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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 847 records · Page 47

Threshold Assessment of Gear Diagnostic Tools on Flight and Test Rig Data

A method for defining thresholds for vibration-based algorithms that provides the minimum number of false alarms while maintaining sensitivity to gear damage was developed. This analysis focused on two vibration based gear damage detection algorithms, FM4 and MSA. This method was developed using vibration data collected during surface fatigue tests performed in a spur gearbox rig. The thresholds were defined based on damage progression during tests with damage. The thresholds false alarm rates were then evaluated on spur gear tests without damage. Next, the same thresholds were applied to flight data from an OH-58 helicopter transmission. Results showed that thresholds defined in test rigs can be used to define thresholds in flight to correctly classify the transmission operation as normal.

Dempsey, Paula J.↗

Rotating Reverse Osmosis for Wastewater Reuse

Membrane filtration such as Reverse Osmosis (RO) removes ions, proteins, and organic chemicals which are generally very difficult to remove using conventional treatment. Moreover, membrane is an absolute filtration method, so its treatment efficiency and performance are stable and predictable. We are currently working on the development of rotating RO membrane system. Dynamic rotating membrane filtration, which can produce a high shear rate, may be helpful to obtain high rejection of organic pollutants.The goal of our current work is to improve the flux of the device by increasing pressure by a factor of 3 to 4. In addition, the rejections for a wider variety of inorganic and organic compounds typically found in space mission wastewater are measured.

Lueptow, Richard M.↗

Statistical optical link budget analysis

In this paper, we describe work on extending statistical analysis methods to optical communications links, with a primary focus on intensity modulated, direct detected photon-counting channel utilizing pulse-position-modulation (PPM). We performed analysis on the relationship between bit error rate (BER) requirement, statistical characteristics of the received signal power and noise power, and the coded performance curves. We presented link analysis results with preliminary uncertainty quantifications of signal power and noise power. We used the Consultative Committee for Space Data Systems (CCSDS) Serially Concatenated convolutionally coded Pulse Position Modulation (SCPPM) prototype software [1] to obtain coded performance curves under different operating conditions with varying signal power, background noise power, code rates,and PPM modulation orders. Comparison with traditional, deterministic analysis shows that extra margin needs to be reserved to compensate for the performance losses caused by uncertainties of the link parameters.

Cheung, Kar-Ming↗

The HUNTER Dynamic Human Reliability Analysis Tool: Development of a Module for Performance Shaping Factors

The Human Unimodel for Nuclear Technology to Enhance Reliability (HUNTER) is a framework to support dynamic human reliability analysis (HRA) in communication with a variety of methods and tools. This paper explores how we developed one of the HUNTER modules: namely, the Individual module for evaluating performance shaping factors (PSFs). A PSF is any factor that influences human performance (e.g., workload or complexity). In the existing HRA, they are used to highlight human errors and adjust error probabilities. We consider the eight PSFs suggested in the Standardized Plant Analysis Risk-HRA (SPAR-H) method, a representative HRA method widely used in the nuclear field. To support our dynamic modeling using the eight SPAR-H PSFs, we reviewed the human performance literature and developed data-based mathematical models to rate and quantify PSFs in the context of dynamic HRA. We also designed the Individual module to consist of two functions: (1) the PSF qualification function for automatically or manually evaluating PSF levels, and (2) the PSF quantification function for dynamically or statically determining PSF multiplier values and integrating them to adjust human error probabilities (HEPs). How each function works in regard to the SPAR-H PSFs, and how the PSFs serve to adjust the HEPs, were investigated via literature review and are discussed in this paper.

99 GENERAL AND MISCELLANEOUS↗

Determination of Scopolamine in Human Saliva Using Solid Phase Extraction and LC/MS/MS

Purpose: Scopolamine is the preferred treatment for motion sickness during space flight because of its quick onset of action, short half-life and favorable side-effect profile. The dose administered depends on the mode of administration and usually ranges between 0.1 and 0.8 mg. Such small doses make it difficult to detect concentrations of scopolamine in biological fluids by using conventional HPLC methods. To measure scopolamine in saliva and thereby to evaluate the pharmacokinetics of scopolamine, we developed an LC/MS/MS method using off-line solid phase extraction. Method: Samples (0.5mL) were loaded onto Waters Oasis HLB co-polymer cartridges (10 mg, 1 mL) and eluted with 0.5 mL methanol without evaporation and reconstitution. HPLC separation of the eluted sample was performed using an Agilent Zorbax SB-CN column (50 x 2.1 mm) at a flow rate of 0.2 mL/min for 4 minutes. The mobile phase for separation was 90:10 (v/v) methanol: ammonium acetate (2 mM) in water, pH 5.0 +/- 0.1. Concentrations of scopolamine were determined using a Micromass Quattro Micro(TM) mass spectrometer with electrospray ionization (ESI). ESI mass spectra were acquired in positive ion mode with multiple reaction monitoring for the determination of scopolamine m/z = 304.2 yields 138.1 and internal standard (IS) hyoscyamine m/z = 290.2 yields 124.1. Results: The method is rapid, reproducible, specific and has the following parameters: scopolamine and the IS are eluted at 1.7 and 3.2 min respectively. The linear range is 50-5000 pg/mL for scopolamine in saliva with correlation coefficients > 0.99 with a CV < 0.5 %. The intra-day and inter-day CVs are < 15 % for quality control samples with concentrations of 75, 300, 750 and 3000 pg/mL of scopolamine in human saliva. Conclusion: Solid phase extraction allows more rapid sample preparation and greater precision than liquid extraction. Furthermore, we increased the sensitivity and specificity by adjusting the LC mobile phase and using an MS/MS detector.

Wang, Zuwei↗

Low-thrust mission risk analysis.

A computerized multi-stage failure process simulation procedure is used to evaluate the risk in a solar electric space mission. The procedure uses currently available thrust-subsystem reliability data and performs approximate simulations of the thrust subsystem burn operation, the system failure processes, and the retargetting operations. The application of the method is used to assess the risks in carrying out a 1980 rendezvous mission to Comet Encke. Analysis of the results and evaluation of the effects of various risk factors on the mission show that system component failure rates is the limiting factor in attaining a high mission reliability. But it is also shown that a well-designed trajectory and system operation mode can be used effectively to partially compensate for unreliable thruster performance.

Yen, C. L.↗

Lightning Jump Algorithm Development for the GOES·R Geostationary Lightning Mapper

Current work on the lightning jump algorithm to be used in GOES‐R Geostationary Lightning Mapper (GLM)'s data stream is multifaceted due to the intricate interplay between the storm tracking, GLM proxy data, and the performance of the lightning jump itself. This work outlines the progress of the last year, where analysis and performance of the lightning jump algorithm with automated storm tracking and GLM proxy data were assessed using over 700 storms from North Alabama. The cases analyzed coincide with previous semi‐objective work performed using total lightning mapping array (LMA) measurements in Schultz et al. (2011). Analysis shows that key components of the algorithm (flash rate and sigma thresholds) have the greatest influence on the performance of the algorithm when validating using severe storm reports. Automated objective analysis using the GLM proxy data has shown probability of detection (POD) values around 60% with false alarm rates (FAR) around 73% using similar methodology to Schultz et al. (2011). However, when applying verification methods similar to those employed by the National Weather Service, POD values increase slightly (69%) and FAR values decrease (63%). The relationship between storm tracking and lightning jump has also been tested in a real‐time framework at NSSL. This system includes fully automated tracking by radar alone, real‐time LMA and radar observations and the lightning jump. Results indicate that the POD is strong at 65%. However, the FAR is significantly higher than in Schultz et al. (2011) (50‐80% depending on various tracking/lightning jump parameters) when using storm reports for verification. Given known issues with Storm Data, the performance of the real‐time jump algorithm is also being tested with high density radar and surface observations from the NSSL Severe Hazards Analysis & Verification Experiment (SHAVE).

Schultz. E.↗

Performance comparisons on spatial lattice algorithm and direct matrix inverse method with application to adaptive arrays processing

Lattice algorithm has been employed in numerous adaptive filtering applications such as speech analysis/synthesis, noise canceling, spectral analysis, and channel equalization. In this paper the application to adaptive-array processing is discussed. The advantages are fast convergence rate as well as computational accuracy independent of the noise and interference conditions. The results produced by this technique are compared to those obtained by the direct matrix inverse method.

An, S. H.↗

Axial-Flow Turbine Rotor Discharge-Flow Overexpansion and Limit-Loading Condition: Method of Analysis and Performance Evaluation of Computer Code AXOD2 - Part 2

The supercritical flow model-treatment implemented in AXOD2 is unique of its kind, and unique to axial-flow turbines. It is a rather simple, one-dimensional modeling concept which utilizes and captures two supercritical flow characteristics: 1. The mass flow rate remains to be a constant in supercritical flow conditions. 2. The flow angle at the choked blade-row-discharge deflects against the blade angle.

axial-flow↗

Integrated Plastic Substrates for OLED Lighting

OLED lighting has immense potential as aesthetically pleasing, energy-efficient general illumination. Unlike other light sources, such as incandescents, fluorescents, and inorganic LEDs, OLEDs naturally emit over a large-area surface. They are glare free, do not need to be shaded, and are cool to the touch, requiring no heatsink. The best efficiencies and lifetimes reported are on par with or better than current forms of illumination. However, the cost for OLED lighting remains high – so much so that these products are not market competitive and there is very low consumer demand. We believe that flexible, plastic-based devices will highlight the advantages of aesthetically-pleasing OLED lighting systems while paving the way for lowering both materials and manufacturing costs. These flexible devices require new development in substrate and support technology, which was the focus of the work reported here. The project team, led by Sinovia Technologies, has developed integrated plastic substrates to serve as supports for flexible OLED lighting. The substrates created in this project would enable large-area, flexible devices and are specified to perform three functions. They include a barrier to protect the OLED from moisture and oxygen-related degradation, a smooth, highly conductive transparent electrode to enable large-area device operation, and a light scattering layer to improve emission efficiency. Through the course of this project, integrated substrates were fabricated, characterized, evaluated for manufacturing feasibility and cost, and used in white OLED demonstrations to test their impact on flexible OLED lighting. Our integrated substrates meet or exceed the DOE specifications for barrier performance in water vapor and oxygen transport rates, as well as the transparency and conductivity of the anode film. We find that these integrated substrates can be manufactured in a completely roll-to-roll, high throughput process and have developed and demonstrated manufacturing methods that can produce thousands of feet of material without defects. We have evaluated the materials and manufacturing costs of these films at scale and find that they meet the current and future cost targets for bringing down the cost of OLED lighting while enabling future roll-to-roll manufacturing of the complete device. And finally, we have demonstrated that the inherent light-scattering properties of our films enhance white OLED emission efficiency from 20% to 50% depending on the metric. This work has shown that these substrates can be created, manufactured, and will perform as needed to enable flexible OLED lighting to enter the marketplace.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Combining dual domain material point method with molecular dynamics for thermodynamic nonequilibriums

The dual domain material point method (DDMP) combined with molecular dynamics (MD) is used to simulate a material undergoing a large deformation with a high strain rate. In the simulation, the continuum scale equation of motion is solved using DDMP, while the stresses required at the material points are obtained by performing MD simulations in small domains surrounding the material points following the entire history of the material deformation without reinitialization of the MD systems; therefore the history dependence, a common feature for thermodynamically nonequilibrium systems, can be tracked accurately. Two algorithms are introduced to avoid distortion of the MD domains and to ensure consistence in the energy density between the MD and macroscopic calculations. As an example, a hyper-velocity impact problem is simulated. The results of the combined DDMP-MD calculations are then compared to a pure MD simulation. The method of the combined simulation is applicable to macroscopic systems, although the size of the simulation domain is only a few hundred nanometers in this example because of the limitation of the pure MD simulation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Lunar gravity - A long-term Keplerian rate method

Nearside tracking data from Apollo subsatellites and Lunar Orbiter 5 are used to construct a model of the farside lunar gravity field. An indirect method of calculating the average effect of all the gravity anomalies which affect spacecraft orbits is reduced to a linear estimation problem by eliminating the integration of spacecraft dynamics. Doppler frequency shifts between the lunar satellite and earth-based tracking station are used to measure the line of sight velocity component between the orbiter and the tracker; gravity determination is then performed in a weighted least squares estimator which employs the orbital rates as data and formulates the normal equations using the associated Keplerian state. Simulations performed demonstrate that farside gravity features can be economically determined by use of gravity estimates obtained from long-period models of nearside orbiting tracks.

Ferrari, A. J.↗

CFD-Assisted Nodal Modeling of Sloshing in a Cryogenic Propellant Tank

During autogenous pressurization, tank sloshing causes a significant increase in pressurant consumption to maintain constant ullage pressure during draining of the tank. This increase in pressurant consumption is caused by a significant increase in condensation at the liquid-vapor interface. Sloshing strongly affects the liquid side heat transfer coefficient and thereby the condensation rate. Traditionally, sloshing is modeled by CFD code using the VOF (Volume of Fluid) method to track the liquid vapor interface during sloshing. CFD calculations require a very fine grid to accurately compute the heat and mass transfer at the interface. Therefore, computations are time consuming and prohibit performing many parametric studies often needed during the design of a new system. This paper describes an alternative approach by developing a CFD-assisted nodal model to predict system parameters more economically with reasonable accuracy. In this approach, a multi-node model of tank pressurization was developed using GFSSP. A multi-node model was needed to account for stratification. The model computes heat and mass transfer at the interface to calculate the condensation rate. The liquid side heat transfer is computed using the parameters of sloshing dynamics such as frequency, wave amplitude, and interface area. The parameters of sloshing dynamics are computed by the CFD code LOCI-Stream. The model predictions were compared with test data for several cases.

Cryogenic Tank Sloshing↗

Purification of Lithium-Ion Battery Black Mass through Tailored Alkaline Corrosion

Obtaining high-purity material outputs is crucial to the viability of novel process aimed at direct recycling of lithium-ion batteries. Metallic impurities in recycled cathodes have been shown to inhibit performance, thereby threatening mainstream acceptance of recycled battery products. Thus, shredded black mass (BM) must be purified to remove metallic contaminants, and specifically Al and Cu originating from the electrode current collectors. We herein explore a process to ionize solid copper and aluminum to ionic form based on tailored alkaline chemistry, without incurring damage to the target cathode material (Li(NixMnyCo1-x-y)O2; NMC). Al and Cu corrosion may be enhanced through the addition of chloride salt, elevated temperatures, and the use of ultrasonication - all of which disrupt the formation of passivating films on the metallic surface, and thereby increase corrosion rate. We demonstrate optimized parameters for Al and Cu corrosion both from a kinetic and overall process cost perspective. Further, we analyze the impact of these conditions on the structural (XRD, SEM), chemical (EDS, ICP), and electrochemical (impedance, cycling, dQ/dV) properties of NMC, and suggest that the present purification method does not significantly disrupt NMC performance. Finally, we present preliminary results from a promising bench-scale demonstration of this purification process applied to a simulated black mass.

ADVANCED PROPULSION SYSTEMS,ENERGY STORAGE↗

Simulation of a TRISO MiniFuel irradiation experiment with data-informed uncertainty quantification

An irradiation experiment using tristructural isotropic (TRISO) fuel particles and the miniature fuel (MiniFuel) irradiation vehicle was performed in Oak Ridge National Laboratory’s High Flux Isotope Reactor (HFIR) to support development of the Kairos Power fluoride salt–cooled, high-temperature reactor (KP-FHR). Here, this paper describes modeling predictions of temperatures and fuel burnup for the as-built experiment. An uncertainty quantification (UQ) analysis was performed to determine the effect of TRISO particle volume and position on the temperature predictions at various fuel heat generation rates (HGRs). This UQ study utilized fuel kernel position and volume measurements previously collected using X-ray computed tomography (XCT) techniques and Monte Carlo sampling methods to generate fuel compact cases that were then analyzed using a finite element thermal model. The UQ analysis indicated that uncertainty in calculated temperatures caused by varying TRISO particle arrangement is relatively small, even at high fuel HGR. Final predictions of particle temperatures throughout the irradiation are shown to be relevant to KP-FHR normal and off-normal operating conditions and to previous TRISO irradiation experiments. The combination of XCT with UQ analyses will inform post-irradiation examination (PIE) of the irradiated fuel compacts, and these analyses can be used to develop fuel performance models for coated particle fuel forms. Both PIE of separate-effects irradiation data and enhanced fuel performance modeling support accelerated qualification of TRISO fuels for a broad range of advanced reactor applications. The novel approach demonstrated here of measuring TRISO particle configurations with XCT methods and generating representative fuel compacts for finite element modeling and UQ analysis could be leveraged by the broader particle fuel community in the development of other TRISO fuel experiments in which these variables may have a significant impact on key outcomes.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Ricin Forensic Profiling Approach Based on a Complex Set of Biomarkers

A forensic method for the retrospective determination of preparation methods used for illicit ricin toxin production was developed. The method was based on a complex set of biomarkers, including carbohydrates, fatty acids, seed storage proteins, in combination with data on ricin and Ricinus communis agglutinin. The analyses were performed on samples prepared from four castor bean plant ( Ricinus communis ) cultivars by four different sample preparation methods (PM1 – PM4) ranging from simple disintegration of the castor beans to multi-step preparation methods including different protein precipitation methods. Comprehensive analytical data was collected by use of a range of analytical methods and robust orthogonal partial least squares-discriminant analysis- models (OPLS-DA) were constructed based on the calibration set. By the use of a decision tree and two OPLS-DA models, the sample preparation methods of a test set of ricin preparations were determined. The model statistics of the two models were good and a 100% rate of correct predictions of the test set was achieved.

Fredriksson, Sten-Åke (ORCID:0000000237131990)↗

A High-Performance Sodium-Ion Full Cell with a Layered Oxide Cathode and a Phosphorous-Based Composite Anode

A low-cost sodium-ion full cell with a O3-type layered Na[Cu 0.2 (Fe 1/3 Mn2/3) 0.8 ]O 2 cathode and an alloy-type P-TiP2-C anode is presented. The cathode is synthesized by an oxalate coprecipitation method and optimized cathodes shows a high specific capacity of 135 mAh g -1 at 0.1C rate with a high rate capability of 90 mAh g-1 at 1C rate and 70 mAh g -1 at 2C rate with good cyclability. The full cell exhibits better capacity retention than the half cell with the cathode due to the elimination of the degradation caused by sodium-metal anode. The dramatically enhanced electrochemical performance of the Na[Cu 0.2 (Fe 1/3 Mn 2/3 ) 0.8 ]O 2 / P-TiP 2 -C full cell compared to that of the sample with no Cu is attributed to the structural stabilization imparted by Cu by suppressing the phase change from the O3 structure to the P3 structure during cycling.

25 ENERGY STORAGE↗

Numerical characterization of quasi-steady thermal load for thin crystal at cryogenic temperature with nondiffusive heat transfer

With dramatically improved brightness and repetition rate, the thermal load for crystal optics in x-ray free-electron laser applications has also significantly increased. To mitigate the thermal load, one effective method is cryogenic cooling. However, the emerging nondiffusive heat transfer phenomenon at cryogenic temperature may cause design failure if overlooked. To evaluate the optical performance of thin crystal optics under thermal load at cryogenic temperature, an integrated numerical tool is presented and applied to characterize the thermal load on thin crystals with nondiffusive phenomena accounted. Significant thermally induced distortion of the rocking curve is observed from numerical simulation, leading to potential seed power reduction in hard x-ray self-seeding application. Cryogenic cooling is confirmed necessary by simulation to handle the thermal load at high repetition rate operation.

42 ENGINEERING↗