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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 865 records · Page 48

Classification of particle height in a hopper bin from limited discharge data using convolutional neural network models

Hopper bin discharge processes are ubiquitous in many industrial applications. The preponderance of previous studies of this system has been focused on the forward discharge process given an initial particle packing configuration. Motivated by the needs in reaction design and optimization, we develop here an inverse reconstruction procedure that enables one to obtain the particle height information in the initial packing configuration in the hopper bin from limited discharge dynamics data and particle characteristics. Our procedure is based on convolutional neural network (CNN) models, which take experimentally measurable particle residence time, diameter and density as input, and provide a classification of particle height in the initial packing as output. Using MFIX-DEM simulations with enhanced physical modeling capabilities, we generate extensive discharge data for hoppers containing two distinct solid phase particles with four distinct classes of initial packing geometries. The CNN reconstruction models are subsequently trained and tested using the discharge data. Here, we find that the reconstruction (i.e., particle height classification) accuracy strongly depends on the initial packing geometry. For hopper-specific CNN models exclusively trained using discharge data from a single hopper, the classification can attain an accuracy up to almost 90%. The accuracy decreases for generic reconstruction models trained using a collection of discharge data for multiple hoppers. Finally, we apply the CNN model to accurately reconstruct a hopper containing four distinct solid phases with a layered configuration to further demonstrate its utility.

42 ENGINEERING↗

Evolution of Surface Copper(II) Environments in Cu 2–x Se Nanoparticles

Cu 2–x Se nanoparticles are part of a promising class of alternative plasmonic materials where the location, stability, and structural impact of charge carrier generation are crucial to their optoelectronic performance. Electron paramagnetic resonance spectroscopy is used to identify the location and dynamics of Cu 2+ environments that form upon air-induced oxidation of Cu 2–x Se nanoparticles. The results indicate the formation of two distinct Cu 2+ environments at or near the surface of the nanoparticle. The first environment can be assigned to Cu 2+ bound to oleylamine capping ligands, and the second can be assigned to Cu 2+ located in CuO domains. In addition, these experiments indicate that the observed Cu 2+ environments are consistent with vacancy formation on the Cu sublattice, which are mobile (i.e., vacancy hopping) at temperatures down to 180 K. Taken together, our results elucidate time scales of air-mediated Cu oxidation in Cu 2–x Se nanoparticles, the chemical environments of the resulting Cu 2+ species, and the impact of this oxidation on the overall particle crystallographic structure and optoelectronic properties.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Catalysis as an Enabling Science for Sustainable Polymers

The replacement of current petroleum-based plastics with sustainable alternatives is a crucial but formidable challenge for the modern society. Catalysis presents an enabling tool to facilitate the development of sustainable polymers. This review provides a system-level analysis of sustainable polymers and outlines key criteria with respect to the feedstocks the polymers are derived from, the manner in which the polymers are generated, and the end-of-use options. Specifically, we define sustainable polymers as a class of materials that are derived from renewable feedstocks and exhibit closed-loop life cycles. Among potential candidates, aliphatic polyesters and polycarbonates are promising materials due to their renewable resources and excellent biodegradability. The development of renewable monomers, the versatile synthetic routes to convert these monomers to polyesters and polycarbonate, and the different end-of-use options for these polymers are critically reviewed, with a focus on recent advances in catalytic transformations that lower the technological barriers for developing more sustainable replacements for petroleum-based plastics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Assessment of Technoeconomic Opportunities in Automation for Nuclear Microreactors

Achieving full decarbonization of all economic sectors remains a challenge, especially in niche markets. For example, remote communities and industrial or mining activities detached from the main electric grid heavily rely on fossil fuels, similar to urban and industrial microgrids with combined heat and power needs. A combination of renewables and energy storage is often not suitable due to cost, reliability, intermittency, and large storage requirements. Small nuclear reactors with a flexible purpose could serve these applications. Microreactors (MR) are a class of reactors that are compact, factory manufactured, transportable, and self-regulating. Typically, they generate much less power than their large reactor counterparts. The main advantages of microreactors include the versatile nature of the energy produced, the reliability of supply, and freedom from having to transport and store large quantities of fuels on-site, coupled with the absence of dependence on an electrical grid. A strong business case is needed to move from the microreactor prototype to the commercialization phase. In fact, fossil fuels are still relatively inexpensive, and in the near term, carbon credits will be available to virtually compensate for emissions. For microreactors, one of the main costs in operation and maintenance (O&M) is their staffing levels. In this study, we investigate how to optimize the number (and thus the cost) of workers, moving from a traditional, fully manned, on-site personnel approach to an unmanned, remote personnel approach. We examine four different staffing models that can be implemented as the technology matures and evolves. We estimate the staffing needs of each model and build a business case to justify the substitution of on-site personnel with adequate technologies. To do so, we propose a cost model to quantify potential cost reductions from automating O&M activities. The model accounts for both the reduction in cost derived from the reduced number of full-time-equivalent (FTE) employees and the increase in cost derived from the need to buy new control hardware as needed. Applying the cost model that we created to different scenarios, an on-site O&M cost reduction exceeding 80% can be expected. Additionally, we found that it is more impactful to focus on automating routine O&M tasks rather than attempting to automate transient management (shutdowns, restarts, monitoring condition deviations). In fact, transients typically account for less than 1% of the total FTE time spent on the reactors.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

A comparative genome analysis of the Bacillota ( Firmicutes ) class Dehalobacteriia

Dehalobacterium formicoaceticum is recognized for its ability to anaerobically ferment dichloromethane (DCM), and a catabolic model has recently been proposed. D. formicoaceticum is currently the only axenic representative of its class, the Dehalobacteriia, according to the Genome Taxonomy Database. However, substantial additional diversity has been revealed in this lineage through culture-independent exploration of anoxic habitats. Here we performed a comparative analysis of 10 members of the Dehalobacteriia, representing three orders, and infer that anaerobic DCM degradation appears to be a recently acquired trait only present in some members of the order Dehalobacteriales. Inferred traits common to the class include the use of amino acids as carbon and energy sources for growth, energy generation via a remarkable range of putative electron-bifurcating protein complexes and the presence of S-layers. The ability of D. formicoaceticum to grow on serine without DCM was experimentally confirmed and a high abundance of the electron-bifurcating protein complexes and S-layer proteins was noted when this organism was grown on DCM. We suggest that members of the Dehalobacteriia are low-abundance fermentative scavengers in anoxic habitats.

59 BASIC BIOLOGICAL SCIENCES↗

Geometric quench in the fractional quantum Hall effect: Exact solution in quantum Hall matrix models and comparison with bimetric theory

In this work, we investigate the recently introduced geometric quench protocol for fractional quantum Hall (FQH) states within the framework of exactly solvable quantum Hall matrix models. In the geometric quench protocol, a FQH state is subjected to a sudden change in the ambient geometry, which introduces anisotropy into the system. We formulate this quench in the matrix models and then we solve exactly for the postquench dynamics of the system and the quantum fidelity (Loschmidt echo) of the postquench state. Next, we explain how to define a spin-2 collective variable g ' a b ( t ) in the matrix models, and we show that for a weak quench (small anisotropy), the dynamics of g ' a b ( t ) agrees with the dynamics of the intrinsic metric governed by the recently discussed bimetric theory of FQH states. We also find a modification of the bimetric theory such that the predictions of the modified bimetric theory agree with those of the matrix model for arbitrarily strong quenches. Finally, we introduce a class of higher-spin collective variables for the matrix model, which are related to generators of the W ∞ algebra, and we show that the geometric quench induces nontrivial dynamics for these variables.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A Survey of Colormaps in Visualization

Colormaps are a vital method for users to gain insights into data in a visualization. With a good choice of colormaps, users are able to acquire information in the data more effectively and efficiently. In this survey, we attempt to provide readers with a comprehensive review of colormap generation techniques and provide readers a taxonomy which is helpful for finding appropriate techniques to use for their data and applications. Specifically, we first briefly introduce the basics of color spaces including color appearance models. In the core of our paper, we survey colormap generation techniques, including the latest advances in the field by grouping these techniques into four classes: procedural methods, user-study based methods, rule-based methods, and data-driven methods; we also include a section on methods that are beyond pure data comprehension purposes. We then classify colormapping techniques into a taxonomy for readers to quickly identify the appropriate techniques they might use. Furthermore, a representative set of visualization techniques that explicitly discuss the use of colormaps is reviewed and classified based on the nature of the data in these applications. Lastly, our paper is also intended to be a reference of colormap choices for readers when they are faced with similar data and/or tasks.

97 MATHEMATICS AND COMPUTING↗

Consideration of Decabromodiphenyl Ether Flame Retardant in Thermal and Radiation Aging of Crosslinked Polyethylene Cable Insulation

Decabromodiphenyl ether (decaBDE) has been used as a flame-retardant additive in nuclear-grade electrical cable insulation. However, decaBDE has been identified as a persistent, bioaccumulative and toxic (PBT) substance, leading to regulatory scrutiny. On January 6, 2021, the Environmental Protection Agency (EPA) published a final rule to phase out decaBDE. The 2021 rule set a two-year compliance deadline for “processing and distribution in commerce of decaBDE for use in wire and cable insulation in nuclear power generation facilities.” In recognition of industry concerns following a sudden discontinuation of decaBDE-containing Class 1E wire and cable essential for nuclear power operations and the time needed for qualifying the individual components using the alternative insulation technology, an extended compliance deadline was set in the finalized amendments to the 2021 rule as published by the Environmental Appeals Board on November 12, 2024. The 2024 rule set the compliance deadline for processing and distributing decaBDE-containing wire and cable insulation until the end of the service life of these materials. Since decaBDE has long been relied upon as the flame retardant in one of the most common cross-linked polyethylene (XLPE) nuclear cable insulation formulations, RSCC Firewall III insulation, questions have naturally arisen regarding whether changes in cable performance might be expected for XLPE containing a decaBDE alternative, especially for safety-related cables that must perform their safety function in a design basis event such as a loss of coolant accident.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Augmented Reality for Enabling Smart Nuclear Infrastructure

This work presents a novel, comprehensive framework that leverages emerging augmented reality headset technology to enable smart nuclear industrial infrastructure that a human can easily interact with to improve their performance in terms of safety, security, and productivity. Nuclear industrial operations require some of the most complicated infrastructure that must be managed today. Nuclear infrastructure and their associated industrial operations typically features stringent requirements associated with seismic, personnel management (e.g., access control, equipment access), safety (e.g., radiation, criticality, mechanical, electrical, spark, and chemical hazards), security (cyber/physical), and sometimes international treaties for nuclear non-proliferation. Furthermore, a wide variety of manufacturing and maintenance operations take place within these facilities further complicating their management. Nuclear facilities require very thorough and stringent documentation of the operations occurring within these facilities as well as maintaining a tight chain-of-custody for the materials being stored within the facility. The emergence of augmented reality and a variety of Internet of Things (IoT) devices offers a possible solution to help mitigate these challenges. This work provides a demonstration of a prototype smart nuclear infrastructure system that leverages augmented reality to illustrate the advantages of this system. It will also present example augmented reality tools that can be leveraged to create the next generation of smart nuclear infrastructure. The discussion will layout future directions of research for this class of work.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

TAG user's manual

Transient Analysis Generator /TAG/ program for automatic circuit analysis of transient and steady state behavior of large class of electrical networks

STEADY STATE↗

Investigation of spatial misregistration effects in multispectral scanner data

The author has identified the following significant results. A model for estimating the expected proportion of multiclass pixels in a scene was generalized and extended to include misregistration effects. Another substantial effort was the development of a simulation model to generate signatures to represent the distributions of signals from misregistered multiclass pixels, based on single class signatures. Spatial misregistration causes an increase in the proportion of multiclass pixels in a scene and a decorrelation between signals in misregistered data channels. The multiclass pixel proportion estimation model indicated that this proportion is strongly dependent on the pixel perimeter and on the ratio of the total perimeter of the fields in the scene to the area of the scene. Test results indicated that expected values computed with this model were similar to empirical measurements made of this proportion in four LACIE data segments.

Nalepka, R. F.↗

Space infrared telescope pointing control system. Automated star pattern recognition

The Space Infrared Telescope Facility (SIRTF) is a free flying spacecraft carrying a 1 meter class cryogenically cooled infrared telescope nearly three oders of magnitude most sensitive than the current generation of infrared telescopes. Three automatic target acquisition methods will be presented that are based on the use of an imaging star tracker. The methods are distinguished by the number of guidestars that are required per target, the amount of computational capability necessary, and the time required for the complete acquisition process. Each method is described in detail.

Powell, J. D.↗

Ocean topography experiment (TOPEX) radar altimeter

A spaceflight qualified Radar Altimeter capable of achieving the TOPEX Mission measurement precision requirement of 2-centimeters, is provided and its performance (Engineering Assessment) will be evaluated after launch and continuously during its 3-year mission operational period. Information will be provided to JPL about the calibration of the TOPEX Radar Altimeter. The specifications for the required data processing algorithms which will be necessary to convert the Radar Altimeter mission telemetry data into the geophysical data will also be provided. The stringent 2 cm precision requirement for ocean topography determination from space necessitated examining existing Radar Altimeter designs for their applicability towards TOPEX. As a result, a system configuration evolved using some flight proven designs in conjunction with needed improvements which include: (1) a second frequency or channel to remove the range delay or apparent height bias caused by the electron content of the ionosphere; (2) higher transmit pulse repetition frequencies for correlation benefits at higher sea states to maintain precision; and (3) a faster microprocessor to accommodate two channels of altimetry data. Additionally, examination of past altimeter programs associated data processing algorithms was accomplished to establish the TOPEX-class Radar Altimeter data processing algorithms, and the necessary direction was outlined to begin to generate these for the TOPEX Mission.

Rossi, L. C.↗

Radiative Structures of Lycopodium-Air Flames in Low Gravity

Initially uniform clouds of fuel particulates in air sustain processes which may lead to particle cloud nonuniformities. In low gravity, flame-induced Kundt's Tube phenomena are observed to form regular patterns of nonuniform particle concentrations. Irregular patterns of particle concentrations also are observed to result from selected nonuniform mixing processes. Low gravity flame propagation for each of these classes of particle cloud flames has been found to depend importantly on the flame-generated infrared radiative fields. The spatial structures of these radiative fields are described. Application is made for the observed clases of lycopodium-air flames.

Berlad, A. L.↗

Precedence relationship representations of mechanical assembly sequences

Two types of precedence relationship representations for mechanical assembly sequences are presented: precedence relationships between the establishment of one connection between two parts and the establishment of another connection, and precedence relationships between the establishment of one connection and states of the assembly process. Precedence relationship representations have the advantage of being very compact. The problem with these representations was how to guarantee their correctness and completeness. Two theorems are presented each of which leads to the generation of one type of precedence relationship representation guaranteeing its correctness and completeness for a class of assemblies.

Homendemello, L. S.↗

Coronae on Venus - Morphology, classification, and distribution

Venera 15/16 radar images of Venus show two circular features having no analog among the terrestrial planets: 21 coronae, which have a complex interior zone, and 11 corona-like features, which lack the ridge annuli of the coronae. Each of these two groups of features is subdivisible into three classes; coronae may be symmetrical, asymmetrical, and subdued, while corona-like structures are double, irregular, and heart-shaped. The various classes of both types of classes are interpreted as having a similar mode of origin, namely the uplift and volcanism generated by a thermal anomaly at depth, followed by gravitational relaxation.

Pronin, A. A.↗

Several families of viscous optimized waveriders - A review of waverider research at the University of Maryland

Theoretical and experimental research conducted by the Hypersonic Group at the University of Maryland in the area of viscous optimized waveriders is reviewed. In particular, the motivation for this class of waveriders is discussed, and results obtained to date are presented. Various waverider families generated from different flows and designed for different applications are examined, including waveriders using chemically reacting flow effects and very high altitude applications.

Anderson, John D., Jr.↗

A Study of Viscous Interaction Effects on Hypersonic Waveriders

The effects of viscous interaction in the analysis and design of improved classes of viscous optimized hypersonic waveriders is examined. The Corda computer program is used to generate viscous optimized hypersonic waveriders from conical flow fields without viscous interaction. Each waverider is optimized for maximum L/D, and comparison studies are made between cases with and without viscous interaction. The results show that aerodynamic performance of the viscous interaction waveriders are reduced due mainly to a large increase in skin-friction drag associated with the viscous interaction phenomena that grows with increasing Mach number and altitude, but some of this performance loss can be recouped by including viscous interactions within the optimization procedure. When the waverider is optimized for viscous interaction, the shape can change dramatically. A significant result of the present work delineates on a velocity-altitude map the region where viscous interaction effects are significant for modern hypersonic waveriders by performing parametric runs to produce L/D, C sub L, and C sub D contour plots for Mach numbers from 6 to 30 at altitudes from 30 to 80 km.

Chang, Jinhwa↗