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NASA NTRS2004

Topographic Evidence for Eruptive Style Changes and Magma Evolution of Small Plains-style Volcanoes on Earth and Mars

Topographic profiles and surface characteristics of small (5 - 25 km diameter) plains-style shield volcanoes on the eastern Snake River Plain (ESRP) provide a method to evaluate eruptive processes and magmatic evolution on Martian volcanic plains. The ESRP is an ideal place to observe Mars-like volcanic features where hundreds of small monogenetic basaltic shields dominate the volcanic-sedimentary depositional sequence, and numerous planetary analogues are evident: coalescent mafic shields, hydromagmatic explosive eruptions, the interaction of lava flows with surficial water and glacial ice, and abundant eolian sand and loess. Single flows cannot be correlated over great distances, and are spatially restricted. These relations are useful for planetary exploration when inferring volcanic evolutionary patterns in lava plains represented by numerous eruptive vents. High spatial resolution imagery and digital topographic data for Mars from MOC, MOLA, and THEMIS is allowing for improvements in the level of detail of stratigraphic mapping of fields of small (< 25 km in diameter) volcanoes as well as studies of the morphological characteristics of individual volcanoes. In order to compare Mars and Earth volcanic features, elevation data from U.S.G.S. 10-meter digital elevation models (DEMs) and high-precision GPS field measurements are used in this study to generate approx. 20m spacing topographic profiles from which slope and surface morphology can be extracted. Average ESRP flank and crater slopes are calculated using 100 - 200 m spacing for optimum comparison to MOLA data, and to reduce the effects of surface irregularities.

Hughes, S. S.↗

NASA NTRS2000

Laser Technology in Interplanetary Exploration: The Past and the Future

Laser technology has been used in planetary exploration for many years but it has only been in the last decade that laser altimeters and ranging systems have been selected as flight instruments alongside cameras, spectrometers, magnetometers, etc. Today we have an active laser system operating at Mars and another destined for the asteroid Eros. A few years ago a laser ranging system on the Clementine mission changed much of our thinking about the moon and in a few years laser altimeters will be on their way to Mercury, and also to Europa. Along with the increased capabilities and reliability of laser systems has came the realization that precision ranging to the surface of planetary bodies from orbiting spacecraft enables more scientific problems to be addressed, including many associated with planetary rotation, librations, and tides. In addition, new Earth-based laser ranging systems working with similar systems on other planetary bodies in an asynchronous transponder mode will be able to make interplanetary ranging measurements at the few cm level and will advance our understanding of solar system dynamics and relativistic physics.

Smith, David E.↗

DOE OSTI2017

Challenges to Constraining Exoplanet Masses via Transmission Spectroscopy

MassSpec , a method for determining the mass of a transiting exoplanet from its transmission spectrum alone, was proposed by de Wit and Seager. The premise of this method relies on the planet’s surface gravity being extracted from the transmission spectrum via its effect on the atmospheric scale height, which in turn determines the strength of absorption features. Here, we further explore the applicability of MassSpec to low-mass exoplanets—specifically those in the super-Earth size range for which radial velocity determinations of the planetary mass can be extremely challenging and resource intensive. Determining the masses of these planets is of the utmost importance because their nature is otherwise highly unconstrained. Without knowledge of the mass, these planets could be rocky, icy, or gas-dominated. To investigate the effects of planetary mass on transmission spectra, we present simulated observations of super-Earths with atmospheres made up of mixtures of H{sub 2}O and H{sub 2}, both with and without clouds. We model their transmission spectra and run simulations of each planet as it would be observed with James Webb Space Telescope using the NIRISS, NIRSpec, and MIRI instruments. We find that significant degeneracies exist between transmission spectra of planets with different masses and compositions, making it impossible to unambiguously determine the planet’s mass in many cases.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS1977

Planetary atmospheres with mass spectrometers carried on high-speed probes or satellites

Earth satellite-borne mass spectrometers are considered, taking into account the identification of atomic oxygen in the thermosphere with an 'open' source mass spectrometer flown on a sounding rocket, the conventional closed-source instrument, the mass spectrometers on the Atmosphere Explorer satellites, and mass spectrometer electron multiplier output. A description is presented of mass spectrometers and planetary entry probes. Attention is given to an attempt to obtain an atmospheric composition profile with a terrestrial entry probe, the descending trajectory in the early orbits of the Atmosphere Explorer C satellite, and the molecular nitrogen densities for the descending legs of the orbits. It is pointed out that chemical reactions on the surfaces of the mass spectrometer make the measurement of reactive atmospheric species such as atomic oxygen very difficult.

Nier, A. O.↗

NASA NTRS1981

International Symposium on Remote Sensing of Environment, 15th, University of Michigan, Ann Arbor, MI, May 11-15, 1981, Proceedings. Volumes 1, 2 & 3

Developments related to advanced sensors and sensor systems are being examined, taking into account advanced aerospace remote sensing systems for global resource applications, spaceborne radar observation of the earth surface, a concept for an advanced earth resources satellite system, technologies for the multispectral mapping of earth resources, and the use of Landsat images and morphologic analogs in space exploration. Other topics discussed are related to modeling for terrain analysis, digital processing and analysis of remotely sensed data, microwave remote sensing, new discoveries from planetary remote sensing, and data base utilization. Advances in the area of luminescence are also considered along with future plans and prospects concerning the remote sensing of the earth from space.

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NASA NTRS2012

Mars Ascent Vehicle Development Status

The Mars robotic sample return mission has been a potential flagship mission for NASA s science mission directorate for decades. The Mars Exploration Program and the planetary science decadal survey have highlighted both the science value of the Mars Sample Return (MSR) mission, but also the need for risk reduction through technology development. One of the critical elements of the MSR mission is the Mars Ascent Vehicle (MAV), which must launch the sample cache from the surface of Mars and place it into low Mars orbit. The MAV has significant challenges to overcome due to tight constraints on the MAV s mass and volume, as well as environmental challenges associated with long duration storage on the Martian surface and during Entry Descent and Landing (EDL). In the fall of 2010, NASA selected three industrial partners for study phase contracts to develop MAV system concepts, identify technology needs, and recommend technology developments plans for follow-on work. In addition to the contractor recommendations, JPL s Team-X was used for a comparative assessment of the three vehicle concepts to understand relative strengths, weaknesses, and sensitivity to system growth. The GRC COMPASS team independently evaluated MAV system solutions using liquid bipropellant, solid rocket motors, and an advanced monopropellant option. The results of the study phase contracts and comparative assessment is provided herein.

Dankanich, John W.↗

NASA NTRSDate not supplied

Feasibility Study of a Robotic Science Arm on Future Martian Rotorcraft

Science arms are indispensable tools for planetary exploration, allowing vehicles to interact with and manipulate their surroundings in a manner similar to a human field geologist. A majority of the rovers and landers sent to Mars, beginning with Viking I and II in 1976, have made extensive use of these articulated, arm-like devices that allow for sample collection, surface preparation, instrument positioning, and the deployment of ground-contact sensors. Although proven useful, traditional rovers and landers are limited by the rough and difficult terrain of Mars. However, given the successful demonstration of flight on Mars by the Ingenuity helicopter, efforts are underway to outfit larger rotorcraft with science payloads to allow them to explore Mars’ surface and lower atmosphere with significantly more efficiency than land vehicles. Such vehicles could also be designed to work in tandem with landers or rovers. The Mars Science Helicopter (MSH) is a conceptual hexacopter design that is currently under early development by both NASA Ames and JPL. Equipping a vehicle like MSH with a science arm has the potential to further expand its scientific capabilities. This paper approaches the mission and design requirements to equip a science arm on MSH while highlighting the unique technical challenges for robotic arm and science instrument capability. Current plans for MSH development do not include the addition of a robotic arm to the vehicle. However, it is anticipated that future variants of the MSH design might well incorporate such adaptable surface interactive capabilities.

Robotic Science Arm↗

DOE OSTI2014

Structure and dynamics of cold water super-Earths: the case of occluded CH{sub 4} and its outgassing

In this work, we study the transport of methane in the external water envelopes surrounding water-rich super-Earths. We investigate the influence of methane on the thermodynamics and mechanics of the water mantle. We find that including methane in the water matrix introduces a new phase (filled ice), resulting in hotter planetary interiors. This effect renders the super-ionic and reticulating phases accessible to the lower ice mantle of relatively low-mass planets (∼5 M{sub E} ) lacking a H/He atmosphere. We model the thermal and structural profile of the planetary crust and discuss five possible crustal regimes which depend on the surface temperature and heat flux. We demonstrate that the planetary crust can be conductive throughout or partly confined to the dissociation curve of methane clathrate hydrate. The formation of methane clathrate in the subsurface is shown to inhibit the formation of a subterranean ocean. This effect results in increased stresses on the lithosphere, making modes of ice plate tectonics possible. The dynamic character of the tectonic plates is analyzed and the ability of this tectonic mode to cool the planet is estimated. The icy tectonic plates are found to be faster than those on a silicate super-Earth. A mid-layer of low viscosity is found to exist between the lithosphere and the lower mantle. Its existence results in a large difference between ice mantle overturn timescales and resurfacing timescales. Resurfacing timescales are found to be 1 Ma for fast plates and 100 Ma for sluggish plates, depending on the viscosity profile and ice mass fraction. Melting beneath spreading centers is required in order to account for the planetary radiogenic heating. The melt fraction is quantified for the various tectonic solutions explored, ranging from a few percent for the fast and thin plates to total melting of the upwelled material for the thick and sluggish plates. Ice mantle dynamics is found to be important for assessing the composition of the atmosphere. We propose a mechanism for methane release into the atmosphere, where freshly exposed reservoirs of methane clathrate hydrate at the ridge dissociate under surface conditions. We formulate the relation between the outgassing flux and the tectonic mode dynamical characteristics. We give numerical estimates for the global outgassing rate of methane into the atmosphere. We find, for example, that for a 2 M{sub E} planet outgassing can release 10{sup 27}-10{sup 29} molecules s{sup –1} of methane to the atmosphere. We suggest a qualitative explanation for how the same outgassing mechanism may result in either a stable or a runaway volatile release, depending on the specifics of a given planet. Finally, we integrate the global outgassing rate for a few cases and quantify how the surface atmospheric pressure of methane evolves over time. We find that methane is likely an important constituent of water planets' atmospheres.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRSDate not supplied

Hazards of Lunar Surface Exploration: Determining the Immunogenicity/Allergenicity of Lunar Dust

There are multiple Apollo program reports of lunar dust (LD) exposure leading to significant upper respiratory symptoms in select crewmembers. Possible mechanisms include particulate irritation, oxidization and release of noxious gas, or legitimate adaptive immune-mediated response. Although sterile non-protein matter would not be expected to be an allergen, one Apollo flight surgeon reported increasing symptoms upon repeated exposure, with associated eosinophilia indicative of allergy (*Acta Astronautica. 2008 63 (7–10): 980–987). Many ISS crews display a pattern of persistent immune system dysregulation and latent virus reactivation (NPJ Microgravity. 2015 Sep 3; 1:15013; NPJ Microgravity. 2017 Apr 12; 3:11). Some ISS crews manifest atypical respiratory and/or dermatitis symptoms which could have an allergic pathogenesis (J Allergy Clin. Immunol. Pract. 2016 Jul-Aug; 4(4):759-762.e8). It is logical to anticipate crew immune dysregulation would worsen during prolonged deep space missions. Planetary surface hazards will only complicate crew health risks. This study hypothesizes that LD exposure can alter susceptible individuals’ immune responses such that repeated exposure will elicit an IgE mediated allergic response either to the LD itself or concomitant antigen exposure during spaceflight. This will adversely increase clinical and operational impacts for long-duration lunar astronauts and affect countermeasure requirements for surface vehicles. Specific aims for this study are (1) Does in vitro LD exposure result in increased histamine from human peripheral blood basophils? (2) Can LD impact the capacity of CD4+ helper and/or CD19+ B-cell mediated IgE production? To address these questions, a set of in-vitro cell culture experiments will be employed (short and long term) using human peripheral blood mononuclear cells (PBMC) and basophils from both atopic and non-atopic individuals, as well as established human basophil and mast cell lines. Cells will be co-cultured with cellular mitogens, common recall antigens (tetanus, Der p1), nickel (as a possible allergenic component of LD), with or without graded amounts of LD, to study whether LD exposure for varying time intervals will alter the generation of selective immune responses associated with clinical allergic reactions. Measured outputs include supernatant-derived IgE, tryptase, histamine and selected cytokine levels. Cellular activation will be monitored by assessing activation markers via flow cytometry. EM/x-ray analysis will be used to determine cellular interactions with dust particles. The minimal amount of LD (Apollo 14 dust) and controls/simulants have been requested. This study, originally planned as an FY20/21 activity, was delayed due to the COVID pandemic. It is now scheduled to be performed during FY22.

Brian Crucian↗

NASA NTRS2004

Environmental Test Program for the Mars Exploration Rover Project

On June 10 and July 7, 2003 the National Aeronautics and Space Administration (NASA) launched two spacecraft from Cape Canaveral, Florida for a six (6) months flight to the Red Planet, Mars. The two Mars Exploration Rover spacecraft landed safely on the planet in January 2004. Prior to the successful launch, both of the spacecraft were involved in a comprehensive test campaign that included development, qualification, and protoflight test programs. Testing was performed to simulate the environments associated with launch, inter-planetary cruise, landing on the planet and Mars surface operations. Unique test requirements included operating the spacecraft while the chamber pressure was controlled to simulate the decent to the planet from deep space, high impact landing loads and rover operations on the surface of the planet at 8 Torr and -130 C. This paper will present an overview of the test program that included vibration, pyro-shock, landing loads, acoustic noise, thermal vacuum and solar simulation testing at the Jet Propulsion Laboratory (JPL) Environmental Test Laboratory facilities in Pasadena, California.

Fisher, Terry C.↗

NASA NTRS2011

Planetary Geochemistry Techniques: Probing In-Situ with Neutron and Gamma Rays (PING) Instrument

The Probing In situ with Neutrons and Gamma rays (PING) instrument is a promising planetary science application of the active neutron-gamma ray technology so successfully used in oil field well logging and mineral exploration on Earth. The objective of our technology development program at NASA Goddard Space Flight Center's (NASA/GSFC) Astrochemistry Laboratory is to extend the application of neutron interrogation techniques to landed in situ planetary composition measurements by using a 14 MeV Pulsed Neutron Generator (PNG) combined with neutron and gamma ray detectors, to probe the surface and subsurface of planetary bodies without the need to drill. We are thus working to bring the PING instrument to the point where it can be flown on a variety of surface lander or rover missions to the Moon, Mars, Venus, asteroids, comets and the satellites of the outer planets.

Parsons, A.↗

NASA NTRS2014

Novel Exercise Hardware Requirements, Development, and Selection Process for Long-Duration Space Flight

Long-duration space flight poses many hazards to the health of the crew. Among those hazards is the physiological deconditioning of the musculoskeletal and cardiovascular systems due to prolonged exposure to microgravity. To combat the physical toll that exploration space flight may take on the crew, NASAs Human Research Program is charged with developing exercise protocols and hardware to maintain astronaut health and fitness during long-term missions. The goal of this effort is to preserve the physical capability of the crew to perform mission critical tasks in transit and during planetary surface operations. As NASA aims toward space travel outside of low-earth orbit (LEO), the constraints placed upon exercise equipment onboard the vehicle increase. Proposed vehicle architectures for transit to and from locations outside of LEO call for limits to equipment volume, mass, and power consumption. While NASA has made great strides in providing for the physical welfare of the crew, the equipment currently used onboard ISS is too large, too massive, and too power hungry to consider for long-duration flight. The goal of the Advanced Exercise Concepts (AEC) project is to maintain the resistive and aerobic capabilities of the current, ISS suite of exercise equipment, while making reductions in size, mass, and power consumption in order to make the equipment suitable for long-duration missions.

physical exercise↗

NASA NTRS2017

Parametric Study of an Ablative TPS and Hot Structure Heatshield for a Mars Entry Capsule Vehicle

The National Aeronautics and Space Administration is planning to send humans to Mars. As part of the Evolvable Mars Campaign, different en- try vehicle configurations are being designed and considered for delivering larger payloads than have been previously sent to the surface of Mars. Mass and packing volume are driving factors in the vehicle design, and the thermal protection for planetary entry is an area in which advances in technology can offer potential mass and volume savings. The feasibility and potential benefits of a carbon-carbon hot structure concept for a Mars entry vehicle is explored in this paper. The windward heat shield of a capsule design is assessed for the hot structure concept as well as an ablative thermal protection system (TPS) attached to a honeycomb sandwich structure. Independent thermal and structural analyses are performed to determine the minimum mass design. The analyses are repeated for a range of design parameters, which include the trajectory, vehicle size, and payload. Polynomial response functions are created from the analysis results to study the capsule mass with respect to the design parameters. Results from the polynomial response functions created from the thermal and structural analyses indicate that the mass of the capsule was higher for the hot structure concept as compared to the ablative TPS for the parameter space considered in this study.

Langston, Sarah L.↗

NASA NTRS2018

Chlorine Isotopic Compositions of Apatite in Apollo 14 Rocks: Evidence for Widespread Vapor-Phase Metasomatism on the Lunar Nearside ~4 Billion Years Ago

Compared to most other planetary materials in the Solar System, some lunar rocks display high delta (sup 37) Cl signatures. Loss of Cl in a H<<Cl environment has been invoked to explain the heavy signatures observed in lunar samples, either during volcanic eruptions onto the lunar surface or during large scale degassing of the lunar magma ocean. To explore the conditions under which Cl isotope fractionation occurred in lunar basaltic melts, five Apollo 14 crystalline samples were selected (14053,19, 14072,13, 14073,9, 14310,171 along with basaltic clast 14321,1482) for in situ analysis of Cl isotopes using secondary ion mass spectrometry. Cl isotopes were measured within the mineral apatite, with delta (sup 37) Cl values ranging from +14.6 ± 1.6 per mille to +40.0 ± 2.9 per mille. These values expand the range previously reported for apatite in lunar rocks, and include some of the heaviest Cl isotope compositions measured in lunar samples to date. The data here do not display a trend between increasing rare earth elements contents and delta (sup 37) Cl values, reported in previous studies. Other processes that can explain the wide inter- and intra-sample variability of delta (sup 37) Cl values are explored. Magmatic degassing is suggested to have potentially played a role in fractionating Cl isotope in these samples. Degassing alone, however, could not create the wide variability in isotopic signatures. Our favored hypothesis, to explain small scale heterogeneity, is late-stage interaction with a volatile-rich gas phase, originating from devolatilization of lunar surface regolith rocks ~4 billion years ago. This period coincides with vapor-induced metasomastism recorded in other lunar samples collected at the Apollo 16 and 17 landing sites, pointing to the possibility of widespread volatile-induced metasomatism on the lunar nearside at that time, potentially attributed to the Imbrium formation event.

apatit↗

NASA NTRSDate not supplied

Hazards of Lunar Surface Exploration: Determining the Immunogenicity/Allergenicity of Lunar Dust

Although infrequent, there have been Apollo program reports of lunar dust (LD) exposure leading to notable upper respiratory symptoms in select crewmembers. Possible mechanisms include particulate irritation, oxidization and release of noxious gas, or legitimate adaptive immune-mediated response. Although sterile non-protein matter would not be expected to be an allergen, one Apollo flight surgeon reported increasing symptoms upon repeated exposure with associated eosinophilia, indicative of allergy (*Acta Astronautica. 2008 63 (7–10): 980–987). Many ISS crews display a pattern of persistent immune system dysregulation and latent virus reactivation (NPJ Microgravity. 2015 Sep 3; 1:15013; NPJ Microgravity. 2017 Apr 12; 3:11). Some ISS crews manifest atypical respiratory and/or dermatitis symptoms which could have an allergic pathogenesis (J Allergy Clin. Immunol. Pract. 2016 Jul-Aug; 4(4):759-762.e8). It is logical to anticipate crew immune dysregulation would worsen during prolonged deep space missions. Planetary surface hazards will only complicate crew health risks. This study with investigate if LD exposure will elicit an IgE mediated allergic response either to the LD itself or concomitant antigen exposure during spaceflight. Allergic reactivity could adversely increase clinical and operational impacts for long-duration lunar astronauts and affect countermeasure requirements for surface vehicles. Specific aims for this study are to answer two questions: (1) Does in vitro LD exposure result in increased histamine from human peripheral blood basophils? (2) Can LD impact the capacity of CD4+ T helper and/or CD19+ B-cell mediated IgE production? To address these questions, after the proposal and selection by NASA, our laboratory has separately requested and been approved for receipt of actual LD samples from the Apollo 16 mission. These samples will be used during the study to complete the proposed set of in vitro cell culture experiments (short and long term), using human peripheral blood mononuclear cells (PBMC) and basophils from both atopic and non-atopic individuals. Cells will be co-cultured with cellular mitogens, common recall antigens (Der p1), fine ground silica quartz (as a possible allergenic component of LD), or LD, to study whether LD exposure for varying time intervals will alter the generation of selective immune responses associated with clinical allergic reactions. Measured outputs include supernatant-derived IgE, tryptase, histamine, and selected cytokine levels. Cellular activation will be monitored by assessing activation markers via flow cytometry. EM/x-ray analysis will be used to determine cellular interactions with dust particles. A series of validation experiments was initiated in FY22 once the delivery of LD was received. Based on initial experimental findings, we are optimizing the culture conditions, LD concentrations, and refining our other protocol stimuli.

Audrie A. Colorado↗

NASA NTRSDate not supplied

Hazards of Lunar Surface Exploration: Determining the Immunogenicity/Allergenicity of Lunar Dust

immunology↗

NASA NTRS2001

Development and Demonstration of a Self-Calibrating Pseudolite Array for Task Level Control of a Planetary Rover

Pseudolites can extend the availability of GPS-type positioning systems to a wide range of applications not possible with satellite-only GPS. One such application is Mars exploration, where the centimeter-level accuracy and high repeatability of CDGPS would make it attractive for rover positioning during autonomous exploration, sample collection, and habitat construction if it were available. Pseudolites distributed on the surface would allow multiple rovers and/or astronauts to share a common navigational reference. This would help enable cooperation for complicated science tasks, reducing the need for instructions from Earth and increasing the likelihood of mission success. Conventional GPS Pseudolite arrays require that the devices be pre-calibrated through a Survey of their locations, typically to sub-centimeter accuracy. This is a problematic task for robots on the surface of another planet. By using the GPS signals that the Pseudolites broadcast, however, it is possible to have the array self-survey its own relative locations, creating a SelfCalibrating Pseudolite Array (SCPA). This requires the use of GPS transceivers instead of standard pseudolites. Surveying can be done either at carrier- or code-phase levels. An overview of SCPA capabilities, system requirements, and self-calibration algorithms is presented in another work. The Aerospace Robotics Laboratory at Statif0id has developed a fully operational prototype SCPA. The array is able to determine the range between any two transceivers with either code- or carrier-phase accuracy, and uses this inter-transceiver ranging to determine the at-ray geometry. This paper presents results from field tests conducted at Stanford University demonstrating the accuracy of inter-transceiver ranging and its viability and utility for array localization, and shows how transceiver motion may be utilized to refine the array estimate by accurately determining carrier-phase integers and line biases. It also summarizes the overall system requirements and architecture, and describes the hardware and software used in the prototype system.

Rock, Stephen M.↗

NASA NTRS2004

Lunar and Planetary Science XXXV: Mars: Surface Coatings, Mineralogy, and Surface Properties

The session "Mars: Surface Coatings, Mineralogy, and Surface Properties" contained the following reports:High-Silica Rock Coatings: TES Surface-Type 2 and Chemical Weathering on Mars; Old Desert Varnish-like Coatings and Young Breccias at the Mars Pathfinder Landing Site; Analyses of IR-Stealthy and Coated Surface Materials: A Comparison of LIBS and Reflectance Spectra and Their Application to Mars Surface Exploration; Contrasting Interpretations of TES Spectra of the 2003 Rover:Opportunity-Landing Site: Hematite Coatings and Gray Hematite; A New Hematite Formation Mechanism for Mars; Geomorphic and Diagenetic Analogs to Hematite Regions on Mars: Examples from Jurassic Sandstones of Southern Utah, USA; The Geologic Record of Early Mars: A Layered, Cratered, and "Valley-"ed: Volume; A Simple Approach to Estimating Surface Emissivity with THEMIS; A Large Scale Topographic Correction for THEMIS Data; Thermophysical Properties of Meridiani Planum, Mars; Thermophysical and Spectral Properties of Gusev, the MER-Spirit Landing Site on Mars; Determining Water Content of Geologic Materials Using Reflectance Spectroscopy; and Global Mapping of Martian Bound Water at 6.1 Microns Based on TES Data: Seasonal Hydration.

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