric field in the vicinity of the high-density separatrices. An energy balance calculation by evaluating the terms of the Poynting theorem shows that 40% of the magnetic energy is converted to particle energy, 2/3 of which is transferred to ions and 1/3 to electrons. Further analysis suggests that the energy deposited on particles manifests mostly in the form of thermal kinetic energy in the diffusion regions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Combined Dimensional and Topology Optimization of Interior Permanent Magnet Synchronous Machine Rotors Using a Permanent Magnet Function Interpolation Method

This paper presents a magneto-structural combined dimensional and topology optimization technique for interior permanent magnet synchronous machine (IPMSM) rotors. Dimensional changes to the permanent magnet (PM) location or size are accomplished by interpolating or projecting a smoothed Heaviside rectangular function representing the presence of PM material onto the IPMSM rotor design domain mesh. A density based Solid Isotropic with Material Penalization (SIMP) topology optimization approach is then used to vary the presence of electrical steel in mesh elements to form flux barriers around the PM. The proposed method enforces a defined shape for the PM without requiring the mesh in the design domain to be deformed. Three examples are presented to demonstrate the technique: two flat bar IPMSM and one V-shaped IPMSM.

33 ADVANCED PROPULSION SYSTEMS↗

Effect of processing hydrogen pressure on magnetic properties of HDDR Nd-Fe-B magnet

High coercivity and anisotropic Nd-Fe-B powders for making anisotropic bonded magnets have been prepared by hydrogenation-disproportionation-desorption-recombination (HDDR). In this work, we found that the processing hydrogen pressure is intimately correlated with the formation of c-axis crystal texture of Nd 2 Fe 14 B phase. There exists a critical hydrogen pressure, P crit , during hydrogen-disproportionation stage, that promotes the formation of c-axis crystal texture. When processing hydrogen pressure is higher than P crit , the formation of c-axis texture deteriorates and results in isotropic Nd-Fe-B magnetic powders. The existence of P crit is ascribed to the thermodynamics and kinetics origin during HDDR process.

36 MATERIALS SCIENCE↗

Isotope-Specific Analysis of Neutron-Irradiated Lithium Aluminate Ceramics by Nuclear Magnetic Resonance Spectroscopy

The effects of neutron irradiation on lithium aluminate targets and the permeation of tritium into surrounding components are primary concerns in the development of materials for use in tritium production. The high specific activity and volatility of the tritium in activated samples greatly increase the challenges of experimental analysis. This paper reports the determination of the chemical forms and quantities of H-3 and Li-6 in irradiated and non-irradiated LiAlO2 by nuclear magnetic resonance (NMR) spectroscopy, and demonstrates that measurements can be performed in a non-destructive, safe manner to obtain isotope-selective, quantitative information on highly hazardous materials.

Tritium, solid state nuclear magnetic resonance sp↗

Influence of the Magnetic Moment of the Probe of a Magnetic Resonance Force Microscope on the Spin-Wave Resonance Spectra

Abstract—The ferromagnetic resonance in an array of permalloy microstrips 3000 × 500 × 30 nm{sup 3} in size, which are ordered on a rectangular 3.5 × 6 μm{sup 2} lattice, is studied using magnetic resonance force microscopy with strong probe–sample interaction. This interaction induces intricate modifications of the observed spectra, which are manifested both in line splitting and in changes in shape. The dependences of the observed spectra on the sample–probe distance and the orientation of the magnetic moment of the probe are analyzed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A mechanism for the dynamo terms to sustain closed-flux current, including helicity balance, by driving current which crosses the magnetic field

An analysis of imposed dynamo current drive (IDCD) [T.R. Jarboe et al., Nucl. Fusion 52 083017 (2012)] reveals: (a) current drive on closed flux surfaces seems possible without relaxation, reconnection, or other flux-surface-breaking large events; (b) the scale size of the key physics may be smaller than is often computationally resolved; (c) helicity can be sustained across closed flux; and (d) IDCD current drive is parallel to the current which crosses the magnetic field to produce the current driving force. In addition to agreeing with spheromak data, IDCD agrees with selected tokamak data.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Ensemble-Based Support Vector Regression with Gravitational Search Algorithm Optimization for Estimating Magnetic Relative Cooling Power of Manganite Refrigerant in Magnetic Refrigeration Application

Magnetic refrigeration technology (MRT) is considered an energy-efficient and environmental-friendly system of refrigeration that has a considerable potential of replacing the classical gas-compression expansion method of refrigeration. Inclusion of manganite-based material (MBM) in MRT as a magnetic refrigerant has attracted significant attention recently due to cost effectiveness of the refrigerant as well as better resistance to oxidation and corrosion as compared to the commonly used metal gadolinium refrigerant. Relative cooling power (RCP) is one of the most important parameters to be considered while assessing the usefulness of MBM. Its value can be altered through doping with external materials and accurate estimation of the dopant influence is required to achieve the right amount of RCP. This present research work proposes support vector regression (SVR) ensemble models with gravitational search algorithm (GSA) hyper-parameters optimization, for estimating RCP of MBM and to determine the influence of dopants on RCP using ionic radii and dopant concentrations as descriptors. GSA-SVR ensemble model (GSE) is developed by employing the outputs of five different SVR models as descriptors while GSA-SVR ensemble model with averaging (GSEA) uses the average of the five different SVR models as its descriptor. The novel ensemble models outperform other SVR models, specifically; GSE performs better than GSA-SVR model and the conventional SVR model with performance improvement of 269.14% and 283.61%, respectively on the basis of root mean square error (RMSE). Furthermore, GSEA outperforms GSE, GSA-SVR model and conventional SVR with performance improvement of 27.51%, 370.70%, and 389.14%, respectively on the basis of RMSE. The developed GSE and GSEA also perform better than the existing RCP model in the literature with performance improvement of 11.53% and 42.21%, respectively. The results of this research work will not only serve to circumvent the experimental challenges of RCP measurement without loss of experimental precision but also further promotes environment-friendly system of refrigeration.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

29 Si nuclear magnetic resonance study of URu 2 Si 2 under pressure

Wereport 29Si nuclearmagneticresonancemeasurementsofsinglecrystalsandalignedpowdersof URu2Si2 under pressureinthehiddenorderandparamagneticphases.We find thattheKnightshift decreases withappliedpressure,consistentwithpreviousmeasurementsofthestaticmagneticsus- ceptibility.Previousmeasurementsofthespinlatticerelaxationtimerevealedapartialsuppressionof the densityofstatesbelow30K.Thissuppressionpersistsunderpressure,andtheonsettemperatureis mildly enhanced.

Hidden order↗

Spin-Selective Oxygen Evolution Reaction in Chiral Iron Oxide Nanoparticles: Synergistic Impact of Inherent Magnetic Moment and Chirality

Electron spin polarization is identified as a promising avenue for enhancing the oxygen evolution reaction (OER), which is the bottleneck that limits the energy efficiency of water-splitting. Here, in this work, we report that both ferrimagnetic (f-Fe 3 O 4 ) and superparamagnetic iron oxide (s-Fe 3 O 4 ) catalysts can exhibit external magnetic field (Hext)-induced OER enhancement, and the activity is proportional to their intrinsic magnetic moment. Additionally, the chirality-induced spin selectivity (CISS) effect was utilized in synergy with Hext to get a maximum enhancement of up to 89% improvement in current density (at 1.8 V vs RHE) with a low onset potential of 270 mV in s-Fe 3 O 4 catalysts. Spin polarization and the resultant spin selectivity suppress the production of H 2 O 2 and promote the formation of ground state triplet O 2 during the OER. Furthermore, the design of chiral s-Fe 3 O 4 with synergistic spin potential effect demonstrates a high spin polarization of ∼42%, as measured using conductive atomic force microscopy (c-AFM).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Interaction of Hydrocarbons with Clays under Reservoir Conditions: In Situ Infrared and Nuclear Magnetic Resonance Spectroscopy and X-ray Diffraction for Expandable Clays with Variably Wet Supercritical Methane

The results from novel in situ high-pressure nuclear magnetic resonance (NMR) spectroscopy, infrared (IR) spectroscopy, and X-ray diffraction (XRD) investigation of the interaction of the smectite hectorite with variably wet supercritical methane (scCH4) at 90 bar and 323 K (hydrostatic conditions equivalent to ~1 km depth) show that CH4 occurs in the clay interlayers, in pores external to the individual clay particles, and as bulk fluid. The occupancy of each environment depends on the relative humidity (RH) of the CH4-rich fluid and the hydration energy and size of the charge-balancing cation. As RH increases, the fraction of interlayer and interparticle CH4 decreases, although with Cs+, addition of a small amount of H2O initially increases CH4 uptake. Maximum interlayer CH4 adsorption occurs when the mean basal spacing just permits methane intercalation (~11.5 Å) and never below this basal spacing. It is also higher with divalent cations than with monovalent cations. The data show that CH4 adsorption occurs predominantly via a weak dispersion interaction with the clay and that its intercalation occurs via a passive space-filling hydrophobic mechanism. The results suggest that, under reservoir conditions, smectite interlayers may provide a reservoir for CH4 under low-water conditions.

Bowers, Geoffrey M.↗