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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 847 records · Page 47
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Microwave-Free Dynamic Nuclear Polarization via Sudden Thermal Jumps

Dynamic nuclear polarization (DNP) presently stands as the preferred strategy to enhance the sensitivity of nuclear magnetic resonance measurements, but its application relies on the use of high-frequency microwave to manipulate electron spins, an increasingly demanding task as the applied magnetic field grows. Here we investigate the dynamics of a system hosting a polarizing agent formed by two distinct paramagnetic centers near a level anticrossing. We theoretically show that nuclear spins polarize efficiently under a cyclic protocol that combines alternating thermal jumps and radio-frequency pulses connecting hybrid states with opposite nuclear and electronic spin alignment. Central to this process is the difference between the spin-lattice relaxation times of either electron spin species, transiently driving the electronic spin bath out of equilibrium after each thermal jump. Without the need for microwave excitation, this route to enhanced nuclear polarization may prove convenient, particularly if the polarizing agent is designed to feature electronic level anticrossings at high magnetic fields.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2022

The CMS Magnetic Field Measuring and Monitoring Systems

This review article describes the performance of the magnetic field measuring and monitoring systems for the Compact Muon Solenoid (CMS) detector. To cross-check the magnetic flux distribution obtained with the CMS magnet model, four systems for measuring the magnetic flux density in the detector volume were used. The magnetic induction inside the 6 m diameter superconducting solenoid was measured and is currently monitored by four nuclear magnetic resonance (NMR) probes installed using special tubes outside the barrel hadron calorimeter. Two more NRM probes were installed at the faces of the tracking system. The field inside the superconducting solenoid was precisely measured in 2006 in a cylindrical volume of 3.448 m in diameter and 7 m in length using 10 three-dimensional (3D) B-sensors based on the Hall effect. These B-sensors were installed on each of the two propeller arms of an automated field-mapping machine. In addition to these measurement systems, a system for monitoring the magnetic field during the CMS detector operation has been developed. Inside the solenoid in the horizontal plane, 4 3D B-sensors were installed at the faces of the tracking detector. Twelve 3D B-sensors were installed on the surfaces of the flux-return yoke nose disks. Seventy 3D B-sensors were installed in the air gaps of the CMS magnet yoke. A specially developed flux loop technique was used for the most complex measurements of the magnetic flux density inside the steel blocks of the CMS magnet yoke. The flux loops are installed in 22 sections of the flux-return yoke blocks. The areas enclosed by these coils varied from 0.3 to 1.59 m$^{2}$ in the blocks of the barrel wheels and from 0.5 to 1.12 m$^{2}$ in the blocks of the yoke endcap disks. The development of these systems and the results of the magnetic flux density measurements across the CMS magnet are presented and discussed in this review article.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Measurement of Local Magnetic Fields in Actinide Tetrafluorides

Fluorine-19 magnetic shielding tensors have been measured in a series of actinide tetrafluorides (AnF4) by solid state nuclear magnetic resonance (NMR) spectroscopy. Tetravalent actinide centers with 0 to 8 valence electrons can form tetrafluorides with the same unit cell, making these compounds an attractive choice for a systematic study of the variation in electronic structure across the 5f row of the Periodic Table. Pronounced deviations from predictions based on localized valence electron models have been detected by these experiments, which suggests that this approach may be used as a quantitative probe of electronic correlations.

Walter, Eric D.↗
DOE OSTI2015

Dynamic nuclear polarization solid-state NMR in heterogeneous catalysis research

In this study, a revolution in solid-state nuclear magnetic resonance (SSNMR) spectroscopy is taking place, attributable to the rapid development of high-field dynamic nuclear polarization (DNP), a technique yielding sensitivity improvements of 2–3 orders of magnitude . This higher sensitivity in SSNMR has already impacted materials research, and the implications of new methods on catalytic sciences are expected to be profound.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Magnetic detwinning and biquadratic magnetic interaction in EuFe 2 As 2 revealed by 153 Eu NMR

In the nematic state of iron-based superconductors, twin formation often obscures the intrinsic, anisotropic, in-plane physical properties. Relatively high in-plane external magnetic fields H ext greater than the typical laboratory-scale magnetic fields 10–15 T are usually required to completely detwin a sample. However, recently a very small in-plane H ext ~ 0.1 T was found to be sufficient for detwinning the nematic domains in EuFe 2 As 2 . To explain this behavior, a microscopic theory based on biquadratic magnetic interactions between the Eu and Fe spins has been proposed. In this paper, using 153 Eu nuclear magnetic resonance (NMR) measurements below the Eu 2+ ordering temperature, we show experimental evidence of the detwinning under small in-plane H ext . Our NMR study also reveals the evolution of the angles between the Eu and Fe spins during the detwinning process, which provides experimental evidence for the existence of biquadratic coupling in the system.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Noncollinear antiferromagnetism of coupled spins and pseudospins in the double perovskite La 2 CuIrO 6

This article reports the structural, magnetic, and thermodynamic properties of the double perovskite compound La 2 CuIrO 6 from x-ray, neutron diffraction, neutron depolarization, dc magnetization, ac susceptibility, specific heat, muon-spin-relaxation ( μ SR ) , electron-spin-resonance (ESR) and nuclear magnetic resonance (NMR) measurements. Below ~113 K, short-range spin-spin correlations occur within the Cu 2+ sublattice.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Magnetic field induced anisotropy of 139 La spin-lattice relaxation rates in stripe ordered La 1.875 Ba 0.125 CuO 4

We report 139 La nuclear magnetic resonance studies performed on a La 1.875 Ba 0.125 CuO 4 single crystal. The data show that the structural phase transitions (high-temperature tetragonal → low-temperature orthorhombic → low-temperature tetragonal phase) are of the displacive type in this material. The 139 La spin-lattice relaxation rate T –1 1 sharply upturns at the charge-ordering temperature T CO = 54 K, indicating that charge order triggers the slowing down of spin fluctuations. Detailed temperature and field dependencies of the T –1 1 below the spin-ordering temperature T SO =40 K reveal the development of enhanced spin fluctuations in the spin-ordered state for H ∥ [001], which are completely suppressed for large fields along the CuO 2 planes. Lastly, our results shed light on the unusual spin fluctuations in the charge and spin stripe ordered lanthanum cuprates.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Formation of Stable Radicals by Mechanochemistry and Their Application for Magic Angle Spinning Dynamic Nuclear Polarization Solid-State NMR Spectroscopy

High-field magic angle spinning (MAS) dynamic nuclear polarization (DNP) solid-state nuclear magnetic resonance (SSNMR) is becoming a common technique for improving the sensitivity in NMR by the hyperpolarization of nuclear spins. Recently, we have shown that gamma irradiation is capable of creating long-lived free radicals that are amenable to MAS DNP in quartz and a variety of organic solids. Here, we demonstrate that mechanochemical ball milling is able to generate millimolar concentrations of stable radical species in diverse materials, such as polystyrene, cellulose, borosilicate glass, and fused quartz. High-field electron paramagnetic resonance (EPR) was used to obtain further insight into the nature of the radicals formed in ball milled quartz and borosilicate glass. Finally, we further show that radicals generated in quartz by ball milling can be used for solid-effect DNP. We obtained 29 Si DNP enhancements of approximately 114 and 33 at 110 K and room temperature, respectively, from a sample of ball milled quartz.

36 MATERIALS SCIENCE↗
DOE OSTI2018

First Observation of Low-Temperature Magnetic Transition in CuAgSe

In this Article, the temperature-dependent magnetic properties of CuAgSe pellet sintered from surfactant-free CuAgSe nanoparticles synthesized by a wet chemistry method were investigated in the temperature range of 4–300 K. A magnetic transition between diamagnetism and weak ferromagnetism is observed at around 60–70 K. The results from magnetic measurements under different machines/magnetic fields, room-temperature X-ray photoelectron spectroscopy, and temperature-dependent nuclear magnetic resonance all demonstrate that this magnetic transition is an intrinsic property rather than an effect of impurities. Combining these results with temperature-dependent neutron diffraction, the origin of the weak ferromagnetism is ascribed to a structural crossover-induced canted antiferromagnetism and possible deviation of Cu valence. In conclusion, the transition is strongly dependent on the sintering temperature and pressure, which could induce the structural phase transition.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Measurement of the muon spin precession frequency using the straw tracking detectors at the Fermilab Muon g-2 experiment

The measurement of the anomalous magnetic dipole moment of the muon ($a_{\mu}$) has long stood as an excellent precision test of the Standard Model (SM). The Fermilab Muon g-2 experiment has recently finished data-taking and in July 2023 published its latest determination of $a_\mu$ with a world-leading precision of 0.2\,ppm. In this publication, it surpassed the systematic uncertainty goal defined in the TDR. The analyses of a dataset approximately four times larger than this recent publication is now underway. The principle measurement of the Muon g-2 experiment measures $a_{\mu}$ by taking the ratio of two frequencies; the anomalous precession frequency ($\omega_a$) and the muon-weighted magnetic field of the experiment's storage ring measured from the precession frequency of protons in water using nuclear magnetic resonance (NMR) probes. In all publications to date, $\omega_a$ has been determined using energy deposits in the 24 calorimeters. However, the Fermilab experiment has t wo straw tracker detectors measuring the time and momentum of charged particles which can in principle also be used to to measure $\omega_a$ and such a measurement can provide an invaluable cross-check of the calorimeter result with different, and reduced, systematic uncertainties. This thesis presents the first (blinded) determination of $\omega_a$ using just charged tracks from the straw tracking detectors as opposed to calorimeter energy deposits. This analysis was undertaken using the Run-2/3 dataset which represents approximately 25\% of the final dataset. A total uncertainty of 2.19\,ppm on $\omega_a$ was obtained which is dominated by the statistical uncertainty of 2.16\,ppm. Additionally two new methodologies important to the analysis of the straw tracking data have been developed: one to better determine the track arrival time ($t_0$) and one to determine the level of pileup in the tracking detectors. The new $t_0$ algorithm which incorporates angular information improves t he resolution on the determination of the $t_0$ by a factor of two and results in 19\% more tracks being successfully reconstructed. The data from the trackers is also used to determine the beam profile that weights the magnetic field in the determination of $a_\mu$ and in determining several of the systematic uncertainties in the calorimeter-based $\omega_a$ analysis. A detailed study of the impact of the internal alignment of the tracker, the $t_0$ and pileup on the determination of the beam position was undertaken and propagated through to an uncertainty in the $\omega_a$ determination. These uncertainties were used in the Fermilab Muon g-2 experiment's recent publication in Phys. Rev. Lett.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Single nuclear spin detection and control in a van der Waals material

Optically active spin defects in solids are leading candidates for quantum sensing and quantum networking. Recently, single spin defects were discovered in hexagonal boron nitride (hBN), a layered van der Waals (vdW) material. Owing to its two-dimensional structure, hBN allows spin defects to be positioned closer to target samples than in three-dimensional crystals, making it ideal for atomic-scale quantum sensing, including nuclear magnetic resonance (NMR) of single molecules. However, the chemical structures of these defects remain unknown and detecting a single nuclear spin with a hBN spin defect has been elusive. Here we report the creation of single spin defects in hBN using 13 C ion implantation and the identification of three distinct defect types based on hyperfine interactions. We observed both S = 1/2 and S = 1 spin states within a single hBN spin defect. We demonstrated atomic-scale NMR and coherent control of individual nuclear spins in a vdW material, with a π-gate fidelity up to 99.75% at room temperature. By comparing experimental results with density functional theory (DFT) calculations, we propose chemical structures for these spin defects. Our work advances the understanding of single spin defects in hBN and provides a pathway to enhance quantum sensing using hBN spin defects with nuclear spins as quantum memories.

Quantum metrology↗
DOE OSTI2023

Antiferromagnetic order and its interplay with superconductivity in CaK(Fe$_{1-x}$Mn$_x$) 4 As 4

The magnetic order for several compositions of CaK(Fe$_{1-x}$Mn$_x$) 4 As 4 has been studied by nuclear magnetic resonance (NMR), Mössbauer spectroscopy, and neutron diffraction. Our observations for the Mn-doped 1144 compound are consistent with the hedgehog spin vortex crystal (hSVC) order which has previously been found for Ni-doped CaKFe 4 As 4 . The hSVC state is characterized by the stripe-type propagation vectors $(\pi\,0)$ and $(0\,\pi)$ just as in the doped 122 compounds. The hSVC state preserves tetragonal symmetry at the Fe site, and only this SVC motif with simple antiferromagnetic (AFM) stacking along $\ c$ is consistent with all our observations using NMR Mössbauer spectroscopy, and neutron diffraction. We find that the hSVC state in the Mn-doped 1144 compound coexists with superconductivity (SC), and by combining the neutron scattering and Mössbauer spectroscopy data we can infer a quantum phase transition, hidden under the superconducting dome, associated with the suppression of the AFM transition temperature ($T_N$) to zero for $x$ ≈ 0.01. In addition, unlike several 122 compounds and Ni-doped 1144, the ordered magnetic moment is not observed to decrease at temperatures below the superconducting transition temperature ($T_c$).

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1973

Precise measurement of charged defects in III-V compounds (supplement 2)

Experimental methods and related theory which will permit the measurement of low concentrations of vacancies and other defects in III-V compound semiconductors are discussed. Once the nature of these defects has been determined, this information can be incorporated into a transport theory for devices constructed from these materials, and experiments conducted to test the theory. The vacancies and other defects in the III-V compounds are detected by measurement of the nuclear magnetic resonance (NMR) line width. Most of the III-V compounds have at least one isotope with a nuclear quadrupole moment. In a crystal with a cubic crystal field (characteristic of most III-V compounds) there is no quadrupole splitting of the Zeeman resonance line. However, a defect removes the cubic symmetry locally and causes splitting which result in a change of the NMR width. This change can be used to detect the presence of vacancies.

Soest, J. F.↗
DOE OSTI2022

Magnetic Field Analysis for Fermilab Muon $g-2$

The Muon g-2 experiment E989 at Fermilab measures the anomalous magnetic moment of the muon $a_\mu$ with improved precision compared to the Brookhaven (E821) experiments. The Brookhaven results are in tension with the Standard Model by more than $3\sigma$. The determination of $a_\mu$ requires the measurement of both the muon anomaly frequency, $\omega_a$, and the magnetic field, $\mathbf{B}$, that confines muons in a storage ring. The field is monitored by a set of coordinated nuclear magnetic resonance (NMR) measurements. NMR probes at fixed locations above and below the storage region constantly monitor the field. An in-vacuum trolley equipped with 17 NMR probes maps the muon storage region, and a special water-based NMR probe provides the calibration for the trolley probes. This presentation focuses on the determination of the time-dependent field maps from combining the fixed probe measurements and the trolley maps. The field maps are combined with the muon distribution to derive the average field observed by the muons during the measurement. These proceedings will cover the analysis from the first data run.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2018

Conceptual Design of a Large Aperture Dipole for Testing of Cables and Insert Coils at High Field

© 2017 IEEE. Advances in the performance of low- and high-temperature superconductors enable the development of advanced magnets for a range of applications, including tokamaks for fusion energy, dipoles, and quadrupoles for hadron colliders, and solenoids for nuclear magnetic resonance studies. The capability of testing prototype cables and insert coils at high field is critical to these developments. We present here the conceptual design of a test facility dipole with features suitable to support the advanced magnet development efforts of both Fusion and HEP communities. In particular, a background field of 15 T is provided over a minimum homogeneous length of 1000 mm, and the magnet clear bore of approximately 144 × 94 mm can accommodate large fusion conductors as well as prototype coils for high field dipoles, along with flexible cryogenic and mechanical provisions for sample characterization. Two technical solutions are considered. The first uses a forced flow cable-in-conduit conductor and follows the design developed by EFDA for the EDIPO magnet. The second uses a bath cooled Rutherford cable and follows a block-coil design similar to the CERN FRESCA2 dipole, and the LBNL HD and LD1 dipoles. Following a comparison between the two approaches, we present two designs for the Rutherford cable approach including performance objectives, key parameters, and preliminary magnetic, mechanical and quench protection analysis.

Bruzzone, Pierluigi↗
DOE OSTI2016

Ultra-sensitive atomic magnetometer for studying magnetization fields produced by hyperpolarized helium-3

An ingenious approach to acquire the absolute magnetization fields produced by polarized atoms has been presented in this paper. The method was based on detection of spin precession signal of the hyperpolarized helium-3 with ultra-sensitive atomic magnetometer of potassium by referring to time-domain analysis. At first, dynamic responses of the mixed spin ensembles in the presence of variant external magnetic fields have been analyzed by referring to the Bloch equation. Subsequently, the relevant equipment was established to achieve the functions of hyperpolarizing helium-3 and detecting the precession of spin-polarized noble gas. By analyzing the transient response of the magnetometer in time domain, we obtained the relevant damping ratio and natural frequency. When the value of damping ratio reached the maximum value of 0.0917, the combined atomic magnetometer was in equilibrium. We draw a conclusion from the steady response: the magnetization fields of the polarized electrons and the hyperpolarized nuclei were corresponding 16.12 nT and 90.74 nT. Under this situation, the nuclear magnetization field could offset disturbing magnetic fields perpendicular to the orientation of the electronic polarization, and it preserved the electronic spin staying in a stable axis. Therefore, the combined magnetometer was particularly attractive for inertial measurements.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

NP-MRD: the Natural Products Magnetic Resonance Database

The Natural Products Magnetic Resonance Database (NP-MRD) is a comprehensive, freely available electronic resource for the deposition, distribution, searching and retrieval of nuclear magnetic resonance (NMR) data on natural products, metabolites and other biologically derived chemicals. NMR spectroscopy has long been viewed as the ‘gold standard’ for the structure determination of novel natural products and novel metabolites. NMR is also widely used in natural product dereplication and the characterization of biofluid mixtures (metabolomics). All of these NMR applications require large collections of high quality, well-annotated, referential NMR spectra of pure compounds. Unfortunately, referential NMR spectral collections for natural products are quite limited. It is because of the critical need for dedicated, open access natural product NMR resources that the NP-MRD was funded by the National Institute of Health (NIH). Since its launch in 2020, the NP-MRD has grown quickly to become the world's largest repository for NMR data on natural products and other biological substances. It currently contains both structural and NMR data for nearly 41,000 natural product compounds from >7400 different living species. All structural, spectroscopic and descriptive data in the NP-MRD is interactively viewable, searchable and fully downloadable in multiple formats. Extensive hyperlinks to other databases of relevance are also provided. The NP-MRD also supports community deposition of NMR assignments and NMR spectra (1D and 2D) of natural products and related meta-data. The deposition system performs extensive data enrichment, automated data format conversion and spectral/assignment evaluation.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2026

Noncollinear spin order, field-induced transitions, and short-range correlations in Cu 4 ⁢SO 4 ⁢(OH) 6

We report a comprehensive study of spin-$\frac{1}{2}$ quantum magnet brochantite, Cu 4 ⁢SO 4 ⁢(OH) 6 , combining high-field thermodynamic measurements, polarized neutron diffraction, inelastic neutron scattering, and nuclear magnetic resonance spectroscopy. Using bulk magnetization and specific heat measurements we construct the magnetic 𝐻−𝑇 phase diagram for magnetic fields applied along main crystallographic directions up to 24.1 T. Polarized neutron diffraction reveals a noncollinear magnetic ground state confined to the 𝑎⁢𝑏 plane. A field-induced transition is observed for magnetic fields in the 𝑎⁢𝑏 plane whose critical field and character evolve continuously with field direction in the 𝑎⁢𝑏 plane. While the transition for 𝐻 ∥ 𝑏 might be a spin-flop-like transition, the one for 𝐻 ∥ 𝑎 resembles the short-range correlated state above 𝑇 N , suggesting a magnetic configuration related to the quasi-two-dimensional correlations in the 𝑏⁢𝑐 planes. The experimental results demonstrate that the ground-state and field-induced phases cannot be explained by a simple XXZ model with a single dominant exchange interaction and that weaker interchain and anisotropic interactions have to be taken into account. Our work establishes brochantite as a low-symmetry Cu-based quantum magnet with noncollinear order and complex field-induced behavior.

Prokhnenko, Oleksandr [Helmholtz-Zentrum Berlin (H↗