LED Color Stability
DOE Solid-State Lighting program technology fact sheet that addresses key questions about color stability and color shift in LED lighting applications.
DOE, SSL, EERE, fact sheet, LED, color, stability,↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Color Rendering: What do we want?
This article is for LD+A. It describes the difference between color fidelity and color preference, and explores so hypotheses for why we don't always prefer high fidelity lighting.
Color rendering↗
LED Color Characteristics
A technology fact sheet that reviews the fundamentals regarding light and color, summarizing the most important color issues related to white-light LED systems.
ssl, lighting, LED, color, SPD, white, light, tuni↗
Evaluation of the use of color-set geometry during lattice physics constants generation for boiling water reactor simulation
Current methods for BWR nuclear design and analysis consist of using lattice physics neutron transport methods to generate the two-group homogenized cross-sections that are then used in a nodal diffusion theory code. The lattice transport solutions are performed for a single assembly with reflective boundary conditions, which is a practical approximation. A method is developed to account for assembly exposure distributions (environment) in the core within the lattice transport calculations with the use of color-sets (2x2) geometry. The loading pattern is examined and an appropriate number of characteristic color-set cells are selected for analysis. Treatment of the co-resident exposed fuel within this method is also presented. The calculation process was followed for a recent BWR cycle design with comparisons being performed on both a lattice and core-wide basis to evaluate the proposed method. The lattice based comparisons show noticeable differences in the pin power distribution predictions, which require further investigation to see how this translates into core performance calculations. The core-wide comparisons show minor differences and are generally in a good agreement, which is expected with this small perturbation. A slight improvement was noticed in the reduction of the power distribution uncertainty. However, given the additional amount of work and computer run time increase, further evaluation, especially of core pin power predictions, is needed to consider this method for production level design and safety analysis calculations. (authors)
21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
Color‐Stable, All‐Phosphorescent White Organic Light Emitting Diodes Using the Polariton‐Enhanced Purcell Effect
Abstract The short operational lifetimes of high efficiency phosphorescent organic blue light emitting devices (PHOLEDs) has limited their use in displays and lighting. Previously, this problem has been avoided by using less efficient fluorescent blue devices in separately biased red, green, and blue emissive elements to achieve stable full color emission. However, the operational lifetime of blue phosphorescent OLEDs has been significantly improved through the utilization of the plasmon‐exciton‐polariton‐enhanced (PEP) Purcell effect. Here, a white emitting PHOLED comprising stacked red, green, and blue elements is demonstrated that exploits PEPs to extend the operational lifetime of the blue element such that all emissive layers degrade at the same rate. The device features white light emission with an external quantum efficiency of 19.1 ± 0.4%, luminous power efficiency of 13.3 ± 0.3 lm W −1 at a luminance of 1000 cd m −2 when measured over 4π solid angle, with a color rendering index of 76 unchanged throughout the device aging to 70% of its initial luminance, T 70 . A 2.9 times enhancement in the operational lifetime of the Purcell‐enhanced device is achieved to yield T 70 = 2900 ± 100 h for an initial luminance of 1000 cd m −2 , compared to devices lacking this enhancement with T 70 = 1000 ± 100 h.
36 MATERIALS SCIENCE↗
Electrically Reconfigurable Liquid Metal Nanophotonic Platform for Color Display and Imaging
Dynamically tunable optical materials and device architectures are essential for future photonic technologies, yet conventional solid metals lack the intrinsic tunability required for advanced functionalities. Gallium-based liquid metals (LMs) present an appealing alternative thanks to their distinctive mechanical and optical properties; however, their practical integration in tunable photonic elements remains largely unexplored. Here, in this study, an electrochemically controlled nanophotonic platform is demonstrated that integrates a dynamically reconfigurable LM ground plane with gold nanoantenna arrays within a microfluidic system, enabling precise and reversible modulation of optical resonances across the visible to mid-infrared spectral ranges. By employing moderate operational voltages (1.5–3.0 V), real-time tuning of high-resolution structural color patterns is achieved through nanoscale control of the interfacial gap between the LM and Au nanoantennas. This innovative platform facilitates electrically programmable, high-contrast color patterns suitable for dynamic optical displays, secure anti-counterfeiting labels, and imaging applications. Additionally, this platform enables tunable mid-infrared spectral responses, which may be utilized for chemical and biological sensing applications. This versatile integrated LM-based nanophotonic platform opens new paths toward multifunctional, actively tunable/reconfigurable photonic device and system technologies.
Imaging↗
Methods for Color Center Preserving Hydrogen‐Termination of Diamond
Abstract Chemical functionalization of diamond surfaces by hydrogen is an important method for controlling the charge state of near‐surface fluorescent color centers, an essential process in fabricating devices such as diamond field‐effect transistors and chemical sensors, and a required first step for realizing families of more complex terminations through subsequent chemical processing. In all these cases, termination is typically achieved using hydrogen plasma sources that can etch or damage the diamond, as well as deposited materials or embedded color centers. This work explores alternative methods for lower‐damage hydrogenation of diamond surfaces, specifically the annealing of diamond samples in high‐purity, non‐explosive mixtures of nitrogen and hydrogen gas, and the exposure of samples to microwave hydrogen plasmas in the absence of intentional stage heating. The effectiveness of these methods are characterized by x‐ray photoelectron spectroscopy (XPS), and comparison of the results to density‐functional modelling of the surface hydrogenation energetics implicates surface oxygen ligands as the primary factor limiting the termination quality of annealed samples. Finally, photoluminescence (PL) spectroscopy is used to verify that both the annealing and reduced sample temperature plasma methods are non‐destructive to near‐surface ensembles of nitrogen‐vacancy (NV) centers, in stark contrast to plasma treatments that use heated sample stages.
36 MATERIALS SCIENCE↗
Enhanced Photoreversible Color Switching of Redox Dyes Catalyzed by Barium-Doped TiO 2 Nanocrystals
We developed colloidal barium-doped TiO 2 nanocrystals that enable the highly reversible light-responsive color switching of redox dyes with excellent cycling performance and high switching rates. Oxygen vacancies resulting from the Ba doping serve as effective sacrificial electron donors (SEDs) to scavenge the holes photogenerated in TiO 2 nanocrystals under UV irradiation and subsequently promote the reduction of methylene blue to its colorless leuco form. Effective color switching can therefore be realized without relying on external SEDs, thus greatly increasing the number of switching cycles. Moreover, Ba doping can also accelerate the recoloration under visible-light irradiation by shifting the absorption edge of TiO 2 nanocrystals to a shorter wavelength. Such a system can be further casted into a solid film to produce a rewritable paper on which letters and patters can be repeatedly printed using UV light and then erased by heating; this process can be repeated for many cycles and does not require additional inks.
36 MATERIALS SCIENCE↗
Highly luminescent and color-tunable salicylate ionic liquids
High quantum yields of up to 40.5 % can be achieved in salicylate-bearing ionic liquids. A range of these ionic liquids have been synthesized and their photoluminescent properties studied in detail. The differences noted can be related back to the structure of the ionic liquid cation and possible interionic interactions. It is found that shifts of emission, particularly in the pyridinium-based ionic liquids, can be related to cation–anion pairing interactions. Furthermore, facile and controlled emission color mixing is demonstrated through combining different ILs, with emission colors ranging from blue to yellow.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Loop amplitudes monodromy relations and color-kinematics duality
Color-kinematics duality is a remarkable conjectured property of gauge theory which, together with double copy, is at the heart of a wealth of new developments in scattering amplitudes. So far, its validity has been verified in most cases only empirically, with limited ab initio understanding beyond tree-level. In this paper we provide initial steps in a first-principle understanding of color-kinematics duality and double-copy at loop level, through a detailed analysis of the field-theory limit of the monodromy relations of string theory at one loop. In this limit, we dissect the type of Feynman graphs generated and the relations they obey. We find that graphs with contact-terms are unavoidable and are generated in the field theory limit of “bulk” contours which do not have a standard physical interpretation in string perturbation theory. We show how they are related to ambiguities in the definition of the loop momentum and that their role is precisely to cancel those ambiguities.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Direct quarkonium-plus-gluon production in DIS in the color glass condensate
We compute the differential cross-section for direct quarkonium production accompanied by a gluon in high-energy deep inelastic scattering (DIS) at small- x . We employ the Non-Relativistic QCD factorization framework, focusing on the S -wave contribution to the formation of the quarkonium, and including both color singlet and octet contributions. Our short distance coefficients for the production of the heavy quark pair are obtained within the Color Glass Condensate effective field theory. Our results pave the way towards the next-to-leading order computation of direct quarkonium in DIS, as well as the study of azimuthal correlations of direct quarkonium and jet.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Color-octet scalars in Dirac gaugino models with broken R symmetry
In this work we study the collider phenomenology of color-octet scalars ( sgluons ) in supersymmetric models with Dirac gaugino masses that feature an explicitly broken R symmetry ( R - broken models ). We construct such models by augmenting minimal R -symmetric models with a fairly general set of supersymmetric and softly supersymmetry-breaking operators that explicitly break R symmetry. We then compute the rates of all significant two-body decays and highlight new features that appear as a result of R symmetry breaking, including enhancements to extant decay rates, novel tree- and loop-level decays, and improved cross sections of single sgluon production. We demonstrate in some detail how the familiar results from minimal R -symmetric models can be obtained by restoring R symmetry. In parallel to this discussion, we explore constraints on these models from the Large Hadron Collider. We find that, in general, R symmetry breaking quantitatively affects existing limits on color-octet scalars, perhaps closing loopholes for light CP-odd (pseudoscalar) sgluons while opening one for a light CP-even (scalar) particle. Qualitatively, however, we find that — much as for minimal R -symmetric models, despite stark differences in phenomenology — scenarios with broken R symmetry and two sgluons below the TeV scale can be accommodated by existing searches.
79 ASTRONOMY AND ASTROPHYSICS↗
On-shell correlators and color-kinematics duality in curved symmetric spacetimes
We define a perturbatively calculable quantity — the on-shell correlator — which furnishes a unified description of particle dynamics in curved spacetime. Specializing to the case of flat and anti-de Sitter space, on-shell correlators coincide precisely with on-shell scattering amplitudes and boundary correlators, respectively. Remarkably, we find that symmetric manifolds admit a generalization of on-shell kinematics in which the corresponding momenta are literally the isometry generators of the spacetime acting on the external kinematic data. These isometric momenta are intrinsically non-commutative but exhibit on-shell conditions that are identical to those of flat space, thus providing a common language for computing and representing on-shell correlators which is agnostic about the underlying geometry. Afterwards, we compute tree-level on-shell correlators for biadjoint scalar (BAS) theory and the nonlinear sigma model (NLSM) and learn that color-kinematics duality is manifested at the level of fields under a mapping of the color algebra to the algebra of gauged isometries on the spacetime manifold. Last but not least, we present a field theoretic derivation of the fundamental BCJ relations for on-shell correlators following from the existence of certain conserved currents in BAS theory and the NLSM.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Relationship Between Integrated Autocorrelation Parameters of Optical Spectra and Color Characteristics of Multicomponent Hydrocarbon Media
The relationship between the integrated autocorrelation parameters of optical spectra of multicomponent hydrocarbon solutions and their color characteristics is established. The obtained functions enable the color characteristics of solutions of nonideal multicomponent hydrocarbon media such as petroleum and high-boiling petroleum distillates to be estimated from their optical spectra.
02 PETROLEUM↗
Coaxial color channel focus evaluation to estimate standoff height in directed energy deposition additive manufacturing
Directed energy deposition (DED) is an additive manufacturing process that is being rapidly adopted by industry and is well suited for the fabrication of complex components in a variety of metal alloys. In laser cladding systems such as DED, powder is blown in a stream to a metal substrate coincident with a laser necessary to deposit molten metal with 3D spatial control. The focus of both the laser and the powder stream are crucial, and best deposition occurs at a predetermined standoff height between the build surface and the print head. Generally, no monitoring of this distance is implemented in commercial DED systems. Due to potential over or under building, the standoff height often changes over time but tends to self-correct. However, inexpensive and minimally intrusive methods to identify optimal standoff are required to provide real-time control to maintain the optimal distance. The present work explores the quantification of the focus of the three-color channels of a coaxial camera to determine the standoff height. An experiment was performed in which a 254 mm wall is built and the standoff height, initially 5.0 mm below the optimal position, was then intentionally increased every 25.4 mm of wall length by an amount of 1.0 mm to a final position 7.0 mm above optimal. Computer vision is demonstrated to monitor the amount of focus in each color band and estimate standoff distance. Finally, a response can be calculated in under 40 ms using simple hardware and can work in most laser-based DED systems.
36 MATERIALS SCIENCE↗
Mining Unexplored Chemistries for Phosphors for High-Color-Quality White-Light-Emitting Diodes
There is a critical need for new earth-abundant phosphors to enable next-generation, highly efficient solid-state lighting. Here we report the discovery of Sr 2 LiAlO 4 , the first known Sr-Li-Al-O quaternary crystal, via a carefully targeted data-driven structure prediction and screening effort using density functional theory calculations. Sr 2 LiAlO 4 is predicted and experimentally confirmed to be a thermodynamically and thermally stable phosphor host that can be excited with near-UV/blue sources. The Eu 2+ - and Ce 3+ -activated Sr 2 LiAlO 4 phosphors exhibit broad emissions at λ max ~ 512 nm (green-yellow) and λ max ~ 434 nm (blue), respectively, with excellent thermal quenching resistance of >88% intensity at 150°C. A prototype phosphor-converted white LED utilizing Sr 2 LiAlO 4 -based phosphors yields an excellent color-rendering index exceeding 90. Sr 2 LiAlO 4 therefore exhibits great potential for industrial applications in low-cost, high-color-quality WLEDs.
Wang, Zhenbin↗
Tunable color and energy transfer in single-phase white-emitting Ca{sub 20}Al{sub 26}Mg{sub 3}Si{sub 3}O{sub 68}:Ce{sup 3+},Dy{sup 3+} phosphors for UV white light-emitting diodes
Ce{sup 3+} and/or Dy{sup 3+} activated Ca{sub 20}Al{sub 26}Mg{sub 3}Si{sub 3}O{sub 68} phosphors were synthesized by high temperature solid state reaction and their luminescent properties were studied. There are two emissions peaking at 407 and 577 nm in the emission spectra of Ca{sub 20}Al{sub 26}Mg{sub 3}Si{sub 3}O{sub 68}:Ce{sup 3+}, Dy{sup 3+}, which are due to the transitions of Ce{sup 3+} and Dy{sup 3+} ions, respectively. More importantly, the effective energy transfer from Ce{sup 3+} to Dy{sup 3+} ions has been confirmed and investigated by emission/excitation spectra and luminescent decay behaviors. Furthermore, the energy level scheme and mechanism of energy transfer were investigated and it was demonstrated to be resonant type via dipole–dipole reaction. Under the excitation of 345 nm, the emitting color can change from blue to white by adjusting the relative doping concentration of Ce{sup 3+} and Dy{sup 3+} ions, indicating that the phosphors Ca{sub 20}Al{sub 26}Mg{sub 3}Si{sub 3}O{sub 68}:Ce{sup 3+}, Dy{sup 3+} are promising single-phase white-emitting phosphors for application in pc-white LEDs. - Highlights: • The Ca{sub 20}Al{sub 26}Mg{sub 3}Si{sub 3}O{sub 68}:Ce{sup 3+},Dy{sup 3+} are novel luminescent materials that have not been reported before. • The crystal structure of Ca{sub 20}Al{sub 26}Mg{sub 3}Si{sub 3}O{sub 68} and energy transfer from Ce{sup 3+} to Dy{sup 3+} were investigated. • The emission color of Ca{sub 20}Al{sub 26}Mg{sub 3}Si{sub 3}O{sub 68}:Ce{sup 3+},Dy{sup 3+} can be adjusted from blue to white. • The phosphors have great application value in WLEDs as a kind of blue-to-white emitting phosphors.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Color tunable and thermally stable luminescence of Tb{sup 3+} doped Li{sub 4}SrCa(SiO{sub 4}){sub 2} phosphors
Highlights: ► Lowest spin-allowed and spin-forbidden f–d transitions locate at 250 and 280 nm. ► Cross relaxation shortens lifetime of {sup 5}D{sub 3} level, while that of {sup 5}D{sub 4} are unaffected. ► Cross-relaxation can explain concentration quenching of the {sup 5}D{sub 3} emission. ► Dipole–quadrupole interaction is responsible for the non-radiative relaxation. ► Li{sub 4}SrCa(SiO{sub 4}){sub 2}:Tb{sup 3+} is thermally stable and color tunable phosphor. -- Abstract: Tb{sup 3+} ions activated Li{sub 4}SrCa(SiO{sub 4}){sub 2} phosphors were synthesized using a solid state reaction method. The phase impurity was checked by XRD. The photoluminescence (PL) excitation spectrum, emission spectra at room and high temperature, decay curves of samples with different Tb{sup 3+} ions concentration were studied in detail. Cross-relaxation and the Inokuti–Hirayama model were used to analyze the experimental results. Li{sub 4}SrCa(SiO{sub 4}){sub 2}:xTb{sup 3+} are thermally stable and color tunable phosphors.
36 MATERIALS SCIENCE↗