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At least 847 records · Page 47

Solving Two-Equation Turbulence Models With a Perspective on Solving Transport Equations

There are three principal objectives of this report. The first objective is to investigate frequently used two-equation models when solving the RANS equations. In this study, we consider the 2006Wilcox and the 2003 Menter Shear Stress Transport (SST) models. Also, a simple change of the Wilcox model is introduced to improve computational predictions for transonic flows. Computations for flows over two different airfoils are examined to compare these turbulence models. Effects on modeling the physics of each flow due to variations in the models, such as using either strainrate or vorticity in the turbulence production term, are considered and discussed. The second objective of this report is to not only explore but also evaluate the performance of the solution algorithm for the mean flow and the transport equations. The RANS and turbulence modeling equations aresolved in a weakly coupled manner with a diagonal implicit Runge-Kutta (DIRK) solution algorithm. Throughout this report, emphasis is given to reducing the residuals to machine zero in all flow calculations, so as to eliminate the error due to numerical integration of the discrete governing equations. The final objective is to provide a perspective on solving transport equations for turbulence modeling. Aspects of solving such stiff systems of equations, as well as various numerical difficulties and possible techniques to overcome them, are considered. Discussion is also provided concerning what is called ’numerical compatibility’, which is an essential requirement when designing a solution algorithm for solving transport equations.

turbulence modeling↗

Galactic origin of relativistic bosons and XENON1T excess

We entertain the exotic possibility that dark matter (DM) decays or annihilations taking place in our galaxy may produce a flux of relativistic very weakly-coupled bosons, axions or dark photons. We show that there exist several upper bounds for this flux on Earth assuming generic minimal requirements for DM, such as a lifetime longer than the age of the Universe or an annihilation rate that leaves unaffected the background evolution during matter domination. These bounds do not depend on the identity or the couplings of the bosons. We then show that this new flux cannot be large enough to explain the recent XENON1T excess, while assuming that the bosons’ couplings to the Standard Model are consistent with all current experimental and observational constraints. We also discuss a possible caveat to these bounds and a route to explain the excess.

Jatan Buch↗

Assimilation of SMAP Observations Over Land Improves the Simulation and Prediction of Tropical Cyclone Idai

This work is focused on the role of soil moisture in the prediction of tropical cyclones (TCs) approaching land and after landfall. Soil moisture conditions can impact the circulation and structure of an existing tropical cyclone (TC) when part or all of the circulation is over land. For example, dry land surface conditions may lead to faster dissipation of a TC over land (often associated with changes in precipitation structure), whereas very wet conditions may help sustain or in rare cases re-intensify a TC. Moreover, the presence of strong soil moisture gradients may affect the symmetry and development of the TC circulation leading to changes in its over-land track. While the link between soil moisture conditions and TC evolution in proximity to land is relatively well understood in theory, applications of these findings in the context of numerical weather prediction (NWP) have been limited. Here we present a case study that explores the potential of improving TC predictions through an improved soil moisture initialization in an NWP framework. Specifically, we examine the impact of assimilating observations from the NASA Soil Moisture Active Passive (SMAP) mission into the NASA Goddard Earth Observing System (GEOS) global weather model on the prediction of South-West Indian Ocean TC Idai (2019). SMAP provides accurate L-band (1.4 GHz) brightness temperatures (Tb) observations that are sensitive to soil moisture globally and at high revisit times of 2-3 days. It has previously been shown that the assimilation of SMAP Tb observations significantly improves modeled land surface states. Thus, it is expected that SMAP can be used to constrain land surface initial conditions and potentially benefit TC forecasts. Here we present two sets of retrospective forecasts of TC Idai that are compared in an Observing System Experiment framework at ¼ degree resolution: (i) forecasts initialized from an analysis that is comparable to the GEOS operational analysis (without SMAP Tb assimilation) and (ii) forecasts initialized from an analysis that additionally assimilates SMAP brightness temperature observations over land using a weakly-coupled land analysis. We find that the assimilation of SMAP meaningfully improves the representation of TC Idai’s structure as well as the prediction of its intensity and track. The analyzed TC size, as measured by the wind speed radius, is improved by up to 18% in the analysis with SMAP assimilation relative to the control run. The forecast intensity error, measured against the observed intensity, is reduced by up to 23%. At the 1/4-degree resolution used here, GEOS unavoidably under-estimates TC intensity and over-estimates TC size. The SMAP assimilation therefore corrects the model in the right direction, leading to a storm that is more energetic and more compact. Furthermore, we find that the along-track forecast error is reduced by up to 34%, indicating a more accurate propagation speed, which is consistent with the fact that TC speed over land is strongly affected by surface processes. The impact of SMAP assimilation on the forecast cross-track error is neutral. Across the TC forecast skill metrics used here, the improvements from SMAP DA are largest at lead times of 36 to 72 hours, suggesting that the predictability of forecasts at shorter lead times may be dominated by short-term convective processes, while the land and its longer memory gains in importance as a source of predictability on a 2-3 day timescale. We further investigated the underlying mechanisms leading to the skill improvements from SMAP data assimilation by isolating the land areas that directly influence TC Idai using a back trajectory analysis. We find that the assimilation of SMAP leads to wetter soil moisture conditions that cause an increased latent heat flux, which ultimately results in TC analyzed representation that has higher column-integrated total moisture content and total energy compared to the analysis in the control run without SMAP assimilation. Overall, the results highlight that the assimilation of SMAP observations into a global numerical weather prediction model can lead to pronounced improvements of TC predictions. This is a crucial step towards a better mitigation of the socio-economic impact of landfalling TCs and thus safeguarding human lives. Finally, our study presents an event-based approach that assesses the impact of land data assimilation for a particular weather event rather than by globally averaging differences in skill. We argue that global skill assessments – while necessary – can mute the impact of land data assimilation, because the land’s influence on the atmosphere is constrained to certain locations and certain times. Instead, the event-based approach better highlights the true potential of land data assimilation in the context of NWP, especially for extreme events when accurate predictions are critical.

Jana Kolassa↗

Assimilation of SMAP Observations Over Land Improves the Simulation and Prediction of Tropical Cyclone Idai

This work is focused on the role of soil moisture in the prediction of tropical cyclones (TCs) approaching land and after landfall. Soil moisture conditions can impact the circulation and structure of an existing tropical cyclone (TC) when part or all of the circulation is over land. For example, dry land surface conditions may lead to faster dissipation of a TC over land (often associated with changes in precipitation structure), whereas very wet conditions may help sustain or in rare cases re-intensify a TC. Moreover, the presence of strong soil moisture gradients may affect the symmetry and development of the TC circulation leading to changes in its over-land track. While the link between soil moisture conditions and TC evolution in proximity to land is relatively well understood in theory, applications of these findings in the context of numerical weather prediction (NWP) have been limited. Here we present a case study that explores the potential of improving TC predictions through an improved soil moisture initialization in an NWP framework. Specifically, we examine the impact of assimilating observations from the NASA Soil Moisture Active Passive (SMAP) mission into the NASA Goddard Earth Observing System (GEOS) global weather model on the prediction of South-West Indian Ocean TC Idai (2019). SMAP provides accurate L-band (1.4 GHz) brightness temperatures (Tb) observations that are sensitive to soil moisture globally and at high revisit times of 2-3 days. It has previously been shown that the assimilation of SMAP Tb observations significantly improves modeled land surface states. Thus, it is expected that SMAP can be used to constrain land surface initial conditions and potentially benefit TC forecasts. Here we present two sets of retrospective forecasts of TC Idai that are compared in an Observing System Experiment framework at ¼ degree resolution: (i) forecasts initialized from an analysis that is comparable to the GEOS operational analysis (without SMAP Tb assimilation) and (ii) forecasts initialized from an analysis that additionally assimilates SMAP brightness temperature observations over land using a weakly-coupled land analysis. We find that the assimilation of SMAP meaningfully improves the representation of TC Idai’s structure as well as the prediction of its intensity and track. The analyzed TC size, as measured by the wind speed radius, is improved by up to 18% in the analysis with SMAP assimilation relative to the control run. The forecast intensity error, measured against the observed intensity, is reduced by up to 23%. At the 1/4-degree resolution used here, GEOS unavoidably under-estimates TC intensity and over-estimates TC size. The SMAP assimilation therefore corrects the model in the right direction, leading to a storm that is more energetic and more compact. Furthermore, we find that the along-track forecast error is reduced by up to 34%, indicating a more accurate propagation speed, which is consistent with the fact that TC speed over land is strongly affected by surface processes. The impact of SMAP assimilation on the forecast cross-track error is neutral. Across the TC forecast skill metrics used here, the improvements from SMAP DA are largest at lead times of 36 to 72 hours, suggesting that the predictability of forecasts at shorter lead times may be dominated by short-term convective processes, while the land and its longer memory gains in importance as a source of predictability on a 2-3 day timescale. We further investigated the underlying mechanisms leading to the skill improvements from SMAP data assimilation by isolating the land areas that directly influence TC Idai using a back trajectory analysis. We find that the assimilation of SMAP leads to wetter soil moisture conditions that cause an increased latent heat flux, which ultimately results in TC analyzed representation that has higher column-integrated total moisture content and total energy compared to the analysis in the control run without SMAP assimilation. Overall, the results highlight that the assimilation of SMAP observations into a global numerical weather prediction model can lead to pronounced improvements of TC predictions. This is a crucial step towards a better mitigation of the socio-economic impact of landfalling TCs and thus safeguarding human lives. Finally, our study presents an event-based approach that assesses the impact of land data assimilation for a particular weather event rather than by globally averaging differences in skill. We argue that global skill assessments – while necessary – can mute the impact of land data assimilation, because the land’s influence on the atmosphere is constrained to certain locations and certain times. Instead, the event-based approach better highlights the true potential of land data assimilation in the context of NWP, especially for extreme events when accurate predictions are critical.

Jana Kolassa↗

The Representation of Aerosols in GMAO’s Newest Reanalyses

Over the past few years, NASA’s Global Modelling and Assimilation Office has been working on the configuration and production of three new reanalysis products, GEOS-IT, GiOcean, and MERRA-21C. GEOS-IT, or the Goddard Earth Observing System for Instrument Teams, is a 3D variational data assimilation system that runs in a near real time framework however retrospectively provides data back through 1998 to deliver a consistent view of the Earth-atmosphere system for the production of observational NASA products. Retrospective production for GEOS-IT is complete and the meteorology has since been used to produce the one way weakly coupled GiOcean reanalysis. Due to differences in the atmospheric model, particularly related to scavenging, aerosols are not identical in GEOS-IT and GiOcean. MERRA-21C, or the Modern Era Restrospective analysis for Research and Applications in the 21st century, is a hybrid 4D ensemble variational system at a finer horizontal resolution of 0.25 degrees. Although different in their intended use, and therefore configuration, these systems prominently feature coupling between meteorology and aerosols. The differences and similarities in the aerosol configuration between the three systems will be discussed, covering biomass burning and anthropogenic emissions as well as observations used for the assimilation of aerosol optical depth. A large emphasis will be placed on the version of the underlying aerosol module, GOCART, which underwent a complete refactoring and the addition of radiatively active brown carbon between GEOS-IT and MERRA-21C. Independent observations will be used to evaluate the performance of aerosols in both reanalyses, focusing on aerosol optical depth, surface particulate matter, and vertical profiles of aerosol backscatter.

Allison Collow↗

MODELING OF THE GROUNDWATER TRANSPORT AROUND A DEEP BOREHOLE NUCLEAR WASTE REPOSITORY

The concept of disposal of high-level nuclear waste in deep boreholes drilled into crystalline bedrock is gaining renewed interest and consideration as a viable mined repository alternative. A large amount of work on conceptual borehole design and preliminary performance assessment has been performed by researchers at MIT, Sandia National Laboratories, SKB (Sweden), and others. Much of this work relied on analytical derivations or, in a few cases, on weakly coupled models of heat, water, and radionuclide transport in the rock. Detailed numerical models are necessary to account for the large heterogeneity of properties (e.g., permeability and salinity vs. depth, diffusion coefficients, etc.) that would be observed at potential borehole disposal sites. A derivation of the FALCON code (Fracturing And Liquid CONvection) was used for the thermal-hydrologic modeling. This code solves the transport equations in porous media in a fully coupled way. The application leverages the flexibility and strengths of the MOOSE framework, developed by Idaho National Laboratory. The current version simulates heat, fluid, and chemical species transport in a fully coupled way allowing the rigorous evaluation of candidate repository site performance. This paper mostly focuses on the modeling of a deep borehole repository under realistic conditions, including modeling of a finite array of boreholes surrounded by undisturbed rock. The decay heat generated by the canisters diffuses into the host rock. Water heating can potentially lead to convection on the scale of thousands of years after the emplacement of the fuel. This convection is tightly coupled to the transport of the dissolved salt, which can suppress convection and reduce the release of the radioactive materials to the aquifer. The purpose of this work has been to evaluate the importance of the borehole array spacing and find the conditions under which convective transport can be ruled out as a radionuclide transport mechanism. Preliminary results show that modeling of the borehole array, including the surrounding rock, predicts convective flow in the system with physical velocities of the order of 10-5 km/yr over 105 years. This results in an escape length on the order of kilometers, which is comparable to the repository depth. However, a correct account of the salinity effects reduces convection velocity and escape length of the radionuclides from the repository.

Modeling↗

LOKI

LOKI is a simulation code that models weakly-coupled plasma evolution using Eulerian kinetic models in four phase space dimensions. The code is useful to understand basic plasma nonlinear plasma physics phenomena - in particular, wave-particle and wave-wave resonances that occur in laser plasma interactions. LOKI can simulate fundamental physical process in low-density plasmas on a scale of hundreds of light wavelengths. It does so by solving the Vlasov and Valsov-Fokker-Planck differential transport equations describing the collision less and low-collisionality evolution of charged particles in electromagnetic fields in two configuration space and two velocity space dimensions. Two principle electromagnetic models are provided: electrostatic (Poisson's Equation) and electromagnetic (Maxwell's equations).

Banks, Jeffrey↗

Detecting Axion Dark Matter with Superconducting Qubits

Axion dark matter haloscopes aim to detect dark matter axions converting to single photons in resonant cavities bathed in a uniform magnetic field. A qubit (two level system) operating as a single microwave photon detector is a viable readout system for such detectors and may offer advantages over the quantum limited amplifiers currently used. When weakly coupled to the detection cavity, the qubit transition frequency is shifted by an amount proportional to the cavity photon number. Through spectroscopy of the qubit, the frequency shift is measured and the cavity occupation number is extracted. At low enough temperatures, this would allow sensitivities exceeding that of the standard quantum limit.

Dixit, Akash↗

A blessing in disguise : Characterisations of ProtoDUNE photon showers for neutrino measurements in DUNE

There are few areas of particle physics as open to new discoveries as the neutrino sector. Although these particles are among the most abundant in the universe, their weak coupling to ordinary matter makes them a challenge to study. The Deep Underground Neutrino Experiment (DUNE) is an upcoming precision experiment in neutrino physics planned to be built between Illinois and South Dakota in the US. The most powerful neutrino beam in the world will be aimed at the largest liquid argon time projection chamber in the world through 1300 km of solid rock. In order to prototype this detector, a scale model was constructed and operated at CERN in 2018 called ProtoDUNE. This thesis presents three studies performed on this detector. The first concerns the readout of detector data by the FELIX data acquisition system, as well as compression studies performed on the same data. The second study concerns the identification of photons created in neutral pion decay, which form a major background to neutrino-produced electrons. The distinction between electrons and photons is based on the differing energy deposition in the initial part of the particle showers they produce. The third study concerns the energy reconstruction of particle showers in the detector. Although photon showers created from neutral pion decay are a major background to the eventual neutrino signal, they have a known energy profile and can thus be used to calibrate the energy reconstruction of particle showers in general, a vital requirement for DUNE’s physics goals.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Dark Sector Physics at High-Intensity Experiments

Is Dark Matter part of a Dark Sector? The possibility of a dark sector neutral under Standard Model (SM) forces furnishes an attractive explanation for the existence of Dark Matter (DM), and is a compelling new-physics direction to explore in its own right, with potential relevance to fundamental questions as varied as neutrino masses, the hierarchy problem, and the Universe's matter-antimatter asymmetry. Because dark sectors are generically weakly coupled to ordinary matter, and because they can naturally have MeV-to-GeV masses and respect the symmetries of the SM, they are only mildly constrained by high-energy collider data and precision atomic measurements. Yet upcoming and proposed intensity-frontier experiments will offer an unprecedented window into the physics of dark sectors, highlighted as a Priority Research Direction in the 2018 Dark Matter New Initiatives (DMNI) BRN report. Support for this program -- in the form of dark-sector analyses at multi-purpose experiments, realization of the intensity-frontier experiments receiving DMNI funds, an expansion of DMNI support to explore the full breadth of DM and visible final-state signatures (especially long-lived particles) called for in the BRN report, and support for a robust dark-sector theory effort -- will enable comprehensive exploration of low-mass thermal DM milestones, and greatly enhance the potential of intensity-frontier experiments to discover dark-sector particles decaying back to SM particles.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Quantum Sensors for High Energy Physics

Strong motivation for investing in quantum sensing arises from the need to investigate phenomena that are very weakly coupled to the matter and fields well described by the Standard Model. These can be related to the problems of dark matter, dark sectors not necessarily related to dark matter (for example sterile neutrinos), dark energy and gravity, fundamental constants, and problems with the Standard Model itself including the Strong CP problem in QCD. Resulting experimental needs typically involve the measurement of very low energy impulses or low power periodic signals that are normally buried under large backgrounds. This report documents the findings of the 2023 Quantum Sensors for High Energy Physics workshop which identified enabling quantum information science technologies that could be utilized in future particle physics experiments, targeting high energy physics science goals.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Low-Energy Neutrino-Nucleus Scattering and New Physics

The interactions of low-energy neutrinos with nuclei provide a unique window to explore various Standard Model (SM) and Beyond the Standard Model (BSM) processes. In particular, the recent observation of coherent elastic neutrino-nucleus scattering (CEvNS), predicted over five decades ago, has generated significant interest across disciplines. With its high cross section and suitability for compact detectors, particularly with stopped pion neutrinos, CEvNS offers a powerful probe for light, weakly coupled new physics. Ongoing global experimental efforts now aim to leverage CEvNS to test SM predictions and search for BSM signals, where deviations in event rates or spectra could reveal new physics. We present here an estimate of the number of recoil events obtained from CEvNS using the current and upcoming liquid argon based experiments. Furthermore, the event rate due to the inclusion of neutrino magnetic moment is also discussed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Searching for Strongly-Interacting Dark Matter with the Heavy Photon Search Experiment

The Heavy Photon Search Experiment (HPS) is a fixed-target experiment at Jefferson Lab’s Hall B, designed to explore a hidden sector (HS) of particles containing dark matter and a new force mediator known as the “heavy photon” (A'). The A' is a massive spin-1 gauge boson associated with a new U (1)D symmetry in the HS that kinetically mixes with the Standard Model () photon with a weak coupling strength parameterized by ¿, with ¿2 ~ 10-2 -10-10. HPS utilizes a high-intensity electron beam on a thin tungsten target to produce heavy photons in the MeV-GeV mass range via “dark bremsstrahlung,” a process analogous to SM bremsstrahlung but suppressed by ¿2. The A' can decay resonantly to SM leptons, allowing HPS to conduct both mass resonance searches for prompt decays (large ¿) and displaced vertex searches for long-lived particles (small ¿). In addition to the minimal A' model, HPS probes more complex extensions such as the QCD-like strongly-interacting massive particles (SIMPs) HS containing “dark” pions (pD) and vector mesons (VD), with pD as dark matter candidates. These particles introduce new thermal dark matter freeze- out scenarios and visible signals through long-lived VD decays to SM leptons, which are accessible to HPS. This analysis conducted a displaced vertex search for VD ¿ e-e+ in the mass range 30 MeV to 124 MeV and ¿ between 10-6 < ¿ < 10-2 using data from the 2016 Engineering Run (10.753 nb-1) at 2.3 GeV. Unlike the minimal A' search, SIMP signal kinematics required new approaches to signal normalization and SM background rejection. The strongest signal evidence was a local p-value of 0.01317 for mVD = 119 MeV, corresponding to a global significance of 0.9s. Although no signal was found, this search excluded a region of the SIMP parameter space at 90 % confidence. This work demonstrates HPS’s competitive capability to probe SIMP sectors within cosmologically significant parameters and introduces a new method for HPS displaced vertex searches using track vertical impact parameter cuts

Spellman, Alic [Univ. of California, Santa Cruz, C↗

Transition of electron kinetics in weakly magnetized inductively coupled plasmas

Transition of the electron kinetics from nonlocal to local regime was studied in weakly magnetized solenoidal inductively coupled plasma from the measurement of the electron energy probability function (EEPF). Without DC magnetic field, the discharge property was governed by nonlocal electron kinetics at low gas pressure. The electron temperatures were almost same in radial position, and the EEPFs in total electron energy scale were radially coincided. However, when the DC magnetic field was applied, radial non-coincidence of the EEPFs in total electron energy scale was observed. The electrons were cooled at the discharge center where the electron heating is absent, while the electron temperature was rarely changed at the discharge boundary with the magnetic field. These changes show the transition from nonlocal to local electron kinetics and the transition is occurred when the electron gyration diameter was smaller than the skin depth. The nonlocal to local transition point almost coincided with the calculation results by using nonlocal parameter and collision parameter.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Origin of the magnetic couplings for the weak ferromagnet Li + [TCNE] •- (TCNE = Tetracyanoethylene)

Based upon the 16-K crystal structure, the nearest-neighbor spin couplings (J; H = –2JS a •S b ) for the weak ferromagnet (=canted antiferromagnet) Li + [TCNE] •- (TCNE = tetracyanoethylene) (T c = 21 K), which possesses two interpenetrating diamondoid sublattices with two layers of parallel [TCNE] •- s canted with respect to each other by ~60°, are computed at the B3LYP/aug-cc-pV-TZ-level. Li[TCNE] has computed interlattice, through-space interactions that exceed the intralattice, through-bonding to Li + interactions, that are antiferromagnetic. The interlattice interactions dominate the spin coupling leading to the observed weak ferromagnetic behavior. Finally, the computed J's based upon the 50-K structure have the strongest ferromagnetic intralayer interlattice interactions increase by 2.9 ± 0.6% while the antiferromagnetic interlayer interlattice interaction increases by 23% with respect to the 16K results and are in accord with the observed initial increase and subsequent decrease in the temperature dependence of the canting angle that is a consequence of the these changing opposed interactions arising from the change in structure as a function of temperature.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Quarkonium transport in weakly and strongly coupled plasmas

We report on progress in the nonperturbative understanding of quarkonium dynamics inside a thermal plasma. The time evolution of small-size quarkonium is governed by two-point correlation functions of chromoelectric fields dressed with an adjoint Wilson line, known in this context as generalized gluon distributions (GGDs). The GGDs have been calculated in both weakly and strongly coupled plasmas by using perturbative and holographic methods. Strikingly, the results of our calculations for a strongly coupled plasma indicate that the quarkonium dissociation and recombination rates vanish in the transport descriptions that assume quarkonium undergoes Markovian dynamics. However, this does not imply that the dynamics is trivial. As a starting point to explore the phenomenological consequences of the result at strong coupling, we show a calculation of the Y(1 S ) formation probability in time-dependent perturbation theory. This is a first step towards the development of a transport formalism that includes non-Markovian effects, which, depending on how close the as of yet undetermined nonperturbative QCD result of the GGDs is to the strongly coupled N = 4 SYM result, could very well dominate over the Markovian ones in quark-gluon plasma produced at RHIC and the LHC.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Weak Electron–Phonon Coupling and Enhanced Thermoelectric Performance in n-type PbTe–Cu 2 Se via Dynamic Phase Conversion

This study investigates Ga-doped n-type PbTe thermoelectric materials and the dynamic phase conversion process of the second phases via Cu 2 Se alloying. Introducing Cu 2 Se enhances its electrical transport properties while reducing its lattice thermal conductivity (κlat) via weak electron–phonon coupling. Additionally, Cu 2 Te and CuGa(Te/Se) 2 (tetragonal phase) nanocrystals precipitate during the alloying process, resulting in Te vacancies and interstitial Cu in the PbTe matrix. At room temperature, Te vacancies and interstitial Cu atoms serve as n-type dopants, increasing the carrier concentration and electrical conductivity from ≈1.18 × 10 19 cm –3 and ≈1870 S cm –1 to ≈2.26 × 10 19 cm –3 and ≈3029 S cm –1 , respectively. With increasing temperature, the sample exhibits a dynamic change in Cu 2 Te content and the generation of a new phase of CuGa(Te/Se) 2 (cubic phase), strengthening the phonon scattering and obtaining an ultralow k lat . Pb 0.975 Ga 0.025 Te-3%CuSe exhibits a maximum figure of merit of ≈1.63 at 823 K, making it promising for intermediate-temperature device applications.

36 MATERIALS SCIENCE↗