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At least 883 records · Page 49

The Development of a PdCr Integral Weldable Strain Measurement System Based on NASA Lewis PdCr/Pt Strain Sensor for User-Friendly Elevated Temperature Strain Measurements

This report describes the development of a user friendly weldable strain gage employing the NASA Lewis PdCr/Pt wire strain sensor. The NASA sensors are pre-attached to Hastelloy X or Titanium alloy shims using name spray techniques developed under previous NASA programs. The weldable sensors are then pre-stabilized for 50 hours at 780 C in air. A weldable terminal and high temperature cable is then connected to the sensor and the assembly is pre-calibrated over the full test temperature range. Calibrated resistors are inserted into a bridge completion module at the cool end of the cable to condition the sensor in half or full bridge configuration. The sensor is attached to the structure using a common capacitive discharge spot welder. No additional high temperature stabilization or calibration is required. The resultant device is a pre-calibrated strain transducer which can be plugged into any common variety strain instrumentation.

Wnuk, S. P., Jr.↗

Contributions of Spherical Harmonics to Magnetic and Gravitational Fields

Gravitational forces are of cardinal importance in the dynamics of spacecraft; magnetic attractions sometime play a significant role also, as was the case with the Long Duration Exposure Facility, and as is now true for the first segment of Space Station Freedom. Both satellites depend on gravitational moment and a device known as a magnetic damper to stabilize their orientation. Magnetic fields are mathematically similar to gravitational fields in one important respect: each can be regarded as a gradient of a potential function that, in turn, can be described as an infinite series of spherical harmonics. Consequently, the two fields can be computed, in part, with quantities that need only be evaluated once, resulting in a savings of time when both fields are needed. The objective of this material is to present magnetic field and gravitational force expressions, and point out the terms that belong to both this is accomplished in Section 1 and 2. Section 3 contains the deductive reasoning with which one obtains the expressions of interest. Finally, examples in Section 4 show these equations can be used to reproduce others that arise in connection with special cases such as the magnetic field produced by a tilted dipole, and gravitational force exerted by an oblate spheroid. The mathematics are discussed in the context of terrestrial fields; however, by substituting appropriate constants, the results can be made applicable to fields belonging to other celestial bodies. The expressions presented here share the characteristics of algorithms set forth for computing gravitational force. In particular, computation is performed speedily by means of recursion formulae, and the expressions do not suffer from the shortcoming of a singularity when evaluated at points that lie on the polar axis.

Roithmayr, Carlos M.↗

Blended-Wing-Body Transonic Aerodynamics: Summary of Ground Tests and Sample Results

The Blended-Wing-Body (BWB) concept has shown substantial performance benefits over conventional aircraft configuration with part of the benefit being derived from the absence of a conventional empennage arrangement. The configuration instead relies upon a bank of trailing edge devices to provide control authority and augment stability. To determine the aerodynamic characteristics of the aircraft, several wind tunnel tests were conducted with a 2% model of Boeing's BWB-450-1L configuration. The tests were conducted in the NASA Langley Research Center's National Transonic Facility and the Arnold Engineering Development Center s 16-Foot Transonic Tunnel. Characteristics of the configuration and the effectiveness of the elevons, drag rudders and winglet rudders were measured at various angles of attack, yaw angles, and Mach numbers (subsonic to transonic speeds). The data from these tests will be used to develop a high fidelity simulation model for flight dynamics analysis and also serve as a reference for CFD comparisons. This paper provides an overview of the wind tunnel tests and examines the effects of Reynolds number, Mach number, pitch-pause versus continuous sweep data acquisition and compares the data from the two wind tunnels.

Carter, Melissa B.↗

FX2 advanced fogging technology - 15711

Problem statement: The need for an advanced technology that can better address potential airborne contaminants at DOE Savannah River Site 235-F. Current methods of knocking down or fixing this contamination are labor intensive, costly, and sometimes ineffective. Thus, to make exposure ALARA, the advanced fogging effort is being tested using Idaho National Laboratory's FX2 fixative agent. The FX2 fogging agent is a proprietary mixture of water, latex paint (LTX), glycerin (GLY) and sodium lauryl sulfate (SLS). Initial development began in 2006 when a DOE Small Business Innovative Research (SBIR) grant resulted in the development of a conceptual advanced capture coating fog system. This coating is shown to be excellent at reducing airborne contamination and 'fixing' particulates in place as demonstrated by Idaho National Lab. Controlling Potential Airborne Particulates: Testing capacity to knockdown airborne particulates. Evaluating ability to fix to different surfaces (e.g., glass, wood, steel, concrete, brick). Line of sight as well as non-line of sight (shadowed) locations will be tested for coverage. Adhesiveness and Coverage of Surface Area: Contact area will be placed under air pressure to attempt dislodging of dried mixture. Particle analysis utilizing ImageJ will be conducted to determine quantifiable coverage. Ignitability: Observation of the FX2's reactivity to flame and heat sources as it is being applied. Results will provide useful information for the prevention of potential hazards. Determine Shielding Properties Against Alpha Sources: Determine the shielding abilities of the FX2. Fogging agent against an alpha particle emitting point source. Evaluating Critical Properties: These properties will be evaluated to better characterize the FX2 and allow for optimal understanding of results: ASTM E1354 - Burn Rate; NFPA 296-Flashover; ASTM D2196 - Viscosity; ASTM D1331 - Surface Tension; ASTM D792 - Density. Testing Innovations: Developed by the National Institutes of Health, ImageJ is a public domain image processing program that allows for the analysis that this effort requires. Coverage: Through contrast analysis, ImageJ can be used to determine the coverage of the agent upon any of the testing surfaces. Correlations: With the feature of coverage evaluation, a relationship, and thus a graphical representation, can be made between surface coverage and radiation shielding. Future work: Engineering and manufacturing of mobile robotic fogging device. ASTM WK5394: establishing performance specifications for stabilizers to minimize migration of dispersible radioactive contamination.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Interface modified thermally stable hole transporting layer for efficient organic light emitting diodes

Electrical transport in thermally stable 2, 7-bis [N, N-bis (4-methoxy-phenyl) amino]-9, 9-spirobifluorene (MeO-Spiro-TPD) thin films has been investigated as a function of temperature and organic layer thickness. ITO/MeO-Spiro-TPD interface was found to be injection limited and has been studied in detail to find barrier height for hole injection. The thickness of tetra-fluoro-tetracyano-quinodimethane thin films were optimized to be used as hole injection buffer layer which resulted in switching of charge transport mechanism from injection limited to space charge limited conduction above a critical thickness of 3 nm. Hole mobility has been measured using transient space charge limited conduction (SCLC), field dependent SCLC, and top contact transistor characteristics. The charge carrier transport in interface modified hole only devices was analysed using Gaussian disorder model. The thermal stability of MeO-Spiro-TPD has been investigated by atomic force microscopy and X-ray diffraction studies. The study indicates a thermally stable and highly efficient hole transport material for application in organic semiconductor based devices.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Combustion stability with baffles, absorbers and velocity sensitive combustion

Analytical and computational techniques were developed to predict the stability behavior of liquid propellant rocket combustors using damping devices such as acoustic liners, slot absorbers, and injector face baffles. Models were developed to determine the frequency and decay rate of combustor oscillations, the spatial and temporal pressure waveforms, and the stability limits in terms of combustion response model parameters.

Mitchell, C. E.↗

Detector Interface for Streaming, Control, and Open-source integration (DISCO) v1.0.0

This suite consists of a multi-package ecosystem featuring detector emulators, EPICS areaDetector drivers, and remote server frameworks designed for the Advanced Light Source (ALS). Engineered for high-bandwidth devices—including VFCCD, Timepix3, Timepix4, and related pixel detectors—the software simulates hardware, wraps vendor SDKs into remote-callable servers, and integrates with open-source control systems. Key Capabilities: Distributed SDK Architecture: Server packages wrap hardware-specific SDKs, allowing areaDetector drivers to execute remote framework calls. This isolates proprietary libraries from the EPICS IOC, enhancing stability and enabling distributed computing across beamline networks. Device Support: Custom drivers for VFCCD, the Timepix family, and similar sensors optimize the data path from hardware control to high-speed transport. Full-Stack Emulation: Sophisticated emulator packages allow end-to-end pipeline testing and software development without requiring physical hardware or beam time. Integrated Workflows: Supports high-bandwidth streaming for real-time analysis and robust, metadata-rich file-based workflows (e.g., HDF5/NeXus). By standardizing interfaces across heterogeneous hardware, this suite reduces technical debt. It provides the ALS with a scalable, open-source solution to manage massive data rates within a unified control environment.

Mahl, Johannes [Lawrence Berkeley National Laborat↗

Methods for determining optical power, for power-normalizing laser measurements, and for stabilizing power of lasers via compliance voltage sensing

A method is disclosed for power normalization of spectroscopic signatures obtained from laser based chemical sensors that employs the compliance voltage across a quantum cascade laser device within an external cavity laser. The method obviates the need for a dedicated optical detector used specifically for power normalization purposes. A method is also disclosed that employs the compliance voltage developed across the laser device within an external cavity semiconductor laser to power-stabilize the laser mode of the semiconductor laser by adjusting drive current to the laser such that the output optical power from the external cavity semiconductor laser remains constant.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Acoustic radiation force on a rigid elliptical cylinder in plane (quasi)standing waves

The acoustic radiation force on a 2D elliptical (non-circular) cylinder centered on the axis of wave propagation of plane quasi-standing and standing waves is derived, based on the partial-wave series expansion (PWSE) method in cylindrical coordinates. A non-dimensional acoustic radiation force function, which is the radiation force per unit length, per characteristic energy density and per unit cross-sectional surface of the ellipse, is defined in terms of the scattering coefficients that are determined by applying the Neumann boundary condition for an immovable surface. A system of linear equations involving a single numerical integration procedure is solved by matrix inversion. Numerical simulations showing the transition from the quasi-standing to the (equi-amplitude) standing wave behaviour are performed with particular emphasis on the aspect ratio a/b, where a and b are the ellipse semi-axes, as well as the dimensionless size parameter kb (where k is the wavenumber), without the restriction to a particular range of frequencies. It is found that at high kb values > 1, the radiation force per length with broadside incidence is larger, whereas the opposite situation occurs in the long-wavelength limit (i.e., kb < 1). The results are particularly relevant in acoustic levitation of elliptical cylinders, the acoustic stabilization of liquid columns in a host medium, acousto-fluidics devices, and other particle dynamics applications to name a few. Moreover, the formalism presented here may be effectively applied to compute the acoustic radiation force on other 2D surfaces of arbitrary shape such as super-ellipses, Chebyshev cylindrical particles, or other non-circular geometries.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Surfactant Engineering and Its Role in Determining the Performance of Nanoparticulate Organic Photovoltaic Devices

The fabrication of organic photovoltaics (OPVs) from non-hazardous nanoparticulate (NP) inks offers considerable promise for the development of ecofriendly large-scale printed solar modules. However, the typical NP core-shell morphology (driven by the different donor/acceptor affinities for the surfactant used in NP synthesis) currently hinders the photovoltaic performance. As such, surfactant engineering offers an elegant approach to synthesizing a more optimal intermixed NP morphology and hence an improved photovoltaic performance. In this work, the morphology of conventional sodium dodecyl sulfate (SDS) and 2-(3-thienyl) ethyloxybutylsulfonate (TEBS)-stabilized poly(3-hexylthiophene) (P3HT) donor:phenyl-C 61 -butyric acid methyl ester (PC 61 BM) acceptor NPs is probed using scanning transmission X-ray microscopy, UV-vis spectroscopy, grazing-incidence X-ray diffraction, and scanning electron microscopy. While the SDS-stabilized NPs exhibit a size-independent core-shell morphology, this work reveals that TEBS-stabilized NPs deliver an intermixed morphology, the extent of which depends on the particle size. Consequently, by optimizing the TEBS-stabilized NP size and distribution, NP-OPV devices with a power conversion efficiency that is ~50% higher on average than that of the corresponding SDS-based NP-OPV devices are produced.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Aryl ether-free polymer electrolytes for electrochemical and energy devices

Anion exchange polymers (AEPs) play a crucial role in green hydrogen production through anion exchange membrane water electrolysis. The chemical stability of AEPs is paramount for stable system operation in electrolysers and other electrochemical devices. Given the instability of aryl ethercontaining AEPs under high pH conditions, recent research has focused on quaternized aryl ether-free variants. The primary goal of this review is to provide a greater depth of knowledge on the synthesis of aryl ether-free AEPs targeted for electrochemical devices. Synthetic pathways that yield polyaromatic AEPs include acid-catalysed polyhydroxyalkylation, metal-promoted coupling reactions, ionene synthesis via nucleophilic substitution, alkylation of polybenzimidazole, and Diels–Alder polymerization. Polyolefinic AEPs are prepared through addition polymerization, ring-opening metathesis, radiation grafting reactions, and anionic polymerization. Discussions cover structure–property–performance relationships of AEPs in fuel cells, redox flow batteries, and water and CO 2 electrolysers, along with the current status of scale-up synthesis and commercialization.

25 ENERGY STORAGE↗

Deuterium-substituted cations enhance perovskite solar cell efficiency and stability

Halide perovskite solar cells with mixed-cation compositions often face instabilities under continuous illumination due to the deprotonation of methylammonium (CH 3 NH 3 + , MA + ) cations. Here, to address this, we systematically evaluate the partial and complete deuteration of MA + cations. This approach inhibits deprotonation and degradation, reduces the formation energy of the perovskite phase, improves grain growth, passivates defects, and restrains ion migration. As a result, perovskite solar cells incorporating this deuteration strategy achieve exceptional performance, including a high fill factor (FF) of 82.6% and a power conversion efficiency (PCE) of 25.6%. Their modules with a device area of 56 cm 2 demonstrate remarkable stability, maintaining over 93.7% of their initial PCE after 1,000 h at the maximum power point under continuous illumination at 40°C. This novel deuteration strategy presents a promising approach to enhance both the efficiency and stability of perovskite solar cells.

14 SOLAR ENERGY↗

Flexible and high-performance electrochromic devices enabled by self-assembled 2D TiO 2 /MXene heterostructures

Transition metal oxides (TMOs) are promising electrochromic (EC) materials for applications such as smart windows and displays, yet the challenge still exists to achieve good flexibility, high coloration efficiency and fast response simultaneously. MXenes (e.g. Ti 3 C 2 T x ) and their derived TMOs (e.g. 2D TiO 2 ) are good candidates for high-performance and flexible EC devices because of their 2D nature and the possibility of assembling them into loosely networked structures. Here we demonstrate flexible, fast, and high-coloration-efficiency EC devices based on self-assembled 2D TiO 2 /Ti 3 C 2 T x heterostructures, with the Ti 3 C 2 T x layer as the transparent electrode, and the 2D TiO 2 layer as the EC layer. Benefiting from the well-balanced porosity and connectivity of these assembled nanometer-thick heterostructures, they present fast and efficient ion and electron transport, as well as superior mechanical and electrochemical stability. We further demonstrate large-area flexible devices which could potentially be integrated onto curved and flexible surfaces for future ubiquitous electronics.

36 MATERIALS SCIENCE↗

Stability Diagrams of a Tunnel Nanoheterostructure in the Free-Electron Approximation

One of important characteristics of a magnetic tunneling junction (MTJ) nanoheterostructure that is used as magnetic random access memory (MRAM) cell and is switched by the spin transfer torque (STT) effect is its stability diagram, which determines the range of values of the external magnetic field and applied voltage under which a cell is in one of two stable states. To numerically construct such diagrams, one usually uses the solution of the Landau–Lifshitz dynamic equation in the single-domain approximation along with phenomenological constants that determine the values of spin torque in the material. In the present paper, the problem of spin-dependent electron transfer in an MTJ structure is considered, whose solution in the free-electron approximation allows one to calculate the values of spin torque for a given material in any magnetic configuration of the system and apply them to the integration of the Landau–Lifshitz equation. The method used allows one to more precisely reproduce the shape of the stability diagram and predict the critical values of the magnetic field and voltage necessary to switch an MTJ-based MRAM cell.

79 ASTRONOMY AND ASTROPHYSICS↗

Performance of a Smart Vibration Isolator for Precision Spacecraft Instruments

Under the ARPA SMS Partnership Program for Synthesis and Processing of Smart Materials, Lockheed Missiles and Space company, Inc. has developed a demonstration prototype vibration cancelling mount using electrostrictive ceramic and shape-memory alloy actuators. Shape-memory actuators provide an adaptive-passive, self-damping support for isolation, while the electrostrictive actuators are employed to provide force and position control. The demonstration device was designed to address generic requirements for vibration stabilization of precision spacecraft instruments. It is reconfigurable to operate in any of four modes; passive isolation, active-passive isolation using force cancellation, active precision positioning, and active disturbance rejection. The presentation summarizes design of the device design and results of experimental evaluations of the device in isolation (active and passive) and positioning modes. Rejection of payload-borne disturbances is also discussed with reference to predictions from experimentally calibrated simulations. Finally, avenues for further development and refinement of the device are discussed.

Regelbrugge, Marc E.↗

Polymer Hole Transport Material Functional Group Tuning for Improved Perovskite Solar Cell Performance

As lead halide perovskites (LHPs) continue to achieve success as a light-harvesting material in perovskite solar cells (PSCs), exploring and understanding other materials in the device stack become increasingly important. Particularly, selection of suitable hole transport materials (HTMs) that demonstrate high performance and stability is imperative in the design of P-I-N PSCs. Presented here are a family of 12 structurally related polymers based on either fluorene or carbazole main chains with select aromatic side groups that introduce tunable properties for use in PSCs. How properties such as the highest occupied molecular orbital energy level, conductivity, glass-transition temperature, and wettability of the HTM affect the PSC performance is explored. Devices that incorporate the polymer HTMs perform well relative to PTAA in benchmark P-I-N PSC architectures while exhibiting similar or superior stability under accelerated aging studies. The relative synthetic simplicity and resultant performance of the HTMs in PSCs coupled with the ability to customize properties with different functional groups demonstrates the potential of this family of HTMs for a variety of LHP materials.

14 SOLAR ENERGY↗

Topology-dependent stability of vortex-antivortex structures

The non-trivial topology of magnetic structures such as vortices and skyrmions is considered as a key concept to explain the stability of those structures. The stability, dictated by non-trivial topology, provides great potential for device applications. Although it is a very critical scientific and technological issue, it is elusive to experimentally study the topology-dependent stability owing to the difficulties in establishing stably formed magnetic structures with different topologies. Here, we establish a platform for vortex-antivortex structures with different topological charges within Ni 80 Fe 20 rectangular elements thick enough to stabilize a unique three-dimensional magnetic structure with non-uniform magnetization along the thickness of the elements. The detailed magnetization configurations of the three-dimensional vortex-antivortex structures and their annihilations during their field-driven motions are investigated by utilizing magnetic transmission soft x-ray microscopy and micromagnetic simulation. We demonstrate that the stability of vortex-antivortex structures significantly depends on their topologies and the topology-dependent stability is associated with their different annihilation mechanisms. Furthermore, we believe that this work provides in-depth insight into the stability of magnetic structures and its topology dependence.

36 MATERIALS SCIENCE↗