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Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 2: Residual-fired nocogeneration process boiler

About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. Computer generated reports of the fuel consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented. Two nocogeneration base cases are included: coal fired and residual fired process boilers.

Knightly, W. F.↗

Cogeneration Technology Alternatives Study (CTAS). Volume 3: Industrial processes

Cogenerating electric power and process heat in single energy conversion systems rather than separately in utility plants and in process boilers is examined in terms of cost savings. The use of various advanced energy conversion systems are examined and compared with each other and with current technology systems for their savings in fuel energy, costs, and emissions in individual plants and on a national level. About fifty industrial processes from the target energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. An attempt was made to use consistent assumptions and a consistent set of ground rules specified by NASA for determining performance and cost. Data and narrative descriptions of the industrial processes are given.

Palmer, W. B.↗

Cogeneration Technology Alternatives Study (CTAS). Volume 4: Energy conversion systems

Industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed-cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum-based residual and distillate liquid fuels, and low Btu gas obtained through the on-site gasification of coal. An attempt was made to use consistent assumptions and a consistent set of ground rules specified by NASA for determining performance and cost. The advanced and commercially available cogeneration energy conversion systems studied in CTAS are fined together with their performance, capital costs, and the research and developments required to bring them to this level of performance.

Brown, D. H.↗

Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 1: Coal-fired nocogeneration process boiler, section A

Various advanced energy conversion systems (ECS) are compared with each other and with current technology systems for their savings in fuel energy, costs, and emissions in individual plants and on a national level. About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidates which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on-site gasification of coal. Computer generated reports of the fuel consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented for coal fired process boilers. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented.

Knightly, W. F.↗

Alkali metal vapors - Laser spectroscopy and applications

The paper examines the rapidly expanding use of lasers for spectroscopic studies of alkali metal vapors. Since the alkali metals (lithium, sodium, potassium, rubidium and cesium) are theoretically simple ('visible hydrogen'), readily ionized, and strongly interacting with laser light, they represent ideal systems for quantitative understanding of microscopic interconversion mechanisms between photon (e.g., solar or laser), chemical, electrical and thermal energy. The possible implications of such understanding for a wide variety of practical applications (sodium lamps, thermionic converters, magnetohydrodynamic devices, new lasers, 'lithium waterfall' inertial confinement fusion reactors, etc.) are also discussed.

Stwalley, W. C.↗

Comments on TEC trends

The paper comments on published and projected thermionic-energy-conversion (TEC) performance trends. This commentary includes graphs and an appendix relating TEC performance parameters, plots of predicted and actual TEC trends, a figure relating projected cost of electricity to overall efficiency for TEC topping, and a discussion of the implications of these relationships.

Morris, J. F.↗

The adsorption of cesium on lanthanum hexaboride surfaces

The adsorption/desorption characteristics of cesium on clean and oxygen-covered LaB6 (100) surfaces were studied using various surface analysis techniques. On the initially clean surface (phi = 2.77 eV), adsorption produces a minimum work function of 1.96 eV and a saturation work function of 2.07 eV. For the oxygen-saturated surface, the cesium adsorption curve shows no minimum, the lowest work function (1.35 eV) occurring at cesium saturation. The utility of LaB6 (100) as an emitter or collector in thermionic converter applications (particularly for space nuclear electric propulsion) is evaluated.

Davis, P. R.↗

Cogeneration Technology Alternatives Study (CTAS). Volume 5: Cogeneration systems results

The use of various advanced energy conversion systems is examined and compared with each other and with current technology systems for savings in fuel energy, costs, and emissions in individual plants and on a national level. About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. The methodology and results of matching the cogeneration energy conversion systems to approximately 50 industrial processes are described. Results include fuel energy saved, levelized annual energy cost saved, return on investment, and operational factors relative to the noncogeneration base cases.

Gerlaugh, H. E.↗

High power densities from high-temperature materials interactions

Thermionic energy converters and metallic-fluid heat pipes are well suited to serve together synergistically. The two operating cycles appear as simple and isolated as their material problems seem forebodingly deceptive and complicated. Simplified equations verify material properties and interactions as primary influences on the operational effectiveness of both. Each experiences flow limitations in thermal emission and vaporization because of temperature restrictions redounding from thermophysicochemical stability considerations. Topics discussed include: (1) successful limitation of alkali-metal corrosion; (2) protection against external hot corrosive gases; (3) coping with external and internal vaporization; (4) controlling interfacial reactions and diffusion; and (5) meeting other thermophysical challenges; expansion matches and creep.

Morris, J. F.↗

Ion and advanced electric thruster research

A phenomenological model of the orificed, hollow cathode based on the field enhanced, thermionic mechanism of electron emission is presented. High frequency oscillations associated with the orificed, hollow cathode are shown to be a consequence of current flow through the cathode orifice. A procedure for Langmuir probing of the hollow cathode discharge and analyzing the resulting probe characteristics is discussed. The results of sputter yield measurements made for molybdenum, tantalum, type 304 stainless steel and copper surfaces being bombarded by low energy argon or mercury ions are also given. The effects of nitrogen and alternated copper layers on the sputter yields of molybdenum, tantalum and 304 stainless steel are also discussed. A dynamic model of electrothermal rocket and ramjet thrusters is developed. The gross performance of these devices is compared to that of an electromagnetic gun for the case of a high acceleration, Earth launch mission. The theoretical performance of electrothermal rockets and ramjets is shown to be comparable to that of the electromagnetic gun.

Wilbur, P. J.↗

A phenomenological model describing orificed, hollow cathode operation

A phenomenological model is presented which describes the emission processes occurring within the orificed, hollow cathode. The model defines a region of ion production inside the cathode and assumes that the cathode emission current can be accounted for by considering the ion and electron currents which cross the boundary of this region. Most of the current (approximately 72%) comes from electrons produced by field-enhanced, thermionic emission from a well-defined emission surface at the downstream end of the insert which circumscribes the ion product region. The electrons produced at the emission surface feed the ionization process in the region of ion production; the rest of the current (approximately 28%) is carried by the ions produced in the process. Moving at the Bohm velocity, these ions leave the production volume; they then complete the current path by being collected at various cathode potential surfaces, including the emission surface. The model establishes the ratio of ion to electron currents at the emission surface on the basis of the energy balance at that surface. Experimental results corroborating the principal assumptions of the model are presented and discussed.

Siegfried, D. E.↗

High power densities from high-temperature material interactions

Thermionic energy conversion (TEC) and metallic-fluid heat pipes (MFHPs), offering unique advantages in terrestrial and space energy processing by virtue of operating on working-fluid vaporization/condensation cycles that accept great thermal power densities at high temperatures, share complex materials problems. Simplified equations are presented that verify and solve such problems, suggesting the possibility of cost-effective applications in the near term for TEC and MFHP devices. Among the problems discussed are: the limitation of alkali-metal corrosion, protection against hot external gases, external and internal vaporization, interfacial reactions and diffusion, expansion coefficient matching, and creep deformation.

Morris, J. F.↗

Advanced space propulsion thruster research

Experiments showed that stray magnetic fields can adversely affect the capacity of a hollow cathode neutralizer to couple to an ion beam. Magnetic field strength at the neutralizer cathode orifice is a crucial factor influencing the coupling voltage. The effects of electrostatic accelerator grid aperture diameters on the ion current extraction capabilities were examined experimentally to describe the divergence, deflection, and current extraction capabilities of grids with the screen and accelerator apertures displaced relative to one another. Experiments performed in orificed, mercury hollow cathodes support the model of field enhanced thermionic electron mission from cathode inserts. Tests supported the validity of a thermal model of the cathode insert. A theoretical justification of a Saha equation model relating cathode plasma properties is presented. Experiments suggest that ion loss rates to discharge chamber walls can be controlled. A series of new discharge chamber magnetic field configurations were generated in the flexible magnetic field thruster and their effect on performance was examined. A technique used in the thruster to measure ion currents to discharge chamber walls is described. Using these ion currents the fraction of ions produced that are extracted from the discharge chamber and the energy cost of plasma ions are computed.

Wilbur, P. J.↗

Radially uniform electron source

A thermionic electron source capable of producing uniform count rates in a number of channel electron multipliers simultaneously was required for conditioning multipliers for an extended space mission. It was found that a straight tungsten filament in the center of a cylindrically symmetric geometry surrounded by an array of multipliers emits a radially asymmetric distribution of electrons that changes with time. A source was developed which successfully produces a time-independent radially uniform distribution of electrons by moving the filament out of the direct line of sight and replacing it with a centrally located electron 'cloud.'

Mccomas, D.↗

The International Ultraviolet Explorer

The instrumentation and functioning of the IUE are discussed. The design of the telescope, fine error sensors, echelle spectrographs, and television cameras, as well as their integration, is described. The optical characteristics of the IUE are listed and the schematic arrangement of the detector is depicted. Sources of background noise are assessed, including the thermionic effects in the UV converters and television tubes, radiation from the earth's trapped electron belts, wide angle white light scattering from the earth and sun, scattering of dispersed light caused by low dispersion gratings, photometric calibration, and photometric stability. IUE sensitivity changes during the first three years of operation are shown together with sensitivity curves for short and long wavelengths. Modes of wavelength determination are considered.

Boggess, A.↗

Space power technology into the 21st Century

The space power systems of the early 21st century are discussed. The capabilities which are anticipated to evolve from today's state of the art and the technology development programs presently in place or planned for the remainder of the century are emphasized. The power system technologies considered include: solar thermal, nuclear, radioisotope, photovoltaic, thermionic, thermoelectric, and dynamic conversion systems such as the Brayton and Stirling cycles. Energy storage technologies considered include: nickel hydrogen biopolar batteries, advanced high energy rechargeable batteries, regenerative fuel cells, and advanced primary batteries. The present state of the art of these space power and energy technologies is discussed along with their projections, trends and goals. A speculative future mission model is postulated which includes manned orbiting space stations, manned lunar bases, unmanned Earth orbital and interplanetary spacecraft, manned interplanetary missions, military applications, and Earth to space and space to space transportation systems. The various space power/energy system technologies which are anticipated to be operational by the early 21st century are matched to these missions.

Faymon, K. A.↗

On Io, all that flickers is not cold

The 4.8 micron flux from the Galilean satellite Io was shown to fluctuate with an amplitude of approximately 10 percent on time scales of every 28 seconds, 40 minutes, night-to-night, and perhaps year-to-year. Such behavior was found to be the result of random fluctuations for which the mean square fluctuation varies inversely with frequency for constant bandwidth measurement. The theory developed for thermionic emission from barium oxide cathodes in vacuum tubes might be applicable to this situation. If so, the fluctuations in the flux from Io's volcanoes may be caused by diffusion of hot convective cells onto the surface of Io. Long term fluctuations may furnish a means by which the Io volcanism can shut down and conserve energy. Thus the discrepancy that exists between measurements of the current heat flow from Io and calculations of tidal dissipation may be resolved. Tests for rapid flickering at 10 microns showed no fluctuations greater than one percent. This agrees with the prediction of the flow model theory in which the 10 microns volcanic thermal emission arises from cooling of old flows.

Sinton, W. M.↗

Cogeneration Technology Alternatives Study (CTAS). Volume 2: Comparison and evaluation of results

CTAS compared and evaluated various advanced energy conversion systems that can use coal or coal-derived fuels for industrial cogeneration applications. The principal aim of the study was to provide information needed by DOE to establish research and development (R&D) funding priorities for advanced-technology systems that could significantly advance the use of coal or coal-derived fuels in industrial cogeneration. Steam turbines, diesel engines, open-cycle gas turbines, combined cycles, closed-cycle gas turbines, Stirling engines, phosphoric acid fuel cells, molten carbonate fuel cells, and thermionics were studied with technology advancements appropriate for the 1985-2000 time period. The various advanced systems were compared and evaluated for a wide diversity of representative industrial plants on the basis of fuel energy savings, annual energy cost savings, emissions savings, and rate of return on investment (ROI) as compared with purchasing electricity from a utility and providing process heat with an on-site boiler.

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