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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 865 records · Page 48

Inertial Electrostatic Confinement Fusion: The Laser Elevator Solar System Survey for Propellants Abstract

Dr. Wayne Pryor worked on three projects this summer. These were: 1) Inertial Electrostatic Confinement; 2) The Laser Elevator; and 3) Solar System Survey for Propellants Abstract. We Assisted Jon Nadler from Richland Community College in assembling and operating a table-top nuclear fusion reactor. We successfully demonstrated neutron production in a deuterium plasma. Pryor also obtained basic spectroscopic information on the atomic and molecular emissions in the plasma. The second project consisted of the completion of a paper on a novel propulsion concept (due to Tom Meyer of Colorado, the first author): a laser sail that bounces light back to the laser source. Recycling the photons from source to sail perhaps 100-1000 times dramatically improves the energy efficiency of this system, which may become very important for high-velocity missions in the future. Lastly, we compiled a very basic inventory of solar system propellant resources, their locations, and their accessibility. This initial inventory concentrates on sunlight availability, water availability, and the difficulty (delta-velocity requirement and radiation environment) in getting there.

Pryor, Wayne↗

An Improved Hf Vapor Etching Apparatus for Stardust Particle Extraction

Introduction: The NASA Stardust mission captured thousands of particles from the Jupiter-family comet 81P/Wild 2 in a collector composed of aluminum foil and blocks of silica aerogel [1]. To date, most Wild 2 particles available for study are relatively large and coherent particles extracted individually from the ends of hollow, carrot-shaped impact tracks produced during impact into aerogel. However, >65% of the impacting mass can be found in the ‘bulb’ of the track, including nearly all of the <1 μm size fraction [2]. This fraction contains organic-rich material and is likely to include presolar grains, representing a critical opportunity to constrain the organic and presolar inventory of primitive outer solar system materials. However, the small size and susceptibility of this fraction to melting or alteration during capture poses significant analytical challenges. Previous attempts to extract and concentrate fine-grained material from the bulb of Stardust tracks have attempted to develop techniques that efficiently destroy aerogel and leave impactor particles relatively unharmed. The low density and high porosity of silica aerogel makes it more susceptible to attack by etching with hydrofluoric acid (HF) [3] or CF4 plasma ashing [4] than collected cometary silicates. Previous studies of HF vapor etching used HF solutions varying between 5 to 49% and noted that at high concentrations and etch rates, a liquid droplet was produced according to the etching reaction 4HF + SiO2 → SiF4 (g) + 2H2O [3]. SiF4 readily decomposes into HF and silicic acid in water, which has the potential to alter the freed cometary silicates. The plasma ashing technique avoids production of a liquid droplet and minimizes damage to embedded silicates but requires specialized equipment [4]. In this abstract, we present recent improvements to the HF etching procedure with the aim of constructing an etching chamber capable of slowly etching silica aerogel using small quantities of dilute HF. The etching chamber can be assembled using readily available materials.

Stardust↗

Plasma-Based Sustainability Architecture for Space Habitation: Perspective

Increasing independence from Earth is essential for sustained life off-planet. New technologies are constantly being developed to further drive innovation. As commercial and public interest in the space sector has grown, technological improvements have shone a spotlight towards the field of plasma science. Although they have been studied for two centuries, plasma physics and plasma chemistry have advanced significantly in the last two decades. Recent years have advanced electrical power supplies and diagnostic equipment to a point where plasma is able to provide complex processing with little to no consumables beyond electrical power. This work presents a perspectives discussion to provide an overview of the applications and versatility of plasma systems. In this perspectives paper, we discuss the development and infusion of plasma-based architecture that would allow plasma to act as an excellent addition to many applications, a perfect side dish for many meals.

Plasma↗

Comparative study of glow discharge wall conditioning using H{sub 2} and Ar-H{sub 2} gas mixture of ADITYA Tokamak vacuum vessel

Low temperature glow discharge wall conditioning (GDC) using H{sub 2} gas is effective in reduction of oxygen and carbon (low-Z) contain impurities on near surface region of vessel wall. The high retention of hydrogen in vessel wall/components due to long operation of H{sub 2} GDC increases hydrogen out-gassing during tokamak operation and affects the production of high temperature plasma. The hydrogen retention can be reduced using inert gas GDC by sputter cleaning for short duration. But in that case the out-gassing rate of inert gas increases, that again impairs the plasma performance. To overcome above problems, the GDC with hydrogen-inert gas mixture can be used for better removal of C and O surface contaminants and low hydrogen retention in surface. In ADITYA tokamak, H{sub 2}-GDC is carried out regularly after plasma operation, while the GDC with argon-hydrogen (Ar-H{sub 2}) mixture has been experimentally tested to observe the reduction of oxygen and carbon impurities along with low hydrogen retention. In Ar-H{sub 2} GDC, the reason being the formation of ArH{sup +} hydride ions, which has quite long life and more energy compared to H{sub 2}{sup +} ions formed in H{sub 2} GDC for breaking the bond of wall molecules. A systematic comparative study of H{sub 2} GDC and Ar-H{sub 2} Mixture GDC by changing the mixture ratio has been carried out in ADITYA tokamak. The relative levels of oxygen and carbon contain impurities have been measured using residual gas analyzer in both GDC's. We have observed a substantial reduction in oxygen and carbon impurities with a significant improvement in wall condition with Ar-H{sub 2} GDC compared to the H{sub 2} GDC. The effect of wall conditioning by Ar-H{sub 2} GDC on the performance of high temperature plasma operation will be presented in this paper. (author)

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Methods and systems for microwave assisted production of graphitic materials

Systems and methods for plasma based synthesis of graphitic materials. The system includes a plasma forming zone configured to generate a plasma from radio-frequency radiation, an interface element configured to transmit the plasma from the plasma forming zone to a reaction zone, and the reaction zone configured to receive the plasma. The reaction zone is further configured to receive feedstock material comprising a carbon containing species, and convert the feedstock material to a product comprising the graphitic materials in presence of the plasma.

Zeller, Kurt W.↗

Detachment-induced electron production in the early afterglow of pulsed cc-rf oxygen plasmas

Line integrated electron densities are measured by 160.28 GHz Gaussian beam microwave interferometry in a 10 Hz pulsed (50% duty cycle) cc-rf oxygen discharge, operating at 13.56 MHz. Depending on the processing parameters, the oxygen rf discharge displays two different operation modes regarding its electronegativity. For higher rf power with negative self-bias voltage above -220 V, the oxygen discharge acts as electropositive plasma (n{sub -}/n{sub e} Much-Less-Than 1), whereas at lower rf power and self-bias voltage the plasma becomes strongly electronegative (n{sub -}/n{sub e}>2). In the latter mode, a significant electron density increase is measured in the early afterglow (<100 {mu}s) within a pressure range from 20 to 100 Pa. By use of a simple rate equation model, the temporal behavior of the electron density could be reproduced for both modes of electronegativity. The electron production in the early afterglow is mainly caused due to the detachment of negative atomic oxygen ions by metastable oxygen molecules.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Plasma Cytokine Levels During Long-Duration Spaceflight

Determine the in-flight status of immunity, physiological stress, viral immunity/reactivation. Specific measurements include leukocyte distribution, T cell function, cytokine production profiles (mRNA, intracellular, secreted, plasma), virus-specific T cell number/function, latent herpesvirus reactivation, stress hormone levels. Determine the clinical risk related to immune dysregulation for exploration class spaceflight, as well as an appropriate monitoring strategy for spaceflight-associated immune dysfunction, that could be used for the evaluation of countermeasures. Specific Study Objectives: Determine the nutritional status of astronauts before, during, and after spaceflight ensure adequate intake of energy, protein, and vitamins during missions. The Clinical Nutritional Status Assessment measures dietary intake, body composition, protein, bone, iron, mineral, vitamin, and antioxidant status (60 total analytes). Currently, it is a medical requirement for U.S. crewmembers on-board the ISS. The results of data analysis are used both to understand the connections between nutrition and human health during space flight, and to develop effective dietary strategies to reduce adverse health impacts (including bone loss, loss of important vitamins and minerals, and increased genetic damage from radiation).

Crucian, Brian E.↗

Thermonuclear breakup reactions of light nuclei. II - Gamma-ray line production and other applications

The main consequence of nuclear breakup reactions in high-temperature plasmas is shown to be to reduce the production of the gamma-ray lines, due to the breakup of these species at high temperature. Results of the emissivities of all the relevant gamma-ray lines are discussed. It is shown that the magnitude of the breakup effect on the line emissivities depends strongly on temperature, but more importantly on the plasma density and on the available time for the ion processes. Other effects considered include the production of neutrons (from the breakup of helium) and its consequences (such as the production of gamma rays from n-capture reactions and dynamical effects in accretion disk plasmas).

Guessoum, Nidhal↗

Impact of suprathermal ions on neutron yield in the pre-DT phase of ITER operation

An assessment of neutron production during the pre-fusion power-operation (PFPO) phase has been carried out for a representative set of plasma scenarios predicted by the ITER Research Plan. A range of heating systems, namely neutral beam injection (NBI) (hydrogen), electron cyclotron resonance heating (ECRH), and ion cyclotron resonance heating (ICRH) are planned to be used for PFPO studies in helium, hydrogen, and mixed hydrogen–helium plasmas. Fast ions (protons and 3He) originating from NBI and ICRH systems can increase neutron production in PFPO plasmas by directly interacting with intrinsic Be impurities or through secondary processes, as also evidenced at JET. The generation of fast ions in ITER PFPO scenarios has been modelled using the ASTRA-NBI and TORIC-SSFPQL codes. A significant impact of the synergy between hydrogen NBI and hydrogen-minority ICRH on neutron production in helium plasmas is reported. In addition, the stability of the toroidicity-induced Alfvén eigenmodes (TAE) is analyzed for PFPO plasmas with a high pressure of suprathermal ions and a weak reversed shear. The possible impact of sawtooth oscillations and TAEs on neutron production is discussed, based on a linear stability analysis.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Characteristics of the spacecraft optical glow

The optical glow induced by spacecraft-environment interaction under daytime conditions is analyzed using photometric data obtained by the Visible Airglow Experiment on board the Atmospheric Explorer Satellite. Because of the increased ambient oxygen density, the glow is more intense in the daytime. The daytime production efficiency, meausured in Rayleighs per oxygen atom, is similar to the nighttime value. No dependence of the glow intensity on the ambient plasma density was found. The production efficiency increased with time throughout the duration of the spacecraft in orbit.

Yee, J.-H.↗

Features of semiplanotron surface plasma sources

Features of the semiplanotron surface plasma sources (SPS) with cesiation used for high efficient negative ion beam production from first development to modern condition are considered. Design features of semiplanotrons SPS with cylindrical and spherical geometric focusing and the features of the negative ion production in the semiplanotrons are reviewed. Several versions of semiplanotrons with efficiency up to 0.1 A of H{sup -} per kW of discharge power are discussed. Modifications of the semiplanotrons for dc operation and for heavy negative ion production are reviewed.

43 PARTICLE ACCELERATORS↗

Experimental methods to test photoionized plasma models in emission

The expanding foil photoionized plasma platform was developed on the Z-machine at Sandia National Laboratories to produce terrestrial photoionized plasmas at some of the same conditions as those observed in astrophysical black hole accretion disks. The specific scientific goals of the platform are motivated by long-standing astrophysical puzzles related to accreting black hole systems. Ultimately, the experimental goal is to inform the supersolar Fe abundance problem by testing photoionized plasma models in emission with at-parameter laboratory data. High quality high resolution emission data with absolute intensity calibration from a laboratory photoionized plasma have never been collected prior to the experiments described here, providing broader motivation. A robust test of the model predictions requires the successful production of a laboratory photoionized plasma along with measurements of the supporting model inputs including the radiation drive spectrum used to create the photoionized plasma, the electron density, and the temperature. The measured absolute spectral radiance in emission collected from the independently diagnosed plasma can be compared against model calculations performed using the measured inputs. In this paper, we focus on the experimental platform and the model inputs, specifically detailing the methodology used to measure the plasma conditions. The moderate electron temperature of ∼41 eV ± 15 eV and electron density of ∼1e19 ± 1.6e18 e−/cm3 and the ∼3e12 W/cm2 x-ray irradiance at the sample confirm that photoionization dominates the plasma ionization and spectra.

Cho, P. B. (ORCID:0000000291632905)↗

Upcycling plastic waste into polyhydroxyalkanoates with high carbon conversion via CO 2 plasma-enabled deconstruction

Plastic deconstruction into fermentable intermediates is a key step for microbial bio-upcycling into value-added products. In this study, CO 2 plasma deconstruction was used as an electrified route to convert polyethylene into oxygenated intermediates and liquid (OIL). The resulting OIL was rich in fatty acids, fatty alcohols, and hydrocarbons, making it a suitable feedstock for medium-chain-length polyhydroxyalkanoate (mcl-PHA) production by Pseudomonas putida NRRL B-14688 and Pseudomonas resinovorans NRRL B-2649. Compared with batch fermentation and monocultures, fed-batch co-cultivation markedly improved biomass formation and PHA accumulation, likely due to complementary substrate utilization, particularly hydrocarbon conversion by P. resinovorans. Using virgin polyethylene-derived OIL (Vir-OIL), the co-culture achieved 40.11% mcl-PHA content and about 18% PHA yield based on total OIL fed. More importantly, OIL produced from post-consumer single-use plastic films (PCR-OIL) was directly fermented and well supported the cell growth and PHA accumulation, achieving 38.11% PHA content and about 14.7% PHA yield. Based on emulsified OIL fractions, PHA yields for Vir-OIL and PCR-OIL were comparable (∼28%). PHA granules were extracted from PCR-OIL-grown cells with high recovery (88.25%) and purity (94.8%). Five monomers were identified in the polymer, including 3-hydroxyhexanoate (3HHx), 3-hydroxyoctanoate (3HO), 3-hydroxydecanoate (3HD), 3-hydroxydodecanoate (3HDD), and 3-hydroxytetradecanoate (3HTD), with 3HO (44.28%) and 3HD (40.60%) as the dominant units. The polymer exhibited moderate molecular weight and narrow dispersity (M n = 65.4 kDa, M w = 92.1 kDa, Đ = 1.40) and low crystallinity (T m ≈ 76.6 °C, X c ≈ 15.5%). These characteristics indicate elastomer-like behavior, making the material suitable for flexible applications such as films, coatings, adhesives, and blend modifiers. Overall, this study establishes a CO 2 plasma-assisted route for generating fermentable polyethylene-derived intermediates and demonstrates that fed-batch co-culture fermentation can effectively funnel plastic-derived carbon into mcl-PHA.

42 ENGINEERING↗

Evidence of plasma‐driven decomposition of common plastics exposed to an atmospheric nonthermal discharge

Abstract A nonthermal, pulsed spark discharge is applied to three polymer powders in Ar and Ar– gas mixtures. Hydrogen is introduced to assess plasma‐driven decomposition. Gaseous decomposition products, including methane, acetylene, and ethylene, are observed with Fourier‐transform infrared (FTIR). Surface modifications are observed on the residual polymer via attenuated total internal reflection‐FTIR. Time‐averaged rotational, vibrational, and excitation temperatures are characterized in the discharge. The plasma density is found to be around , with rotational and vibrational temperatures ranging from 1500 to 2200 K and an excitation temperature of 1–2 eV. While spark properties did not change with either gas composition or polymer composition, it was determined that the addition of hydrogen promoted higher concentrations of gaseous phase products (promoting hydrogenolysis).

36 MATERIALS SCIENCE↗

Plasma ammonia synthesis over mesoporous silica SBA-15

Herein we demonstrate the synthesis of ammonia via atmospheric DBD plasma discharge over silica. We evaluated the performance of three structural different silicas: non-porous silica, fumed-silica and mesoporous SBA-15 silica. The mesoporous SBA-15 sample resulted in an ammonia synthesis rate per gram of catalyst at least 3 times higher than that of the non-porous and fumed silica when employing a hydrogen rich gas feed. The hierarchical ordered pore size in the mesoporous range of SBA-15 allowed us to observe experimentally, the pore size effect in the plasma discharge. Specifically, the ammonia production is enhanced by the presence of mesopores that can effectively enable the discharge diffusion into the pore as predicted by theoretical calculations. The importance of the porous structure was confirmed by optical emission spectra which indicates a similarity on the relative intensity on the main plasma activated species in the gas phase such as N2+, NH and H_α for the three silicas employed in this work i.e., non-porous, fumed and mesoporous (SBA-15). Furthermore, the remarkable ammonia production when employing the SBA-15 shows that despite the similarities in the gas phase the main differences might be attributed to the diffusion of the plasma discharge into the pores.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Plasma-Assisted Catalytic Conversion of CO 2 and Propane to Propylene and CO

Ethylene and propylene are critical pillars of the petrochemical and plastics industry. The current industrial route for producing these olefins, which is via steam cracking process, is extremely endothermic and highly CO 2 -intensive. In this work, Susteon, in partnership with the North Carolina State University (NCSU), New Castle University (NU), and SoCalGas, has investigate catalytic materials and process designs to produce propylene from propane by utilizing CO 2 as a soft oxidant in the presence of low temperature dielectric barrier discharge plasma. This route integrates the effect of catalysis and the presence of a plasma environment to intensify the production of the important three carbon olefin from propane at a lower temperature and near atmospheric pressure. This CO 2 oxidative dehydrogenation (CO 2 -ODH) process coproduces CO, which is a valuable by-product, critical for the petrochemical sector. Through this work, Susteon and the team have made significant progress in developing catalysts and gaining insights on the plasma-assisted CO 2 -ODH process.

01 COAL, LIGNITE, AND PEAT↗

Laser wakefield acceleration of electron beams beyond 1 GeV from an ablative capillary discharge waveguide

Laser wakefield acceleration of electrons well beyond 1 GeV and optical guiding of ultraintense laser pulses of peak powers up to 160 TW over a 4-cm long ablative capillary discharge plasma channel were experimentally demonstrated. Electron beams, with energies up to 1.8 GeV, were generated by using the 130 TW, 55 fs driving laser pulses. A comparison of oxygen-containing acrylic resin (C:O:H = 4:2:7) capillary and no oxygen-containing polyethylene (C:O:H = 1:0:2) capillary measurements suggests that the injection of electron into the laser wakefield is assisted by the ionization of oxygen K-shell electrons.

43 PARTICLE ACCELERATORS↗