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At least 865 records · Page 48

Elastic wave analyzer for icy sub-surfaces (EWAIS) in the solar system

The sub-surface structures of water-bearing icy worlds (e.g., Europa, Enceladus, and Titan) and the structures of icy regions on Mars contain critical information about their origin and evolution. These bodies have been identified as high-priority targets in the NRC Planetary Science Decadal Survey, which noted a lack of technology readiness as one impediment to related missions. An Elastic Wave Analyzer for Icy Sub-surfaces (EWAIS) instrument is being developed to acquire data that can provide answers to fundamental science questions related to these bodies. The EWAIS instrument generates and receives elastic waves using an array of piezoelectric transducers capable of operating at temperatures as low as 30K. A developed breadboard acquires reflected signals from discontinuities in the traveled materials’ impedance (the product of wave velocity and density) along the wave path. Analysis of the acquired data can be used to determine the elastic properties, presence of cracks, locations of cavities and other discontinuities, as well as the thicknesses of ice and liquid layers. The EWAIS instrument is being developed with a novel dual-frequency transmitter array that will enable reaching distances of kilometers through ice, as well as resolving smaller acoustic reflectors nearer the EWAIS instrument. The selected dual frequencies correspond to two depth ranges that can be analyzed, with resolutions of tens of centimeters in the region of tens to hundreds of meters and tens of meters on the kilometers scale, respectively. The EWAIS will be applicable for operation from any in-situ platform, including surface assets (e.g., lander and rover) and sub-surface assets (e.g., melting probes).

Bar-Cohen, Y.↗

Changes in Arctic and Antarctic Sea-Ice Properties and Processes

Although sea ice covers ~9% of the world’s oceans, its presence, and absence, vastly alter the energetic balance of Earth’s climate. Because of geographic differences, Arctic and Antarctic sea ice have different dominant properties and processes, which produce different responses to natural variability and anthropogenic change. In this Review, we survey changes in sea-ice properties and processes of the Arctic and Antarctic environments. In the Arctic, the melt season has lengthened by ~7.4 days decade −1 (1979-2024). There has been a corresponding decrease in winter sea-ice thickness (1.6 m mean total over 1980-2023), summer surface albedo (0.03 decade −1 over 1979-2020), and spring snow depth (2.5 cm decade −1 over 1954-2024). In comparison, corresponding changes in the Antarctic are small overall due to contrasting regional and temporal trends. From a dynamic perspective, sea-ice motion in both hemispheres has increased, with 0.63 cm s −1 decade −1 in the Arctic (1978-2024) and 0.69 cm s −1 decade −1 in the Antarctic (1982-2024), whereas trends in polynya occurrence differ by region. Future research should prioritize sea-ice observations that can inform how the climate system responds to natural variability and anthropogenic change, be standardized to increase uptake by the broader scientific community, and target process-oriented interactions to support model development.

Melinda A Webster↗

The Role of Disruptive Impacts on Ocean Generation and Longevity in Icy Moons

Among icy moons of the outer Solar System, subsurface water oceans and large collisions both seem to be common, but the impact of the latter on the presence and persistence of the former is unclear and has rarely been investigated. Here we interface a smoothed-particle hydrodynamics model to simulate collisions with a thermal-structural evolution model to simulate the evolution of moons pre-collision, post-collision and without a collision. Overall, even such large-scale collisions affect only the ocean thickness or longevity, and the presence or absence of an ocean is affected for only a part of a moon’s history. In reaccreted moons, the ocean survives the impact and becomes much thicker inside larger moons with radius near 1,000 km, whereas an ocean that would otherwise arise inside moons with radius near 500 km is absent because the collision promotes ice–rock differentiation. Our simulations have not yielded an ocean developed post-impact—whether directly via collisional or reaccretional heating or indirectly through tidal heating due to collision-induced orbital changes—in a moon that would otherwise have remained frozen. The ocean-enhancing effect is pronounced only for late disruptive impacts onto large, 1,000-km-class targets, which are unlikely in recent solar system history.

Marc Neveu↗

Effects of Heat Treatment on the Ballistic Impact Properties of Inconel 718 for Jet Engine Fan Containment Applications

The effects of heat treating Inconel 718 on the ballistic impact response and failure mechanisms were studied. Two different annealing conditions and an aged condition were considered. Large differences in the static properties were found between the annealed and the aged material, with the annealed condition having lower strength and hardness and greater elongation than the aged. High strain rate tests show similar results. Correspondingly large differences were found in the velocity required to penetrate material in the two conditions in impact tests involving 12.5 mm diameter, 25.4 mm long cylindrical Ti-6-4 projectiles impacting flat plates at velocities in the range of 150 to 300 m/sec. The annealed material was able to absorb over 25 percent more energy than the aged. This is contrary to results observed for ballistic impact response for higher velocity impacts typically encountered in military applications where it has been shown that there exists a correlation between target hardness and ballistic impact strength. Metallographic examination of impacted plates showed strong indication of failure due to adiabatic shear. In both materials localized bands of large shear deformation were apparent, and microhardness measurements indicated an increase in hardness in these bands compared to the surrounding material. These bands were more localized in the aged material than in the annealed material. In addition the annealed material underwent significantly greater overall deformation before failure. The results indicate that lower elongation and reduced strain hardening behavior lead to a transition from shear to adiabatic shear failure, while high elongation and better strain hardening capabilities reduce the tendency for shear to localize and result in an unstable adiabatic shear failure. This supports empirical containment design methods that relate containment thickness to the static toughness.

Pereira, J. Michael↗

Effects of Heat Treatment on the Ballistic Impact Properties of Inconel 718 for Jet Engine Fan Containment Applications

The effects of heat treating Inconel 718 on the ballistic impact response and failure mechanisms were studied. Two different annealing conditions and an aged condition were considered. Large differences in the static properties were found between the annealed and the aged material, with the annealed condition having lower strength and hardness and greater elongation than the aged. High strain rate tests show similar results. Correspondingly large differences were found in the velocity required to penetrate material in the two conditions in impact tests involving 12.5 mm diameter, 25.4 mm long cylindrical Ti-6-4 projectiles impacting flat plates at velocities in the range of 150 to 300 m/sec. The annealed material was able to absorb over 25 percent more energy than the aged. This is contrary to results observed for ballistic impact response for higher velocity impacts typically encountered in military applications where it has been shown that there exists a correlation between target hardness and ballistic impact strength. Metallographic examination of impacted plates showed strong indication of failure due to adiabatic shear. In both materials localized bands of large shear deformation were apparent, and microhardness measurements indicated an increase in hardness in these bands compared to the surrounding material. These bands were more localized in the aged material than in the annealed material. In addition the annealed material underwent significantly greater overall deformation before failure. The results indicate that lower elongation and reduced strain hardening behavior lead to a transition from shear to adiabatic shear failure, while high elongation and better strain hardening capabilities reduce the tendency for shear to localize and result in an unstable adiabatic shear failure. This supports empirical containment design methods that relate containment thickness to the static toughness.

Pereira, J. Michael↗

NASA's Near Earth Asteroid Scout Mission

NASA is developing solar sail propulsion for a near-term Near Earth Asteroid (NEA) reconnaissance mission and laying the groundwork for their future use in deep space science and exploration missions. The NEA Scout mission, funded by NASA's Advanced Exploration Systems Program and managed by NASA MSFC, will use the sail as primary propulsion allowing it to survey and image one or more NEA's of interest for possible future human exploration. NEA Scout uses a 6U cubesat (to be provided by NASA's Jet Propulsion Laboratory), an 86 m2 solar sail and will weigh less than 14 kilograms. The solar sail for NEA Scout will be based on the technology developed and flown by the NASA NanoSail-D and The Planetary Society's Lightsail-A. Four ~7 m stainless steel booms wrapped on two spools (two overlapping booms per spool) will be motor deployed and pull the sail from its stowed volume. The sail material is an aluminized polyimide approximately 3 microns thick. NEA Scout will launch on the Space Launch System (SLS) first mission in 2018 and deploy from the SLS after the Orion spacecraft is separated from the SLS upper stage. The NEA Scout spacecraft will stabilize its orientation after ejection using an onboard cold-gas thruster system. The same system provides the vehicle Delta-V sufficient for a lunar flyby. After its first encounter with the moon, the 86 m2 sail will deploy, and the sail characterization phase will begin. A mechanical Active Mass Translation (AMT) system, combined with the remaining ACS propellant, will be used for sail momentum management. Once the system is checked out, the spacecraft will perform a series of lunar flybys until it achieves optimum departure trajectory to the target asteroid. The spacecraft will then begin its two year-long cruise. About one month before the asteroid flyby, NEA Scout will pause to search for the target and start its approach phase using a combination of radio tracking and optical navigation. The solar sail will provide continuous low thrust to enable a relatively slow flyby of the target asteroid under lighting conditions favorable to geological imaging. Once complete, NASA will have demonstrated the capability to fly low-cost, high Delta-V cubesats to perform interplanetary missions.

Johnson, Les↗

Development of a Novel Magnesium Alloy for Thixomolding® of Automotive Components (Final Report)

Magnesium (Mg) alloy die-castings are increasingly used in the automobile industry to achieve cost effective mass reduction, especially in systems where multiple components can be integrated into a single thin wall die-casting. However, there are several component quality restrictions in thin-walled Mg die castings, including variability in dimensional accuracy, part-to-part variation in mechanical properties, and porosity in the final part, which has limited the continued growth of die-cast components in the automobile industry. An alternative to die-casting is the process of thixomolding®. While the die-casting process relies on filling a mold at high speeds with the alloy in the completely molten state, the thixomolding® process fills a mold with a thixotropic alloy in a semi-solid slurry state at a temperature between the liquidus and solidus temperatures. Ideally, the material should be ~30–65% solid rather than being completely liquid at the beginning of the injection process. Advantages of the thixomolding® process include a finer grain structure, lower porosity, improved dimensional accuracy, improved part-to part consistency, improved mechanical properties, particularly ductility in the component, the ability to reduce wall thickness for mass savings, and longer tool life due to lower process temperatures. The objective of this collaborative project between Oak Ridge National Laboratory, FCA US LLC, and Leggera Technologies was to develop one or more novel Mg alloys more suitable for thixomolding® automotive structural components than the current die-casting alloys used for this process. The primary interest was to improve ductility while maintaining tensile and fatigue strengths, as these are properties that are critical for use in body and chassis structural applications. Since good corrosion resistance is also desirable for this application, this property was also considered when evaluating promising alloy compositions. An initial evaluation of existing components thixomolded® using AM60 was performed and microstructure, and tensile properties were evaluated for the baseline alloy. Targets were established for ease of processing (characterized by the melting range defined as the difference between the liquidus and the solidus), strength, and ductility. Computational modeling was used to identify promising alloys and selected alloys were cast in laboratory scale heats. Properties measured from laboratory scale heats were used to down-select two alloys for further evaluation and component fabrication. Two alloys were prepared in industrial scale heats, cut into small pieces (chips), and thixomolding® trials were initiated. Trial components were successfully fabricated using one alloy composition, but it was concluded that further refinement of the thixomolding® process parameters are required to successfully fabricate component using second alloy. Microstructure and mechanical properties were evaluated on the material removed from the fabricated component and properties were compared to the baseline alloy. Although mechanical properties of the alloys showed improvement over the baseline alloy, it was determined that modifications to the thixomolding® process would result in better microstructure control with further improvement in properties leading to successful commercialization. A provisional patent application has already been filed on the new alloys developed as part of the project.

36 MATERIALS SCIENCE↗

Sub-GeV dark matter and neutrino searches with Skipper-CCDs: status and prospects

Thick fully-depleted charge-coupled devices (CCDs) with high-resistivity silicon are used in a wide range of scientific applications, from particle detection to astronomical imaging. Their low noise and high charge collection efficiency allow us to reach unprecedented sensitivity to physical processes with low-energy transfers. The newly-developed Skipper-CCD enhances this sensitivity by reducing the read-out noise reaching a sub-electron resolution. In this work, we summarize the fundamentals of the skipper-CCD operation and the prospects for both sub-GeV dark-matter searches and the detection of coherent elastic neutrino-nucleus scattering. A brief discussion of the challenges associated with the construction of the foreseen detectors with multi-kilogram target mass is also presented.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Energy Exascale Earth System Model v2.0.2

Second patch release of v2.0.0 Changes since v2.0.1 [Important change] Add and update SSP370 and SSP585 cases, add tests, fix use-case files, Change ocean and sea-ice IC for ARRM60to10. [EAM] allow thetaxx as a CAM_TARGET, enable northamericax4v1pg2_WC14to60E2r3 for AMIP, fix ndrop initialization, allow up to 15 history files. [EAMxx] allow use of readnl [EAM-MMF] allow transient SST case for C++ MMF, remove specific task/thread count for ESMT test, modify the variance transport diagnostic, reorg tests, [HOMME] Allow optional sponge layer. [ELM] add 2 land-atm compsets, update FATES to API 17.0.0, allow FATES sp mode, allow ELM harvest to drive FATES harvest, fix memleaks, reduce test build times, modified parameters for miscanthus and switchgrass based on calibration [MPAS-Ocean] turn on ocean BGC in BGC cases, fix interface locations for 60L PHC grid, add mode spec to conservation check streams, allow oRRS18to6v3 grid to run with JRA, update ocean and sea ice ICs for ARRM60to10 (needed for v2), GPU port of thickness tendency, add CMPASO-JRA1p4, [MPAS framework] Add new reproducible global sum module for MPAS components, Add mostRecentAccessTime attribute to streams [MPAS-landice] Update MALI version and Greenland mesh [MPAS-seaice] add single-cell test case, fix BGC restart, Adds omp critical directives for ice warnings seen on cori. [CIME] Fix component namelist creation bugs when NINST>1, add OpenACC, OpenMP and CXX GPU tests, fix nonBFB tests, stop using config_compilers, reduce ELM test build times with shared executable, update OpenMPI on Chrysalis. fix baseline handling, provenance handling with update to cime6.0.33, also use component-specific config_pes files and add the ones from master [Machine updates] cori modules after maint, Chrysalis to OpenMPI-4.1.3 [run_e3sm] replace default case name and group. [Externals] update SCORPIO to 1.3.2

ECP↗

Injection data analysis using material balance time for CO 2 storage capacity estimation in deep closed saline aquifers

Estimating the ultimate storage capacity of deep saline aquifers is important to address the formation potential to store the envisioned large volumes of CO 2 . Injection data (i.e. injection rate, bottomhole pressure, and cumulative injected volume of CO 2 ) are routinely recorded during storage operations. These data contain valuable information on the subsurface (e.g. the reservoir pore volume and the formation storage capacity) that can be extracted. In this paper, we present a two-step graphical technique to infer the pore volume and the ultimate storage capacity of closed saline aquifers by analyzing the available injection data. First, the pore volume is inferred through adapting the concept of the material balance time. Material balance time is an approximate superposition time function developed to interpret production data from oil and gas wells operating at variable pressure/rate conditions during the boundary-dominated flow period. Using material balance techniques, the ultimate storage capacity is then estimated through linear extrapolation of the average pressure trend to the maximum allowable pressure the formation can withstand. The average pressure is not available in practice, but is can be obtained from the injection data. Two approaches are presented in this study to calculate the average pressure; namely the rigorous and the approximate approaches. Unlike the rigorous approach, the approximate approach does not require a prior knowledge of some reservoir properties (e.g. relative permeability, absolute permeability, formation porosity and thickness) to calculate the average pressure. To investigate its potential and reliability in analyzing CO 2 injection data, the proposed technique is applied to four synthetic cases representing different well operating conditions. Results indicate that the approximate approach consistently overestimates the actual (simulated) storage capacity as compared to the rigorous approach. The agreement - between the inferred and the simulated reservoir pore volume, and between the analytical and numerical estimates of storage capacity - validates the potential application of the technique to CO 2 storage in closed saline aquifers. The technique is further substantiated through application to a field data set utilized from a commercial-scale geological storage (CGS) project. Finally, field data interpretation shows that the proposed technique can be utilized to identify the degree of hydraulic continuity and reservoir compartmentalization within a target formation by interpreting the corresponding pressure and rate responses.

02 PETROLEUM↗

Rossi-alpha Analysis of CURIE Experiment

Critical assembly measurement and operations are crucial to the development of benchmark data to support research into criticality safety, radiation-detection development, and the overall application of nuclear technologies. Accurate nuclear data are needed for accurate predictive simulations, and validation using critical experiments is an important part of the nuclear data pipeline. The accuracy of nuclear data are improved using more robust and targeted measurements. In particular, the intermediate energy range of uranium is of great interest. LANL has successfully performed the Zeus series of experiments on the Comet assembly to investigate the intermediate energy range for HEU with various moderators. A successor to these experiments is the benchmark for the Critical Unresolved Region Integral Experiment (CURIE), designed to be sensitive to the unresolved resonance region (URR). This experiment is designed using polytetrafluoroethylene, more commonly known as Teflon, moderators. The CURIE experiment was successfully conducted at the National Criticality Experiments Research Center (NCERC). The Rossi-alpha method was used to evaluate the propensity of the CURIE configurations to sustain fission chains by estimating the prompt neutron decay constant α. This work evaluates the α at delayed critical using Rossi-alpha for different Teflon moderator thicknesses in the CURIE experiment. These results will help improve understanding of the CURIE benchmark experiments.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

A lateral guidance algorithm to reduce the post-aerobraking burn requirements for a lift-modulated orbital transfer vehicle

A lateral guidance algorithm which controls the location of the line of intersection between the actual and desired orbital planes (the hinge line) is developed for the aerobraking phase of a lift-modulated orbital transfer vehicle. The on-board targeting algorithm associated with this lateral guidance algorithm is simple and concise which is very desirable since computation time and space are limited on an on-board flight computer. A variational equation which describes the movement of the hinge line is derived. Simple relationships between the plane error, the desired hinge line position, the position out-of-plane error, and the velocity out-of-plane error are found. A computer simulation is developed to test the lateral guidance algorithm for a variety of operating conditions. The algorithm does reduce the total burn magnitude needed to achieve the desired orbit by allowing the plane correction and perigee-raising burn to be combined in a single maneuver. The algorithm performs well under vacuum perigee dispersions, pot-hole density disturbance, and thick atmospheres. The results for many different operating conditions are presented.

Herman, G. C.↗

Perspectives on the relationship between materials chemistry and roll-to-roll electrode manufacturing for high-energy lithium-ion batteries

As lithium-ion battery (LIB) active material and cell manufacturing costs continue to drop with wider adoption of electric vehicles, electrode and cell processing costs remain too high in terms of reaching the ultimate U.S. Department of Energy (DOE) cell cost target of $80/kWh. This paper primarily covers major materials chemistry advancements made over the last 10 years at Oak Ridge National Laboratory (ORNL) in the space of advanced manufacturing science for LIBs with the aim of simultaneously meeting the ultimate cost target, 500 Wh/kg gravimetric energy density, 10-15-min fast charge times, and 1000 deep discharge cycles. Aqeous electrode processing with a variety of active anode and cathode materials is now a standard procedure at the DOE Battery Manufacturing R&D Facility at ORNL (BMF), including the latest processes developed for Ni-rich cathodes. New results on cobalt-free LiNi 0.8 Fe 0.1 Al 0.1 O 2 (NFA 811) are also included and discussed in an electrode processing advantage context. In addition, colloidal processing advancements have been made for Si/C composite anodes for achieving >600 mA h/g capacities. Optimization of electrode coating parameters and drying protocols have been completed, which has elucidated how key processing variables need to be changed when parameters such as slurry solids loading, solvent type, and wet electrode thickness are changed. ORNL has also increased the line speeds at which thick cathodes can be processed using ultra-fast electron beam (EB) curing and substantially decreased formation cycling times to <1 day. Finally, key details of these advancements are discussed in the context of materials chemistry and process-property-performance relationships.

25 ENERGY STORAGE↗

Mechanisms of a novel regulatory light chain–dependent cardiac myosin inhibitor

Hypertrophic cardiomyopathy (HCM) is a genetic disease of the heart characterized by thickening of the left ventricle (LV), hypercontractility, and impaired relaxation. HCM is caused primarily by heritable mutations in sarcomeric proteins, such as β myosin heavy chain. Until recently, medications in clinical use for HCM did not directly target the underlying contractile changes in the sarcomere. Here, we investigate a novel small molecule, RLC-1, identified in a bovine cardiac myofibril high-throughput screen. RLC-1 is highly dependent on the presence of a regulatory light chain to bind to cardiac myosin and modulate its ATPase activity. In demembranated rat LV trabeculae, RLC-1 decreased maximal Ca2+-activated force and Ca2+ sensitivity of force, while it increased the submaximal rate constant for tension redevelopment. In myofibrils isolated from rat LV, both maximal and submaximal Ca2+-activated force are reduced by nearly 50%. Additionally, the fast and slow phases of relaxation were approximately twice as fast as DMSO controls, and the duration of the slow phase was shorter. Structurally, x-ray diffraction studies showed that RLC-1 moved myosin heads away from the thick filament backbone and decreased the order of myosin heads, which is different from other myosin inhibitors. In intact trabeculae and isolated cardiomyocytes, RLC-1 treatment resulted in decreased peak twitch magnitude and faster activation and relaxation kinetics. In conclusion, RLC-1 accelerated kinetics and decreased force production in the demembranated tissue, intact tissue, and intact whole cells, resulting in a smaller cardiac twitch, which could improve the underlying contractile changes associated with HCM.

Physiology↗

Lithium Divertor Targets and Walls for the ASTER Liquid Stellarator Reactor, Distributed Divertor

Stellarators may have advantages for certain liquid metal options as Plasma Facing Components (PFC) for divertor targets and first walls due to the wide range of possible magnetic configurations, which additionally are free of disruptions and fast field variations. In a previous work (V. Queral et al., IEEE Trans. Plasma Sci. 52, 2024), a concept of stellarator reactor (ASTER-CP) based on swirling Li-molten salts and liquid lithium floating on the molten salt as PFC was presented. The divertor matters were not studied then and, thus, they are being studied and experimentally tested now. The ASTER-CP reactor concept, the initial liquid metal experiments and potential concepts for the ASTER-CP divertor and first wall are reported. Concerning the experiments, several small scale experiments of galinstan in a small rotating cylinder under magnetic field have been produced, including one experiment with high viscosity galinstan-mixture for increased thickness of layer. An experiment of floating lithium on the molten salt LiCl-PbCl2 gave fast volatilization/decomposition of the molten salt. Particularly for divertors, the traditional free-flow, Capillary Porous Systems and ‘divertorlets’ have been studied for application to ASTER-CP. Surface waves (hot spots), lack of enough surface fluid turbulence and excessive fluid speed are the main issues found in fast free-flow. The perhaps original concept of Distributed Divertor and Equi-power Surface is tentatively proposed and studied, taking advantage of stellarator fields and low recycling regime.

distributed divertor↗

Machine-Learning-aided Approach for Predicting the Thermal Expansion Behaviors in Advanced Test Reactor Capsules (NURETH-20 full paper)

Instrumented experiments at test reactors are essential to deploying new advanced reactor systems. Designing new experiments and generating data on specific conditions require both time and cost investment. A high-fidelity model of the experiment environment can be created using finite element analysis software to support the actual experiments, but computation time is still a concern in applying outcomes to real-time usage (e.g., a digital twin). This research proposes a machine-learning-aided approach to temperature and displacement predictions, based on the thickness of the outer gas gap on the experimental capsule used for the in-pile demonstration of a novel thermal conductivity probe in the Advanced Test Reactor. The capsule consisted of U10Zr fuel, a rodlet, sodium, and inner and outer capsules. There were gas gaps between the fuel and rodlet and between the inner and outer capsule. The learning data consisted of an experimental capsule’s radial distributions of temperature and displacement, as obtained from Abaqus and the physical features. For the first step, temperature was predicted using three positional parameters. Then the displacement was predicted using six different positional parameters. Each physical feature was normalized to be both nondimensional and standardized. The temperature and displacement predictions showed good agreement in all cases involving interpolation and extrapolation. Also, data similarity enhancement increased the similarity between training and target data increasing the predictive accuracy of machine-learning models. In some cases of extrapolation, the accuracy of the machine-learning model showed limited performance, but still data similarity enhancement improved the accuracy.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Advanced Method Optimization for Sampling and Analysis Instrumentation

This work presents a generalized approach for analytical method optimization that branches the gap between techniques historically employed and accurate modern optimization techniques suitable for various applications. The novelty of the described strategy is the utilization of multivariate, multiobjective optimization with Karush-Kuhn-Tucker conditions to bound the optimization space to solutions within the physical limitations of instrumentation. Briefly, the basic steps outlined in this paper are to (1) determine the objective(s) that should be maximized or minimized based on the goals of the analytical application, (2) conduct a screening experiment, (3) perform ANOVA to determine the parameters which have a statistically significant effect on the objective, (4) conduct an experiment (e.g., Box-Behnken design) to collect data for fitting the objective equation, and (5) determine the physical constraints of the parameters and solve the Lagrangian to determine the optimal method parameters. A broad approach to optimization target selection allows for robust method tuning to develop improved data sets amenable for chemometrics and machine learning algorithm development. Gas chromatography-mass spectrometry was selected as a use case due to its broad use across scientific fields and time-consuming method development involving numerous parameters. In conclusion, this strategy can reduce the cost of research, improve data quality, and enable the rapid development of new analytical technique.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Large Impact Features on Icy Galilean Satellites: Implications for Ice Shell Thickness and Habitability.

Nowhere in the solar system are impact morphologies observed in greater variety than on the icy Galilean satellites. This is very likely a consequence of the structural and thermal state of the crust at the time of impact, and perhaps impact velocity. We have conducted a multi-disciplinary investigation to study how these features formed. The particular combination of geophysical factors and impactor characteristics that is shared by these satellites is likely responsible for these features. We have derived Digital Terrain Models for a number of these features, which have been used as a tool for producing facies maps. Impact features on Ganymede and Callisto are relatable to impact features on Europa, with implications for its ice shell history. We have identified two broad classes of these impact features: (a) Crater forms, which variously include pits, central domes, and crater rims; and (b) Palimpsests (including pene-palimpsests), which all have smooth enclosed central plains, an extensive outer undulating plains unit, concentric arcuate ridges(in the case of pene-palimpsests), and no recognizable rim. The very large, measured volume of the undulating plains unit of the pene-palimpsest Buto, Ganymede, substantially exceeds the amount of target material that could have been both melted and excavated by the impact event itself. Therefore, we conclude that the undulating plains material was derived from a fluid or “slushy” layer in the near-surface target at the time of impact. The recognition of undulating plains as the dominant unit in Memphis and Nidaba, two other palimpsests on Ganymede that we have mapped(which display highly variable crater counts, with Buto being the least cratered),leads us to a working hypothesis that these plains only form where and when the target has substantial near surface fluid or “slush.” By extension, all other impact features on Ganymede and Callisto, such as those with central pits and central domes, formed in targets with no pre-existing, or at most inconsequential, amounts of fluid or “slush.” Supporting this conclusion, modeling by members of our group indicates that the present topography of impact features with central pits and domes can be largely explained by the behavior of ice alone, with no or little contribution from fluids. Our study supports explanations for the formation and final appearance of palimpsests (and pene-palimpsests) that are entirely applicable to this feature class, and sharply distinct from explanations for other impact features (crater forms) on Ganymede and Callisto.

Jeffrey M Moore↗