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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

The (IR-)relevance of the Gribov ambiguity in SU(2)×U(1) gauge theories with fundamental Higgs matter

It is well accepted that dealing with the Gribov ambiguity has a major impact on correlation functions in gauge-fixed Yang–Mills theories, in particular in the low momentum regime where standard perturbation theory based on the Faddeev–Popov approach fails. Recent results, derived from functional tools (Dyson–Schwinger equations or exact RG) or the effective Gribov–Zwanziger action method, pointed towards e.g. gauge boson correlation functions that are not compatible with the properties of observable degrees of freedom. Although such an observation is a welcome feature for gauge theories exhibiting confinement, it would be a discomfort for gauge theories supplemented with Higgs fields, cf. the experimental success of the electroweak model based on a SU(2)×U(1) gauge group. The purpose of this short note is to assure that the effective action resolution to the Gribov ambiguity reduces to the standard Faddeev–Popov method in the perturbative regime of sufficiently small coupling/large Higgs condensate, thereby not compromising the physical particle spectrum of massive gauge bosons and a massless photon for the SU(2)×U(1) gauge–Higgs model. The closer the theory gets to the limit of vanishing Higgs condensate, the more the Gribov problem resurfaces with all its consequences. We give some speculations w.r.t. the Fradkin–Shenker insights about the phase diagram. -- Highlights: •Gribov horizon influences gauge propagators in a strong-coupling regime. •No influence of Gribov horizon in weak-coupling. •Inclusion of U(1) factor leads to very rich behavior of propagators.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2023

Fundamentals of bio-electrochemical sensing

The utilization of bio-functionalities such as biorecognition or catalysis derived them their name biosensors. Bio-electrochemical sensing is a new discipline that combines the advantages of biological detection and electrochemical transduction. Bio-electrochemical sensors are devices that use biological materials such as enzymes, antibodies, DNA, or cells as receptors to detect target analytes in a variety of samples. Electrodes convert biological interactions into electrical impulses, which can be studied using various electrochemical techniques. Bio-electrochemical sensors have demonstrated significant promise for use in clinical diagnostics, environmental monitoring, food safety, and biotechnology. Biosensors have received numerous applications in recent years because they are fast, simple, and inexpensive for practical applications. In this article, we cover the basic principles, design strategies, immobilization and regeneration techniques, along with the advantages and applications of bio-electrochemical sensors. Finally, this article discusses the rationale for developing electrochemical biosensors in the context of the various bio-receptors that can be applied.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Fundamentals of alkali-silica gel formation and swelling: Condensation under influence of dissolved salts

The current theory of ASR gel formation in concrete between silicic acid anions with cations and is unable to explain the differences in concentration required for gel formation between e.g. potassium and sodium or the effect of calcium on the gel formation. In this paper, a new gelation mechanism is explained by means of a condensation between silicic acid anions. The role of salts on the ASR gel formation and gel time is described by their charge screening capacity of the silicic acid, resulting in the decreasing concentration range for gelation: Ca < Mg < Cs < Rb < K < Na < Li. A Cation Gelling Strength (CGS) is defined to assess the cation strength when different cations are present. Silica gel formation will moreover in many cases form a calcium silica precipitate rather than a gel that will be difficult to distinguish from CSH formed during hydration.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Application of neutron imaging to investigate fundamental aspects of durability of cement-based materials: A review

Service life and durability of reinforced concrete structures have become crucial issues in all industrialized countries because of their economic and ecological relevance. Limited durability is frequently due to deterioration of steel and cement-based materials, such as mortar and concrete, by interactions with water and aggressive aqueous solutions. Neutron imaging has proved to be a powerful non-destructive technique to study quantitatively water content and water movement in porous materials. A neutron beam is much more attenuated by hydrogen in water than by most other elements present in cement-based materials. In this review, focus is placed on applications of both two-dimensional neutron radiography and three-dimensional neutron tomography to investigate specific aspects of durability and deterioration of cement-based materials. Examples of results obtained by qualitative and quantitative investigations of moisture movement in cracked and uncracked cement-based materials are presented. Self-healing, efficiency of water repellent treatment, internal curing, frost damage, fire spalling, ettringite formation and observations of various reinforced concrete components are addressed. The results obtained by neutron imaging provide a solid basis for better understanding of deterioration mechanisms of cement-based materials. Recent improvements of neutron imaging facilities have allowed unexpected possibilities to study complex processes in cement-based materials. The potential for further research based on this promising technology is outlined and discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Fundamental insights on ignition and combustion of natural gas in an active fueled pre-chamber spark-ignition system

Pre-chamber spark-ignition (PCSI), either fueled or non-fueled, is a leading concept with the potential to enable diesel-like efficiency in medium-duty (MD) and heavy-duty (HD) natural gas (NG) engines. However, the inadequate scientific base and simulation tools to describe/predict the underlying processes governing PCSI systems is one of the key barriers to market penetration of PCSI for MD/HD NG engines. To this end, experiments were performed in a heavy-duty, optical, single-cylinder engine fitted with an active fueled PCSI module. Furthermore, the spatial and temporal progress of ignition and subsequent combustion of lean-burn natural gas using PCSI system were studied using optical diagnostic imaging and heat release analysis based on main-chamber and pre-chamber pressure measurements.

42 ENGINEERING↗
DOE OSTI2016

Formation of environmentally persistent free radicals (EPFRs) on ZnO at room temperature: Implications for the fundamental model of EPFR generation

Environmentally persistent free radicals (EPFRs) have significant environmental and public health impacts. Here, we demonstrate that EPFRs formed on ZnO nanoparticles provide two significant surprises. First, EPR spectroscopy shows that phenoxy radicals form readily on ZnO nanoparticles at room temperature, yielding EPR signals similar to those previously measured after 250°C exposures. Vibrational spectroscopy supports the conclusion that phenoxy-derived species chemisorb to ZnO nanoparticles under both exposure temperatures. Second, DFT calculations indicate that electrons are transferred from ZnO to the adsorbed organic (oxidizing the Zn), the opposite direction proposed by previous descriptions of EPFR formation on metal oxides.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗