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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 865 records · Page 48
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Theoretical study of miscibility and glass-forming trends in mixtures of polystyrene spheres

A theoretical study of glass-forming trends and miscibility in mixtures of polystyrene spheres (polyballs) of different diameters, suspended in an aqueous solution, is presented. The polyballs are assumed to be charged and to interact via a Debye-Hueckel screened Coulomb potential. The Helmholtz free energy is calculated from a variational principle based on the Gibbs-Bogoliubov inequality, in which a mixture of hard spheres of different diameters is chosen as the reference system. It is found that when the charges of the two types of polyballs are sufficiently different, the variationally determined ratio of hard-sphere diameters differs substantially, leading to packing difficulties characteristic of glass formation. The experimentally observed range of glass formation corresponds to a ratio of hard-sphere diameters of 0.8 or less. Calculations of the free energy as a function of concentration indicate that the liquid polyball mixture is stable against the phase separation, even for widely different polyball charges.

Shih, W.-H.↗
NASA NTRS1984

Explanation of the Normal Winter Anomaly from the Seasonal Variation of Short Wave Absorption

The frequency dependence of the winter anomaly (WA) of radio wave absorption indicates the altitude range where the considered seasonal variation of absorption, L, takes place: 75-95 km. In this height region considerable seasonal variations of ionic composition and effective recombination coefficient, alpha sub e, exist, which can cause seasonal variations of electron concentration, N, and absorption, L. An attempt to render a qualitative estimation of the normal WA, i.e., the increased ratio of winter over summer absorption, L sub w/L sub s, at medium latitudes 40 deg and 50 deg, for solar zenith angles CHi = 60 deg and 75 deg is made. This is compared with existing experimental data.

Velinov, P. J.↗
NASA NTRS1983

A Sr and Nd isotopic study of five Yamato polymict eucrites and a comparison to other Antarctic and ordinary eucrites

Sr and Nd isotopic analysis of five Yamato polymict eucrites indicate that these samples formed at about 4.6 Ga ago with initial Sr and Nd ratios essentially the same as the analyzed non-Antarctic eucrites. The Yamato eucrites have Sr, Sm, and Nd concentrations that consistently lie among the highest found in eucritic samples. This characteristic identifies these Yamato samples as a closely related group. Comparisons between these Yamato samples and other Antarctic polymict eucrites clearly estabishes that they all share some characteristic trace element features. Comparisons of Antarctic polymict eucrites with non-Antarctic ordinary eucrites reveal consistent differences. The most obvious is an enrichment of Rb in the polymict eucrites. These comparisons suggest that the Antarctic polymict eucrites belong to a single large family of material that is itself fairly diverse and distinct from the non-Antarctic eucrites.

Wooden, J. L.↗
NASA NTRS1987

Ru, Re, Os, Pt and Au in iron meteorites

Neutron activation analysis is used to ascertain the proportions of Ru, Re, Os, and Pt refractory siderophiles, and moderately volatile Au, in 41 iron meteorites. The Ni-element trends defined for groups IID and IIIF support a magmatic origin; in addition, the results obtained for groups IAB and IIICD contrast with trends observed in magmatic groups, where the Ru and Pt slopes are substantially less steep. In group IIIAB, at Ni concentrations above 90 mg/g, the steep decrease of Re, Os, and Ir with Ni levels off, and the interelement ratios exhibit considerable scatter. These observations may be explained in terms of the contamination of the residual molten core with small amounts of late primitive melts draining from the mantle.

Pernicka, Ernst↗
NASA NTRS1988

Biomass-burning emissions and associated haze layers over Amazonia

The characteristics of haze layers, which were visually observed over the central Amazon Basin during many of the Amazon Boundary Layer Experiment 2A flights in July/August 1985, were investigated by remote and in situ measurements, using the broad range of instrumentation and sampling equipment on board the Electra aircraft. It was found that these layers strongly influenced the chemical and optical characteristics of the atmosphere over the eastern Amazon Basin. Relative to the regional background, the concentrations of CO, CO2, O3, and NO were significantly elevated in the plumes and haze layers, with the NO/CO ratio in fresh plumes much higher than in the aged haze layers. The haze aerosol was composed predominantly of organic material, NH4, K(+), NO3(-), SO4(2-), and organic anions (formate, acetate, and oxalate).

Andreae, M. O.↗
NASA NTRS1988

Olivine vitrophyres - A nonpristine high-Mg component in lunar breccia 14321

The presence of olivine vitrophyres in breccia 14321 is discussed, suggesting that olivine vitrophyres could account for the high-Mg component of soils and breccias in the lunar highlands. The olivine vitrophyre clasts from 14321 have high bulk MgO and the Mg/(Mg+Fe) ratio is 78 percent. The olivine vitrophyres are impact melt rocks and are rich in KREEP. The high MgO concentration is manifest by skeletal quench crystals of olivine that constitute about 30 percent of the mode.

Shervais, John W.↗
NASA NTRS1989

Low angle injection into a supersonic flow

A study of helium jets injected into a Mach 3 airflow through circular sonic nozzles angled downstream at 15 and 30 deg is presented. An aspirating hot-film probe was employed to measure helium concentrations. The results of Schlieren and nonoshadowgraph photography show the presence of large-scale turbulent structures in the high pressure jets. Concentration data reveal some asymmetries both in the cross section of the jet and in the trajectory of the jet relative to the centerline of the jet. Plotting the decay of maximum concentration with axial distance, it is found that the mixing rate can be increased significantly by increasing the pressure ratio. These low angle jets display good cross-stream penetration.

Mays, R. B.↗
NASA NTRS1989

Transport into the south polar vortex in early spring

The effect of transport on the springtime decline in ozone in the southern polar vortex was investiated using data on long-lived gas tracers (N2O, CH4, CCl4, CH3CCl3, CO, CFC-11, CFC-12, and CFC-113) obtained by the ER-2 aircraft in the period between August 23 and September 22 during the Airborne Antarctic Ozone Experiment. It was found that, while the concentrations of long-lived trace gases remained relatively constant for fixed potential temperature and latitude, the ozone mixing ratio over the same period declined by more than 50 percent inside the polar vortex near 18-km altitude. These data indicate a substantial photochemical sink of ozone. The evidence of the zero or negative time tendencies for long-lived trace gases and the meridional and vertical gradients of ozone imply that transport is supplying ozone to the polar region during springtime.

Hartmann, D. L.↗
NASA NTRS1991

Mixing studies of helium in air at Mach 6

Concentration and mean flow measurements with nanoshadowgraphs and surface flow visualization have been obtained by a study of mixing phenomena during gas injection into hypersonic flow. At Mach 6, a comparison of the matched-pressure injection case with the underexpanded case indicated a greater injectant core penetration rate and a greater concentration-decay rate, leading to a shorter distance for the injectant core to reach an H2-air stoichiometric ratio. The entire injectant plume remained supersonic, and only moderate pressure losses were found. While injector yaw did not increase the mixing rates, it led to an increase in overall injectant plume cross-section, with consequent increase in the size of the mixing region.

Thomas, R. H.↗
NASA NTRS1991

Cosmogenic Ar-36 from neutron capture by Cl-35 in the Chico L6 chondrite: Additional evidence for large shielding

The cosmic ray produced Ar-36/Ar-38 ratio measured in iron meteorites is about 0.65, but is not well determined for stone meteorites due to the common presence of trapped Ar or absorbed atmospheric Ar in bulk analysis. Almost all single-extraction measurements of stones give Ar-36/Ar-38 ratios intermediate between the trapped and air values of 5.3 and the expected cosmogenic value of about 0.65. The isotopic composition of Ar was measured for stepwise temperature release of both chondritic and melt portions of Chico. The Chico data suggest that for large chondrites, the cosmogenic Ar-36/Ar-38 ratio may well be higher than 0.65, and therefore the procedure of correcting bulk analysis results may underestimate the concentration of cosmogenic Ar-38. In this context we note that in analysis of many Antarctic chondrites observed that determined amounts of cosmogenic Ar-38 averaged about 13 percent too low in comparison to that expected from measurements of other cosmogenic species.

Garrison, D. H.↗
NASA NTRS1991

Radiometric remote sensing of mesospheric and stratospheric water vapor

The remote sensing of stratospheric and mesospheric water vapor by microwave and millimeter radiometry is described. The received radiation is emitted by and interacts with all levels of the atmosphere. The pressure dependence of the linewidth for the absorption cross section of water vapor permits retrieval of vapor mixing ratios. The 183.31-GHz line of water vapor can also be used for remote sensing of the water vapor concentration in the upper atmosphere, but due to the much stronger absorption cross section for this line, ground-based observations are difficult. To date all measurements at 183 GHz have been made from platforms above the troposphere.

Croskey, Charles L.↗
NASA NTRS1993

Performance and heat transfer characteristics of a carbon monoxide/oxygen rocket engine

The combustion and heat transfer characteristics of a carbon monoxide and oxygen rocket engine were evaluated. The test hardware consisted of a calorimeter combustion chamber with a heat sink nozzle and an eighteen element concentric tube injector. Experimental results are given at chamber pressures of 1070 and 3070 kPa, and over a mixture ratio range of 0.3 to 1.0. Experimental C efficiency was between 95 and 96.5 percent. Heat transfer results are discussed both as a function of mixture ratio and axial distance in the chamber. They are also compared to a Nusselt number correlation for fully developed turbulent flow.

Linne, Diane L.↗
NASA NTRS1993

High purity isotopically enriched Ge-70 and Ge-74 single crystals - Isotope separation, growth, and properties

Ge-70 and Ge-74 isotopes were successfully separated from natural Ge, and were zone purified. Several highly enriched, high purity Ge-70 and Ge-74 single crystals were grown by the vertical Bridgman method. The growth system was designed for reliable growth of low dislocation density, high purity Ge single crystals of about 4 g weight. A Ge-70 and a Ge-74 crystal were selected for complete characterization. In spite of the large surface-to-volume ratio of these ingots, both Ge-70 and Ge-74 crystals contain low electrically active chemical net-impurity concentrations of about 2 x 10 exp 12/cu cm, which is 2 orders of magnitude better than that of Ge-74 crystals previously grown by two different groups. Isotopic enrichment of the Ge-70 and the Ge-74 crystals is 96.3 percent and 96.8 percent, respectively. The residual donors and acceptors present in both crystals were identified as phosphorus and copper, respectively. In addition, less than 10 exp 11/cu cm Ga, Al, and In were found in the Ge-70 crystal.

Itoh, Kohei↗
NASA NTRS1952

Variation of pressure limits of flame propagation with tube diameter for various isooctane-oxygen-nitrogen mixtures

An investigation was made of the change in the pressure limits of flame propagation with tube diameter for various isooctane-oxygen-nitrogen mixtures. Pressure limits were measured in cylindrical glass tubes of four different inside diameters at six different oxygen-nitrogen ratios. Under the experimental conditions, flame propagation was found to be impossible in isooctane-oxygen mixtures with oxygen concentrations less than 11 to 12 percent. Critical tube diameters for flame propagation were calculated and the effect of pressure was determined and compared with the effect of pressure on quenching distance. Critical diameters were related to flame speeds for various isooctane-oxygen-nitrogen mixtures.

FUELS-PROPERTIES,PHYSICAL AND CHEMICAL↗
NASA NTRS1997

An Experimental Study of Swirling Flows as Applied to Annular Combustors

This thesis presents an experimental study of swirling flows with direct applications to gas turbine combustors. Two separate flowfields were investigated: a round, swirling jet and a non-combusting annular combustor model. These studies were intended to allow both a further understanding of the behavior of general swirling flow characteristics, such as the recirculation zone, as well as to provide a base for the development of computational models. In order to determine the characteristics of swirling flows the concentration fields of a round, swirling jet were analyzed for varying amount of swirl. The experimental method used was a light scattering concentration measurement technique known as marker nephelometry. Results indicated the formation of a zone of recirculating fluid for swirl ratios (rotational speed x jet radius over mass average axial velocity) above a certain critical value. The size of this recirculation zone, as well as the spread angle of the jet, was found to increase with increase in the amount of applied swirl. The annular combustor model flowfield simulated the cold-flow characteristics of typical current annular combustors: swirl, recirculation, primary air cross jets and high levels of turbulence. The measurements in the combustor model made by the Laser Doppler Velocimetry technique, allowed the evaluation of the mean and rms velocities in the three coordinate directions, one Reynold's shear stress component and the turbulence kinetic energy: The primary cross jets were found to have a very strong effect on both the mean and turbulence flowfields. These cross jets, along with a large step change in area and wall jet inlet flow pattern, reduced the overall swirl in the test section to negligible levels. The formation of the strong recirculation zone is due mainly to the cross jets and the large step change in area. The cross jets were also found to drive a four-celled vortex-type motion (parallel to the combustor longitudinal axis) near the cross jet injection plane.

Seal, Michael Damian, II↗
NASA NTRS1999

An ET Origin for Stratospheric Particles Collected during the 1998 Leonids Meteor Shower

On 17 November 1998, a helium-filled weather balloon was launched into tfle strato- sphere, equipped with a xerogel microparticle collector. The three-hour flight was designed to sample the dust environment in the stratosphere during the Leonid meteor shower, and possibly to capture Leonid meteoroids. Environmental Scanning Election Microscope analyses of the returned collectors revealed the capture of a -30-pm particle. with a smooth, multigranular shape, and partially melted, translucent rims; similar to known Antarctic micrometeorites. Energy-dispersive X-ray Mass Spectroscopy shows en- riched concentrations of the non-volatile elements, Mg, Al, and Fe. The particle possesses a high magnesium to iron ratio of 2.96, similar to that observed in 1998 Leonids meteors (Borovicka, et al. 1999) and sharply higher than the ratio expected for typical material from the earth's crust. A statistical nearest-neighbor analysis of the abundance ratios Mg/Si, Al/Si, and Fe/Si demonstrates that the particle is most similar in composition to cosmic spherules captured during airplane flights throucrh the stratosphere. The mineralogical class is consistent with a stony (S) type of silicates. olivine [(Mg, Fe)2SiO4] and pyroxene [(Mg,Fe)SiO3]-or oxides, herecynite [(Fe,Mg) Al2O4]. Attribution to the debris stream of the Leonids' parent body, comet Tempel-Tuttle, would make it the first such material from beyond the orbit of Uranus positively identified on Earth.

Noever, David A.↗
NASA NTRS1994

The Response of ClO Radical Concentrations to Variations in NO2 Radical Concentrations in the Lower Stratosphere

The response of ClO concentrations to changes in NO2 concentrations has been inferred from simultaneous observations of [ClO], [NO], [NO2] and [O3] in the mid-latitude lower stratosphere. This analysis demonstrates that [ClO] is inversely correlated with [NO2], consistent with formation and photolysis of [ClONO2]. A factor of ten range in the concentration of NO2 was sampled (0.1 to 1 x 10(exp 9) mol/cc), with a comparable range in the ratio of [ClO] to total available inorganic chlorine (1% <= [ClO]/[Cl(sub y)] <= 5%). This analysis leads to an estimate of [ClONO2]/[Cl(sub y)] = 0.12 (x/divided by 2), in the mid-latitude, lower-stratospheric air masses sampled.

Stimpfle, R. M.↗
NASA NTRS2002

Photonic Bandgaps in Mie Scattering by Concentrically Stratified Spheres

The Mie formulation for homogeneous spheres is generalized to handle core/shell systems and multiple concentric layers in a manner that exploits an analogy with stratified planar systems, thereby allowing concentric multi-layered structures to be treated as photonic bandgap materials. Representative results from a Mie code employing this analogy demonstrate that photonic bands are present for periodic concentric spheres, though not readily apparent in extinction spectra. Rather, the periodicity simply alters the scattering profile, enhancing the ratio of backscattering to forward scattering inside the bandgap, whereas modification of the interference structure is evident in extinction spectra in accordance with the optical theorem

Smith, David D.↗