Analysis of Sludge Batch 10 Samples from Tank 51H (HTF-51-18-94, -95)
Savannah River National Laboratory characterized sludge samples from Tank 51H that is being used to generate Sludge Batch 10. The composite slurry sample from Tank 51H was analyzed and determined to contain a concentrated salt solution with a sodium concentration of 5.79 M (1.33E+05 mg/L) and insoluble sludge solids content of 7.20 wt% (using all nine replicates from the 3 wt% total solids measurements). Hydroxide is the main anionic species in the salt solution with a concentration of 3.00 M followed by nitrate (0.728 M) and nitrite (0.657 M). The sum of the major cations versus the sum of the major anions from the analysis of the filtered supernatant liquid phase shows a difference of <5% indicating good data quality. The results from the analysis of the digestions of the well mixed composite slurry sample show sodium to be the main component of the total dried solids of the sample followed by aluminum, iron, manganese, and thorium. Additional measurements of the weight percent total solids and density using hand shaking of the sample bottle and recirculation through a peristaltic pump indicate both methods provide adequate mixing of the sludge slurry sample.