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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 865 records · Page 48

Crown Ether Modulation Enables over 23% Efficient Formamidinium-Based Perovskite Solar Cells

The use of molecular modulators to reduce the defect density at the surface and grain boundaries of perovskite materials has been demonstrated to be an effective approach to enhance the photovoltaic performance and device stability of perovskite solar cells. Herein, we employ crown ethers to modulate perovskite films, affording passivation of undercoordinated surface defects. This interaction has been elucidated by solid-state nuclear magnetic resonance and density functional theory calculations. The crown ether hosts induce the formation of host-guest complexes on the surface of the perovskite films, which reduces the concentration of surface electronic defects and suppresses nonradiative recombination by 40%, while minimizing moisture permeation. As a result, we achieved substantially improved photovoltaic performance with power conversion efficiencies exceeding 23%, accompanied by enhanced stability under ambient and operational conditions. This work opens a new avenue to improve the performance and stability of perovskite-based optoelectronic devices through supramolecular chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Enhanced convection for higher module and system efficiency (Final Technical Report)

The goal of this work is to develop new solar photovoltaic (PV) modules and solar system-scale designs that promote an increase of the convective heat transfer coefficient of at least 40%, reducing the operating temperature of the solar PV panels, and leading to a boost on the annual energy yield by at least 5%. By achieving this goal, we further foresee decreasing solar panel degradation by +0.3%/year, reducing the LCOE by 2.9-4.5¢/kWh. Currently, this question and/or approach is not considered though it is a relevant factor in performance/efficiency. The technology proposed will be at a mature stage by the end of the project and could be aligned to be proven on a full-field test. PV users, installers and manufacturers will be interested in the technology due to the aforementioned benefits. The work was conducted through a suite of wind tunnel experiments, numerical simulations and field experiments. These were then evaluated through a correlation encompassing the entire data set and implementing findings into NREL SAM. The work resulted in eight peer reviewed publications with three others in preparation. The key results of the project are 1.) Showing the capability of increasing the solar farm power production by increasing the heat transfer coefficient; 2.) Providing strategies for achieving this through large scale arrangement manipulation (heights, spacings, angles), flow deflectors and vortex generators; 3.) Demonstrating scalability of results by comparing numerical simulations, wind tunnel experiments and field experiments; 4.) Providing a correlation to be able to capture the various arrangements while exploiting the heat transfer coefficient; and 5.) Proving the feasibility of such strategies and their capacity through a comprehensive techno-economic analysis. For the heat transfer coefficients, gains of 40% were attained and increases in power in the excess of 5% were observed. For heat mitigation strategies, consideration at the PV array scale were inter-panel spacing, panel height and panel angles while at the module level, wind breaks such as solid walls and selected gaps were evaluated as well as vortex generators on the panel. All proposed strategies saw an increase in heat transfer coefficient. For scalability, results were compared against field experiments and a correlation for the heat transfer quantity was attained leading to a parametric understanding of the variations and impact in the heat transfer coefficient independent of tools implemented (wind tunnel/numerical simulations). The strategies were also further assessed by a technoeconomic analysis finding improvements based on LCOE with respect to location (several states with varies atmospheric conditions/geographic locations) yielded different results. Improvements on this end were also observed especially towards the colder climates and when considering bi-facial modules. The quantitative demonstrations of such conclusions are provided in the main portion of this document with complementary results and their narration. Milestones and go/no-go points were successfully met in the project.

14 SOLAR ENERGY↗

Automated aray assembly, phase 2

A manufacturing process suitable for the large-scale production of silicon solar array modules at a cost of less than $500/peak kW is described. Factors which control the efficiency of ion implanted silicon solar cells, screen-printed thick film metallization, spray-on antireflection coating process, and panel assembly are discussed. Conclusions regarding technological readiness or cost effectiveness of individual process steps are presented.

Daiello, R. V.↗

Precision Solar Disk Photometry - A Tool for Understanding Changes in the Sun's Luminosity

The principal scientific aim of this project is to better understand the observed long-term temporal variations in the Sun's luminosity. Satellite observations have revealed that the flux of solar radiation striking the Earth is modulated by the solar magnetic cycle, being approximately 0.1 percent larger during solar maximum. The impact of this irradiance modulation on terrestrial climate is difficult to model. However, the correlation between the Maunder minimum (a period of low solar magnetic activity in the late 1600s) and the 'Little Ice Age' in Europe during the same period does suggest that small changes in the solar luminosity can profoundly affect the Earth's climate.

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Quantifying the Relationship Between Higher Photovoltaic Module Efficiency and the Adoption of Distributed Solar: Preprint

The purpose of this study is understanding the relationship between module efficiency, system costs, and the economic and adoption potential of distributed rooftop solar. We use the dGen model to project the economic potential and adoption of high-efficiency photovoltaic (PV) modules across a range of efficiencies and cost scenarios in the continental United States. Our results reveal that high-efficiency modules can modestly increase the projected adoption of distributed solar, but system capital costs may play a larger role in changing the amount of projected adoption.

14 SOLAR ENERGY↗

Evidence of active region imprints on the solar wind structure

A common descriptive framework for discussing the solar wind structure in the inner heliosphere uses the global magnetic field as a reference: low density, high velocity solar wind emanates from open magnetic fields, with high density, low speed solar wind flowing outward near the current sheet. In this picture, active regions, underlying closed magnetic field structures in the streamer belt, leave little or no imprint on the solar wind. We present evidence from interplanetary scintillation measurements of the 'disturbance factor' g that active regions play a role in modulating the solar wind and possibly contribute to the solar wind mass output. Hence we find that the traditional view of the solar wind, though useful in understanding many features of solar wind structure, is oversimplified and possibly neglects important aspects of solar wind dynamics

Hick, P.↗

Barriers and variable spacing enhance convective cooling and increase power output in solar PV plants

When the temperature of solar photovoltaic (PV) modules rises, efficiency drops and module degradation accelerates. Thus, it is beneficial to reduce module operating temperatures. Previous studies of solar power plants have illustrated that incoming flow characteristics, turbulent mixing, and array geometry can strongly impact convective cooling, as measured by the convective heat transfer coefficient h. In the fields of heat transfer and plant canopy flow, previous work has shown that system-scale arrangement modifications—e.g., variable spacing, barriers, or windbreaks—can passively alter the flow, enhance turbulent mixing, and influence convection. However, researchers have not yet explored how variable spacing or barriers might enhance convective cooling in solar power plants. Here, high-resolution large-eddy simulations model the air flow and heat transfer through solar power plant arrangements modified with missing modules and barrier walls. We then perform a control volume analysis to evaluate the net heat flux and compute h, which quantifies the influence of these spatial modifications on convective cooling and, thus, module temperature and power output. Installing barrier walls yields the greatest improvements, increasing h by 3.4%, reducing module temperature by an estimated 2.5 °C, and boosting power output by an estimated 1.4% on average. These findings indicate that incorporating variable spacing or barrier-type elements into PV plant designs can reduce module temperature and, thus, improve PV performance and service life.

14 SOLAR ENERGY↗

Solar wind and extreme ultraviolet modulation of the lunar ionosphere/exosphere

The ALSEP/SIDE detectors routinely monitor the dayside lunar ionosphere. Variations in the ionosphere are found to correlate with both the 2800 MHz radio index which can be related to solar EUV and with the solar wind proton flux. For the solar wind, the ionospheric variation is proportionately greater than that of the solar wind. This suggests an amplification effect on the lunar atmosphere due perhaps to sputtering of the surface or, less probably, an inordinate enhancement of noble gases in the solar wind. The surface neutral number density is calculated under the assumption of neon gas. During a quiet solar wind this number agrees with or is slightly above that expected for neon accreted from the solar wind. During an enhanced solar wind the neutral number density is much higher.

Freeman, J. W.↗

Assessing photovoltaic module life from long-term environmental tests

An assessment is made of results obtained by an experimental program having as its aim the identification of critical temperature-humidity bias degradation mechanisms in solar cell modules intended to have an operating lifetime of the order of 20-30 years. These mechanisms are studied in the context of conditions encountered over the course of long term operation in various sites in the U.S. Accelerated tests for the assessment of product lifetime entail the development of a correlation between test and application conditions; this has been accomplished through an analytical procedure for the correlation of time-varying field exposures to constant-stress accelerated environments.

Otth, D. H.↗

Real time intensity display system.

Intensity display system similar to radar output, showing real time intensity and pattern variations created by solar lamp modules in testing of spacecraft systems in simulation facilities

REAL TIME↗

Solar activity influence on cosmic ray penetration in the middle atmosphere

A new improved model for cosmic rays-middle atmosphere interaction is developed. The ionization q(h)-profile dependence on penetrating high energy particles composition (protons, alpha-particles and heavier nuclei) and energy spectra (solar activity modulation included) are investigated. A computer program, realizing the Gaussian algorithm for solving of multidimensional integrals is created. The corresponding electron density profiles N(h) at solar minimum and maximum are obtained.

Vellinov, P. I.↗

Forbush decreases and particle acceleration in the outer heliosphere

Consideration is given to Pioneer 10 and 11 observations of the solar flares that occurred during the period March 6-19, 1989. The observations shown that Forbush decreases propagate with an essentially constant magnitude to 47 AU and with similar magnitude at widely different ecliptic longitudes. The times of recovery from Forbush decreases become progressively greater as the radial distance increases. A scheme is proposed to explain this behavior, giving support to the hypothesis that the solar cycle modulation of the galactic cosmic ray intensity is attributable primarily to overlapping Forbush decreases that are more frequenct and of greater magnitude near times of maximum solar activity.

Van Allen, J. A.↗

Outdoor Testing of c-Si Photovoltaic Modules with Spectrally-Selective Mirrors for Operating Temperature Reduction

The efficiency of a c-Si cell drops with increasing cell temperature. A typical photovoltaic module with a c-Si cell will operate 20-30K above ambient temperature. Spectrally-selective photonic mirrors which reflect sub-bandgap light can reduce waste heat generated by parasitic absorption in the module and reduce module operating temperature. Here, a spectrally selective 4-layer and 12-layer mirror are designed and fabricated on module cover glass. When integrated into modules, these mirrors reduce the operating temperature of the module by 0.16K and 1.5K, respectively when compared to a module with bare outer glass.

14 SOLAR ENERGY↗

Geomagnetic activity and local modulations of cosmic rays circa 1 GV

Solar-sector synchronous modulations of the particulate cosmic radiation reaching the earth's atmosphere have been studied using low altitude satellite and surface data. The flux in the broad maximum of the galactic cosmic ray differential spectrum (near GV rigidity) exhibits an intermittent north-south asymmetry (NSA) in mid and high geomagnetic latitudes. During the 1964 and 1965 years of sunspot minimum, this modulation had a negative rigidity dependence and strong correlations with geomagnetic disturbance index (ap) and interplanetary magnetic field direction. Taken together with other features, this ap dependence is consistent with the hypothesis that reconnection of the interplanetary and geomagnetic fields should produce a local NSA independent of much larger scale NSAs associated with cosmic ray gradients in the heliosphere. This finding is also consistent with suggestions that solar activity influence on atmospheric processes may be mediated by the resulting modulations of upper tropospheric ionization.

Ely, J. T. A.↗

Assessment of SEPS solar array technology for orbital service module application

Work performed in the following assessment areas on the SEPS solar array is reported: (1) requirements definition, (2) electrical design evaluation, (3) mechanical design evaluation, and (4) design modification analysis. General overall assessment conclusions are summarized. There are no known serious design limitations involved in the implementation of the recommended design modifications. A section of orbiter and array engineering drawings is included.

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