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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2018

Hi-5: A Potential High-Contrast Thermal Near-Infrared Imager for the VLTI

Hi-5 is a high-contrast (or high dynamic range) infrared imager project for the VLTI. Its main goal is to characterize young extra-solar planetary systems and exozodiacal dust around southern main-sequence stars. In this paper, we present an update of the project and key technology pathways to improve the contrast achieved by the VLTI. In particular, we discuss the possibility to use integrated optics, proven in the near-infrared, in the thermal near-infrared (L and M bands, 3-5 μm) and advanced fringe tracking strategies. We also address the strong exoplanet science case (young exoplanets, planet formation, and exozodiacal disks) offered by this wavelength regime as well as other possible science cases such as stellar physics (fundamental parameters and multiplicity) and extragalactic astrophysics (active galactic nuclei and fundamental constants). Synergies and scientific preparation for other potential future instruments such as the Planet Formation Imager are also briefly discussed.

exozodiacal dust↗
NASA NTRSDate not supplied

Stirling Power Conversion for Lunar Applications

NASA is developing Stirling power convertors for use in nuclear power systems that would provide electricity to users on the lunar surface. NASA’s Radioisotope Power Systems (RPS) Program is maturing advanced dynamic convertor technologies that would increase the efficiency beyond the heritage systems for missions to the Moon and other solar system bodies of interest. Development efforts have focus on Stirling and Brayton designs that meet reliability and robustness requirements for operation in the lunar environment. GRC is also maturing low power convertors in the range of 1-40 watts to power micro-spacecraft or a network of distributed probes and include basic demonstration of in-house designs for convertors and controllers. In addition to RPS applications, conceptual fission systems have been demonstrated using Stirling convertors in multiple electrically heated tests and one test heated by a nuclear reactor. The Stirling convertors used in these fission system concepts include 100 We convertors to enable a 1 kWe system, 1 kWe convertors to enable a 10 kWe system, and 6 kWe convertors to enable a 40 kWe system. The maturation of Stirling power convertors for nuclear applications includes verification of performance in relevant environments and validation of the design with a focus on high reliability and robustness. Over 1 million hours of testing has been accumulated on dozens of convertors since 1999 in the Stirling Research Laboratory at the NASA Glenn Research Center located in Cleveland Ohio, where the longest running convertor is the work record holder at 137,000 hours, or 15.5 years. These maturation efforts have been instrumental in increasing the technology readiness level of Stirling technologies for space applications.

S. Wilson↗
DOE OSTI2020

A Survey of Multizone Airflow Simulation Software

H-Canyon simulates the building and process ventilation to ensure positive contamination control for any modifications as well as evaluating off-normal conditions. Simulations can also be used to identify air quality of personnel occupied areas. The models can be classified into two groups, single and multi-zone models. As the name states, a single zone model assumes that the building can be described by a single, well-mixed zone. Whereas large buildings have structures that must be described as multizone. Multizone airflow models deal with the difficulty of flows in a building by distinguishing the effects of internal flow restrictions. Several models have been developed that take internal partitions into account. CONTAM (currently used) is a multizone airflow program created by NIST to determine airflows including infiltration, exfiltration, wind pressures acting outside the building, buoyancy effects caused by the indoor and outdoor air temperature difference. COMIS is a multizone air infiltration, ventilation, and contaminant transport model that was developed at Lawrence Berkeley National Laboratory. COMIS deals with applied pressure distribution, airflow components, HVAC systems, schedules, and contaminant transport. EnergyPlus is designed by DOE. It supports flexible component level configuration of HVAC models and simulates sub-hourly time steps to control fast dynamic systems. The program features include providing accurate environmental performance data including energy consumption and carbon emissions, and reporting solar gains on surfaces. Heavent is used to model industrial ventilation systems to control airborne contaminants. It's designed based on the American Conference of Governmental Industrial Hygienists (ACGIH) Ventilation manual. DesignBuilder is the most recognized and advanced user interface to EnergyPlus. It gives access to all of the most frequently required simulation capabilities covering building fabric, thermal mass, glazing, shading renewables, and HVAC analysis. The objective of this study is to identify all relevant software available including commercially licensed, freely licensed, and open source, that can be used to simulate large, complex process facility ventilation systems. All discovered software tools are evaluated for salient features and compared to the software tool currently used to simulate the H-Canyon ventilation system. The design criteria of a ventilation system has two basic requirements: Supplying fresh air for the occupants and changing the air in the room sufficiently; therefore, the smells, fumes, and contaminants will be removed. In this study, first, whether the software simulates airflow (infiltration, natural ventilation, and interzonal) or considers them to be inputs is discussed. Second, if indoor contaminant levels are considered; and finally suggestions on how airflow analysis can be more appropriately accounted for when performing airflow simulation of a building. All of the airflow software reviewed for this study can account for constant infiltration and natural ventilation rates that are not affected by changes in indoor and outdoor conditions. Modelling infiltration in EnergyPlus or DesignBuilder are applicable for small buildings and not appropriate for larger buildings like the H-Canyon. The effect of wind on external pressures, infiltration, and natural and mechanical ventilation, can also be calculated using all of these software. These programs have control options to switch between natural to mechanical ventilation modes or both (hybrid). Interzonal airflow can be applied which means one zone can be specified to receive a fixed amount of air from another zone. The following ventilation modeling software is recommended for further testing: CONTAM, COMIS, Heavent. The next step in evaluating the software will consist of creating test facility simulations using evaluation copies of the software.

42 ENGINEERING↗
DOE OSTI2024

Predicting Instability and the Effect of Wind Loading on Single-Axis Trackers

As PV modules continue to trend toward larger, thinner, and more flexible forms they grow more susceptible to damage from dynamic wind loading. As a result, understanding the impact of wind on PV systems, particularly when mounted on solar-tracking hardware, and identifying robust, stable array layouts and stow strategies is becoming increasingly important for the PV community. In our ongoing DuraMAT project, we are developing an open-source software package, PVade (PV aerodynamic design engineering), to simulate the cascading fluid-structure interaction that occurs within solar-tracking arrays to enable researchers to test hardware, layout, and tracker control changes, leading to enhanced stability and a reduction in wind-driven damage. We will give an overview of the PVade software, highlighting recent user-interface and algorithm developments, before presenting the latest outcomes from our ongoing validation campaign in which we analyze and compare with experimental data obtained from a DuraMAT 1 project. From there, we will present simulated results from a larger, multi-row array and highlight relationships between varying tracker angles and stability as measured by different experimentally validated metrics.

fluid structure interaction↗
DOE OSTI2024

A Simulation and Optimization Framework for Managing Wind-Driven Loading on PV Systems

As PV modules continue to trend toward larger, thinner, and more flexible forms they grow more susceptible to damage from dynamic wind loading. As a result, understanding the impact of wind on PV systems, particularly when mounted on solar-tracking hardware, and identifying robust, stable array layouts and stow strategies is becoming increasingly important for the PV community. We are developing an open-source software package, PVade (PV aerodynamic design engineering), to simulate the cascading fluid-structure interaction that occurs within solar-tracking arrays to enable researchers to test hardware, layout, and tracker control changes, leading to enhanced stability and a reduction in wind-driven damage. We will give an overview of the PVade software and present the latest outcomes from our ongoing validation campaign in which we compare statistical structural responses with field data. From there, we will present simulated results from a larger, multi-row array and highlight the effect of varying tracker angles on stability as measured by both acceleration and deformation, focusing on the stability differences between positive and negative tilt angles.

fluid structure interaction↗
DOE OSTI2024

Exploring the Photophysics of N-Type Polymer N2200

The polymer interphase is a complex environment comprised of polymer chains, solvent molecules, and electrolyte ions. However, the microenvironments that these ingredients produce is both poorly-understood and difficult to investigate given the system's inherent structural heterogeneity. Nonetheless, a fundamental understanding of the structure, electrochemical behavior, and excited-state dynamics is a key prerequisite to optimizing devices based on such a system - for instance, photoelectrochemical cells for the direct, light-driven production of solar hydrogen, which may minimize efficiency losses compared to sequential light harvesting and electrochemical hydrogen production in separate but linked devices. This work combines transient absorption (TA) spectroscopy, which is a powerful tool for the observation of a variety of excited states on a femto- to microsecond timescale, with time-resolved microwave conductivity (TRMC) spectroscopy, which selectively probes the dynamics of free charge carriers (FC), of a blend of a donor polymer (PTB7-Th) and acceptor polymer (N2200) in a bulk heterojunction. Initial results indicate an extension of FC lifetime and homogenization of the microenvironment on a whole-film level, not just at the surface of the polymer; however, many questions are still under active investigation, including the changes in energy of the involved polaron states, effective conjugation length, FC mobility and migration distance, etc. Additional experiments regarding the photoinitiated behavior of the blend in different environments and on different timescales are ongoing.

charge recombination↗
NASA NTRS2019

Small Stirling Technology Exploration Power for Future Space Science Missions

High efficiency dynamic Radioisotope Power Systems (RPS) could be mission enabling for low power space applications such as small probes, landers rovers, and communication repeaters. These applications would contain science instruments and be distributed across planetary surfaces or near objects of interest where solar flux is insufficient for using solar cells. Small RPS could be used to provide power for sensing radiation, temperature, pressure, seismic activity, and other measurements of interest to planetary scientists. Small RPS would use fractional versions of the General Purpose Heat Source (GPHS) or Light Weight Radioisotope Heater Units (LWRHU), to heat power conversion technologies. Dynamic power systems are capable of three to four times higher conversion efficiency compared to static power conversion technologies, and would provide an equal amount of power using less fuel or more power using an equal amount of fuel. Providing spacecraft with more power could decrease duty cycling of basic functions and, therefore, increase the quality and abundance of science data. NASA GRC is developing a low power dynamic RPS that would convert heat from multiple LWRHU to one watt of usable direct current electric power for spacecraft instrumentation and communication. The power system could be used to charge batteries or capacitors for higher power burst usage. The initial design, called Small Stirling Technology Exploration Power (smallSTEP), is around 3 kg, 11 cm diameter X 32 cm long, and converts 8 watts of heat to one watt of electricity using a Stirling convertor. This low power conversion system represents a new class of RPS with power levels two orders of magnitude lower than prototypes currently being developed for space applications under NASA contracts. Development of the 1-watt RPS includes maturation of convertor and controller designs, performance evaluation of an evacuated metal foil insulation, and development of system interfaces. Initial demonstration of the subsystems has been completed in a laboratory environment and a higher fidelity system is being pursued for demonstration in relevant environments for use on small spacecraft needed to carry out future space science missions.

Wilson, Scott D.↗
NASA NTRS2019

Small Stirling Technology Exploration Power for Future Space Science Missions

High efficiency dynamic Radioisotope Power Systems (RPS) could be mission enabling for low power space applications such as small probes, landers rovers, and communication repeaters. These applications would contain science instruments and be distributed across planetary surfaces or near objects of interest where solar flux is insufficient for using solar cells. Small RPS could be used to provide power for sensing radiation, temperature, pressure, seismic activity, and other measurements of interest to planetary scientists. Small RPS would use fractional versions of the General Purpose Heat Source (GPHS) or Light Weight Radioisotope Heater Units (LWRHU), to heat power conversion technologies. Dynamic power systems are capable of three to four times higher conversion efficiency compared to static power conversion technologies, and would provide an equal amount of power using less fuel or more power using an equal amount of fuel. Providing spacecraft with more power could decrease duty cycling of basic functions and, therefore, increase the quality and abundance of science data. NASA Glenn Research Center (GRC) is developing a low power dynamic RPS that would convert heat from multiple LWRHU to one watt of usable direct current electric power for spacecraft instrumentation and communication. The power system could be used to charge batteries or capacitors for higher power burst usage. The initial design, called Small Stirling Technology Exploration Power (smallSTEP), is around 3 kg, 11 cm diameter X 32 cm long, and converts 8 watts of heat to one watt of electricity using a Stirling convertor. This low power conversion system represents a new class of RPS with power levels two orders of magnitude lower than prototypes currently being developed for space applications under NASA contracts. Development of the 1-watt RPS includes maturation of convertor and controller designs, performance evaluation of an evacuated metal foil insulation, and development of system interfaces. Initial demonstration of the subsystems has been completed in a laboratory environment and a higher fidelity system is being pursued for demonstration in relevant environments for use on small spacecraft needed to carry out future space science missions.

Wilson, Scott↗
DOE OSTI2017

0.7–2.5 μ m Spectra of Hilda Asteroids

The Hilda asteroids are primitive bodies in resonance with Jupiter whose origin and physical properties are not well understood. Current models posit that these asteroids formed in the outer solar system and were scattered along with the Jupiter Trojans into their present-day positions during a chaotic episode of dynamical restructuring. In order to explore the surface composition of these enigmatic objects in comparison with an analogous study of Trojans, we present new near-infrared spectra (0.7–2.5 μ m) of 25 Hilda asteroids. No discernible absorption features are apparent in the data. Synthesizing the bimodalities in optical color and infrared reflectivity reported in previous studies, we classify 26 of the 28 Hildas in our spectral sample into the so-called less-red and red sub-populations and find that the two sub-populations have distinct average spectral shapes. Combining our results with visible spectra, we find that Trojans and Hildas possess similar overall spectral shapes, suggesting that the two minor body populations share a common progenitor population. A more detailed examination reveals that while the red Trojans and Hildas have nearly identical spectra, less-red Hildas are systematically bluer in the visible and redder in the near-infrared than less-red Trojans, indicating a putative broad, shallow absorption feature between 0.5 and 1.0 μ m. We argue that the less-red and red objects found in both Hildas and Trojans represent two distinct surface chemistries and attribute the small discrepancy between less-red Hildas and Trojans to the difference in surface temperatures between the two regions.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2010

The Impact History Of The Moon

The bombardment history of the Earth-Moon system has been debated since the first recognition that the circular features on the Moon may be impact craters. Because the lunar impact record is the only planetary impact record to be calibrated with absolute ages, it underpins our understanding of geologic ages on every other terrestrial planet. One of the more remarkable results to come out of lunar sample analyses is the hypothesis that a large number of impact events occurred on the Moon during a narrow window in time approximately 3.8 to 4.1 billion years ago (the lunar cataclysm ). Subsequent work on the lunar and martian meteorite suites; remote sensing of the Moon, Mars, asteroids, and icy satellites; improved dynamical modeling; and investigation of terrestrial zircons extend the cataclysm hypothesis to the Earth, other terrestrial planets, and possibly the entire solar system. Renewed US and international interest in exploring the Moon offers new potential to constrain the Earth-Moon bombardment history. This paper will review the lunar bombardment record, timing and mechanisms for cataclysmic bombardment, and questions that may be answered in a new age of exploration.

Cohen, B. A.↗
NASA NTRSDate not supplied

Identification of Additional Ceres-Like Asteroids in the Main Belt

Primitive (i.e., low-albedo and water-rich) asteroids are remnants from the early formation of the solar system. They offer insight into the physical and chemical processes that took place during this early period. Previous research has shown that many large primitive asteroids (with a diameter greater than 100 km) have similar spectral characteristics to the dwarf planet Ceres. These asteroids are found in a specific region beyond Ceres' orbit, between approximately 3.0 AU and 3.4 AU from the Sun. These Ceres-like asteroids have highly porous interiors, formed relatively late (1.5-3.5 million years after the formation of calcium-aluminum-rich inclusions), and experienced maximum interior temperatures of less than 900K. We have obtained new spectra of additional large primitive asteroids with similar spectral characteristics to Ceres, such as asteroid (168) Sibylla, some of which are located beyond 3.4 AU. The new spectra were measured at the NASA Infrared Telescope Facility in Hawai'i, using the prism (0.7-2.5 μm) and the long-wavelength cross-dispersed (LXD: 1.9–4.2-μm) modes of the SpeX spectrograph/imager. We will also discuss the implications of these new results on the mechanisms responsible for implanting Ceres-like asteroids into the Main Belt, such as dynamical instability.

Asteroids↗
NASA NTRS1994

Dynamical and observational constraints on satellites in the inner Pluto-Charon system

It is not known if Pluto has other satellites besides its massive partner Charon. In the past, searches for additional satellites in the Pluto-Charon system have extended from the solar-tidal stability boundary (approximately 90 arcsec from Pluto) inward to about 1 arcsec from Pluto. Here we further explore the inner (i.e., less than 10 arcsec) region of the Pluto-Charon system to determine where additional satellites might lie. In particular, we report on (1) dynamical simulations to delineate the region where unstable orbits lie around Charon, (2) dynamical simulations which use the low orbital eccentricity of Charon to constrain the mass of any third body near Pluto, and (3) analysis of Hubble Space Telescope (HST) archival images to search for satellites in the inner Pluto-Charon system. Although no objects were found, significant new constraints on bodies orbiting in the inner Pluto-Charon system were obtained.

Stern, S. Alan↗
NASA NTRSDate not supplied

Characterization of Slosh Damping for Ortho-Grid and Iso-Grid Internal Tank Structures

Grid stiffened tank structures such as Ortho-Grid and Iso-Grid are widely used in cryogenic tanks for providing stiffening to the tank while reducing mass, compared to tank walls of constant cross-section. If the structure is internal to the tank, it will positively affect the fluid dynamic behavior of the liquid propellant, in regard to fluid slosh damping. As NASA and commercial companies endeavor to explore the solar system, vehicles will by necessity become more mass efficient, and design margin will be reduced where possible. Therefore, if the damping characteristics of the Ortho-Grid and Iso-Grid structure is understood, their positive damping effect can be taken into account in the systems design process. Historically, damping by internal structures has been characterized by rules of thumb and for Ortho-Grid, empirical design tools intended for slosh baffles of much larger cross-section have been used. There is little or no information available to characterize the slosh behavior of Iso-Grid internal structure. Therefore, to take advantage of these structures for their positive damping effects, there is much need for obtaining additional data and tools to characterize them. Recently, the NASA Marshall Space Flight Center conducted both sub-scale testing and computational fluid dynamics (CFD) simulations of slosh damping for Ortho-Grid and Iso-Grid tanks for cylindrical tanks containing water. Enhanced grid meshing techniques were applied to the geometrically detailed and complex Ortho-Grid and Iso-Grid structures. The Loci-STREAM CFD program with the Volume of Fluid Method module for tracking and locating the water-air fluid interface was used to conduct the simulations. The CFD simulations were validated with the test data and new empirical models for predicting damping and frequency of Ortho-Grid and Iso-Grid structures were generated.

Douglas G. Westra↗
DOE OSTI2024

An Adaptive Dynamic Agrivoltaic Production Tool

In the pursuit of sustainable and land-use-efficient solutions to mitigate climate change, the concept of agrivoltaic systems, which integrate renewable solar energy into conventional agriculture, has emerged. By deploying solar arrays above the crop field, these systems are designed to maximize the land use efficiency or, in other words, the value of generated electricity and crop yield per unit area. While power generation has been extensively studied and modeled, research gaps persist in simulating crop performance [1], [2]. Early studies utilized generalized relationships between photosynthetically active radiation (PAR) and crop production. However, significant variations in crop performance due to other factors, such as weather and soil, can compromise the reliability of the results [2]. Current studies focus on comprehensive process-based crop models, such as DSSAT [3] and STICS [4]. Nevertheless, the validation status varies greatly across different species, and the validation process requires well-designed experiments to adjust specific processes. For less common shade-tolerant crops with limited validation, such as cabbage, physiological behaviors can be difficult to predict [5]. This study investigates an adaptive dynamic agrivoltaic production tool (ADAPT) with few data requirements and minimal on-site calibration that can be easily applied in real applications.

Long, Qirui↗
DOE OSTI2016

DATA ASSIMILATION APPROACH FOR FORECAST OF SOLAR ACTIVITY CYCLES

Numerous attempts to predict future solar cycles are mostly based on empirical relations derived from observations of previous cycles, and they yield a wide range of predicted strengths and durations of the cycles. Results obtained with current dynamo models also deviate strongly from each other, thus raising questions about criteria to quantify the reliability of such predictions. The primary difficulties in modeling future solar activity are shortcomings of both the dynamo models and observations that do not allow us to determine the current and past states of the global solar magnetic structure and its dynamics. Data assimilation is a relatively new approach to develop physics-based predictions and estimate their uncertainties in situations where the physical properties of a system are not well-known. This paper presents an application of the ensemble Kalman filter method for modeling and prediction of solar cycles through use of a low-order nonlinear dynamo model that includes the essential physics and can describe general properties of the sunspot cycles. Despite the simplicity of this model, the data assimilation approach provides reasonable estimates for the strengths of future solar cycles. In particular, the prediction of Cycle 24 calculated and published in 2008 is so far holding up quite well. In this paper, I will present my first attempt to predict Cycle 25 using the data assimilation approach, and discuss the uncertainties of that prediction.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Dynamic optimization and economic evaluation of flexible heat integration in a hybrid concentrated solar power plant

Hybridization of concentrated solar power (CSP) plants provides flexibility in operation that can drastically improve the solar-to-electric (STE) efficiency and levelized cost of electricity (LCOE) relative to standalone CSP plants. Flexible heat integration (FHI) is a novel concept where the collection and integration of CSP within a power plant is modified relative to the amount of solar energy available. FHI improves the thermal efficiency of a hybrid solar tower steam Rankine cycle power plant but leads to increased pumping needs due to continuously elevated molten salt flow rates through the collection system, which can negatively impact STE efficiency. The present work is carried out to maximize the STE efficiency of a hybrid CSP plant utilizing FHI by employing a dynamic optimization framework where a genetic algorithm optimizes the operation of the plant over a given solar irradiance profile. The study concerns a plant hypothetically located in Salt Lake City, Utah. Here, the optimization results confirm the accuracy of a predictive heuristic where the preferred operation of the plant can be estimated relative to local peaks in the incident power generated by the heliostat collection field. The optimized FHI operation demonstrates a yearly STE efficiency of 13.8%, whereas the equivalent base-level hybrid and solar-only plants exhibit solar efficiencies of 13.4% and 11.2%, respectively. Economic analysis shows that FHI reduces yearly natural gas costs, leading to a $\$0.5$/MWh reduction in LCOE relative to the base-level hybrid configuration. Overall, the results show that hybrid FHI schemes exhibit economic benefits along with observed thermodynamic improvements.

14 SOLAR ENERGY↗
NASA NTRS1993

Cloud, dust, and ozone vertical profiles from solar occultation measurements: Implications for dynamics

An instrument was designed for solar occultation measurements of the martian atmosphere from the Phobos spacecraft. It was composed of three different dispersive systems working in the ultraviolet (UV: 0.22-0.32 microns) for the measurement of O3 and aerosols, in the near infrared (NIR: 0.76 microns, 0.94 microns) for the detection of O2 and H2O, and in the infrared (IR: 1.9 microns, 3.7 microns) where CO2 and H2O were measured. A detailed description of the instrument may be found in the special issue of Nature. Its principle objective is to measure from the Phobos orbit the spectrum of the Sun, modified by atmospheric extinction, during sunset. The UV-NIR spot has an angular diameter of 1 arcmin, or approximately 3 km vertical resolution, and is located near the center of the solar disk. The IR field is about twice as large and its line of sight is shifted by 8.5 arcmin, or approximately 20 km, relative to the previous one. It is therefore located near the edge of the solar disk. Sampling times are generally 0.5, 1, and 2 s for IR, UV, and NIR channels respectively, corresponding to vertical excursions of the line of sight of 1, 2, and 4 km respectively under nominal conditions. The instrument operated from February 8 to March 26 (the martian equinox occurred on February 17). The latitude of the intersection of the Sun-spacecraft axis with the surface of Mars varied from -11 to +20, the seasonal date L(sub s) being in the range 0 - 20. All measurements were therefore made near northern spring equinox in equatorial regions. Due to an error in the pointing system, only partial results were obtained, the region below approximately equals 30 km altitude being never sounded by the UV-NIR spectrometer. On the contrary, nine complete occultations were obtained in the IR channels, whose line of sight was fortunately approximately equals 20 km below the UV-NIR axis.

Chassefiere, E.↗
DOE OSTI2025

Light induced ion migration studies in perovskite solar cell using nonlinear impedance spectroscopy

Complex interactions between mobile ions and charge carriers in perovskite solar cells (PSCs) make it challenging to fully understand their dynamic interplay. Exposure to light further complicates these interactions, altering the system’s dynamics and inducing nonlinear effects that lead to changes in the J−V curve. Understanding these effects is crucial for improving the operational stability of PSCs. Impedance spectroscopy (IS) is a powerful technique for evaluating relaxation processes in the frequency domain; however, it is limited in capturing nonlinear contributions. Here, in this work, nonlinear impedance spectroscopy (NLIS) is employed to analyze the higher harmonic response to AC perturbation, both in the dark and after short-term light exposure. A shift in the low-frequency (LF) higher harmonic peak is observed after open-circuit light exposure, attributed to an altered electric field suggesting ion re-distribution, whereas closed-circuit exposure shows no LF shift, indicating minimal ion movement. Additionally, light exposure reduces higher-order admittance, more notably in open-circuit conditions, suggesting decreased recombination. Temperature-dependent analysis was conducted to characterize the activation energy of migrating species, identifying iodide as the dominant migrating ion.

14 SOLAR ENERGY↗