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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49

Numerical studies of new stellarator concepts

A three-dimensional computer code has been developed to study the magnetohydrodynamic equilibrium and stability of a diffuse or sharp boundary plasma in toroidal geometry. It is shown how equilibria with net toroidal current identically zero can be determined and how growth rates of instabilities can be calculated. Applications are made to an l = 2, 3 stellarator configuration that offers the possibility of achieving a critical value as high as 10% for the plasma parameter

Bauer, F.↗

A normative price for energy from an electricity generation system: An Owner-dependent Methodology for Energy Generation (system) Assessment (OMEGA). Volume 1: Summary

The utility owned solar electric system methodology is generalized and updated. The net present value of the system is determined by consideration of all financial benefits and costs (including a specified return on investment). Life cycle costs, life cycle revenues, and residual system values are obtained. Break even values of system parameters are estimated by setting the net present value to zero. While the model was designed for photovoltaic generators with a possible thermal energy byproduct, it applicability is not limited to such systems. The resulting owner-dependent methodology for energy generation system assessment consists of a few equations that can be evaluated without the aid of a high-speed computer.

Chamberlain, R. G.↗

A normative price for energy from an electricity generation system: An Owner-dependent Methodology for Energy Generation (system) Assessment (OMEGA). Volume 2: Derivation of system energy price equations

The methodology presented is a derivation of the utility owned solar electric systems model. The net present value of the system is determined by consideration of all financial benefits and costs including a specified return on investment. Life cycle costs, life cycle revenues, and residual system values are obtained. Break-even values of system parameters are estimated by setting the net present value to zero.

Chamberlain, R. G.↗

Analytical performance prediction for large antennas

The coupled free-free modes of the 55M LMSS antenna configuration are shown. They were determined using modal synthesis. Reflector modes clamped at the hub were calculated adopting the efficient cyclic symmetry technique. Similarly, clamped hub modes of the offset boom structure were calculated. The modes of the two substructures were then combined through the process of modal synthesis on the assumption that the interface at the hub structure is rigid thus satisfying statically determinate matching conditions. For attitude control purposes, only modes associated with symmetric components zero and one involve net motions of the center of gravity of the reflector. This condition restricts the set of admissible eigenfunctions for modal synthesis. Modes with symmetric components higher than one are excited only by forces acting on the ribs. These modes are totally uncoupled from the boom dynamics.

El-Raheb, M.↗

Device, system and method for a sensing electrical circuit

The invention relates to a driven ground electrical circuit. A driven ground is a current-measuring ground termination to an electrical circuit with the current measured as a vector with amplification. The driven ground module may include an electric potential source V.sub.S driving an electric current through an impedance (load Z) to a driven ground. Voltage from the source V.sub.S excites the minus terminal of an operational amplifier inside the driven ground which, in turn, may react by generating an equal and opposite voltage to drive the net potential to approximately zero (effectively ground). A driven ground may also be a means of passing information via the current passing through one grounded circuit to another electronic circuit as input. It may ground one circuit, amplify the information carried in its current and pass this information on as input to the next circuit.

Vranish, John M.↗

DOE Zero Energy Ready Home Case Study HIA 2020: TC Legend Homes, Everson Net Positive, Everson, WA

Case study of a DOE 2020 Housing Innovation Award winning custom home in a cold climate that got a HERS -19 with PV, with 2,538 square feet and a large south-facing roof, which is designed to hold over 80 solar panels, and the large south-facing windows, bringing in sunlight to warm the concrete floors and provide passive solar heating.

Building America, residential construction, home b↗

Magnetocaloric Pumping of Liquid Oxygen

The field-induced force density on a magnetic fluid is proportional to the magnetic susceptibility times the gradient of the magnetic field squared. The direction of the force is towards increasing magnetic field (positive gradient). Applying a magnetic field to a magnetic fluid will result in a force from all directions towards the location of peak field. Since the magnetic field is conservative and there are no magnetic monopoles, the net field-induced force on any fluid of constant susceptibly will be zero. The only manner to obtain a nonzero net field-induced force is to vary the susceptibility of the fluid. At the gas/liquid interface of liquid oxygen, the susceptibility varies drastically, and the exploitation of the resultant large net forces. An alternative method of varying the magnetic susceptibility is to vary the temperature of the fluid. The magnetic susceptibility of paramagnetic liquid oxygen obeys the Curie-Weiss law: it is inversely proportional to temperature. By applying a temperature gradient in the presence of a symmetric magnetic field, a nonzero net force results. Much of the theory of the so-called Magnetocaloric Effect has previously been developed for and applied to ferromagnetic fluids, or ferrofluids, but is readily applied to paramagnetic liquid oxygen.

Immer, Christopher↗

DOE Zero Energy Ready Home Case Study HIA 2020: United Way of Long Island, Net Positive All Electric Home, Port Jefferson Station, NY

Case study of a DOE 2020 Housing Innovation Award winning custom home in a mixed-humid climate that got a HERS -2 with PV, with 2,500 square feet, featuring a novel attic truss specifically designed to accommodate a ducted mini-split heat pump tucked into an insulated chase in the vented attic. The walls are constructed of 2x6 studs installed at 24 inches on center and incorporating advanced framing techniques to reduce the amount of lumber needed and to provide more room for insulation.

Building America, residential construction, home b↗

Process-informed adsorbent design guidelines for direct air capture

Direct air capture using solid adsorbents is a proven technology critical to reducing our net greenhouse gas emissions to zero and beyond. Currently, academic research into the technology mainly focuses on the development of new adsorbents. However, there is a discord between the adsorbent design and process performance. Many materials scientists focus on maximising metrics such as the CO 2 capacity of their adsorbent. Here, we combine detailed process modelling, machine learning, and extensive global sensitivity analysis, which entails varying all of the model parameters together, on a direct air capture process to show that the dry CO 2 adsorption capacity does not influence process performance for an amine-functionalised adsorbent operating in a temperature vacuum swing adsorption (TVSA) process, while it is important in a steam-assisted TVSA (S-TVSA) process. In fact, adsorption kinetics, density, and thermal conductivity are all critical attributes to obtaining a low energy penalty and reduced costs. The analysis also highlights the importance of heat transfer, directing process engineers to (alternative) adsorber designs that maximise this. By an in-depth evaluation of how process performance indicators are affected by materials properties and process operating parameters, this work provides guidance to both material scientists and process engineers towards the design of a “unicorn adsorbent” and intensified DAC processes. This will improve the performance of solid adsorbent direct air capture and help drive down the costs of this vital technology to avert the worst impacts of climate change.

42 ENGINEERING↗

Acetate as a Platform for Carbon-Negative Production of Renewable Fuels and Chemicals (Final Technical Report)

This project was an industrial-academic collaboration between experts at the University of Wisconsin-Madison, the University of Kentucky, and LanzaTech, a world leader in the use of gas fermentation to sustainably produce fuels and chemicals. The project developed technologies to create an integrated process for converting carbon dioxide and renewable hydrogen into molecules that can be blended with liquid transportation fuels or used in an array of chemical applications. The project was motivated by the Program Objectives of eliminating carbon dioxide release in the production of chemicals by integrating the unique and efficient capabilities of two microorganisms into a single process. The first microbe, an acetogen, produces acetate from carbon dioxide and hydrogen while the second microbe upgrades acetate from acetogen fermentation permeates to higher-value chemical products. The carbon dioxide released in the upgrading process is recycled internally to produce more acetate. As such, the process can be designed to operate with zero carbon dioxide release and net positive carbon dioxide capture. The process has the potential to provide an alternative paradigm to the current bioeconomy – one in which acetate is the primary energy carrier instead of sugars. Our process by-passes photosynthesis and the barriers created by biomass as primary chemical feedstock. As such, the process can be scaled to meet existing sources of carbon dioxide emissions and located anywhere renewable hydrogen can be provided. Our work developed microorganisms with optimized metabolism for producing acetate and other microorganisms with improved conversion of acetate to dodecanol and dodecyl-acetate. We developed synthetic biology tools for a promising non-model bacterium that could enhance metabolic engineering efforts to convert acetate to chemical products. We conducted protein engineering studies to improve the activity of key enzymes involved in our metabolic pathways. We conducted a full technoeconomic analysis that set technical targets for each strain to meet economic goals. We identified key technical barriers in our process and proposed strategies to overcome them.

09 BIOMASS FUELS↗

Thermochemical water decomposition processes

Thermochemical processes which lead to the production of hydrogen and oxygen from water without the consumption of any other material have a number of advantages when compared to other processes such as water electrolysis. It is possible to operate a sequence of chemical steps with net work requirements equal to zero at temperatures well below the temperature required for water dissociation in a single step. Various types of procedures are discussed, giving attention to halide processes, reverse Deacon processes, iron oxide and carbon oxide processes, and metal and alkali metal processes. Economical questions are also considered.

Chao, R. E.↗

Metabolic and endocrine studies - The second manned Skylab mission

Complete metabolic collections were performed on the Skylab 3 crew in the preflight, inflight, and postflight phases of the mission. Changes in fluid and electrolyte balance have been correlated with weight loss, changes in the excretion of aldosterone, vasopressin, and fluid compartments. The initial changes observed were consistent with an increase in thoractic blood volume upon transition to a zero gravity environment, producing a net fluid loss. Compensatory mechanisms reestablished positive water balance. The indicators investigated returned to thin preflight levels during the recovery period postflight

Leach, C. S.↗

Parametric amplification and oscillation at 36 GHz using a point-contact Josephson junction

The paper reports observation of doubly degenerate parametric amplification and oscillation at 36 GHz from a single point-contact Josephson junction. The experimental results agree qualitatively with theoretical calculations based on the resistively shunted junction model. The estimated noise temperature of an amplifier with 11 dB net gain is consistent with zero, but has an upper limit of 50 K. Attempts to observe parametric amplification in the singly degenerate mode with a pump frequency of 72 GHz were not successful.

Taur, Y.↗

The systematic radial downflow in the transition region of the quiet sun from limb-to-limb observations of the C IV resonance lines

This paper presents absolute velocities of C IV 1548, 1550 nm measured as a function of position along the solar equator, which was free of both active regions and coronal holes, and uniformly representative of the quiet sun. These observations were made with moderate spatial resolution (18 arcsec) using an EUV spectrometer dedicated to measuring absolute wavelengths (velocities) by direct comparison with a platinum spectrum generated on board the sounding rocket. On the assumption that systematic horizontal motions cancel statistically so that the line-of-sight velocities approach zero at the limb, a net radial downflow of 7.5 + or - 1.0 km/sec was found. The assumption was tested using the wavelength reference and found to be valid within the absolute accuracy of the rest wavelengths of the C IV lines.

Rottman, Gary J.↗

Electroform/Plasma-Spray Laminates for X-Ray Optics

Electroform/plasma-spray laminates have shown promise as lightweight, strong, low-thermal-expansion components for xray optics. The basic idea is to exploit both (1) the well-established art of fabrication of optical components by replication and (2) plasma spraying as a means of reinforcing a thin replica optic with one or more backing layer(s) having tailorable thermomechanical properties. In x-ray optics as in other applications, replication reduces the time and cost of fabrication because grinding and polishing can be limited to a few thick masters, from which many lightweight replicas can thereafter be made. The first step in the fabrication of a component of the type in question is to make a replica optic by electroforming a thin layer of nickel on a master. Through proper control of the electroforming process conditions, it is possible to minimize residual stress and, hence, to minimize distortion in the replica. Next, a powder comprising ceramic particles coated with a metal compatible with the electroformed nickel is plasma-sprayed onto the backside of the nickel replica. Then through several repetitions and variations of the preceding steps or perhaps a small compressive stress, alternating layers of electroformed nickel and plasma-sprayed metal-coated ceramic powder are deposited. The thicknesses of the layers and the composition of the metal-coated ceramic powder are chosen to optimize the strength, areal mass density, and toughness of the finished component. An important benefit of using both electroforming and plasma spraying is the possibility of balancing stresses to a minimum level, which could be zero or perhaps a small net compressive stress designed to enhance the function of the component in its intended application.

Ulmer, Melville P.↗

Sea-Level Rise: Projections for Maryland 2018

In fulfillment of requirements of the Maryland Commission on Climate Change Act of 2015, this report provides updated projections of the amount of sea-level rise relative to Maryland coastal lands that is expected into the next century. These projections represent the consensus of an Expert Group drawn from the Mid-Atlantic region. The framework for these projections is explicitly tied to the projections of global sea-level rise included in the Intergovernmental Panel on Climate Change Fifth Assessment (2014) and incorporates regional factors such as subsidence, distance from melting glaciers and polar ice sheets, and ocean currents. The probability distribution of estimates of relative sea-level rise from the baseline year of 2000 are provided over time and, after 2050, for three different greenhouse gas emissions pathways: Growing Emissions (RCP8.5), Stabilized Emissions (RCP4.5), and meeting the Paris Agreement (RCP2.6). This framework has been recently used in developing relative sea-level rise projections for California, Oregon, Washington, New Jersey, and Delaware as well as several metropolitan areas. The Likely range (66% probability) of the relative rise of mean sea level expected in Maryland between 2000 and 2050 is 0.8 to 1.6 feet, with about a one-in-twenty chance it could exceed 2.0 feet and about a one-in-one hundred chance it could exceed 2.3 feet. Later this century, rates of sea-level rise increasingly depend on the future pathway of global emissions of greenhouse gases during the next sixty years. If emissions continue to grow well into the second half of the 21st century, the Likely range of sea-level rise experienced in Maryland is 2.0 to 4.2 feet over this century, two to four times the sea-level rise experienced during the 20th century. Moreover, there is a one-in-twenty chance that it could exceed 5.2 feet. If, on the other hand, global society were able to bring net greenhouse gas emissions to zero in time to meet the goals of the Paris Climate Agreement and reduce emissions sufficient to limit the increase in global mean temperature to less than 2°Celsius over pre-industrial levels, the Likely range for 2100 is 1.2 to 3.0 feet, with a one-in-twenty chance that it would exceed 3.7 feet. The difference in sea-level rise between these contrasting scenarios would diverge even more during the next century, with the failure to reduce emissions in the near term resulting in much greater sea-level rise 100 years from now. Moreover, recent research suggests that, without imminent and substantial reductions in greenhouse gas emissions, the loss of polar ice sheets-and thus the rate of sea-level rise-may be more rapid than assumed in these projections, particularly under the Growing Emissions scenario. These probabilistic sea-level rise projections can and should be used in planning and regulation, infrastructure siting and design, estimation of changes in tidal range and storm surge, developing inundation mapping tools, and adaptation strategies for high-tide flooding and saltwater intrusion.

Boesch, D. F.↗

Design, Isolation, and Spectroscopic Analysis of a Tetravalent Terbium Complex

Synthetic strategies to glean molecular complexes of high-valent lanthanides, other than the ubiquitous Ce 4+ ion, are exceptionally rare, and thorough, detailed characterization in these systems is limited by complex lifetime and reaction and isolation conditions. The synthesis of high-symmetry complexes in high purity with significant lifetimes in solution and the solid state is essential for determining the role of ligand-field splitting, multiconfigurational behavior, and covalency in governing the reactivity and physical properties of these potentially technologically transformative tetravalent ions. We report the synthesis and physical characterization of an S 4 symmetric, four-coordinate tetravalent terbium complex, [Tb(NP(1,2-bis- t Bu-diamidoethane)(NEt 2 )) 4 ] (where Et is ethyl and t Bu is tert-butyl). The ligand field in this complex is weak and the metal–ligand bonds sufficiently covalent so that the tetravalent terbium ion is stable and accessible via a mild oxidant from the anionic, trivalent, terbium precursor, [(Et 2 O)K][Tb(NP(1,2-bis- t Bu-diamidoethane)(NEt 2 )) 4 ]. The crucial stability of the tetravalent complex enables its thorough characterization. The stepwise development of the supporting ligand points to key ligand control elements for further extending the known tetravalent lanthanide ions in molecular complexes. Magnetic susceptibility, electron paramagnetic resonance (EPR) spectroscopy, X-ray absorption near-edge spectroscopy (XANES), and density functional theory studies indicate a 4ƒ 7 ground state for [Tb(NP(1,2-bis- t Bu-diamidoethane)(NEt 2 )) 4 ] with considerable zero-field splitting, demonstrating that magnetic, tetravalent lanthanide ions engage in covalent metal–ligand bonds. This result has significant implications for the use of tetravalent lanthanide ions in magnetic applications since the observed zero-field splitting is intermediate between that observed for the trivalent lanthanides and for the transition metals. The similarity of the multiconfigurational behavior in the ground state of [Tb(NP(1,2-bis- t Bu-diamidoethane)(NEt 2 )) 4 ] (measured by Tb L 3 -edge XAS) to that observed in TbO 2 implicates ligand control of multiconfigurational behavior as a key component of the stability of the complex.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The one and a half monopoles solution of the SU(2) Yang–Mills–Higgs field theory

Recently we have reported on the existence of finite energy SU(2) Yang–Mills–Higgs particle of one-half topological charge. In this paper, we show that this one-half monopole can co-exist with a ’t Hooft–Polyakov monopole. The magnetic charge of the one-half monopole is of opposite sign to the magnetic charge of the ’t Hooft–Polyakov monopole. However the net magnetic charge of the configuration is zero due to the presence of a semi-infinite Dirac string along the positive z-axis that carries the other half of the magnetic monopole charge. The solution possesses gauge potentials that are singular along the z-axis, elsewhere they are regular. The total energy is found to increase with the strength of the Higgs field self-coupling constant λ. However the dipole separation and the magnetic dipole moment decrease with λ. This solution is non-BPS even in the BPS limit when the Higgs self-coupling constant vanishes. -- Highlights: •This one-half monopole can co-exist with a ’t Hooft–Polyakov monopole. •The magnetic charge of the one-half monopole and one monopole is of opposite sign. •This solution is non-BPS. •The net magnetic charge of the configuration is zero. •This solution upon Cho decomposition is only singular along the negative z-axis.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗