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All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

Reflectance Spectroscopy and Lunar Sample Science: Finally a Marriage After Far Too Long an Engagement

Inferences about the igneous and impact evolution of planetary bodies are based upon spectral remote sensing of their surfaces. However, it is not the rocks of a body that are seen by the remote sensing, but rather the regolith, that may contain small pieces of rock but also many other phases as well. Indeed, recent flybys of objects even as small as asteroid Ida have shown that these objects are covered by a regolith. Thus, spectral properties cannot be directly converted into information about the igneous history of the object. It is imperative to fully understand the nature of the regolith, particularly its finer fraction termed "soil," to appreciate the possible effects of "space weathering" on the reflectance spectra. We have initiated a study of our nearest, regolith-bearing body, the Moon, as "ground truth" for further probes of planetary and asteroidal surfaces. the foundation for remote chemical and mineralogical analyses lies in the physics underlying optical absorption and the linking of spectral properties of materials measured in the laboratory to well understood mineral species and their mixtures. From this statement, it is obvious that there should be a thorough integration of the material science of lunar rocks and soils with the remote-sensing observations. That is, the lunar samples returned by the Apollo missions provide a direct means for evaluation of spectral characteristics of the Moon. However, this marriage of the remote-sensing and lunar sample communities has suffered from a prolonged unconsummated betrothal, nurtured by an obvious complacency by both parties. To make more direct and quantitative links between soil chemistry/mineralogy and spectral properties, we have initiated a program to (1) obtain accurate characterization of the petrography of lunar soils (in terms relevant to remote analyses), coupled with (2) measurement of precise reflectance spectra, with testing and use of appropriate analytical tools that identify and characterize individual mineral and glass components. It is the finest-sized fractions of the bulk lunar soil that dominate the observed spectral signatures.

Taylor, Lawrence A.↗
NASA NTRS2010

Extraterrestrial Amino Acids in the Almahata Sitta Meteorite

Amino acid analysis of a meteorite fragment of asteroid 2008 TC3 called Almahata Sitta was carried out using reverse-phase liquid chromatography coupled with UV fluorescence detection and time-of-flight mass spectrometry (LC-FD/ToF-MS) as part of a sample analysis consortium. LC-FD/ToF-MS analyses of hot-water extracts from the meteorite revealed a complex distribution of two- to seven-carbon aliphatic amino acids and one- to three-carbon amines with abundances ranging from 0.5 to 149 parts-per-billion (ppb). The enantiomeric ratios of the amino acids alanine, R-amino-n-butyric acid (beta-ABA), 2-amino-2-methylbutanoic acid (isovaline), and 2-aminopentanoic acid (norvaline) in the meteorite were racemic (D/L approximately 1), indicating that these amino acids are indigenous to the meteorite and not terrestrial contaminants. Several other non-protein amino acids were also identified in the meteorite above background levels including alpha-aminoisobutyric acid (alpha-AIB), 4-amino-2- methylbutanoic acid, 4-amino-3-methylbutanoic acid, and 3-, 4-, and 5-aminopentanoic acid. The total abundances of isovaline and alpha-AIB in Almahata Sitta are 1000 times lower than the abundances of these amino acids found in the CM carbonaceous chondrite Murchison. The extremely low abundances and unusual distribution of five carbon amino acids in Almahata Sitta compared to Cl, CM, and CR carbonaceous chondrites may reflect extensive thermal alteration of amino acids on the parent asteroid by partial melting during formation or subsequent impact shock heating. It is also possible that amino acids were synthesized by catalytic reactions on the parent body after asteroid 2008 TC3 cooled to lower temperatures.

Glavin, Daniel P.↗
NASA NTRS1988

Part 1: Aspects of lithospheric evolution on Venus. Part 2: Thermal and collisional histories of chondrite parent bodies

The geological evolution of distinctly different kinds of solar system objects is addressed. Venus has been observed over the past decade by orbital radars on both American and Soviet spacecraft. These surface measurements provide clues to the structure and evolution of the lithosphere. The parent bodies of chondritic meteorites, thought to resemble asteroids, represent the other end of the size spectrum of terrestrial objects. Their early thermal and collisional histories may be constrained by the chemical and textural record preserved in meteorite samples. Impact craters on Venus have been observed by the Soviet Venera 15/16 spacecraft. A formalism is presented by which the size-frequency distribution of impact craters may be used to estimate upper bounds on the mean global rates of volcanic resurfacing and lithospheric recycling on that planet over the past several hundred million years. The impact crater density reported from Venera observations, if valid for the entire Venus surface, indicates a mean volcanic flux no greater than 2 cu km/y, corresponding to a maximum average rate of resurfacing of about 4 km/b.y. For the lowest estimated mean crater retention age of the surface of Venus imaged by Venera 15/16, the rate of lithospheric recycling on Venus does not exceed 1.5 sq km/y. Ordinary chondrite meteorites show textural and chemical patterns indicative of varying intensities of thermal metamorphism. The conventional onion-shell model, which envisions highly metamorphosed material in the core and less intensely heated rocks near the surface, predicts an inverse relation between peak temperature and cooking rate, but none has been observed. A metamorphosed-planetesimal model is devised to explain this discrepancy, whereby heating occurs in planetesimals a few kilometers in radius which then accrete to form 100-km-radius parent bodies. Cooling rates are then randomly controlled by burial depth. Thermal and collisional constraints are examined, and the model is found to be applicable only to highly insulating Al-26-rich planetesimals that remain closely aggregated upon accretion. An alternative model is presented, in which onion-shell parent bodies are collisionally fragmented during metamorphism and then gravitationally reassembled. If reassembly times are short, then cooling rates would be determined by burial depth in the reaccreted parent body. This model, unlike previous ones, can explain both coherent and incoherent cooling of Breccia clasts by collisions during or after metamorphism, respectively.

Grimm, Robert E.↗
NASA NTRS2000

Amino Acid Chemistry as a Link Between Small Solar System Bodies and Carbonaceous Chondrites

Establishing chemical links between meteorites and small solar system bodies, such as comets and asteroids, provides a tool for investigating the processes that occurred during the formation of the solar system. Carbonaceous meteorites are of particular interest, since they may have seeded the early Earth with a variety of prebiotic organic compounds including amino acids, purines and pyrimidines, which are thought to be necessary for the origin of life. Here we report the results of high-performance liquid chromatography (HPLC) based amino acid analyses of the acid-hydrolyzed hot water extracts from pristine interior pieces of the CI carbonaceous chondrites Orgueil and Ivuna and the CM meteorites Murchison and Murray. We found that the CI meteorites Orgueil and Ivuna contained high abundances of beta-alanine and glycine, while only traces of other amino acids like alanine, alpha-amino-n-butryic acid (ABA) and alpha-aminoisobutyric acid (AIB) were detected in these meteorites. Carbon isotopic measurements of beta-alanine and glycine in Orgueil by gas chromatography combustion-isotope ratio mass spectrometry clearly indicate an extraterrestrial origin of these amino acids. The amino acid composition of Orgueil and Ivuna was strikingly different from the CM chondrites Murchison and Murray. The most notable difference was the high relative abundance of B-alanine in Orgueil and Ivuna compared to Murchison and Murray. Furthermore, AIB, which is one of the most abundant amino acids found in Murchison and Murray, was present in only trace amounts in Orgueil and Ivuna. Our amino acid data strongly suggest that the CI meteorites Orgueil and Ivuna came from a different type of parent body than the CM meteorites Murchison and Murray, possibly from an extinct comet. It is generally thought that carbonaceous meteorites are fragments of larger asteroidal bodies delivered via near Earth objects (NEO). Orbital and dynamic studies suggest that both fragments of main belt asteroids and comets replenish the NEO population, therefore extinct comets may contribute up to half of all NEO's. A comparison of an amino acid analysis of a returned NEO sample to CI and CM carbonaceous chondrites would help establish a link between small solar system bodies and meteorites. Based on our amino acid measurements of CI and CM chondrites, amino acid chemistry can be included as an additional set of criteria to constrain the nature of meteorite parent bodies.

Glavin, Daniel P.↗
NASA NTRS2004

Radioisotope Electric Propulsion Missions Utilizing a Common Spacecraft Design

A study was conducted that shows how a single Radioisotope Electric Propulsion (REP) spacecraft design could be used for various missions throughout the solar system. This spacecraft design is based on a REP feasibility design from a study performed by NASA Glenn Research Center and the Johns Hopkins University Applied Physics Laboratory. The study also identifies technologies that need development to enable these missions. The mission baseline for the REP feasibility design study is a Trojan asteroid orbiter. This mission sends an REP spacecraft to Jupiter s leading Lagrange point where it would orbit and examine several Trojan asteroids. The spacecraft design from the REP feasibility study would also be applicable to missions to the Centaurs, and through some change of payload configuration, could accommodate a comet sample-return mission. Missions to small bodies throughout the outer solar system are also within reach of this spacecraft design. This set of missions, utilizing the common REP spacecraft design, is examined and required design modifications for specific missions are outlined.

Fiehler, Douglas↗
NASA NTRS2006

LAD-C: A large area debris collector on the ISS

The Large Area Debris Collector (LAD-C) is a 10 sq m aerogel and acoustic sensor system under development by the U.S. Naval Research Laboratory (NRL) with main collaboration from the NASA Orbital Debris Program Office at Johnson Space Center, JAXA Institute of Space and Astronautical Science (ISAS), Chiba University (Japan), ESA Space Debris Office, University of California at Berkeley, and University of Kent at Canterbury (UK). The U.S. Department of Defense (DoD) Space Test Program (STP) has assumed the responsibility for having the system manifested and deployed on the International Space Station (ISS), and then having it retrieved and returned to Earth after one to two years. LAD-C will attempt to utilize the ISS as a scientific platform to characterize the near-Earth meteoroid and orbital debris environment in the size regime where little data exist. In addition to meteoroid and orbital debris sample return, the acoustic sensors will record impact time, location, signal strength, and acoustic waveform data of the largest collected samples. A good time-dependent meteoroid and orbital debris flux estimate can be derived. Analysis of the data will also enable potential source identification of some of the collected samples. This dynamical link can be combined with laboratory composition analysis of impact residuals extracted from aerogel to further our understanding of orbital debris population, and the sources of meteoroids, asteroids and comets.

Liou, J.-C.↗
NASA NTRS2010

Mid-IR Spectra of HED Meteorites and Synthetic Pyroxenes: Reststrahlen Features (9-12 micron)

In an earlier study. Hamilton (2000) mapped the behavior of the 9-12 micron reststrahlen structures with composition in a suite of primarily natural terrestrial pyroxenes. Here we examine the same set of reststrahlen features in the spectra of diogenites and eucrites and place them in the context of the terrestrial samples and of a suite of well-characterized synthetic pyroxenes. The results will be useful to the interpretation of mid-IR spectra of 4 Vesta and other basaltic asteroids.

Lim, Lucy F.↗
NASA NTRS2017

Search for Primitive Matter in the Solar System

Recent astronomical observations and theoretical modeling led to a consensus regarding the global scenario of the formation of young stellar objects (YSO) from a cold molecular cloud of interstellar dust (organics and minerals) and gas that, in some cases, leads to the formation of a planetary system. In the case of our Solar System, which has already evolved for approximately 4567 Ma, the quest is to access, through the investigation of planets, moons, cometary and asteroidal bodies, meteorites, micrometeorites, and interplanetary dust particles, the primitive material that contains the key information about the early Solar System processes and its evolution. However, laboratory analyses of extraterrestrial samples, astronomical observations and dynamical models of the Solar System evolution have not brought yet any conclusive evidence on the nature and location of primitive matter in the Solar System, preventing a clear understanding of its early stages.

Libourel, G.↗
NASA NTRSDate not supplied

Carbonate Mineralogy of the C1 Clasts in Kaidun Meteorite

The Kaidun meteorite is a polymict microbreccia weighing approximately 850 g that fell in the People's Republic of South Yemen on December 3, 1980. Although the host material is CR chondrite, it is unique in that it contains many clasts of various chondritic and achondritic materials. Chondritic clasts include EH3-5, EL3, C1, C2, CM1, CM2, CV3, and ordinary chondrite-related materials. Achondrites include a high-Ca primitive achondrite, fragments of alkali-rich differentiated materials, and an aubrite-like clasts [1]. In this study, we focused on C1 materials. There is plenty of evidence that aqueous alteration in the carbonaceous chondrite clasts in Kaidun occurred primarily on their parent bodies before accumulation to a Kaidun body/ Therefore, observations of the C1 materials, which are highly aqueously altered, can provide quantitative constraints on the geologic history of their asteroid parent bodies. In addition, although the lack of petrological features can make the classification of C1 material more difficult, recent studies and analysis of new meteorite fall and returned samples continue to emphasize the diversity of C1 materials.

K Ogiya↗
NASA NTRS2012

Search for Olivine Spectral Signatures on the Surface of Vesta

The occurrence of olivines on Vesta were first postulated from traditional petrogenetic models which suggest the formation of olivine as lower crustal cumulates. An indirect confirmation is given by their presence as a minor component in some samples of diogenite meteorites, the harzburgitic diogenites and the dunitic diogenites, and as olivine mineral clasts in howardites. Another indication for this mineral was given by interpretations of groundbased and Hubble Space Telescope observations that suggested the presence of local olivine-bearing units on the surface of Vesta. The VIR instrument onboard the DAWN mission has been mapping Vesta since July 2011. VIR acquired hyperspectral images of Vesta s surface in the wavelength range from 0.25 to 5.1 m during Approach, Survey and High Altitude Mapping (HAMO) orbits that allowed a 2/3 of the entire asteroid surface to be mapped. The VIR operative spectral interval, resolution and coverage is suitable for the detection and mapping of any olivine rich regions that may occur on the Vesta surface. The abundance of olivine in diogenites is typically lower than 10% but some samples richer in olivine are known. However, we do not expect to have extensive exposures of olivine-rich material on Vesta. Moreover, the partial overlap of olivine and pyroxene spectral signatures will make olivine difficult to detect. Different spectral parameters have been used to map olivine on extraterrestrial bodies, and here we discuss the different approaches used, and develop new ones specifically for Vesta. Our new methods are based on combinations of the spectral parameters relative to the 1 and 2 micron bands (the most prominent spectral features of Vesta surface in the visible and the infrared), such as band center locations, band depths, band areas, band area ratios. Before the direct application to the VIR data, the efficiency of each approach is evaluated by means of analysis of laboratory spectra of HED meteorites, pyroxenes, olivines and their mixtures.

Palomba, E.↗
DOE OSTI2025

Non-traditional stable isotope measurements using laser desorption Orbitrap mass spectrometry: Implications for planetary missions.

Isotopic fractionation recorded in planetary materials provides insights into physical, chemical, and/or potential biological processes occurring on Solar System bodies. As we enter into the next decades of planetary exploration, the crucial information revealed by isotopic compositions of rocky and icy samples mandates that next generation spaceflight instrumentation possess the capability to measure isotope ratios in situ with sufficient precision/accuracy to distinguish between such processes. Here, in addition to identifying and fingerprinting complex organic materials with high accuracy and ultrahigh mass resolutions, laser desorption Orbitrap™ mass spectrometry (LD-O-MS) has the capability to determine the elemental and isotopic composition of solid planetary materials such as rock, regolith, organics, ice, etc. Here, we use a space-qualified LD-O-MS instrument comprising a 266 nm ultraviolet (UV) laser and Orbitrap mass analyzer ruggedized for planetary applications to investigate the stable isotopic composition of Ti and Zn metal plates. Based on the isotopic analyses, we constrain the performance of the CORALS instrument to sub per mille (‰) level accuracy and precision for Ti and at the per mille (‰) level for Zn. An LD-O-MS instrument is a versatile instrument capable of measuring isotopic composition of a variety of planetary samples and would constitute a critical instrument in the exploration of various planetary bodies including but not limited to Moon, Mars, Enceladus and other ocean or icy worlds, Ceres and other asteroids, and comets, thereby answering several high-priority questions pertaining to the formation and evolution of our Solar System.

58 GEOSCIENCES↗
NASA NTRS1988

The Mariner Mark II program

The Mariner Mark II spacecraft is a modular design that can be inexpensively reconfigured for different missions beyond the inner solar system. The first three missions will be described. The Comet Rendezvous Asteroid Flyby mission has a February 1993 launch to comet Tempel 2. The Cassini mission has a May 1995 launch to Saturn and Titan. The third mission is a Comet Nucleus Sample Return launch in 1998.

Draper, Ronald F.↗
NASA NTRS1989

Enstatite meteorites and their parent bodies

The properties of enstatite meteorites (which are known to be comprised of the EH and EL chondrites and the aubrites) are discussed together with the nature and number of their parent bodies. It is pointed out that the bulk compositional differences in nonvolatile major elements exhibited by EH and EL chondrites in nonvolatile major elements were established by nebular rather than planetary processes. The occurrence of abundant breccias among these chondirites and a lack of clasts suggest that EH and EL chondrites represent two separate parent bodies. Aubrites are considered to represent samples from a third enstatite meteorite parent body, which may have experienced collisional break-up and gravitational reassembly of the debris. Shallowater may be a sample from yet a fourth enstatite meteorite parent body. It is suggested that, if unipolar dynamo induction by a primordial T Tauri sun was the dominant heat source that heated asteroidal-sized bodies in the early solar system, then the aubrite and Shallowater parent bodies may have melted because they were of intermediate sizes, whereas the EH and EL bodies did not melt.

Keil, Klaus↗
NASA NTRS2018

Probing the Composition of Primitive Solar System Materials with a Compact Laser Mass Spectrometer

To contribute to and complement our understanding of the processes governing the formation,distribution, and evolution of primitive materials throughout the solar system, it will be critical toform connections between broad remote sensing spectroscopic surveys, laboratorymeasurements of analogs and samples delivered to Earth, and in situ measurements of thesurface composition on future primitive body missions. Recently, a laboratory prototypeemploying resonance two-step laser mass spectrometry [Getty et al., 2012] has been coupledto a cryogenic sample stage to enable measurements of analog samples that are relevant tothese fundamental questions. Analyses of mineral-aromatic mixtures and meteorite powderswill be presented. Our goals are twofold: (1) to conduct laboratory studies on solar systemanalog, meteoritic, and potentially returned samples to elucidate composition, and (2) toprovide a compact but capable analytical instrument for discovery-driven in situ interrogationof surface chemistry on a future mission, such as to a Trojan asteroid, comet, or icy moon.

Getty, Stephanie A.↗
NASA NTRS2020

Aqueous Alteration in the Kuiper Belt: Evidence from Hydrated Interplanetary Dust Particles

Edgeworth-Kuiper belt objects (EKBOs) formed in the outer reaches of the protoplanetary disk and thus avoided much of the high tempera-ture processing experienced by bodies in the inner solar system. For this reason, they contain a wealth of information on the nature of nebular solids and the chemical conditions in the earliest solar system. Astronomical observations of EKBOs have been limited largely to the surface chemistry of the ices covering these small and difficult to observe bodies. The mineralogy of EKBO objects are poorly known, but clues regarding their mineralogical makeup come from studies of samples from short period comets (e.g. Wild2), and interplanetary dust particles (IDPs) produced by collisions in the Kuiper belt. Interplanetary dust particles from objects in the solar system (mainly comets and asteroids) spiral in to-wards the Sun under the influence of Poynting-Robertson (PR) drag forces and accumulate solar flare energetic particle tracks. Recent work has shown that the observed solar flare track densities (~1010-1011/sq.cm) in these IDPs are ~two orders of magnitude higher than expected if they were derived from main belt asteroids or Jupiter family comets and thus require an origin from outer solar system source bodies such as EKBOs. The track-rich IDPs include representatives from the two major groups of IDPs: the chondritic-porous, anhydrous IDPs and the chondritic-smooth, hydrated IDPs, although rare IDPs with mineralogies intermediate between these two groups are known. Here, we report on the mineralogy, composition, organic matter content, and isotopic characteristics of track-rich hydrated IDPs, and implications for aqueous alteration in outer solar system bodies.

Keller, L. P.↗
NASA NTRS2024

Analysis of Ryugu Fluid Inclusions: An Update

The most direct and convincing evidence for the presence of water and organic molecules on protoplanetary bodies is provided by fluid inclusions trapped in secondary minerals. Our previous work has demonstrated that early solar system fluids have survived as fluid inclusions in a Ryugu pyrrhotite crystal [2]. We hypothesize that the bulk molecular and isotopic composition of individual Ryugu fluid inclusions can be measured to provide ground truth for exploring and thermochemical modeling of the compositional and isotopic evolution of fluids in protoplanetary bodies including asteroids, comets and icy moons. This presentation is an update on our efforts to make measurements of elemental, molecular and, in particular, isotopic compositions of individual aqueous fluid inclusions in Ryugu samples. The measurements we plan will permit us to (1) understand elemental composition of the aqueous fluids present on Ryugu’s progenitor body, (2) track changes in the chemical and stable isotopic composition of altering fluids in small bodies over time, (3) verify the presence of organics in Ryugu fluids, (4) verify the reported significant CO 2 in Ryugu fluids, (5) measure O and H isotopes in preserved Ryugu fluids, (6) provide constraints on temperature range calculations for the mineralizing reactions being performed by other groups using mineral pairs, (7) measure sulfur/chloride and chloride/phosphorus ratios of Ryugu fluids. We note here that recent results from Enceladus reveal the importance of phosphorus in small body aqueous brines, indicating that our proposed research will benefit studies of all current ocean worlds.

Andrei Dolocan↗
NASA NTRS2017

Distributed Fast Motion Planning for Spacecraft Swarms in Cluttered Environments using Spherical Expansions and Sequence of Convex Optimization Problems

This paper presents a novel guidance algorithm for spacecraft swarms in an environment cluttered with many obstacles like a debris field or the asteroid belt. The objective of this algorithm is to reconfigure the swarm to a desired formation in a distributed manner while minimizing fuel and avoiding collisions among themselves and with the obstacles. The agents first use a spherical-expansion-based sampling algorithm to cooperatively explore the workspace and find paths to the desired terminal positions. Using a distributed assignment algorithm, the agents converge on an optimal assignment of the target locations in the desired formation. Then each agent generates a locally optimal trajectory from its current location to its terminal position by solving a sequence of convex optimization problems. As the agent moves along this trajectory, it receives the position of other agents and updates its trajectory to avoid collisions with other agents and the obstacles. Thus the swarm achieves the desired formation in a distributed manner while avoiding collisions. Moreover, this algorithm is computationally efficient, therefore it can be implemented onboard resource-constrained spacecraft. Simulations results show that the proposed distributed algorithm can be used by a spacecraft swarm to reconfigure a desired formation around an asteroid in a collision-free manner.

Bandyopadhyay, Saptarshi↗
NASA NTRS2017

A Probabilistic Asteroid Impact Risk Model

Asteroid threat assessment requires the quantification of both the impact likelihood and resulting consequence across the range of possible events. This paper presents a probabilistic asteroid impact risk (PAIR) assessment model developed for this purpose. The model incorporates published impact frequency rates with state-of-the-art consequence assessment tools, applied within a Monte Carlo framework that generates sets of impact scenarios from uncertain parameter distributions. Explicit treatment of atmospheric entry is included to produce energy deposition rates that account for the effects of thermal ablation and object fragmentation. These energy deposition rates are used to model the resulting ground damage, and affected populations are computed for the sampled impact locations. The results for each scenario are aggregated into a distribution of potential outcomes that reflect the range of uncertain impact parameters, population densities, and strike probabilities. As an illustration of the utility of the PAIR model, the results are used to address the question of what minimum size asteroid constitutes a threat to the population. To answer this question, complete distributions of results are combined with a hypothetical risk tolerance posture to provide the minimum size, given sets of initial assumptions. Model outputs demonstrate how such questions can be answered and provide a means for interpreting the effect that input assumptions and uncertainty can have on final risk-based decisions. Model results can be used to prioritize investments to gain knowledge in critical areas or, conversely, to identify areas where additional data has little effect on the metrics of interest.

Asteroid↗