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At least 847 records · Page 47

SCR and GCR exposure ages of plagioclase grains from lunar soil

The concentrations of solar wind implanted Ar-36 in mineral grains extracted from lunar soils show that they were exposed to the solar wind on the lunar surface for an integrated time of 10E4 to 10E5 years. From the bulk soil 61501 plagioclase separates of 8 grain size ranges was prepared. The depletion of the implanted gases was achieved by etching aliquot samples of 4 grain sizes to various degrees. The experimental results pertinent to the present discussion are: The spallogenic Ne is, as in most plagioclases from lunar soils, affected by diffusive losses and of no use. The Ar-36 of solar wind origin amounts to (2030 + or - 100) x 10E-8 ccSTP/g in the 150 to 200 mm size fraction and shows that these grains were exposed to the solar wind for at least 10,000 years. The Ne-21/Ne-22 ratio of the spallogenic Ne is 0.75 + or - 0.01 and in very good agreement with the value of this ratio in a plagioclase separate from rock 76535. This rock has had a simple exposure history and its plagioclases have a chemical composition quite similar to those studied. In addition to the noble gases, the heavy particle tracks in an aliquot of the 150 to 200 mm plagioclase separate were investigated and found 92% of the grains to contain more than 10E8 tracks/sq cm. This corresponds to a mean track density of (5 + or - 1) x 10E8 tracks/sq cm. The exploration of the exposure history of the plagioclase separates from the soil 61501 do not contradict the model for the regolith dynamics but also fail to prove it.

Etique, P.↗

Composite interstellar grains

The possibility that interstellar grains are composite collections of very small particles, loosely attached to one another, is investigated. The grains are assumed to include a substantial proportion of vacuum along with solid particles. The optical properties of the composite grains are calculated with the approximate 'Bruggeman mixing rule', and the extinction of the grain is calculated wih standard Mie theory. The derived cross sections are close to those of hollow spheres in which the constituents occupy the proper volume fractions, and the derived optical constants of the mixture also obey the Kramers-Kroenig relations. The calculated interstellar extinction law shows reasonable agreement with observations of the diffuse ISM over the 1500-0.12 micron wavelength range. The predicted albedo is 0.5-0.6. It is predicted that the visual extinction per H nucleus should increase slightly with R(V).

Mathis, John S.↗

Synchrotron emission as a tracer of the outflow in M82

The discovery of radio synchrotron emission from the outflow in M82 is reported. It is found that the outflow in M82 is visible in synchrotron radiation. IC losses are evident in the steepening of the radio spectrum, though this process is not a major contributor to the observed halo X-ray emission. Particle acceleration and/or diffusion in the wind may be important. Outflow speeds of 1000-3000 km/s are inferred from the spectral index profiles, which significantly exceeds the optically determined values. The fraction of the wind energy in the form of relativistic particles is consistent with a supernova origin. A termination shock produced by the intergalactic medium may be shaping the observed halo of M82.

Seaquist, E. R.↗

Preventing Molecular and Particulate Infiltration in a Confined Volume

Contaminants from an instrument's self-generated sources or from sources external to the instrument may degrade its critical surfaces and/or create an environment which limits the instrument's intended performance. Analyses have been carried out on a method to investigate the required purging flow of clean, dry gas to prevent the ingestion of external contaminants into the instrument container volume. The pressure to be maintained and the required flow are examined in terms of their effectiveness in preventing gaseous and particulate contaminant ingestion and abatement of self-generated contaminants in the volume. The required venting area or the existing volume venting area is correlated to the volume to be purged, the allowable pressure differential across the volume, the external contaminant partial pressure, and the sizes of the ambient particulates. The diffusion of external water vapor into the volume while it was being purged was experimentally obtained in terms of an infiltration time constant. That data and the acceptable fraction of the outside pressure into the volume indicate the required flow of purge gas expressed in terms of volume change per unit time. The exclusion of particulates is based on the incoming velocity of the particles and the exit flow speed and density of the purge gas. The purging flow pressures needed to maintain the required flows through the vent passages are indicated. The purge gas must prevent or limit the entrance of the external contaminants to the critical locations of the instrument. It should also prevent self- contamination from surfaces, reduce material outgassing, and sweep out the outgassed products. Systems and facilities that can benefit from purging may be optical equipment, clinical facilities, manufacturing facilities, clean rooms, and other systems requiring clean environments.

Scialdone, John J.↗

Analogies Between Colloidal Sedimentation and Turbulent Convection at High Prandtl Numbers

A new set of coarse-grained equations of motion is proposed to describe concentration and velocity fluctuations in a dilute sedimenting suspension of non-Brownian particles. With these equations, colloidal sedimentation is found to be analogous to turbulent convection at high Prandtl numbers. Using Kraichnan's mixing-length theory, we obtain scaling relations for the diffusive dissipation length delta(sub theta), the velocity variance delta u, and the concentration variance delta phi. The obtained scaling laws over varying particle radius alpha and volume fraction phi(sub ) are in excellent agreement with the recent experiment by Segre, Herbolzheimer, and Chaikin. The analogy between colloidal sedimentation and turbulent convection gives a simple interpretation for the existence of a velocity cut-off length, which prevents hydrodynamic dispersion coefficients from being divergent. It also provides a coherent framework for the study of sedimentation dynamics in different colloidal systems.

Tong, P.↗

Ablation, Thermal Response, and Chemistry Program for Analysis of Thermal Protection Systems

In previous work, the authors documented the Multicomponent Ablation Thermochemistry (MAT) and Fully Implicit Ablation and Thermal response (FIAT) programs. In this work, key features from MAT and FIAT were combined to create the new Fully Implicit Ablation, Thermal response, and Chemistry (FIATC) program. FIATC is fully compatible with FIAT (version 2.5) but has expanded capabilities to compute the multispecies surface chemistry and ablation rate as part of the surface energy balance. This new methodology eliminates B' tables, provides blown species fractions as a function of time, and enables calculations that would otherwise be impractical (e.g. 4+ dimensional tables) such as pyrolysis and ablation with kinetic rates or unequal diffusion coefficients. Equations and solution procedures are presented, then representative calculations of equilibrium and finite-rate ablation in flight and ground-test environments are discussed.

Milos, Frank S.↗

Fe/Mn in olivine of carbonaceous meteorites

Olivines in primitive meteorites show a range of Fe/Mn both within one grain and among grains suggesting that they have recorded changing conditions during or after growth. Because olivine should be an early forming phase, Fe/Mn is used here to infer these earliest conditions. Initial Fe/Mn in cores of isolated, euhedral forsterite in both C2 and C3 meteorites ranges from 25 to 35 but differs at grain edge. Murchison (C2) forsterites show Fe/Mn approaching 1.0 at the grain edge while Ornans Fe/Mn is near 60 at grain edge. These values are lower than the matrix Fe/Mn for both meteorites and the distinct difference in zoning profile indicates different processes operating during and after grain growth. The Fe/Mn of bulk samples from a particular source such as the Moon is nearly constant. Individual samples show variation suggesting that there is some fractionation of Mn from Fe. Minerals have their individual ranges of Fe/Mn which has been used to recognize different types of olivine within one meteorite. Extreme values of Fe/Mn below 1.0 occur in forsterite from some IDP's, UOC matrix, and C1 meteorites. There are apparently no detailed studies of Fe/Mn variation within single olivine grains. Forsterite grains in C2 and C3 carbonaceous chondrites show complex zoning, and the nearly pure forsterites (Fo greater than approximately 99.5) have high levels of some minor elements including Ti, Al, V, and Sc. There is disagreement on the original source of these grains and both chondrule and vapor growth have been proposed. In addition, there is clear evidence that diffusion has affected the outer margins but in some cases the whole grain. Within the cores, the FeO range is limited, and if growing under constant conditions, the Fe/Mn should be near constant as there is little fractionation of Mn from Fe by forsterite. Additionally, there are apparently no co-crystallizing phases as evidenced by a lack of common inclusions in the forsterites. These observations are now followed by analyses of isolated olivine grains in C2 and C3 meteorites.

Steele, Ian M.↗

Molecular Simulations of CO 2 and H 2 Solubility, CO 2 Diffusivity, and Solvent Viscosity at 298 K for 27 Commercially Available Physical Solvents

CO 2 and H 2 solubilities, CO 2 /H 2 solubility selectivities, CO 2 diffusivities, and solvent viscosities in 27 commercially available physical solvents at 298 K were calculated from molecular simulations using the CHARMM36 all-atom force field for most solvents, and the simulation results were compared with available experimental data in this report. The van der Waals radius parameters for solvents were slightly tuned to reproduce the experimental solvent density. The simulated CO 2 solubilities are comparable with the experimental data, with an average absolute difference of 28%. For the homologous compounds containing the –(OCH 2 CH 2 )– repeat unit, both simulated and experimental data show that CO 2 solubility decreases when the number of repeat units is increased; CO 2 solubilities in these homologous compounds exhibit almost a perfect positive linear correlation with the solvent free-volume fractions. The simulated H 2 solubilities and CO 2 /H 2 solubility selectivities are also comparable with the experimental data, with differences of 22% and 17%, respectively. The H 2 solubilities in all solvents researched here correlate very well with the solvent free-volume fractions, exhibiting a positive linear correlation coefficient of 0.84. Additionally, simulations show that CO 2 solubility decreases when the temperature is increased. In contrast, H 2 solubility increases at elevated temperature, which is partly due to the increased solvent free-volume fraction at elevated temperature. Lastly, although the viscosity difference tends to be large (30%–246%) between simulation and experiment, both simulated and experimental data exhibit a similar solvent viscosity trend. Furthermore, simulations show that CO 2 diffusivities in solvents are very strongly correlated with the solvent viscosities and the relationship between them is given by D$_{CO_{2}}$ = (2.6 ± 0.3) × 10 –9 /η solvent 0.59 ± 0.03.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

On the thermal coarsening and transformation of nanoscale oxide inclusions in 316L stainless steel manufactured by laser powder bed fusion and its influence on impact toughness

The thermal evolution of nanoscale oxide inclusions in 316L stainless steel (SS) manufactured by laser powder bed fusion additive manufacturing (AM) was explored. The size, chemical composition, morphology, and distribution of the oxides were characterized as the function of heat treatment conditions. The study revealed the mechanistic driving force of the rapid oxide coarsening during recrystallization. Ostwald ripening governs oxide coarsening. The active grain boundary-oxide interaction at the early stage of recrystallization accelerated oxide coarsening via enhanced solute diffusion along grain boundaries. Pipe diffusion along dislocation cellular boundaries has a negligible contribution to oxide coarsening. At high temperatures (T> 1065 °C), although lattice diffusion primarily controlled the oxide growth, the contribution from the grain-boundary diffusion was necessary. The transformation from MnSiO 3 to CrMn 2 O 4 took place in the un-recrystallized grains but was not observed when recrystallization started. The interaction of grain boundary and oxides during recrystallization resulted in a high fraction of oxides accumulated at grain boundaries. While oxide coarsening does not significantly alter the toughness value, grain-boundary oxides promote microvoid formation and intergranular fracture under Charpy impact in the recrystallized AM 316L SS.

36 MATERIALS SCIENCE↗

Retention of ion-implemented-xenon in olivine - Dependence on implantation dose

The diffusion of Xe in olivine, a major mineral in both meteorites and linear samples, was studied. Xe ions were implanted at 200 keV into single-crystal synthetic-forsterite targets and the depth profiles were measured by alpha particle backscattering before and after annealing for 1 hour at temperatures up to 1500 C. The fraction of implanted XE retained following annealing was strongly dependent on the implantation dose. Maximum retention of 100 percent occurred for an implanting dose of 3 x 10 to the 15th power Xe ions/sq cm. Retention was less at lower doses, with approximately more than or = 50 percent loss at one hundred trillion Xe ions/sq cm. Taking the diffusion coefficient at this dose as a lower limit, the minimum activation energy necessary for Xe retention in a 10 micrometer layer for ten million years was calculated as a function of metamorphic temperature. Previously announced in STAR as N83-18528

Melcher, C. L.↗

Magnetic properties and microstructure of Sm-Co/α-Fe nanocomposite thick film-magnets composed of multi-layers over 700 layers

We synthesized Sm-Co/α-Fe nanocomposite film-magnets, approximately 10 μm in thickness, composed of 780 layers by the pulse laser deposition method. Transmission electron microscopic observations revealed that the synthesized film is composed of Sm-Co and α-Fe layers with the well-controlled α-Fe thickness of approximately 10–20 nm, which is suitable one predicted by the micromagnetic simulation. In spite of the enhanced interlayer diffusion of Fe and Co by annealing for crystallization, the (BH){sub max} value of 100 kJ/m{sup 3} was obtained at the averaged compositions of Sm/(Sm + Co) = 0.16 and Fe/(Sm + Co + Fe) = 0.47. The α-Fe fraction for obtaining the highest (BH){sub max} value was smaller than that expected from the micromagnetic simulation. Although the annealing for crystallization lay the easy direction of magnetization in the plane, the film is not expected to have strong crystallographic texture.

36 MATERIALS SCIENCE↗

Evaluating the efficacy of aluminide coatings to improve oxidation resistance of high performance engine valve alloys

Increasing peak cylinder pressures and operating temperatures of turbo-charged internal combustion engines (ICEs) engines present new challenges for existing materials employed in engine exhaust valves. Oxidation induced degradation of current Ni based alloys for these components will be a life-limiting mechanism while strict cost margins in the automotive transportation industry further limit the choice of suitable candidate materials. Metallic diffusion aluminide coatings can provide a cost-effective way to improve the oxidation resistance of underlying materials. In this study, the high temperature oxidation behavior of diffusion nickel aluminide coatings on two Ni based alloys (commercially available alloy 31V and a developmental alloy) during cyclic oxidation behavior in air+10% H 2 O at 900 °C was investigated. A complete depletion of the beneficial Al-rich β-(NiFe)Al phase was observed in the coating on alloy 31V while a significant fraction of this phase was retained in the coating on the second alloy. A coupled thermodynamic-kinetic model showed that the disappearance of the Al-rich phase in the coating on 31V was mainly due to the combined effect of steeper chemical potential gradients of Al and Ti between the coating and the substrate and their faster diffusivities compared to the coated developmental alloy. Finally, a higher content of Fe was shown to support the retention of β-(NiFe)Al phase in the coating on the developmental alloy while the presence of Ti in the alloy was shown to be detrimental for long-term coating performance.

36 MATERIALS SCIENCE↗

Interdiffusion and Formation of Intermetallic Compounds in High-Temperature Power Electronics Substrate Joints Fabricated by Transient Liquid Phase Bonding

Power electronics packages typically comprise a dielectric substrate bonded to a metal layer and attached to heat sinks using a low-thermal-conductivity solder. These multiple layers increase the effective thermal resistance of the package and are responsible for package failures under cyclic thermal loads. Bonding the aluminum nitride dielectric layer (AlN) directly to a low coefficient of thermal expansion (CTE) aluminum silicon carbide (AlSiC) cold plate using copper-aluminum (Cu-Al) transient liquid phase (TLP) bonding has been shown to improve the mechanical reliability of the power electronic packages while making the package more compact by bringing the cooling solutions closer to the devices. This study aims to characterize the Cu-Al bonds formed during the TLP bonding of AlSiC with three different power electronics substrates: pure aluminum nitride (AlN), aluminum (DBA), and copper (DBC). The material compositions and microstructures of the bonds were analyzed using scanning electron microscopy (SEM), x-ray spectroscopy (EDS), confocal scanning acoustic microscopy (C-SAM), and x-ray diffraction (XRD). ..alpha..-Al solid compound was identified as the dominant phase in AlN-AlSiC and Al-AlSiC, with a notable presence of SiC particles. In contrast, three intermetallic phases - ..theta..-CuAl2, ..eta..-CuAl, and ..gamma..'- Cu9Al4 - were observed in the Cu-AlSiC bond. A computational solid-state diffusion model was developed to predict the intermetallic compounds (IMCs) formed during Cu-Al TLP bonding in each system, which supported the observation that an initial Cu volume fraction of 20 % in the material layers produced a final bond composition of >95 % Al with minimal IMC growth. However, increased Cu concentrations produced higher concentration gradients, leading to increased growth of IMCs, Kirkendall voids, and interstitial cracks.

DIRECT ENERGY CONVERSION↗

Anti-fungal bioactive terpenoids in the bioenergy crop switchgrass (Panicum virgatum) may contribute to ecotype-specific microbiome composition

Abstract Plant derived bioactive small molecules have attracted attention of scientists across fundamental and applied scientific disciplines. We seek to understand the influence of these phytochemicals on rhizosphere and root-associated fungi. We hypothesize that – consistent with accumulating evidence that switchgrass genotype impacts microbiome assembly – differential terpenoid accumulation contributes to switchgrass ecotype-specific microbiome composition. An initial in vitro Petri plate-based disc diffusion screen of 18 switchgrass root derived fungal isolates revealed differential responses to upland- and lowland-isolated metabolites. To identify specific fungal growth-modulating metabolites, we tested fractions from root extracts on three ecologically important fungal isolates – Linnemania elongata, Trichoderma sp. and Fusarium sp. Saponins and diterpenoids were identified as the most prominent antifungal metabolites. Finally, analysis of liquid chromatography-purified terpenoids revealed fungal inhibition structure – activity relationships (SAR). Saponin antifungal activity was primarily determined by the number of sugar moieties – saponins glycosylated at a single core position were inhibitory whereas saponins glycosylated at two core positions were inactive. Saponin core hydroxylation and acetylation were also associated with reduced activity. Diterpenoid activity required the presence of an intact furan ring for strong fungal growth inhibition. These results inform future breeding and biotechnology strategies for crop protection with reduced pesticide application.

09 BIOMASS FUELS↗

Steady state scenario development with elevated minimum safety factor on DIII-D

On DIII-D, a high β scenario with minimum safety factor (q min ) near 1.4 has been optimized with new tools and shown to be a favourable candidate for long pulse or steady state operation in future devices. Furthermore, the new capability to redirect up to 5 MW of neutral beam injection (NBI) from on- to off-axis improves the ability to sustain elevated q min with a less peaked pressure profile. The observed changes increase the ideal magnetohydrodynamics (MHD) n = 1 mode β N limit thus providing a path forward for increasing the noninductive current drive fraction by operating at high β N . Quasi-stationary discharges free of tearing modes have been sustained at βN = 3.5 and β T = 3.6% for two current profile diffusion timescales (about 3 s) limited by neutral beam duration. The discharge performance has normalized fusion performance expected to give fusion gain Q ≈ 5 in a device the size of ITER. Analysis of the poloidal flux evolution and current drive balance show that the loop voltage profile is almost relaxed even with 25% of the current driven inductively, and q min remains elevated near 1.4. Our observations increase confidence that the current profile will not evolve to one unstable to a tearing mode. In preliminary tests a divertor heat flux reduction technique based on producing a radiating mantle with neon injection appears compatible with this operating scenario. 0D model extrapolations suggest it may be possible to push this scenario up to 100% noninductive current drive by raising β N . Similar discharges with q min = 1.5–2 were susceptible to tearing modes and off-axis fishbones, and with q min > 2 lower normalized global energy confinement time is observed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

SU-E-J-149: Establishing the Relationship Between Pre-Treatment Lung Ventilation, Dose, and Toxicity Outcome

Purpose: Recently, there has been an interest in incorporating functional information in treatment planning especially in thoracic tumors. The rationale is that healthy lung regions need to be spared from radiation if possible to help achieve better control on toxicity. However, it is still unclear whether high functioning regions need to be spared or have more capacity to deal with the excessive radiation as compared to the compromised regions of the lung. Our goal with this work is to establish the tools by which we can establish a relationship between pre-treatment lung function, dose, and radiographic outcomes of lung toxicity. Methods: Treatment planning was performed using a single phase of a 4DCT scan, and follow-up anatomical CT scans were performed every 3 months for most patients. In this study, we developed the pipeline of tools needed to analyze such a large dataset, while trying to establish a relationship between function, dose, and outcome. Pre-treatment lung function was evaluated using a recently published technique that evaluates Fractional Regional Ventilation (FRV). All images including the FRV map and the individual follow-up anatomical CT images were all spatially matched to the planning CT using a diffusion based Demons image registration algorithm. Change in HU value was used as a metric to capture the effects of lung toxicity. To validate the findings, a radiologist evaluated the follow-up anatomical CT images and scored lung toxicity. Results: Initial experience in 1 patient shows a relationship between the pre-treatment lung function, dose and toxicity outcome. The results are also correlated to the findings by the radiologist who was blinded to the analysis or dose. Conclusion: The pipeline we have established to study this enables future studies in large retrospective studies. However, the tools are dependent on the fidelity of 4DCT reconstruction for accurate evaluation of regional ventilation. Patent Pending for the technique presented in this work to evaluate FRV incorporating mass correction.

60 APPLIED LIFE SCIENCES↗

On the modeling of the scalar correlations necessary to construct a second-order closure description of turbulent reacting flows

A tentative scheme is proposed for constructing second-order closure models of turbulent reacting flows, with particular reference to mixing processes in turbulent diffusion flows. The model is based on the concepts of typical structure and typical eddy, and treats various hypothetical turbulent flame situations, including the time dependence of species mass fractions passing a point in the flame, the most typical occurrence of species mass fractions, and the case of a rather bizarre typical eddy which shows the effects of nonmixedness.

Donaldson, C. DUP.↗

Development of a Reactor Model for Chemical Conversion of Lunar Regolith

Lunar regolith will be used for a variety of purposes such as oxygen and propellant production and manufacture of various materials. The design and development of chemical conversion reactors for processing lunar regolith will require an understanding of the coupling among the chemical, mass and energy transport processes occurring at the length and time scales of the overall reactor with those occurring at the corresponding scales of the regolith particles. To this end, a coupled transport model is developed using, as an example, the reduction of ilmenite-containing regolith by a continuous flow of hydrogen in a flow-through reactor. The ilmenite conversion occurs on the surface and within the regolith particles. As the ilmenite reduction proceeds, the hydrogen in the reactor is consumed, and this, in turn, affects the conversion rate of the ilmenite in the particles. Several important quantities are identified as a result of the analysis. Reactor scale parameters include the void fraction (i.e., the fraction of the reactor volume not occupied by the regolith particles) and the residence time of hydrogen in the reactor. Particle scale quantities include the time for hydrogen to diffuse into the pores of the regolith particles and the chemical reaction time. The paper investigates the relationships between these quantities and their impact on the regolith conversion. Application of the model to various chemical reactor types, such as fluidized-bed, packed-bed, and rotary-bed configurations, are discussed.

Hedge, uday↗