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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49

The g$p\atop{2}$ Experiment: A Measurement of the Proton's Spin Structure Functions

The E08-027 (g$p\atop{2}$) experiment measured the spin structure functions of the proton at Jefferson Laboratory in Newport News, Va. Longitudinally polarized electrons were scattered from a transversely and longitudinally polarized solid ammonia target in Hall A, with the polarized NH$_3$ acting as an effective proton target. Focusing on small scattering angle events at the electron energies available at Jefferson Lab, the experiment covered a kinematic phase space of 0.02 GeV$^2$ $< Q^2 <$ 0.20 GeV$^2$ in the proton's resonance region. The spin structure functions, $g_{1}^p(x,Q^2)$ and $g_{2}^p(x,Q^2)$ , are extracted from an inclusive polarized cross section measurement of the electron-proton interaction. Integrated moments of $g_1(x,Q^2)$ are calculated and compared to theoretical predictions made by Chiral Perturbation Theory. The $g_1(x,Q^2)$ results are in agreement with previous measurements, but include a significant increase in statistical precision. The spin structure function contributions to the hyperfine energy levels in the hydrogen atom are also investigated. The $g_2(x,Q^2)$ measured contribution to the hyperfine splitting is the first ever experimental determination of this quantity. The results of this thesis suggest a disagreement of over 100% with previously published model results.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Assessment of Jupiter's trapped radiation by pioneer

The experiments planned for Pioneers F and G during their Jupiter flybys are discussed. The complement includes four energetic charged particle experiments: University of Iowa package consisting of Geiger-Mueller tubes; University of California, San Diego, trapped radiation package consisting of solid state detectors, thin scintillators, and an alcohol water Cerenkov radiator; University of Chicago package containing charged particle detectors; and a Goddard Space Flight Center package containing solid state, cosmic ray detectors. Other experiments are the Jet Propulsion Laboratory magnetometer and the Ames Research Center plasma analyzer. Pitch angle distributions at Jupiter, and the capabilities for unambiguous identification of energetic protons at Jupiter are also discussed.

Mihalov, J. D.↗

Aerodynamic roll characteristics of a 0.00548 scale 146-inch solid rocket booster reentry configuration (MSFC Model Number 486) over a portion of the reentry flight regime in the NASA MSF 14-inch trisonic wind tunnel

An experimental investigation was conducted in the MSFC 14 inch TWT to study the roll characteristics of a 0.00548 scale model of the 146 inch shuttle solid rocket booster to obtain more accurate rolling moment data on the solid rocket booster. A sensitive single component roll balance was utilized. Data were obtained for a single nose mounted sting. The angle of attack range consisted of angles from 150 deg to 190 deg; roll angles consisted of angles from 0 deg to 337 1/2 deg in increments of 22 1/2 deg; and Mach numbers were 1.46, 1.96, 2.74 and 2.48.

Ramsey, P. E.↗

Analysis of the free-tip rotor wind-tunnel test results

The results from a wind tunnel test of a small scale free-tip rotor are analyzed. The free-tip rotor has blade tips that are free to weathervane into the tip's relative wind, thus producing a more uniform lift around the azimuth. The free-tip assembly, which includes the controller, functioned flawlessly throughout the test. In a test of the free-tip's response after passing through a vertical air jet, the tip pitched freely and in a controlled manner. Analysis of the tip's response characteristics showed the free-tip system's damped natural frequency to be 5.2 per rev. Tip pitch angle responses to the local airstream are presented for an advance-ratio range of 0.1 to 0.397 and for a solidity weighted rotor lift coefficient range of 0.038 to 0.092. Harmonic analysis of the responses showed a dominance by the first harmonic. As a result of the tip being free, forward flight power requirements were reduced by 8% or more. More power reduction was recorded for high thrust conditions. In addition to the power reduction, flatwise blade bending moments were reduced by as much as 30% at the inboard blade stations.

Stroub, Robert H.↗

Free-streamline analysis of deformation and dislodging by wind force of drops on a surface

Free-streamline theory is used to analyze the deformation and dislodging by wind pressure of drops of liquid adhered by surface tension to a solid surface. The critical Weber number for droplets to be dislodged is determined as a function of advancing and receding contact angle. Graphical results for drop shape are in good agreement with observation.

Durbin, P. A.↗

Primary mirror and mount technology for the Stratospheric Observatory for Infrared Astronomy (SOFIA) telescope

Candidate technologies for a lightweight primary mirror for the SOFIA telescope are evaluated for both mirror blank fabrication and polishing. Two leading candidates for the type mirror blank are considered: the frit-bonded, structured form, and the thin meniscus form. The feasible mirror is required to be very lightweight with an areal density of approximately 100 kg/sq m, have an f/ratio near 1.0, and have surface quality that permits imaging in the visible as well as the infrared. Also considered are the results of a study conducted to assess the feasibility of designing a suitable mounting system for the primary mirror. The requirements for the mount design are given both in terms of the environmental conditions and the expected optical performance. PATRAN and NASTRAN programs are used to model mirror and mounting. The sandwich-type mirror made of ultra low expansion silica with square cells in the core, is modeled using equivalent solid elements for the core. The design study produces primary mirror surface deflections in 1g as a function of mirror elevation angles. The surface is analyzed using an optical analysis program, FRINGE, to give a prediction of the mirror optical performance. Results from this analysis are included.

Melugin, Ramsey K.↗

The Wettability of LaRC Colorless Polyimide Resins on Casting Surfaces

Two colorless polyimides developed at NASA Langley Research Center, LaRC -CP1 and LaRC -CP2, are noted for being optically transparent, resistant to radiation, and soluble in the imide form. These materials may be used to make transparent, thin polymer films for building large space reflector/collector inflatable antennas, solar arrays, radiometers, etc. Structures such as these require large area, seamless films produced via spin casting or spray coating the soluble imide on a variety of substrates. The ability of the soluble imide to wet and spread over the mandrel or casting substrate is needed information for processing these structures with minimum waste and reprocessing, thereby, reducing the production costs. The wettability of a liquid is reported as the contact angle of the solid/liquid system. This fairly simple measurement is complicated by the porosity and the amount of contamination of the solid substrate. This work investigates the effect of inherent viscosity, concentration of polyimide solids, and solvent type on the wettability of various curing surfaces.

Miner, Gilda A.↗

Crystallization of a Neptunyl Oxalate Hydrate from Solutions Containing Np V and the Uranyl Peroxide Nanocluster U 60 Ox 30

Uranyl peroxide nanoclusters are an evolving family of materials with potential applications throughout the nuclear fuel cycle. While several studies have investigated their interactions with alkali and alkaline earth metals, no studies have probed their interactions with the actinide elements. This work describes a system containing U 60 Ox 30 , [((UO 2 )(O 2 )) 60 (C 2 O 4 ) 30 ] 60- , and neptunium(V) as a function of neptunium concentration. Ultra-small and small angle X-ray scattering were used to observe these interactions in the aqueous phase, and X-ray diffraction was used to observe solid products. The results show that neptunium induces aggregation of U 60 Ox 30 when the neptunium concentration is ≤ 10 mM, whereas (NpO 2 ) 2 C 2 O 4 ·6H 2 O(cr) and studtite ultimately form at 15–25 mM neptunium. Finally, the latter result suggests that neptunium coordinates with the bridging oxalate ligands in U 60 Ox 30 , leaving metastable uranyl peroxide species in solution, and is an important finding given the potential application of uranyl peroxide nanoclusters in the recycling of used nuclear fuel.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Ablating Ion Velocity Distributions in Short-Pulse-Heated Solids via X-Ray Doppler Shifts

Solids ablate under laser irradiation, but experiments have not previously characterized the initiation of this process at ultrarelativistic laser intensities. Here, we present first measurements of bulk ion velocity distributions as ablation begins, captured as a function of depth via Doppler-shifted x-ray line emission from two viewing angles. Bayesian analysis indicates that bulk ions are either nearly stationary or flowing outward at the plasma sound speed. The measurements quantitatively constrain the laser-plasma ablation mechanism, suggesting that a steplike electrostatic potential structure drives solid disassembly.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Single Ion Conducting Hairy Nanoparticle Additive to Improve Cycling Stability of Solid Polymer Electrolytes

The development of a solid electrolyte that can impede dendrite growth while still maintaining an appropriate level of conductivity is essential for improving performance of solid-state Li-ion battery. In this paper, we report the synthesis of single Li-ion conducting hairy nanoparticle (NP) materials that improved the cycling stability of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI)-doped poly(ethylene oxide) (PEO) solid electrolyte without significant reduction in conductivity. To unveil mechanisms leading to improved cycling stability, several characterization techniques including broadband dielectric spectroscopy, differential scanning calorimetry, small angle X-ray scattering, transmission electron microscopy, and shear rheology were used to study properties of polymer composites (PC) with added hairy NPs. It was found that hairy NPs influenced the Li/electrolyte interface and improved mechanical properties of bulk composites, all of which contributed to homogenous Li plating and stripping. The improved performance has been found in composites with concentrations of 4.8 and 9.1 weight % of added hairy NPs, which enabled Li cycling stability at 0.2 mA cm–2 critical current density (>300 h) that was otherwise not possible in either PEO-LiTFSI alone or PEO-LiTFSI composites containing a polymer identical to that attached to hairy NPs. Based on the discovered ability of hairy NP to influence bulk and interfacial properties of solid electrolyte, their use as additives is expected to be equally effective in reducing dendrite formation in other electrolytes relevant for the design of solid-state battery.

25 ENERGY STORAGE↗

Observation of spin-momentum locked surface states in amorphous Bi 2 Se 3

Crystalline symmetries have played a central role in the identification and understanding of quantum materials. Here we investigate whether an amorphous analogue of a well-known three-dimensional strong topological insulator has topological properties in the solid state. We show that amorphous Bi 2 Se 3 thin films host a number of two-dimensional surface conduction channels. Our angle-resolved photoemission spectroscopy data are consistent with a dispersive two-dimensional surface state that crosses the bulk gap. Spin-resolved photoemission spectroscopy shows this state has an anti-symmetric spin texture, confirming the existence of spin-momentum locked surface states. We discuss these experimental results in light of theoretical photoemission spectra obtained with an amorphous topological insulator tight-binding model, contrasting it with alternative explanations. In conclusion, the discovery of spin-momentum locked surface states in amorphous materials opens a new avenue to characterize amorphous matter and triggers the search for an overlooked subset of quantum materials outside of current classification schemes.

36 MATERIALS SCIENCE↗

One-bond 13 C– 13 C spin-coupling constants in saccharides: a comparison of experimental and calculated values by density functional theory using solid-state 13 C NMR and X-ray crystallography

Methyl aldohexopyranosides were 13 C-labeled at contiguous carbons, crystallized, and studied by single-crystal X-ray crystallography and solid-state 13 C nuclear magnetic resonance (NMR) spectroscopy to examine the degree to which density functional theory (DFT) can calculate one-bond 13C–13C spin-coupling constants ( 1 J CC ) in saccharides with sufficient accuracy to permit their use in MA'AT analysis, a newly-reported hybrid DFT/NMR method that provides probability distributions of molecular torsion angles in solution (Zhang et al., J. Phys. Chem. B, 2017, 121, 3042–3058; Meredith et al., J. Chem. Inf. Model., 2022, 62, 3135–3141). Experimental 1 J CC values in crystalline samples of the doubly 13 C-labeled compounds were measured by solid-state 13 C NMR and compared to those calculated from five different DFT models: (1) 1 J CC values calculated from single structures identical to those observed in crystalline samples by X-ray crystallography (all atom refinement); (2) 1 J CC values calculated from the single structures in (1) but after Hirshfeld atom refinement (HAR); (3) 1 J CC values calculated from the single structures in (1) after DFT-optimization of hydrogen atoms only; and (4 and 5) 1 J CC values calculated in rotamers of torsion angle θ 2 (C1–C2–O2–O2H) or ω(C4–C5–C6–O6) from which either specific or generalized parameterized equations were obtained and used to calculate 1 J CC values in the specific θ 2 or ω rotamers observed in crystalline samples. Good qualitative agreement was observed between calculated 1 J CC values and those measured by solid-state 13 C NMR regardless of the DFT model, but in no cases were calculated 1 J CC values quantitative, differing (over-estimated) on average by 4–5% from experimental values. These findings, and those reported recently from solution NMR studies (Tetrault et al., J. Phys. Chem. B 2022, 126, 9506–9515), indicate that improvements in DFT calculations are needed before calculated 1 J CC values can be used directly as reliable constraints in MA'AT analyses of saccharides in solution.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Biomolecular complex viewed by dynamic nuclear polarization solid-state NMR spectroscopy

Solid-state nuclear magnetic resonance (ssNMR) is an indispensable tool for elucidating the structure and dynamics of insoluble and non-crystalline biomolecules. The recent advances in the sensitivity-enhancing technique magic-angle spinning dynamic nuclear polarization (MAS-DNP) have substantially expanded the territory of ssNMR investigations and enabled the detection of polymer interfaces in a cellular environment. This article highlights the emerging MAS-DNP approaches and their applications to the analysis of biomolecular composites and intact cells to determine the folding pathway and ligand binding of proteins, the structural polymorphism of low-populated biopolymers, as well as the physical interactions between carbohydrates, proteins, and lignin. Furthermore, these structural features provide an atomic-level understanding of many cellular processes, promoting the development of better biomaterials and inhibitors. It is anticipated that the capabilities of MAS-DNP in biomolecular and biomaterial research will be further enlarged by the rapid development of instrumentation and methodology.

36 MATERIALS SCIENCE↗

A Woven Supramolecular Metal‐Organic Framework Comprising a Ruthenium Bis(terpyridine) Complex and Cucurbit[8]uril: Enhanced Catalytic Activity toward Alcohol Oxidation

Abstract The self‐assembly of a diamondoid woven supramolecular metal–organic framework wSMOF‐1 has been achieved from intertwined [Ru(tpy) 2 ] 2+ (tpy=2,2′,6′,2′′‐terpyridine) complex M1 and cucurbit[8]uril (CB[8]) in water, where the intermolecular dimers formed by the appended aromatic arms of M1 are encapsulated in CB[8]. wSMOF‐1 exhibits ordered pore periodicity in both water and the solid state, as confirmed by a combination of 1 H NMR spectroscopy, UV‐vis absorption, isothermal titration calorimetry, dynamic light scattering, small angle X‐ray scattering and selected area electron diffraction experiments. The woven framework has a pore aperture of 2.1 nm, which allows for the free access of both secondary and primary alcohols and tert ‐butyl hydroperoxide (TBHP). Compared with the control molecule [Ru(tpy) 2 ]Cl 2 , the [Ru(tpy) 2 ] 2+ unit of wSMOF‐1 exhibits a remarkably higher heterogeneous catalysis activity for the oxidation of alcohols by TBHP in n ‐hexane. For the oxidation of 1‐phenylethan‐1‐ol, the yield of acetophenone was increased from 10 % to 95 %.

Zhang, Yun‐Chang↗

Aerodynamic investigations on a 0.004 scale model MCR 0074 baseline space shuttle launch vehicle at Mach numbers between 0.6 and 4.96

A test of a 0.004-scale MCR 0074 Baseline Launch Configuration Space Shuttle model was conducted in the NASA-MSFC 14 x 14-inch Trisonic Wind Tunnel (MSFC TWT 566). The objective of the test was to determine the effects of model parametric variations on aerodynamic static stability characteristics over a Mach number range from 0.6 to 4.96. Angles-of-attack from minus 10 deg to plus 10 deg at 0 deg sideslip and angles-of-sideslip from minus 10 deg to plus 10 deg at minus 5 deg, 0 deg, and plus 5 deg angle-of-attack were investigated. The basic configuration investigated was the integrated vehicle consisting of the orbiter, and external tank, and two solid rocket boosters. It was designated 03T9S3.

Ramsey, P.↗

Aerodynamic characteristics of MSFC model 454 of the 142 inch solid rocket booster tested in the LeRC 10 foot SWT at Mach numbers of 2.0 and 2.7 (SA6F)

A 2.112 percent scale Space Shuttle Solid Rocket Booster (SRB) was tested in a ten foot, supersonic wind tunnel. The test Mach numbers were 2.0 and 2.7. Test angles of attack were from minus 5 degrees to plus 185 degrees. The Reynolds numbers ranged from 0.514 to 2.81 million per foot. Test roll angles were 0, 22.5, 45, 90, and 135 degrees. The following configurations were tested: (1) SRB without external protuberances, (2) SRB with an electrical tunnel and a thrust attachment structure, (3) SRB with two engine shroud strakes, (4) SRB with eight engine shroud strakes, and (5) SRB with an electrical tunnel, thrust attachment structure, eight engine shroud strakes, and separation motors.

Johnson, J. D.↗

Experimental study of main rotor/tail rotor/airframe interactions in hover. Volume 1: Text and figures

To assist in identifying and quantifying the relevant parameters associated with the complex topic of main rotor/fuselage/tail rotor interference, a model scale hover test was conducted in the Model Rotor Hover Facility. The test was conducted using the basic model test rig, fuselage skins to represent a UH-60A BLACK HAWK helicopter, 4 sets of rotor blades of varying geometry (i.e., twist, airfoils and solidity) and a model tail rotor that could be relocated to give changes in rotor clearance (axially, laterally, and vertically), can't angle and operating model (pusher or tractor). The description of the models and the tests, data analysis and summary (including plots) are included. The customary system of units gas used for principal measurements and calculations. Expressions in both SI units and customary units are used with the SI units stated first and the customary units afterwords, in parenthesis.

Balch, D. T.↗