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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 865 records · Page 48
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Residue Specific Characterization of Electrostatics, Conformational Heterogeneity, and Dynamics of Electron Transfer Proteins with Linear and Nonlinear Infrared Spectroscopy. Final Report

The goal of this research project was to further our understanding of biological electron transfer through the development and application of new methods for studying proteins and their complexes with high spatial and temporal detail. The approach was based on incorporation of reporter bonds with distinct vibrational frequencies at specific locations in proteins and their characterization through the interaction of the bonds with pulses of infrared light. The project focused on the proteins plastocyanin (Pc) and cytochrome (cyt) f, two electron transfer partners in photosynthesis. The first thrust of the project was the incorporation of carbon deuterium bonds as non-perturbative probes at a ligand to the copper ion of Pc and their use to detect changes in the bonding due to the number of electrons at the metal and how the bonding changes upon association with cyt f. Toward developing more advanced approaches to characterize proteins, we incorporated a stronger reporter, the cyano group of cyanophenylalanine, at several locations in Pc and measured the frequency dynamics in the absence and presence of cyt f. The acquired data improved the current model for the protein complex. Notably, the data indicated that the majority of the population is involved in a loosely bound complex, providing insight into the nature of the ensembles formed by electron transfer protein complexes that is not available via other approaches. In addition to learning about the protein complex, we made strides toward developing and improving the new experimental approach to study highly dynamic behaviors of proteins.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1985

The International Cometary Explorer (ICE) mission to comet Giacobini-Zinner (G/Z)

The primary objectives of the International Cometary Explorer (ICE) mission is to provide in situ data on the interaction between solar wind and the atmosphere of the P/Giacobini-Zinner comet (G/Z), making measurements of particles, fields, and waves while passing through the cometary tail of G/Z on September 11, 1985. Following the G/Z tail intercept, the ICE measurements will complement the later upstream measurements obtained by the Comet Halley probe. The major ICE payload includes a vector helium magnetometer, the plasma-wave experiment, the radio-wave experiment, the plasma-electron experiment, and the plasma ion experiment. Other experiments are intended to measure energetic protons, X-rays, low energy to high energy cosmic rays, cosmic ray electrons, and gamma-ray bursts. The ICE measurements of G/Z will be supplemented with ground-based measurements. Schematic diagrams are included.

Brandt, J. C.↗
NASA NTRS1989

Calibration approach to electron probe microanalysis: A study with PWA-1480, a nickel base superalloy

The utility of an indirect calibration approach in electron probe microanalysis is explored. The methodology developed is based on establishing a functional relationship between the uncorrected k-ratios and the corresponding concentrations obtained using one of the ZAF correction schemes, for all the desired elements in the concentration range of interest. In cases where a very large number of analyses are desired, such a technique significantly reduces the total time required for the microprobe analysis without any significant loss of precision in the data. A typical application of the method in the concentration mapping of the transverse cross-section of a dendrite in directionally solidified PWA-1480, a nickel-based superalloy, is described.

Terepka, F. M.↗
NASA NTRS2001

Determining Biosignatures by Complexity Analysis in Antarctic Cryptoendolithic Communities

One of the most difficult problems of life detection is that of identifying biosignatures across a wide range of scales using multiple co-registered probes. The technique should be of equal utility across a wide range of search spaces from remote sensors probing volumes of space or planetary surfaces, visual eye or camera searches across the surface of a rock in Antarctica, low resolution microscopic scanning of a rock or a space craft in situ, or high resolution electron microscope and computerized tomography scanning of geobiological samples. We describe here an approach to this problem which derives in large part from past work done in the area of astrophysics - namely the analysis of complexity in galactic signals by data compression methods. This approach is a radically new one for geobiology and astrobiology, and allows us to assess the complexity (and thus potential biogenicity) of an object being examined. This is done by considering the information within pixels of an image (regardless the sensor used to gather the information) as an energetic system capable of description in terms of classical thermodynamics. The image data space is searched by an algorithm that judges complexity via data compression (e.g., the more compressible it is, the less complex, and vice versa) and maximum entropy as originally outlined by Shannon. At present we are implementing methods to utilize images from multiple sensors gathering different kinds of information (e.g., visible gray-scale data, color analyses, UV fluorescence, chemical information, etc). We present here preliminary data from deep UV fluorescence and ESEM (Environmental Scanning Electron Microscope) images from a layered cryptoendolithic community of an Antarctic rock.

Storrie-Lombardi, M. C.↗
NASA NTRS2008

Evaluation of COTS Electronic Parts for Extreme Temperature Use in NASA Missions

Electronic systems capable of extreme temperature operation are required for many future NASA space exploration missions where it is desirable to have smaller, lighter, and less expensive spacecraft and probes. Presently, spacecraft on-board electronics are maintained at about room temperature by use of thermal control systems. An Extreme Temperature Electronics Program at the NASA Glenn Research Center focuses on development of electronics suitable for space exploration missions. The effects of exposure to extreme temperatures and thermal cycling are being investigated for commercial-off-the-shelf components as well as for components specially developed for harsh environments. An overview of this program along with selected data is presented.

Patterson, Richard L.↗
NASA NTRS2017

Flowing Plasma Interaction with an Electric Sail Tether Element

Electric sails are a relatively new concept for providing high speed propellant-less propulsion. Employing multiple tethers biased to high positive voltage levels (kV), electric sails are designed to gain momentum from the solar wind by repelling solar wind protons. To maximize the area of the sail that interacts with the solar wind, electric sails rely on the formation of a large plasma sheath around each small diameter tether. Motivated by interest in advancing the development of electric sails, a set of laboratory tests has been conducted to study the interaction of a drifting plasma with a sheath formed around a small diameter tether element biased at positive voltages. The laboratory test setup was created with Debye length scaling in mind to offer a path to extrapolate (via modeling) to full scale electric sail missions. Using an instrument known as a Differential Ion Flux Probe (DIFP) the interaction between a positively biased tether element and a drifting plasma has been measured for several scenarios. Clear evidence of the tether element sheath deflecting ions has been obtained. Maps of the flow angle downstream from the tether element have been made and they show the influence of the plasma sheath. Finally, electron current collection measurements have been made for a wide range of plasma conditions and tether element bias voltages. The electron collection data will have an impact on electric sail power requirements, as high voltage power supplies and electron guns will have to be sized to accommodate the electron currents collected by each tether.

Schneider, Todd↗
DOE OSTI2021

New Physics in the Hot Electron Furnace (Final Report)

The primary purpose of this award was experiments and simulations related to the idea of a ‘Hot Electron Furnace’ where nonlocal heat transport would allow unique new experimental opportunities at x-ray free electron lasers. The period of this award included beamtime at the MEC endstation of the LCLS, and the execution of those experiments was a primary goal. Unfortunately, the beamtime had limited success due to (1) inability of the LCLS to deliver the expected two-color operations mode, and (2) failure of the MEC endstation’s own software to save the cavity timing data that would have allowed inference of time delays for the few hours when two-color mode briefly operated. The beamtime was then switched to operate in single-color (one pulse) mode, and studies were performed of x-ray heating and probe, simultaneously. Two interesting manuscripts are finally near submission, having been delayed by student graduations, need for collaborator simulations of x-ray heating processes, and then COVID. I am hopeful that they will soon be submitted (especially the paper on x-ray heating of MgO) because one of the principal students involved has returned from industry to take a postdoc position at SLAC. Below, we first list all publications and other work products (including the two that are nearing submission) and then summarize several outcomes from this effort. During the term of this award three UW physics graduate students were at least partially supported, and all three received their Ph.D.’s with significant components of their supported work in the dissertation.

47 OTHER INSTRUMENTATION↗
NASA NTRS1998

Electronic clinical predictive thermometer using logarithm for temperature prediction

A thermometer that rapidly predicts body temperature based on the temperature signals received from a temperature sensing probe when it comes into contact with the body. The logarithms of the differences between the temperature signals in a selected time frame are determined. A line is fit through the logarithms and the slope of the line is used as a system time constant in predicting the final temperature of the body. The time constant in conjunction with predetermined additional constants are used to compute the predicted temperature. Data quality in the time frame is monitored and if unacceptable, a different time frame of temperature signals is selected for use in prediction. The processor switches to a monitor mode if data quality over a limited number of time frames is unacceptable. Determining the start time on which the measurement time frame for prediction is based is performed by summing the second derivatives of temperature signals over time frames. When the sum of second derivatives in a particular time frame exceeds a threshold, the start time is established.

Cambridge, Vivien J.↗
DOE OSTI2018

Probing the cosmic causes of errors in supercomputers

Cosmic rays from outer space are causing errors in supercomputers. The neutrons that pass through the CPU may be causing binary data to flip leading to incorrect calculations. Los Alamos National Laboratory has developed detectors to determine how much data is being corrupted by these cosmic particles.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Search for long-lived heavy neutrinos in the decays of B mesons produced in proton-proton collisions at $ \sqrt{s} $ = 13 TeV

A search for long-lived heavy neutrinos (N) in the decays of B mesons produced in proton-proton collisions at $ \sqrt{s} $ = 13 TeV is presented. The data sample corresponds to an integrated luminosity of 41.6 fb$^{−1}$ collected in 2018 by the CMS experiment at the CERN LHC, using a dedicated data stream that enhances the number of recorded events containing B mesons. The search probes heavy neutrinos with masses in the range 1 < m$_{N}$ < 3 GeV and decay lengths in the range 10$^{−2}$ < cτ$_{N}$ < 10$^{4}$ mm, where τ$_{N}$ is the N proper mean lifetime. Signal events are defined by the signature B → ℓ$_{B}$NX; N → ℓ$^{±}$π$^{∓}$, where the leptons ℓ$_{B}$ and ℓ can be either a muon or an electron, provided that at least one of them is a muon. The hadronic recoil system, X, is treated inclusively and is not reconstructed. No significant excess of events over the standard model background is observed in any of the ℓ$^{±}$π$^{∓}$ invariant mass distributions. Limits at 95% confidence level on the sum of the squares of the mixing amplitudes between heavy and light neutrinos, |V$_{N}$|$^{2}$, and on cτ$_{N}$ are obtained in different mixing scenarios for both Majorana and Dirac-like N particles. The most stringent upper limit |V$_{N}$|$^{2}$ < 2.0 × 10$^{−5}$ is obtained at m$_{N}$ = 1.95 GeV for the Majorana case where N mixes exclusively with muon neutrinos. The limits on |V$_{N}$|$^{2}$ for masses 1 < m$_{N}$ < 1.7 GeV are the most stringent from a collider experiment to date.[graphic not available: see fulltext]

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Rate Limiting Regimes in Photochemical H2 Generation by Complexes of Colloidal CdS Nanorods and Hydrogenase

Driving redox enzyme catalysis with photoexcited semiconductor nanocrystals is a compelling approach for chemical conversion. We examined how the interplay of the many chemical steps involved determines the rates of photochemical H2 production with complexes of colloidal CdS nanorods and an [FeFe]-hydrogenase. We elucidated the roles of three critical and previously elusive processes-scavenging of photoexcited holes from nanorods, back-electron transfer, and H2 oxidation. Kinetic Monte Carlo simulations and fitting to experimental data revealed that hole transfer becomes the rate-limiting step at high illumination intensities. Comparisons of simulations to experimental H2 production showed that both back-electron transfer and H2 oxidation play an efficiency-limiting role at high catalyst loadings. This work provides guiding principles for tuning experimental parameters to minimize energy-wasting pathways and optimize photochemical product formation. More broadly, we demonstrate how critical but elusive chemical steps in photochemical reactions can be probed with a combination of experiments and simulations.

08 HYDROGEN↗
DOE OSTI2016

Time-resolved photoelectron spectroscopy of a dinuclear Pt(II) complex: Tunneling autodetachment from both singlet and triplet excited states of a molecular dianion

Time-resolved pump-probe photoelectron spectroscopy has been used to study the relaxation dynamics of gaseous [Pt{sub 2}(μ-P{sub 2}O{sub 5}H{sub 2}){sub 4} + 2H]{sup 2−} after population of its first singlet excited state by 388 nm femtosecond laser irradiation. In contrast to the fluorescence and phosphorescence observed in condensed phase, a significant fraction of the photoexcited isolated dianions decays by electron loss to form the corresponding monoanions. Our transient photoelectron data reveal an ultrafast decay of the initially excited singlet {sup 1}A{sub 2u} state and concomitant rise in population of the triplet {sup 3}A{sub 2u} state, via sub-picosecond intersystem crossing (ISC). We find that both of the electronically excited states are metastably bound behind a repulsive Coulomb barrier and can decay via delayed autodetachment to yield electrons with characteristic kinetic energies. While excited state tunneling detachment (ESETD) from the singlet {sup 1}A{sub 2u} state takes only a few picoseconds, ESETD from the triplet {sup 3}A{sub 2u} state is much slower and proceeds on a time scale of hundreds of nanoseconds. The ISC rate in the gas phase is significantly higher than in solution, which can be rationalized in terms of changes to the energy dissipation mechanism in the absence of solvent molecules. [Pt{sub 2}(μ-P{sub 2}O{sub 5}H{sub 2}){sub 4} + 2H]{sup 2−} is the first example of a photoexcited multianion for which ESETD has been observed following ISC.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

First observations of solar halo gamma rays over a full solar cycle

We analyze 15 years of Fermi-LAT data and produce a detailed model of the Sun’s inverse-Compton scattering emission (solar halo), which is powered by interactions between ambient cosmic-ray electrons and positrons with sunlight. By developing a novel analysis method to analyze moving sources, we robustly detect the solar halo at energies between 31.6 MeV and 100 GeV, and angular extensions up to 45° from the Sun, providing new insight into spatial regions where there are no direct measurements of the Galactic cosmic-ray flux. The large statistical significance of our signal allows us to subdivide the data and provide the first 𝛾-ray probes into the time variation and azimuthal asymmetry of the solar modulation potential, finding time-dependent changes in solar modulation both parallel and perpendicular to the ecliptic plane. Our results are consistent with (but with independent uncertainties from) local cosmic-ray measurements, unlocking new probes into astrophysical processes near the solar surface.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

Electronic Raman scattering and the renormalization of the electron spectrum in LuB{sub 12}

The electronic Raman scattering in LuB{sub 12} single crystals of various isotope compositions is studied in the temperature range 10–650 K. The shape and the energy position of spectral maxima depend on the direction and magnitude of a probe wavevector, the temperature, and the excitation symmetry and remain unchanged when the isotope composition changes. Experimental spectra are compared with the spectra simulated on the basis of a calculated electronic structure. The experimental results are successfully described when the electron spectrum renormalization effects caused by electron–phonon coupling are taken into account. This confirms that the origin of the observed spectra in LuB{sub 12} is due to Raman scattering by electrons. A comparison of the calculated and experimental data makes it possible to determine the coupling constant (λ{sub ep} = 0.32) that gives the correct superconducting transition temperature.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1993

Experimental studies of an ECR plasma thruster

The Electron Cyclotron Resonance (ECR) thruster is a proposed electrodeless space electric propulsion device with interesting and little understood physics. A laboratory ECR thruster was run in a vacuum tank at pressures in the 10 exp -5 torr range using 2.12 GHz microwave beam and Ar gas propellant. Movable diagnostic probes (a Faraday cup and a gridded energy analyzer) measured plasma characteristics as propellant gas flow rate and input microwave power level were varied. Ion energy and flux data were used to calculate I(sp), propulsive efficiency, and thrust. The ion flux profiles show an unexpected depression on the thruster axis for low tank pressures that disappears as the tank pressure increases. Ion energies decrease as the flow rate and pressure increase, but the microwave power level affects the energy only negligibly. The calculated propulsion parameters demonstrate that the efficiency of the laboratory device is low, and that tank pressure greatly changes the performance.

Kaufman, D. A.↗
NASA NTRS2005

Characterization of an 8-cm Diameter Ion Source System

Results of tests characterizing an 8-cm diameter ion source are presented. The tests were conducted in three separate vacuum test facilities at the University of Alabama-Huntsville, Colorado State University, and L3 Communications' ETI division. Standard ion optics tests describing electron backstreaming and total-voltage-limited impingement current behavior as a function of beam current were used as guidelines for selecting operating conditions where more detailed ion beam measurements were performed. The ion beam was profiled using an in-vacuum actuating probe system to determine the total ion current density and the ion charge state distribution variation across the face of the ion source. Both current density and ExB probes were utilized. The ion current density data were used to obtain integrated beam current, beam flatness parameters, and general beam profile shapes. The ExB probe data were used to determine the ratio of doubly to singly charged ion current. The ion beam profile tests were performed at over six different operating points that spanned the expected operating range of the DAWN thrusters being developed at L3. The characterization tests described herein reveal that the 8-cm ion source is suitable for use in (a) validating plasma diagnostic equipment, (b) xenon ion sputtering and etching studies of spacecraft materials, (c) plasma physics research, and (d) the study of ion thruster optics at varying conditions.

Li, Zhongmin↗
NASA NTRS2016

Observations of Transient ISS Floating Potential Variations During High Voltage Solar Array Operations

The International Space Station (ISS) continues to be a world-class space research laboratory after over 15 years of operations, and it has proven to be a fantastic resource for observing spacecraft floating potential variations related to high voltage solar array operations in Low Earth Orbit (LEO). Measurements of the ionospheric electron density and temperature along the ISS orbit and variations in the ISS floating potential are obtained from the Floating Potential Measurement Unit (FPMU). In particular, rapid variations in ISS floating potential during solar array operations on time scales of tens of milliseconds can be recorded due to the 128 Hz sample rate of the Floating Potential Probe (FPP) pro- viding interesting insight into high voltage solar array interaction with the space plasma environment. Comparing the FPMU data with the ISS operations timeline and solar array data provides a means for correlating some of the more complex and interesting transient floating potential variations with mission operations. These complex variations are not reproduced by current models and require further study to understand the underlying physical processes. In this paper we present some of the floating potential transients observed over the past few years along with the relevant space environment parameters and solar array operations data.

Willis, Emily M.↗
NASA NTRS2022

EMIC-Wave Driven Electron Precipitation Observed by CALET on the International Space Station

We present an analysis of the relativistic electron precipitation (REP) event measured by the CALorimetric Electron Telescope (CALET) experiment on board the International Space Station during a relatively weak geomagnetic storm on 31 December 2016. CALET observations were compared with the measurements of the Van Allen Probes in the near-equatorial plane to investigate the global radiation belt dynamics and the REP drivers. The magnetically conjugate observations from these two missions demonstrate that the significant MeV precipitation directly detected by CALET in low-Earth orbit during a period of radiation belt depletion following the passage of a high-speed stream, was associated with dusk-side electromagnetic ion cyclotron (EMIC) waves. In addition, the combined wave, REP and trapped electron data suggest that the reported radiation belt depletion can be likely ascribed to the concomitant loss effects of EMIC wave scattering driving the atmospheric precipitation, as well as outward radial diffusion associated with magnetopause shadowing.

Radiation belts↗