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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49

Visualizing nanoscale 3D compositional fluctuation of lithium in advanced lithium-ion battery cathodes

The distribution and concentration of lithium in Li-ion battery cathodes at different stages of cycling is a pivotal factor in determining battery performance. Non-uniform distribution of the transition metal cations has been shown to affect cathode performance; however, the Li is notoriously challenging to characterize with typical high-spatial-resolution imaging techniques. Here, for the first time, laser–assisted atom probe tomography is applied to two advanced Li-ion battery oxide cathode materials—layered Li 1.2 Ni 0.2 Mn 0.6 O 2 and spinel LiNi 0.5 Mn 1.5 O 4 —to unambiguously map the three dimensional (3D) distribution of Li at sub-nanometer spatial resolution and correlate it with the distribution of the transition metal cations (M) and the oxygen. The as-fabricated layered Li 1.2 Ni 0.2 Mn 0.6 O 2 is shown to have Li-rich Li 2 MO 3 phase regions and Li-depleted Li(Ni 0.5 Mn 0.5 )O 2 regions while in the cycled layered Li 1.2 Ni 0.2 Mn 0.6 O 2 an overall loss of Li and presence of Ni rich regions, Mn rich regions and Li rich regions are shown in addition to providing the first direct evidence for Li loss on cycling of layered LNMO cathodes. The spinel LiNi 0.5 Mn 1.5 O 4 cathode is shown to have a uniform distribution of all cations. These results were additionally validated by correlating with energy dispersive spectroscopy mapping of these nanoparticles in a scanning transmission electron microscope. Thus, we have opened the door for probing the nanoscale compositional fluctuations in crucial Li-ion battery cathode materials at an unprecedented spatial resolution of sub-nanometer scale in 3D which can provide critical information for understanding capacity decay mechanisms in these advanced cathode materials.

36 MATERIALS SCIENCE↗

INTERSTELLAR DUST PROPERTIES OF M51 FROM AKARI MID-INFRARED IMAGES

Using mid-infrared (MIR) images of four photometric bands of the Infrared Camera on board the AKARI satellite, S7 (7 μm), S11 (11 μm), L15 (15 μm), and L24 (24 μm), we investigate the interstellar dust properties of the nearby pair of galaxies M51 with respect to their spiral arm structure. The arm and interarm regions are defined based on a spatially filtered stellar component model image and we measure the arm/interarm contrast for each band. The contrast is lowest in the S11 image, which we interpret as meaning that among the four AKARI MIR bands, the S11 image best correlates with the spatial distribution of dust grains including colder components. On the other hand, the L24 image, with the highest contrast, traces warmer dust heated by star forming activity. The surface brightness ratio between the bands, i.e., color, is measured over the disk of the main galaxy, M51a, at 300 pc resolution. We find that the distribution of S7/S11 is smooth and traces the global spiral arm pattern well while L15/S11 and L24/S11 peak at individual H II regions. This result indicates that the ionization state of polycyclic aromatic hydrocarbons (PAHs) is related to the spiral structure. Comparison with observational data and dust models also supports the importance of the variation in the PAH ionization state within the M51a disk. However, the mechanism driving this variation is not yet clear from the currently available datasets. Another suggestion from the comparison with the models is that the PAH fraction in the total dust mass is higher than previously estimated.

79 ASTRONOMY AND ASTROPHYSICS↗

The effect of spatial and temporal wet-troposphere fluctuations on connected element interferometry

Numerical integrations of the structure function of tropospheric inhomogeneities have been performed to assess the impact of water vapor fluctuations on connected element interferometry (CEI). The expectation value of the RMS troposphere error for a differential spacecraft-quasar observation is derived by integrating the spatial refractivity structure function along raypaths to both the spacecraft and quasar from two spatially separated sites. Correlations between the tropospheric conditions at the two sites, which can become significant for short baseline observations, are fully accounted for in this calculation. Temporal effects are treated by assuming a frozen-flow model in which a fixed spatial distribution blows over both sites. Two nominal observation scenarios are considered, along with variations to study the dependence of the resultant differential troposphere errors on baseline length, observation time, source separation angle, and elevation. Consecutive differential observations are found to be almost completely uncorrelated, implying that averaging many repeated differential observations can quickly reduce the troposphere error.

Edwards, C. D.↗

North Polar Radiative Flux Variability from 2002 Through 2014

NASA's Clouds and the Earth's Radiant Energy System (CERES) project produces the SYN1Deg data product. SYN1deg provides global, 1deg gridded, hourly estimates of Top of Atmosphere (TOA) (CERES observations and calculations) and atmospheric and surface radiative flux (calculations). Examples of 12 year North Polar averages of some variables are shown to the right. Given recent interest in polar science we focus here on TOA and Surface validation of calculated irradiant fluxes. TOA upward longwave irradiance calculations match the CERES observations well both spatially and temporally with correlations remaining strong through PC 6. Compare SYN1Deg Calculations & Meteorological Teleconnections. TOA reflected shortwave irradiance calculations match the CERES observations well both spatially and temporally with correlations remaining string through PC 7. Comparing SYN1Deg calculations to teleconnection patterns requires expanding the area to 30N for EOF analyses. Correlating the Principal Components of various variables to teleconnection time series indicates which variable is most highly correlated with which teleconnection signal. The tables indicate the Pacific North American Oscillation is most correlated to the OLR EOF 1, and the North American Oscillation is correlated most closely to surface LW flux down EOF 1.

Rutan, David↗

Hybrid vision activities at NASA Johnson Space Center

NASA's Johnson Space Center in Houston, Texas, is active in several aspects of hybrid image processing. (The term hybrid image processing refers to a system that combines digital and photonic processing). The major thrusts are autonomous space operations such as planetary landing, servicing, and rendezvous and docking. By processing images in non-Cartesian geometries to achieve shift invariance to canonical distortions, researchers use certain aspects of the human visual system for machine vision. That technology flow is bidirectional; researchers are investigating the possible utility of video-rate coordinate transformations for human low-vision patients. Man-in-the-loop teleoperations are also supported by the use of video-rate image-coordinate transformations, as researchers plan to use bandwidth compression tailored to the varying spatial acuity of the human operator. Technological elements being developed in the program include upgraded spatial light modulators, real-time coordinate transformations in video imagery, synthetic filters that robustly allow estimation of object pose parameters, convolutionally blurred filters that have continuously selectable invariance to such image changes as magnification and rotation, and optimization of optical correlation done with spatial light modulators that have limited range and couple both phase and amplitude in their response.

Juday, Richard D.↗

Spatial Distortion of Vibration Modes via Magnetic Correlation of Impurities

Long wavelength vibrational modes in the ferromagnetic semiconductor Ga 0.91 M n0.09 As are investigated using time resolved x-ray diffraction. At room temperature, we measure oscillations in the x-ray diffraction intensity corresponding to coherent vibrational modes with well-defined wavelengths. When the correlation of magnetic impurities sets in, we observe the transition of the lattice into a disordered state that does not support coherent modes at large wavelengths. Our measurements point toward a magnetically induced broadening of long wavelength vibrational modes in momentum space and their quasilocalization in the real space. More specifically, long wavelength vibrational modes cannot be assigned to a single wavelength but rather should be represented as a superposition of plane waves with different wavelengths. Lastly, our findings have strong implications for the phonon-related processes, especially carrier-phonon and phonon-phonon scattering, which govern the electrical conductivity and thermal management of semiconductor-based devices.

36 MATERIALS SCIENCE↗

Spatial Instabilities, Homogeneities and Proximity Effects: Highly Correlated Metals

We have developed a superconducting scanning tunneling microscope (S-STM) which is a direct and local probe of the pair wave function of superconducting materials via the Josephson effect and quasiparticle spectra via scanning tunneling spectroscopy (STS). The novel feature of this device is a superconducting tip (Pb with an Ag capping layer) in close proximity to a superconducting sample to form a superconductor-insulator-superconductor (SIS) tunnel junction. The operation of this S-STM has been verified in the observation of Josephson tunneling between the tip and different sample systems including Pb films and NbSe 2 . At the experimental base temperature (T=2.1K) and large junction normal resistance (R N > 10 4 Ω) the phase is not locked in the washboard potential, but is excited thermally to be diffusive.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Dissipation and particle energization in moderate to low beta turbulent plasma via PIC simulations

Here, we simulate decaying turbulence in electron-positron pair plasmas using a fully-kinetic particle-in-cell (PIC) code. We run two simulations with moderate-to-low plasma β (the ratio of thermal pressure to magnetic pressure). The energy decay rate is found to be similar in both cases. The perpendicular wave-number spectrum of magnetic energy shows a slope between ${k}_{\perp }^{-1.3}$ and ${k}_{\perp }^{-1.1}$, where the perpendicular (⊥) and parallel (∥) directions are defined with respect to the magnetic field. The particle kinetic energy distribution function shows the formation of a non-thermal feature in the case of lower plasma β, with a slope close to E-1. The correlation between thin turbulent current sheets and Ohmic heating by the dot product of electric field (E) and current density (J) is investigated. By heating the parallel E∥ centerdot J∥ term dominates the perpendicular E⊥ centerdot J⊥ term. Regions of strong E∥ centerdot J∥ are spatially well-correlated with regions of intense current sheets, which also appear correlated with regions of strong E∥ in the low β simulation, suggesting an important role of magnetic reconnection in the dissipation of low β plasma turbulence.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Large gradients via correlation in random parameterized quantum circuits

Scaling of variational quantum algorithms to large problem sizes requires efficient optimization of random parameterized quantum circuits. For such circuits with uncorrelated parameters, the presence of exponentially vanishing gradients in cost function landscapes is an obstacle to optimization by gradient descent methods. In this work, we prove that reducing the dimensionality of the parameter space by utilizing circuit modules containing spatially or temporally correlated gate layers can allow one to circumvent the vanishing gradient phenomenon. Here, examples are drawn from random separable circuits and asymptotically optimal variational versions of Grover's algorithm based on the quantum alternating operator ansatz. In the latter scenario, our bounds on cost function variation imply a transition between vanishing gradients and efficient trainability as the number of layers is increased toward $\mathcal{O}\left({2}^{n/2}\right)$, the optimal oracle complexity of quantum unstructured search.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Data–Driven Velocity Model Evaluation Using K–Means Clustering

In this work, we develop a data-driven clustering method to evaluate a velocity model using surface wave velocity dispersion. This is done by first computing theoretical dispersion curves for 1-D velocity profiles of all the grid locations and then splitting the resulting dispersion curves into a certain number of groups via the K-means clustering. The observed dispersion curves are also clustered following the same procedure and the velocity model is assessed by comparing the spatial patterns obtained for the observed and synthetic data sets. The method is applied to evaluate two community velocity models in southern California, CVM-S4.26 and CVM-H15.1, using phase velocity maps derived for 3–16 s Rayleigh waves. We found a good correlation in the spatial distribution of clusters between the result of CVM-S4.26 and that of the observed data, suggesting that the CVM-S4.26 fits the observed dispersion maps better than the CVM-H15.1 in terms of features extracted from the clustering analysis.

58 GEOSCIENCES↗

Dark Energy Survey year 1 results: Galaxy clustering for combined probes

We measure the clustering of DES year 1 galaxies that are intended to be combined with weak lensing samples in order to produce precise cosmological constraints from the joint analysis of large-scale structure and lensing correlations. Two-point correlation functions are measured for a sample of 6.6×10 5 luminous red galaxies selected using the redMaGiC algorithm over an area of 1321 square degrees, in the redshift range 0.15 z /(1+z)=0.017. We quantify and correct spurious correlations induced by spatially variable survey properties, testing their impact on the clustering measurements and covariance. We demonstrate the sample’s robustness by testing for stellar contamination, for potential biases that could arise from the systematic correction, and for the consistency between the two-point auto- and cross-correlation functions. We show that the corrections we apply have a significant impact on the resultant measurement of cosmological parameters, but that the results are robust against arbitrary choices in the correction method. We find the linear galaxy bias in each redshift bin in a fiducial cosmology to be b(σ 8 /0.81)| z=0.24 =1.40±0.07, b(σ 8 /0.81)| z=0.38 =1.60±0.05, b(σ 8 /0.81)| z=0.53 =1.60±0.04 for galaxies with luminosities L/L * >0.5, b(σ 8 /0.81)| z=0.68 =1.93±0.04 for L/L * >1 and b(σ 8 /0.81)| z=0.83 =1.98±0.07 for L/L * >1.5, broadly consistent with expectations for the redshift and luminosity dependence of the bias of red galaxies. We show these measurements to be consistent with the linear bias obtained from tangential shear measurements.

79 ASTRONOMY AND ASTROPHYSICS↗

Spatiotemporal modeling of ecological and sociological predictors of West Nile virus in Suffolk County, NY, mosquitoes

Abstract Suffolk County, New York, is a locus for West Nile virus ( WNV ) infection in the American northeast that includes the majority of Long Island to the east of New York City. The county has a system of light and gravid traps used for mosquito collection and disease monitoring. In order to identify predictors of WNV incidence in mosquitoes and predict future occurrence of WNV , we have developed a spatiotemporal Bayesian model, beginning with over 40 ecological, meteorological, and built‐environment covariates. A mixed‐effects model including spatially and temporally correlated errors was fit to WNV surveillance data from 2008 to 2014 using the R package “R‐INLA,” which allows for Bayesian modeling using the stochastic partial differential equation ( SPDE ) approach. The integrated nested Laplace approximation ( INLA ) SPDE allows for simultaneous fitting of a temporal parameter and a spatial covariance, while incorporating a variety of likelihood functions and running in R statistical software on a home computer. We found that land cover classified as open water and woody wetlands had a negative association with WNV incidence in mosquitoes, and the count of septic systems was associated with an increase in WNV . Mean temperature at two‐week lag was associated with a strong positive impact, while mean precipitation at no lag and one‐week lag was associated with positive and negative impacts on WNV , respectively. Incorporation of spatiotemporal factors resulted in a marked increase in model goodness‐of‐fit. The predictive power of the model was evaluated on 2015 surveillance results, where the best model achieved a sensitivity of 80.9% and a specificity of 77.0%. The spatial covariate was mapped across the county, identifying a gradient of WNV prevalence increasing from east to west. The Bayesian spatiotemporal model improves upon previous approaches, and we recommend the INLA SPDE methodology as an efficient way to develop robust models from surveillance data to develop and enhance monitoring and control programs. Our study confirms previously found associations between weather conditions and WNV and suggests that wetland cover has a mitigating effect on WNV infection in mosquitoes, while high septic system density is associated with an increase in WNV infection.

54 ENVIRONMENTAL SCIENCES↗

4D Imaging of ZnO-Coated Nanoporous Al 2 O 3 Aerogels by Chemically Sensitive Ptychographic Tomography: Implications for Designer Catalysts

The 3D chemical structure (4D spectromicroscopy) of nanoporous Al 2 O 3 aerogels coated with ZnO by atomic layer deposition (ALD) was studied by multienergy scanning transmission X-ray microscopy. These materials are representative of a class of designer catalysts in which the nanoporous support is prepared separately from the active catalyst material, which is subsequently introduced by ALD, thereby allowing independent optimization of the morphology, chemistry, and spatial distribution of the support and catalyst. The samples studied were prepared by Ga ion and Xe plasma focused ion beam (FIB) milling as well as drop casting from water suspension. Zn L and Al K edge spectra of six samples with three different ZnO loadings were measured to investigate how loading and different sample preparation methods affect the 3D distribution of the ZnO and Al 2 O 3 . Scanning transmission X-ray microscopy (STXM) and ptychographic imaging at two energies each at the Zn L 3 and Al K edge were measured. The ptychography data were analyzed by using the SHARP reconstruction code to generate quantitative 2D chemical maps of the Al 2 O 3 and the ZnO. The STXM and ptychography maps were then measured at a sequence of tilt angles, covering up to 160° of rotation. The 3D structure of the ZnO and Al 2 O 3 was derived from the tilt series data by tomographic reconstruction using a compressed sensing algorithm. A twodimensional spatial resolution (half-period) of 6 nm, measured by Fourier ring correlation, and a 3D spatial resolution (half-period) of 9 nm, measured by Fourier shell correlation, were achieved when using the COSMIC beamline at the Advanced Light Source (ALS). The results show that for all of the ZnO loadings studied there is nonuniform coverage of the ZnO on the Al 2 O 3 aerogel framework. In addition, we found that both FIB methods create sample artifacts, although the distortion was less with Xe plasma than Ga ion FIB.

36 MATERIALS SCIENCE↗

High spatial resolution neutron imaging of lithium-ion batteries: Correlating microstructure and lithium transport

Thick electrodes for lithium-ion batteries can increase the overall energy density, but increasing the electrode thickness introduces charge transport limitations. These limitations may be mitigated through proper electrode structuring. Here, high spatial resolution neutron imaging was used to understand the correlation between microstructure and lithium transport in lithium-ion anodes. Batteries with distinct graphite anode microstructures were produced and studied with high spatial resolution in operando neutron radiography to observe the effects of structure on transport. High spatial resolution neutron computed tomography was performed following in operando neutron radiography. X-ray computed tomography and scanning electron microscopy were used to observe the finer scale anode structure to complement neutron imaging. Solvent-free anodes containing a tightly-packed layered structure confined lithium movement close to the separator. This structure limited capacity, but supported better rate capability. Conversely, a more open pore structure in the wet cast anodes yielded higher capacity with reduced rate capability. Together, these results show that lithium distributions can be controlled by the macroscopic structure of the electrodes, the microstructural pore network, and the microscale active areas that support electrochemical reactions. Furthermore, multimodal imaging applying the complementary strengths of neutron and X-ray methods is shown as a tool for advancing battery design.

25 ENERGY STORAGE↗

THE EFFECT OF INTERPLANETARY SCINTILLATION ON EPOCH OF REIONIZATION POWER SPECTRA

Interplanetary Scintillation (IPS) induces intensity fluctuations in small angular size astronomical radio sources via the distortive effects of spatially and temporally varying electron density associated with outflows from the Sun. These radio sources are a potential foreground contaminant signal for redshifted HI emission from the Epoch of Reionization (EoR) because they yield time-dependent flux density variations in bright extragalactic point sources. Contamination from foreground continuum sources complicates efforts to discriminate the cosmological signal from other sources in the sky. In IPS, at large angles from the Sun applicable to EoR observations, weak scattering induces spatially and temporally correlated fluctuations in the measured flux density of sources in the field, potentially affecting the detectability of the EoR signal by inducing non-static variations in the signal strength. In this work, we explore the impact of interplanetary weak scintillation on EoR power spectrum measurements, accounting for the instrumental spatial and temporal sampling. We use published power spectra of electron density fluctuations and parameters of EoR experiments to derive the IPS power spectrum in the wavenumber phase space of EoR power spectrum measurements. The contrast of IPS power to expected cosmological power is used as a metric to assess the impact of IPS. We show that IPS has a spectral structure different from power from foregrounds alone, but the additional leakage into the EoR observation parameter space is negligible under typical IPS conditions, unless data are used from deep within the foreground contamination region.

79 ASTRONOMY AND ASTROPHYSICS↗

Evaluating and Quantifying the Climate-Driven Interannual Variability in Global Inventory Modeling and Mapping Studies (GIMMS) Normalized Difference Vegetation Index (NDVI3g) at Global Scales

Satellite observations of surface reflected solar radiation contain informationabout variability in the absorption of solar radiation by vegetation. Understanding thecauses of variability is important for models that use these data to drive land surface fluxesor for benchmarking prognostic vegetation models. Here we evaluated the interannualvariability in the new 30.5-year long global satellite-derived surface reflectance index data,Global Inventory Modeling and Mapping Studies normalized difference vegetation index(GIMMS NDVI3g). Pearsons correlation and multiple linear stepwise regression analyseswere applied to quantify the NDVI interannual variability driven by climate anomalies, andto evaluate the effects of potential interference (snow, aerosols and clouds) on the NDVIsignal. We found ecologically plausible strong controls on NDVI variability by antecedent precipitation and current monthly temperature with distinct spatial patterns. Precipitation correlations were strongest for temperate to tropical water limited herbaceous systemswhere in some regions and seasons 40 of the NDVI variance could be explained byprecipitation anomalies. Temperature correlations were strongest in northern mid- to-high-latitudes in the spring and early summer where up to 70 of the NDVI variance was explained by temperature anomalies. We find that, in western and central North America,winter-spring precipitation determines early summer growth while more recent precipitation controls NDVI variability in late summer. In contrast, current or prior wetseason precipitation anomalies were correlated with all months of NDVI in sub-tropical herbaceous vegetation. Snow, aerosols and clouds as well as unexplained phenomena still account for part of the NDVI variance despite corrections. Nevertheless, this study demonstrates that GIMMS NDVI3g represents real responses of vegetation to climate variability that are useful for global models.

interference↗

Perceiving the coherent movements of spatially-separated features

When a partially-occluded object is represented in an image, it is defined by a set of spatially-separated features that may be registered at different spatial scales. To understand the image, human vision must organize these fragmented optical features into common and distinct object surfaces. Although the common fate of moving features often is considered a primary source of reliable information for image segmentation, little is known of the visual system's capacity to discriminate the coherent relative movements of spatially-separated features. In a series of experiments, observers viewed elements whose movements were correlated (direction and magnitude) or were uncorrelated. Our results indicate that observers can discriminate the two types of movement about as well as they can detect any movement at all. Moreover, the ability to perceive coherent movements is maintained under a variety of conditions including differences in the elements' spatial frequency content, spatial position and contrast, and temporal phase shifts between the spatially-correlated displacements. These results suggest that coherent relative motion may be a fundamental source of information exploited by vision, despite considerable variability in the spatial and temporal characteristics of the individual features.

Mowafy, Lyn↗

Spatial variations in ac susceptibility and microstructure for the YBa2Cu3O(7-x) superconductor and their correlation with room-temperature ultrasonic measurements

The spatial (within-sample) uniformity of superconducting behavior and microstructure in YBa2Cu3O(7-x) specimens over the pore fraction range of 0.10 to 0.25 was examined. The viability of using a room-temperature, nondestructive characterization method (ultrasonic velocity imaging) to predict spatial variability was determined. Spatial variations in superconductor properties were observed for specimens containing 0.10 pore fraction. An ultrasonic velocity image constructed from measurements at 1 mm increments across one such specimen revealed microstructural variation between edge and center locations that correlated with variations in alternating-current shielding and loss behavior. Optical quantitative image analysis on sample cross-sections revealed pore fraction to be the varying microstructural feature.

Roth, Don J.↗