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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 865 records · Page 48

Mapping Permafrost Variability and Degradation Using Seismic Surface Waves, Electrical Resistivity, and Temperature Sensing: A Case Study in Arctic Alaska

Subsurface processes significantly influence surface dynamics in permafrost regions, necessitating utilizing diverse geophysical methods to reliably constrain permafrost characteristics. This research uses multiple geophysical techniques to explore the spatial variability of permafrost in undisturbed tundra and its degradation in disturbed tundra in Utqiagvik, Alaska. Here, we integrate multiple quantitative techniques, including multichannel analysis of surface waves (MASW), electrical resistivity tomography (ERT), and ground temperature sensing, to study heterogeneity in permafrost’s geophysical characteristics. MASW results reveal active layer shear wave velocities (V s ) between 240 and 370 m/s, and permafrost V s between 450 and 1,700 m/s, typically showing a low-high-low velocity pattern. Additionally, we find an inverse relationship between in situ V s and ground temperature measurements. The V s profiles along with electrical resistivity profiles reveal cryostructures such as cryopeg and ice-rich zones in the permafrost layer. The integrated results of MASW and ERT provide valuable information for characterizing permafrost heterogeneity and cryostructure. Corroboration of these geophysical observations with permafrost core samples’ stratigraphies and salinity measurements further validates these findings. This combination of geophysical and temperature sensing methods along with permafrost core sampling confirms a robust approach for assessing permafrost’s spatial variability in coastal environments. Our results also indicate that civil infrastructure systems such as gravel roads and pile foundations affect permafrost by thickening the active layer, lowering the V s , and reducing heterogeneity. We show how the resulting V s profiles can be used to estimate key parameters for designing buildings in permafrost regions and maintaining existing infrastructure in polar regions.

54 ENVIRONMENTAL SCIENCES↗

Visible Light Assisted Photocatalytic Hydrogen Generation by Ta 2 O 5 /Bi 2 O 3 , TaON/Bi 2 O 3 , and Ta 3 N 5 /Bi 2 O 3 Composites

Composites comprised of two semiconducting materials with suitable band gaps and band positions have been reported to be effective at enhancing photocatalytic activity in the visible light region of the electromagnetic spectrum. Here, we report the synthesis, complete structural and physical characterizations, and photocatalytic performance of a series of semiconducting oxide composites. UV light active tantalum oxide (Ta2O5) and visible light active tantalum oxynitride (TaON) and tantalum nitride (Ta 3 N 5 ) were synthesized, and their composites with Bi 2 O 3 were prepared in situ using benzyl alcohol as solvent. The composite prepared using equimolar amounts of Bi 2 O 3 and Ta 2 O 5 leads to the formation of the ternary oxide, bismuth tantalate (BiTaO 4 ) upon calcination at 1000 °C. The composites and single phase bismuth tantalate formed were characterized by powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), Brunauer–Emmett–Teller (BET) surface area measurement, scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–Vis diffuse reflectance spectroscopy, and photoluminescence. The photocatalytic activities of the catalysts were evaluated for generation of hydrogen using aqueous methanol solution under visible light irradiation (λ ≥ 420 nm). The results show that as-prepared composite photocatalysts extend the light absorption range and restrict photogenerated charge-carrier recombination, resulting in enhanced photocatalytic activity compared to individual phases. The mechanism for the enhanced photocatalytic activity for the heterostructured composites is elucidated based on observed activity, band positions calculations, and photoluminescence data.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Pulsed laser deposition of single layer, hexagonal boron nitride (white graphene, h-BN) on fiber-oriented Ag(111)/SrTiO{sub 3}(001)

We report on the growth of 1–10 ML films of hexagonal boron nitride (h-BN), also known as white graphene, on fiber-oriented Ag buffer films on SrTiO{sub 3}(001) by pulsed laser deposition. The Ag buffer films of 40 nm thickness were used as substitutes for expensive single crystal metallic substrates. In-situ, reflection high-energy electron diffraction was used to monitor the surface structure of the Ag films and to observe the formation of the characteristic h-BN diffraction pattern. Further evidence of the growth of h-BN was provided by attenuated total reflectance spectroscopy, which showed the characteristic h-BN peaks at ∼780 cm{sup −1} and 1367.4 cm{sup −1}. Ex-situ photoelectron spectroscopy showed that the surface of the h-BN films is stoichiometric. The physical structure of the films was confirmed by scanning electron microscopy. The h-BN films grew as large, sub-millimeter sheets with nano- and micro-sheets scattered on the surface. The h-BN sheets can be exfoliated by the micromechanical adhesive tape method. Spectral analysis was performed by energy dispersive spectroscopy in order to identify the h-BN sheets after exfoliation. The use of thin film Ag allows for reduced use of Ag and makes it possible to adjust the surface morphology of the thin film prior to h-BN growth.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Enabling liquid vapor analysis using synchrotron VUV single photon ionization mass spectrometry with a microfluidic interface

Vacuum ultraviolet (VUV) single photon ionization mass spectrometry (SPI-MS) is a vacuum-based technique typically used for analysis of gas phase and solid samples, but not for liquids, due to the challenge in proposing volatile liquids in vacuum. In this work we introduce the first demonstration of in situ liquid analysis by integrating the System for Analysis at the Liquid Vacuum Interface (SALVI) microfluidic reactor into VUV SPI-MS. Four representative volatile organic compound (VOC) solutions were used to illustrate feasibility of liquid analysis. Our results reflect accurate mass identification of the VOC molecules and reliable determination of appearance energy (AE) that is consistent with ionization energy (IE) for gaseous species in literature as reported. This work validates that the vacuum-compatible SALVI microfluidic interface can be utilized at the synchrotron beamline and enable in situ research of gas-phase molecules evaporating off the surface of a liquid, which holds importance in the study of condensed matter chemistry.

47 OTHER INSTRUMENTATION↗

Formation of Non-Doped Cubic Lithium Lanthanum Zirconium Oxide Nanofibers: Insights from In Situ Synchrotron X-Ray Scattering

This study investigates the formation mechanism of non-doped cubic lithium lanthanum zirconium oxide (c-LLZO) nanofibers using in situ synchrotron X-ray scattering techniques. Electrospun polymer precursor nanofibers were annealed at temperatures up to 800 °C, enabling real-time tracking of phase transitions via simultaneous small-angle X-ray scattering (SAXS), wide-angle X-ray scattering (WAXS), and evolved CO 2 gas analysis. The results reveal a three-step transformation pathway: polymer decomposition, formation of La 2 Zr 2 O 7 (LZO), and direct conversion of LZO to c-LLZO without intermediate tetragonal phases detected within the sensitivity of our in situ WAXS measurement. Cryo-electron energy loss spectroscopy (EELS) further elucidates the role of lithium diffusion, showing Li enrichment at fiber surfaces and Li deficiency in the interior, which stabilizes the cubic phase. This Li segregation effect in nanostructured LLZO materials extends beyond the previously reported size effect. This work advances the understanding of c-LLZO formation mechanisms and provides practical insights for optimizing synthesis routes to achieve phase-pure c-LLZO for solid-state battery applications.

LLZO phase stability↗

Infrared algorithm development for ocean observations

Efforts continue under this contract to develop algorithms for the computation of sea surface temperature (SST) from MODIS infrared retrievals. This effort includes radiative transfer modeling, comparison of in situ and satellite observations, development and evaluation of processing and networking methodologies for algorithm computation and data accession, evaluation of surface validation approaches for IR radiances, and participation in MODIS (project) related activities. Efforts in this contract period have focused on radiative transfer modeling, evaluation of atmospheric correction methodologies, involvement in field studies, production and evaluation of new computer networking strategies, and objective analysis approaches.

Brown, Otis B.↗

Cryogenic System for Interferometry of High-precision Optics at 20 K: Design and Performance

This report describes the facility and experimental methods at the Goddard Space Flight Center Optics Branch for the measurement of the surface figure of cryogenically-cooled spherical mirrors using standard phase-shifting interferometry, with a standard uncertainty below 2nm rms. Two developmental silicon carbide mirrors were tested: both were spheres with radius of curvature of 600 mm, and clear apertures of 150 mm. The mirrors were cooled within a cryostat, and the surface figure error measured through a fused-silica window. The GSFC team developed methods to measure the in-situ SFE at 20 K with a combined standard uncertainty below 2 nm rms and the change in SFE with temperature (the cryochange) with a combined standard uncertainty of 0.25 -- 0.75 nm rms. This paper will present the measurement facility, methods, and uncertainty analysis.

Blake,Peter↗

Updated Human Mars Ascent Vehicle Concept in Support of NASA’s Strategic Analysis Cycle 2021

Significant progress has been made to NASA’s Moon to Mars campaign over the last several years, which drives changes to the agency’s current human exploration strategy. With Strategic Analysis Cycle 2021 (SAC21) the team was asked to consider new areas of the trades space not fully understood in the past. Specific to the Mars Ascent Vehicle (MAV), the team was asked to consider a concept based on a nitrogen tetroxide (NTO) and mono-methyl hydrazine (MMH) two stage propulsion system which would utilize surface propellant transfer, as opposed to In Situ Resource Utilization (ISRU). The vehicle supports two crew members from the surface up to 84 hours nominally. This paper presents further details of the current MAV reference design used in NASA’s SAC21, including descriptions of the operations, configuration, subsystem design, and vehicle mass summary. Additional detail is also provided on rational that drove specific design changes since the last MAV concept, published in 2019.

Douglas J. Trent↗

The NASA Eulerian Snow on Sea Ice Model (NESOSIM) v1.0: initial model development and analysis

The NASA Eulerian Snow On Sea Ice Model (NESOSIM) is a new, open-source snow budget model that is currentlyconfigured to produce daily estimates of the depth and density of snow on sea ice across the Arctic Ocean throughthe accumulation season. NESOSIM has been developed in a three-dimensional Eulerian framework and includes two(vertical) snow layers and several simple parameterizations (accumulation, wind packing, advection_divergence, blowingsnow lost to leads) to represent key sources and sinks of snow on sea ice. The model is forced with daily inputs of snowfall and near-surface winds (from reanalyses), sea ice concentration (from satellite passive microwave data) and sea ice drift (from satellite feature tracking) during the accumulation season (August through April). In this study, we present the NESOSIM formulation, calibration efforts, sensitivity studies and validation efforts across an Arctic Ocean domain (100 km horizontal resolution). The simulated snow depth and density are calibrated with in situ data collected on drifting ice stations during the 1980s. NESOSIM shows strong agreement with the in situ seasonal cycles of snow depth and density, and shows good (moderate) agreement with the regional snow depth (density) distributions. NESOSIM is run for a contemporary period (2000 to 2015), with the results showing strong sensitivity to the reanalysis derived snowfall forcing data, with the Modern-Era Retrospective analysis for Research and Applications (MERRA) and the Japanese Meteorological Agency 55-year reanalysis (JRA-55) forced snow depths generally higher than ERA-Interim,and the Arctic System Reanalysis (ASR) generally lower. We also generate and force NESOSIM with a consensus "median" daily snowfall dataset from these reanalyses.The results are compared against snow depth estimates derived from NASA's Operation IceBridge (OIB) snow radar data from 2009 to 2015, showing moderate_strong correlations and root mean squared errors of 10 cm depending on the OIB snow depth product analyzed, similar to the comparisons between OIB snow depths and the commonly used modified Warren snow depth climatology. Potential improvements to this initial NESOSIM formulation are discussed in the hopes of improving the accuracy and reliability of these simulated snow depths and densities.

Petty, Alek A.↗

Direct observation of ice nucleation events on individual atmospheric particles

Heterogeneous ice nucleation is a physical chemistry process of critical relevance to a range of topics in the fundamental and applied sciences and technologies. Heterogeneous ice nucleation remains insufficiently understood, partially due to the lack of experimental methods capable of obtaining in situ microscopic details of ice formation over nucleating substrates or particles. Here, we present microscopic observations of ice nucleation events on kaolinite particles at the nanoscale and demonstrate the capability of direct tracking and micro-spectroscopic characterization of individual ice nucleating particles (INPs) in an authentic atmospheric sample. Furthermore, this approach utilizes a custom-built ice nucleation cell, interfaced with an Environmental Scanning Electron Microscope (IN-ESEM platform) operated at temperatures and relative humidities relevant for heterogeneous ice nucleation. The IN-ESEM platform allows dynamic observations of individual ice formation events over particles in isobaric and isothermal experiments. Isothermal experiments on individual kaolinite particles demonstrate that ice crystals preferably nucleate at the edges of the stacked kaolinite platelets, rather than on their basal planes. Finally, these experimental observations of the location of ice nucleation provide direct information for further theoretical chemistry predictions of ice formation on kaolinite.

54 ENVIRONMENTAL SCIENCES↗

Removable, Sequestration Coatings for Mitigating Hazardous Contaminants Related to Deactivation and Decommissioning Activities

This project is a collaborative effort between InnoSense LLC (ISL) and Oak Ridge National Laboratory (ORNL) aimed at mitigating the mercury (Hg) contamination problem at the Y-12 National Security Complex (NSC). The report summarizes the research and technology development work of the Phase IIB Project, led by Dr. Uma Sampathkumaran at ISL for the period of July 31, 2017–October 31, 2021. The Y-12 site cleanup includes technologies for safe and cost-effective facility demolition, soil remediation, and on-site treatment and disposal of mercury bearing wastes. One of the technology demonstration goals was a reactive strippable coating for targeted pre-demolition and de-contamination to limit Hg mobilization and the volume of debris requiring treatment for disposal. Toward this, ISL has developed a water-based reactive strippable coating (Trap & See-Hg™) to sequester elemental Hg(0) and mercuric Hg(II) species in the coating. The coating provides multiple benefits including (1) Hg vapor suppression, (2) sealing in the hazardous contaminants, (3) visually locating the contaminant through color changes, and (4) remediating the contaminated surfaces upon coating removal. Through collaboration between ORNL and ISL in Phase II work, the team successfully demonstrated the Trap & See-Hg technology to (1) visually locate the presence of Hg on concrete, soil and drywall surfaces, (2) effectively sequester all mercury species (elemental, soluble and insoluble Hg) from lab-generated and ex-situ soil and brick/rubble samples collected from the Y 12 site with 80 to 95% efficiency to capture/reduce Hg vapor concentration, (3) be applied by manual and robotic spray applicators and cure at room ambient, (4) remain a cohesive and peelable coating upon drying, and (5) sequester Hg0 from walls in the alpha-2 building basement at Y-12 during a small scale in-situ field trial. In Phase IIB, ISL’s effort was focused on refining the coating formulations with additives containing passive and reactive sorbents, colorimetric indicator, and thixotropic agents to achieve the desired performance. The paints were then evaluated at ORNL for applicability to metal and concrete surfaces of different sizes and shapes, and soil rubble, Hg-sorption capacity and achieving sag-free coating on surfaces when applied by a manual spray applicator. Ambient cure of the coating resulted in a dry thickness of 16–20 mil. The coatings were removed from smooth or rough surfaces with low to moderate force. Both lab-generated Hg-contaminated samples and soil and brick/rubble samples containing a range of Hg concentrations (collected from the Y-12 site by UCOR) were used in this project. Optimized formulations were applied to these samples and evaluated for ability to suppress Hg vapors, sequester Hg 0 and Hg(II) species and color mapping of mercury species on the test surface. The ORNL team initially identified three to four potential sites at Y-12 and ORNL for potential demonstration. However, the pandemic closed any possible avenues for on-site demonstration of the robotic spray applicator. The metal and concrete samples with low to high Hg content provided by UCOR from an ongoing demolition were subsequently used for ex-situ sample characterization and analysis at ORNL over a period of 25 days. The coatings suppressed Hg vapors with an efficiency of 95–99% from heavily contaminated metal and 60% from concrete substrate. Analysis of total Hg in the peeled paints indicates sorption capacities ranging from 12 µg Hg/g of paint from concrete to 1.2 mg Hg/g of paint from the metal substrates while peeled paints from soil samples could capture a total Hg from 2.3 mg Hg/g to 66 mg/g paint. Toxicity characteristic leaching procedure (TCLP) tests recovered total mercury leached at 0.15±0.0008 µg/L for concrete to 126.81±0.67 µg/L and 377.25±5.67 µg/L for the two metal substrates, to allow for informed decisions on downstream disposal considerations. Together, this Phase IIB demonstrated the potential value of the Trap & See-Hg for Hg uptake, vapor suppression, and color mapping, and may thus be used to enhance worker safety during site cleanup, facility demolition, and downstream waste disposal at Y-12 NSC.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Surface electrical properties experiment

The surface electrical properties (SEP) experiment was used to explore the subsurface material of the Apollo 17 landing site by means of electromagnetic radiation. The experiment was designed to detect electrical layering, discrete scattering bodies, and the possible presence of water. From the analysis of the data, it was expected that values of the electrical properties (dielectric constant and loss tangent) of lunar material in situ would be obtained. The basic principle of the SEP experiment is interferometry. This principle involves only the interference of two or more waves to produce an interference pattern. The inversion of the interference pattern in terms of the spatial distribution of the electrical properties is the basic aim of the experiment (fig. 15-1). The experiment is most easily understood in terms of a single dipole antenna for radiating electromagnetic energy and a loop receiver for measuring the magnitudes of the fields.

Simmons, G.↗

On the Absence of Strike-slip Faults from the Planets and Satellites

Lunar grabens are bounded by two downward converging 60 deg dipping normal faults. These faults intersect below the surface at a major mechanical discontinuity in the shallow crust between the megaregolith (total ejecta built up by repeated cratering) and the underlying in situ fractured rock. The ymmetry and simplicity of lunar grabens demands that the bounding faults initiate at this mechanical discontinuity and propagate up. Wrinkle ridges are though to result from thrust faulting or compressional folding of mare basalts. Identification and analysis of a number of terrestrial analogs that are morphologically similar to lunar and martian examples indicates that wrinkle ridges results from thrust faulting. The location of wrinkle ridges above suggested subsurface basin structures indicates that the trend and location of many wrinkle ridges are inherited from these pre-existing basin structures. This implies that the thrust faults responsible for wrinkle ridges initiate at the ase of the basalt-basin floor contact. This contact almost certainly represents a mechanical discontinuity in the shallow lunar crust because mare basalts are undoubtedly stronger than the underlying fall-back ejecta of the basin floor.

Golombek, M. P.↗

Space dust and debris; Proceedings of the Topical Meeting of the Interdisciplinary Scientific Commission B (Meetings B2, B3, and B5) of the COSPAR 28th Plenary Meeting, The Hague, Netherlands, June 25-July 6, 1990

The present conference on space dust and debris encompasses orbital debris, in situ measurements and laboratory analysis of space-dust particles, comparative studies of comets, asteroids, and dust, the protection and maneuvering of spacecraft in space-debris environments, and the out-of-elliptic distribution of interplanetary dust derived from near-earth flux. Specific issues addressed include asteroid taxonomy, the optical properties of dust from cometary and interplanetary grains, light scattering by rough surfaces on asteroidal/lunar regoliths, and the first results of particulate impacts and foil perforations on the Long Duration Exposure Facility. Also addressed are collision probability and spacecraft disposition in the geostationary orbit, a flash on the moon caused by orbital debris, the limits of population growth in low earth orbit due to collisional cascading, and the simulation of cosmic man-made dust effects on space-vehicle elements in rocket and laboratory experiments.

Kessler, D. J.↗

Quantifying Vegetation Change in Semiarid Environments: Precision and Accuracy of Spectral Mixture Analysis and the Normalized Difference Vegetation Index

Because in situ techniques for determining vegetation abundance in semiarid regions are labor intensive, they usually are not feasible for regional analyses. Remotely sensed data provide the large spatial scale necessary, but their precision and accuracy in determining vegetation abundance and its change through time have not been quantitatively determined. In this paper, the precision and accuracy of two techniques, Spectral Mixture Analysis (SMA) and Normalized Difference Vegetation Index (NDVI) applied to Landsat TM data, are assessed quantitatively using high-precision in situ data. In Owens Valley, California we have 6 years of continuous field data (1991-1996) for 33 sites acquired concurrently with six cloudless Landsat TM images. The multitemporal remotely sensed data were coregistered to within 1 pixel, radiometrically intercalibrated using temporally invariante surface features and geolocated to within 30 m. These procedures facilitated the accurate location of field-monitoring sites within the remotely sensed data. Formal uncertainties in the registration, radiometric alignment, and modeling were determined. Results show that SMA absolute percent live cover (%LC) estimates are accurate to within ?4.0%LC and estimates of change in live cover have a precision of +/-3.8%LC. Furthermore, even when applied to areas of low vegetation cover, the SMA approach correctly determined the sense of clump, (i.e., positive or negative) in 87% of the samples. SMA results are superior to NDVI, which, although correlated with live cover, is not a quantitative measure and showed the correct sense of change in only 67%, of the samples.

Elmore, Andrew J.↗

Reduced and Oxidized Sulfur Compounds Detected by Evolved Gas Analyses of Materials from Yellowknife Bay, Gale Crater, Mars

Sulfate minerals have been directly detected or strongly inferred from several Mars datasets and indicate that aqueous alteration of martian surface materials has occurred. Indications of reduced sulfur phases (e.g., sulfides) from orbital and in situ investigations of martian materials have been fewer in number, but these phases are observed in martian meteorites and are likely because they are common minor phases in basaltic rocks. Here we discuss potential sources for the S-bearing compounds detected by the Mars Science Laboratory (MSL) Sample Analysis at Mars (SAM) instrument’s evolved gas analysis (EGA) experiments.

McAdam, A. C.↗

Quantifying TOLNet Ozone Lidar Accuracy During the 2014 DISCOVER-AQ and FRAPPE Campaigns

The Tropospheric Ozone Lidar Network (TOLNet) is a unique network of lidar systems that measure high-resolution atmospheric profiles of ozone. The accurate characterization of these lidars is necessary to determine the uniformity of the network calibration. From July to August 2014, three lidars, the TROPospheric OZone (TROPOZ) lidar, the Tunable Optical Profiler for Aerosol and oZone (TOPAZ) lidar, and the Langley Mobile Ozone Lidar (LMOL), of TOLNet participated in the Deriving Information on Surface conditions from Column and Vertically Resolved Observations Relevant to Air Quality (DISCOVER-AQ) mission and the Front Range Air Pollution and Photochemistry Experiment (FRAPPA) to measure ozone variations from the boundary layer to the top of the troposphere. This study presents the analysis of the intercomparison between the TROPOZ, TOPAZ, and LMOL lidars, along with comparisons between the lidars and other in situ ozone instruments including ozonesondes and a P-3B airborne chemiluminescence sensor. The TOLNet lidars measured vertical ozone structures with an accuracy generally better than +/-15 % within the troposphere. Larger differences occur at some individual altitudes in both the near-field and far-field range of the lidar systems, largely as expected. In terms of column average, the TOLNet lidars measured ozone with an accuracy better than +/-5 % for both the intercomparison between the lidars and between the lidars and other instruments. These results indicate that these three TOLNet lidars are suitable for use in air quality, satellite validation, and ozone modeling efforts.

TOLNet↗

Analysis of Hypervelocity-Impacted Thin Films for Space Applications

Exposure to the harsh space environment and hypervelocity impacts from micrometeoroids and small orbital debris can affect space operations through long-term degradation of spacecraft materials, surfaces, or systems. Multi-layer insulation (MLI) and coated polyimide films are space-craft materials commonly found on the external surfaces of spacecraft for thermal control and protection. Characterizing the damage to these exposed materials with in-situ and laboratory measurements can better inform spacecraft designers and operators in understanding and mitigating surface or system degradation. In this paper, we examine flown Hubble Space Telescope (HST) Electronic Bay 5 MLI and coated polyimide ground test articles to characterize hyper-velocity impact damage. Impact feature cavities are inspected to identify damage, which can validate long-term degradation models, improve thermal management systems, or improve accuracy of damage predictions. An overview of the impact characterization using optical microscopy, narrow-band spectroscopy, and scanning election microscopy/energy dispersive x-ray (SEM/EDX) of the two materials is presented. Observations of robustness in the space environment, as well as a detailed assessment of cratering and penetration statistics for the space-exposed sample, also are discussed.

Melissa A Ward↗