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At least 847 records · Page 47

Alternative Approaches to Traditional Net Energy Metering

Most jurisdictions in the United States originally implemented net energy metering (NEM) tariffs to support the deployment and interconnection of distributed generation (DG) resources (e.g., rooftop solar photovoltaic systems). Since then, NEM has proven effective in promoting adoption of DG resources. Recently, due to concerns about sufficient recovery of utilities’ revenue requirements and cost-shifting, there is increasing interest in—or statutory requirements to pursue—alternative compensation approaches, especially in U.S. states and territories with robust growth in distributed solar. Recent increases in other forms of distributed energy resources (DERs) that can potentially send power to the distribution grid (e.g., distributed battery energy storage system (BESS)) are further driving compensation reforms. This brief provides an overview of design elements associated with alternative approaches to traditional NEM, summarizes common arguments for and against them, and identifies implementation issues that utilities may need to address. Although this brief may be most useful in jurisdictions that are interested in or required to move beyond NEM, it is also applicable to those jurisdictions that have already done so—and are looking to further implement reforms to their existing compensation mechanisms. In the broadest sense, there are three primary tariff-related components when interconnecting a DER onto the local utility’s distribution system (adapted from Zinaman et al., 2017): 1. Metering and Billing Arrangements: How utilities measure and bill electricity consumption and production. 2. DER Export Tariff Design: The structure under which utilities compensate customers for electricity they export to the grid. 3. Consumption Tariff Design: The structure under which customers pay for electricity they consume from the grid. When implementing changes to any of these primary tariff-related components, there are likely implications for a utility’s metering system, billing system, and other technology systems. Where applicable, this brief explicitly identifies such implementation challenges.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Effects of sample design and landscape features on a measure of environmental heterogeneity

Environmental heterogeneity, an important influence on organisms and ecological processes, can be quantified by the variance of an environmental characteristic over all locations within a study extent. However on landscapes with autocorrelation and gradient patterns, estimating this variance from a sample of locations may lead to errors that cannot be corrected with statistical techniques. We analytically derived the relative expected sampling error of sample designs on landscapes with particular gradient pattern and autocorrelation features. We applied this closed-form approach to temperature observations from an existing study. The expected heterogeneity differed, both in magnitude and direction, amongst sample designs over the study site's likely range of autocorrelation and gradient features. We conducted a simulation study to understand the effects of (i) landscape variability and (ii) design variability on an average sampling error. On 10 000 simulated landscapes with varying gradient and autocorrelation features, we compared estimates of variance from a variety of structured and random sample designs. While gradient patterns and autocorrelation cause large errors for some designs, others yield near-zero average sampling error. Sample location spacing is a key factor in sample design performance. Random designs have larger range of possible sampling errors than structured designs due to the potential for sample arrangements that over- and under-sample certain areas of the landscape. Furthermore, when implementing a new sample design to quantify environmental heterogeneity via variance, we recommend using a simple structured design with appropriate sample spacing. For existing designs, we recommend calculating the relative expected sampling error via our analytical derivation.

54 ENVIRONMENTAL SCIENCES↗

Ultrastable cathodes enabled by compositional and structural dual-gradient design

Cathodes for next-generation batteries are pressed for higher voltage operation (≥4.5 V) to achieve high capacity with long cyclability and thermal tolerance. Current cathodes fail to meet these requirements owing to structural and electrochemical strains at high voltages, leading to fast capacity fading. Here, in this work, we present a cathode with a coherent architecture ranging from ordered to disordered frameworks with concentration gradient and controllable Ni oxidation activities, which can overcome voltage ceilings imposed by existing cathodes. This design enables simultaneous high-capacity and high-voltage operation at 4.5 V without capacity fading, and up to 4.7 V with negligible capacity decay. Multiscale diffraction and imaging techniques reveal the disordered surface is electrochemically and structurally indestructible, preventing surface parasitic reactions and phase transitions. Structural coherence from ordering to disordering limits lattice parameter changes, mitigating lattice strain and enhancing morphological integrity. The dual-gradient design also notably improves thermal stability, driving the advancement of high-performance cathode materials.

36 MATERIALS SCIENCE↗

A critical analysis of hazard resilience measures within sustainability assessment frameworks

Today, numerous sustainability assessment frameworks (SAFs) exist to guide designers in achieving sustainable performance in the design of structures and communities. SAFs are beneficial in educating users and are useful tools for incorporating sustainability strategies into planning, design, and construction; however, there is currently a substantial gap in the ability of existing SAFs to incorporate hazard resistance and hazard mitigation in the broader context of sustainable design. This paper analyzes the incorporation of hazard resistant design and hazard mitigation strategies within SAFs via a multi-level analysis of eleven SAFs. The SAFs analyzed range in scale of application (i.e. building, site, community). Three levels of analysis are presented: (1) macro-level analysis comparing the number of measures strictly addressing resilience versus sustainability, (2) meso-level analysis of the coverage of types of hazards within SAFs (e.g. flood, fire), and (3) micro-level analysis of SAF measures connected to flood-related hazard resilience. The results demonstrate that hazard resistance and hazard mitigation do not figure prominently in the intent of SAFs and that weaknesses in resilience coverage exist that have the potential to lead to the design of structures and communities that are still highly vulnerable to the impacts of extreme events. - Highlights: • Sustainability assessment frameworks (SAFs) were analyzed for resilience coverage • Hazard resistance and mitigation do not figure prominently in the intent of SAFs • Approximately 75% of SAFs analyzed address three or fewer hazards • Lack of economic measures within SAFs could impact resilience and sustainability • Resilience measures for flood hazards are not consistently included in SAFs.

54 ENVIRONMENTAL SCIENCES↗

Design of titania nanotube structures by focused laser beam direct writing

In this work, we report on electrochemical fabrication of titania films consisting of nanotubes (NTs) and their treatment by focused laser beam. The results of sample characterization by optical and scanning electron microscopy, cathodoluminescence imaging, and Raman scattering scanning spectroscopy are compared to those inherent to specimens subjected to thermal treatment in a furnace. The obtained data demonstrate possibilities for controlling crystallographic structure of TiO{sub 2} NTs by focused laser beam direct writing. These findings open new prospects for the design and fabrication of spatial architectures based on titania nanotubes.

36 MATERIALS SCIENCE↗

N-Aryl-benzimidazolones as novel small molecule HSP90 inhibitors

We describe the development of a novel series of N-aryl-benzimidazolone HSP90 inhibitors (9) targeting the N-terminal ATP-ase site. SAR development was influenced by structure-based design based around X-ray structures of ligand bound HSP90 complexes. Lead compounds exhibited high binding affinities, ATP-ase inhibition and cellular client protein degradation.

59 BASIC BIOLOGICAL SCIENCES↗

Potent HIV‑1 protease inhibitors containing oxabicyclo octanol-derived P2-ligands: Design, synthesis, and X‑ray structural studies of inhibitor-HIV-1 protease complexes

Here, we describe here the design, synthesis, and X-ray structural studies of a new class of HIV-1 protease inhibitors containing 8-oxabicyclo[3.2.1]octanol-derived P2 ligands. We investigated the functional effect of these stereochemically defined fused-poly cyclic ligands on enzyme inhibition and antiviral activity in MT-2 cells. The tricyclic core of 8-oxabicyclo[3.2.1]octan-6-ol is designed to interact with the residues in the S2 subsite of HIV-1 protease. The syntheses of the ligands were carried out using the [5+2]-cycloaddition as the key step. Several inhibitors exhibited potent enzyme inhibitory activity. High resolution room-temperature X-ray structures of inhibitor-bound HIV-1 protease were determined. These structures provided important molecular insights for further design and optimization of inhibitor potency.

60 APPLIED LIFE SCIENCES↗

Structural basis for antibody binding to adenylate cyclase toxin reveals RTX linkers as neutralization-sensitive epitopes

RTX leukotoxins are a diverse family of prokaryotic virulence factors that are secreted by the type 1 secretion system (T1SS) and target leukocytes to subvert host defenses. T1SS substrates all contain a C-terminal RTX domain that mediates recruitment to the T1SS and drives secretion via a Brownian ratchet mechanism. Neutralizing antibodies against the Bordetella pertussis adenylate cyclase toxin, an RTX leukotoxin essential for B . pertussis colonization, have been shown to target the RTX domain and prevent binding to the α M β 2 integrin receptor. Knowledge of the mechanisms by which antibodies bind and neutralize RTX leukotoxins is required to inform structure-based design of bacterial vaccines, however, no structural data are available for antibody binding to any T1SS substrate. Here, we determine the crystal structure of an engineered RTX domain fragment containing the α M β 2 -binding site bound to two neutralizing antibodies. Notably, the receptor-blocking antibodies bind to the linker regions of RTX blocks I–III, suggesting they are key neutralization-sensitive sites within the RTX domain and are likely involved in binding the α M β 2 receptor. As the engineered RTX fragment contained these key epitopes, we assessed its immunogenicity in mice and showed that it elicits similar neutralizing antibody titers to the full RTX domain. The results from these studies will support the development of bacterial vaccines targeting RTX leukotoxins, as well as next-generation B . pertussis vaccines.

59 BASIC BIOLOGICAL SCIENCES↗

Advanced Energy Approaches for Mixed-Use Developments in the Front Range Urban Corridor

The primary objective of the document is to present example technical approaches and strategies that planners and developers can reference for all-electric mixed-use developments in the Rocky Mountain Front Range urban corridor that are considering advanced energy performance goals such as high levels of energy efficiency and renewable integration. The strategies are tailored toward the vision for a zero energy, all-electric, district thermal system-connected starter district. In this example, on-site solar generation is emphasized as a strategy that can be combined with electrical and thermal energy storage for enhanced community resilience and demand flexibility. Opportunities for utilizing or adapting these strategies include: sharing with vertical developers for potential integration of strategies into vertical design guidelines; incorporation into Owner Project Requirements (OPRs); providing example strategies to design teams as a starting point for design; informing structure of agenda for a building design charrette; comparing building designs to example strategies at various points in the design process to evaluate design progression. While the technical strategies outlined in this document can help inform the development of guidelines for projects in the Front Range urban corridor, this document does not set requirements for any rating, certification, program, or policy.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Updating the Dry Transfer System - 18110

The Dry Transfer System (DTS) was examined for its ability to be redesigned in order to meet needs associated with repackaging used/spent nuclear fuel (UNF/SNF) from existing storage cask systems into alternative systems, while also incorporating design advances based on some lessons learned from Orano's dry UNF handling facility (T0) located at the La Hague recycling plant. In this redesign, the DTS is envisioned to provide some flexibility through the ability to perform repackaging activities from multiple differently designed cask systems, including those with canisters that will require cutting and welding activities, and potentially with waste packages designed for disposal. The redesigned DTS is also intended to provide some operational flexibility by providing lag storage and include a means for examining UNF/SNF during repackaging, using some features implemented at the T0 facility at La Hague. This paper provides a summary of: the original DTS design, which was evaluated by the NRC and portions of which were cold-tested at Idaho National Lab; the lag storage system designed for the DTS, which is able to flexibly handle different fuel assembly designs while providing structural support for design basis events (e.g., seismic); the incorporation of lessons learned from the La Hague T0 facility into the DTS design to facilitate dry handling of UNF/SNF; and identification of other challenges towards designing a complete system. A revised DTS is envisioned to provide an important tool for the future management of UNF/SNF in preparation for transportation, re-storage, re-transportation, and/or disposal and also provides a means for repackaging UNF/SNF in case recovery from a cask/canister system is necessary (e.g., due to extended storage or a transportation event). (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Development of Lightweight Structural Materials with Improved Properties for Fission Batteries

Fission batteries require lightweight structural materials that demonstrate structural resilience when subjected to repeated shutdown, transportation, startup cycles, and certain external conditions, including rare events such as seismic vibrations and tsunamis. The objectives of this project are (1) to produce lightweight structural materials whose strength-to-weight ratios and fatigue resistance exceed those of current widely used structural materials such as 316 stainless steels (SS316), and (2) to enhance radiation tolerance of structural materials over a suitable service temperature range. To achieve these, (1) a lattice structure will be produced, (2) advanced modeling and simulation tools will be employed to design lattice structures (e.g., a gyroid structure) that reduce stress concentrations and thus increase fatigue resistance, and (3) one-dimensional (1-D) carbon nanotubes will be added to enhance radiation resistance. To validate our solution, high-temperature tensile and fatigue testing, in combination with microstructure characterization, will be conducted on wrought materials, additively manufactured solid materials, and the designed lightweight lattice structure material. Ion irradiation, microstructure characterization, and nanoindentation will be carried out to investigate the effect of 1-D carbon nanotubes on radiation tolerance. Successful completion of this project will deliver a material to serve as a substitute for current SS316 using the same chemistry but with lighter weight and improved mechanical properties. In addition, a material with carbon nanotubes can be designed for improved radiation tolerance over a suitable service temperature range. This project will establish new techniques in innovative materials/lattice design, advanced macroscale properties prediction, and the application of state-of-the-art processes.

36 MATERIALS SCIENCE↗

A Review on Bioinspired Proton Exchange Membrane Fuel Cell: Design and Materials

With the climate crisis gathering recognition, there has been significant interest in clean energy. As a reliable and clean energy solution, markets transitioning toward sustainable energy have identified polymer electrolyte membrane fuel cells (PEMFCs) as a critical technology. The increasing interest in PEMFCs is primarily due to their high energy density, high efficiency and zero greenhouse gas emission. However, additional development is required to overcome the current barriers associated with fuel cell component design, high manufacturing cost, and insufficient stability. Bioinspired designs have the potential to provide new and valuable insights using novel techniques for extracting design inspirations from biological structures. Applying these design concepts to develop materials and structures for various fuel cell components can be transformative. The well–adapted structures and functional features of biological systems have been proven to greatly enhance the performance of current designs through novel and optimized pathways. Bioinspired designs have indeed lived up to performance expectations and even exceed them. Herein, the potential and value of using these bioinspired designs are discussed. Recent studies and advancements based on nature–inspired structures for components of PEMFCs and how these design considerations substantiate their claim as an attractive alternative to conventional designs are discussed.

25 ENERGY STORAGE↗

Buckling of Two-Dimensional Covalent Organic Frameworks under Thermal Stress

Two-dimensional covalent organic frameworks (2D COFs) are periodic, permanently porous, and lightweight solids that are polymerized from topologically designed monomers. The predictable design and structural modularity of these materials make them promising candidates for applications including catalysis, environmental remediation, chemical separations, and organic electronics, many of which will require stability to mechanical and thermal stress. Based on their reinforced structures and high degradation temperatures, as determined by thermal gravimetric analysis (TGA), many reports have claimed that COFs have excellent thermal stability. However, their stability to heat and pressure has not been probed using methods that report on structural changes rather than the loss of volatile compounds. Here, we explore two structurally analogous 2D COFs with different polymerization chemistries using in operando X-ray diffraction (XRD), which demonstrates the loss of crystallinity at lower temperatures than the degradation temperatures measured by TGA. Density functional theory calculations suggest that an asymmetric buckling of the COF lattice is responsible for the observed loss of crystallinity. In addition to their thermal stability, XRD of the 2D COFs under gas pressures up to 100 bar showed no loss in crystallinity or structural changes, indicating that these materials are robust to mechanical stress by applied pressure. We expect that these results will encourage further exploration of COF stability as a function of framework design and isolated form, which will guide the design of frameworks that withstand demanding application-relevant conditions.

Evans, Austin↗

Quantum structure emerging from the transformation design of the Dirac equation

It is shown that a quantum structure can be created by a set of chosen constraint conditions that emerge from the transformation design of the Dirac equation in general relativity. As an explanation, the constraints that cause novel bound states with the quantization rule of a 2D Coulomb system are presented. The discussion in this paper provides a systematic way to look for constraints that generate a required quantization rule. -- Highlights: •We perform the transformation design of space and time for spin-1/2 matter waves. •A quantum rule could naturally emerge as constraints imposed on the Dirac equation itself. •New fermion states share the quantum spectrum of a 2D Coulomb system. •Transformation design uncovers a new exact solvable model. •A quantum spectrum can be created by a geometric structure.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Spatially addressable design of gradient index structures through spatial light modulator based holographic lithography

In this paper, we present an achievable gradient refractive index in bi-continuous holographic structures that are formed through five-beam interference. We further present a theoretic approach for the realization of gradient index devices by engineering the phases of the interfering beams with a pixelated spatial light modulator. As an example, the design concept of a gradient index Luneburg lens is verified through full-wave electromagnetic simulations. These five beams with desired phases can be generated through programming gray level super-cells in a diffractive spatial light modulator. As a proof-of-concept, gradient index structures are demonstrated using synthesized and gradient phase patterns displayed in the spatial light modulator.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Electromagnetic Analysis of ITER Electron Cyclotron Emission Components and Support Structures for the Preliminary Design Review

The ITER electron cyclotron emission (ECE) diagnostic system is located at Design Shield Module (DSM) 2, Equatorial Port (EP) 9 to measure electron temperature profile and electron temperature fluctuations and also to assess nonthermal electron distributions via the oblique view. Therefore, ECE has both radial and oblique views with two couples of mirrors for two different optical views. This ECE diagnostic system shall be exposed to significant power due to unabsorbed electron cyclotron heating power in the plasma. It shall also receive large electromagnetic (EM) loads up to 100 MN/m 3 force density due to the eddy currents generated by the short 16-ms transient plasma disruption. The global EM models of EP12 and EP11 with the worst case of plasma disruption Major Disruption Downward Exponential 16 ms Category III (MD_DW_EXP16MS_CATIII) have been provided by ITER. However, the support structure for these critical components, including four mirrors, is still under the design and development phase, especially during the period of preliminary design reviews (PDRs). For those small in-vessel components that are not modeled explicitly for the PDRs, we can extract the magnetic field (B) data and flux variations (dB/dt) at those locations from the global model and then use the B and dB/dt method to calculate the eddy currents, EM forces, and torques on those components in the local submodels. In conclusion, this paper will present the detailed PDR EM analysis results of the ECE components and support structures.

Electromagnetic↗