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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Optimal model reduction and frequency-weighted extension

In this paper the quadratically optimal model reduction problem for single-input, single-output systems is considered. The reduced order model is determined by minimizing the integral of the magnitude-squared of the transfer function error. It is shown that the numerator coefficients of the optimal approximant satisfy a weighted least squares problem and, on this basis, a two-step iterative algorithm is developed combining a least squares solver with a gradient minimizer. The existence of globally optimal stable solutions to the optimization problem is established, and convergence of the algorithm to stationary values of the cost function is proved. The formulation is extended to handle the frequency-weighted optimal model reduction problem. Three examples demonstrate the optimization algorithm.

Spanos, J. T.↗
NASA NTRS2001

Production, Outflow Velocity, and Radial Distribution of H2O and OH in the Coma of Comet C/1995 O1 [Hale-Bopp] from Wide Field Imaging of OH

Observations of OH are a useful proxy of the water production rate (Q(sub H2O)) and outflow velocity (V(sub out)) in comets. We use wide field images taken on 03/28/1997 and 04/08/1997 that capture the entire scale length of the OH coma of comet C/1995O1 (Hale-Bopp) to obtain Q(sub H2O) from the model-independent method of aperture summation. We also extract the radial brightness profile of OH 3080 angstroms out to cometocentric distances of up to 10(exp 6) km using an adaptive ring summation algorithm. Radial profiles are obtained as azimuthal averages and in quadrants covering different position angles relative to the comet-Sun line. These profiles are fit using both fixed and variable velocity two-component spherical expansion models to determine VOH with increasing distance from the nucleus. The OH coma of Hale-Bopp was more spatially extended than in previous comets, and this extension is best matched by a variable acceleration of H2O and OH that acted across the entire coma, but was strongest within 1-2 x 10(exp 4) km from the nucleus. This acceleration led to VOH at 10(exp 6) km that was 2-3 times greater than that obtained from a 1P/Halleytype comet at 1 AU, a result that is consistent with gas-kinetic models, extrapolation from previous observations of OH in comets with Q(sub H2O) > 10(exp 29)/s, and radio measurements of the outer coma Hale-Bopp OH velocity profile. When the coma is broken down by quadrant, we find an azimuthal asymmetry in the radial distribution that is characterized by an increase in the spatial extent of OH in the region between the orbit-trailing and anti-sunward directions. Model fits to this area and comparison with radio OH measurements suggest greater acceleration in this region, with VOH UP to 1.5 times greater at 10(exp 6) km radial distance than elsewhere in the coma.

Harris, Walter M.↗
DOE OSTI2022

Prompt D 0 , D + , and D* + production in Pb–Pb collisions at $ \sqrt{s_{\mathrm{NN}}} $ = 5.02 TeV

The production of prompt D 0 , D + , and D* + mesons was measured at midrapidity (|y| < 0.5) in Pb–Pb collisions at the centre-of-mass energy per nucleon–nucleon pair $\sqrt{s_{NN}}$ = 5.02 TeV with the ALICE detector at the LHC. The D mesons were reconstructed via their hadronic decay channels and their production yields were measured in central (0–10%) and semicentral (30–50%) collisions. The measurement was performed up to a transverse momentum (p T ) of 36 or 50 GeV/c depending on the D meson species and the centrality interval. For the first time in Pb–Pb collisions at the LHC, the yield of D 0 mesons was measured down to p T = 0, which allowed a model-independent determination of the p T -integrated yield per unit of rapidity (dN/dy). A maximum suppression by a factor 5 and 2.5 was observed with the nuclear modification factor (R AA ) of prompt D mesons at p T = 6–8 GeV/c for the 0–10% and 30–50% centrality classes, respectively. The D-meson RAA is compared with that of charged pions, charged hadrons, and J/ψ mesons as well as with theoretical predictions. The analysis of the agreement between the measured R AA , elliptic (v 2 ) and triangular (v 3 ) flow, and the model predictions allowed us to constrain the charm spatial diffusion coefficient D s . Furthermore the comparison of R AA and v 2 with different implementations of the same models provides an important insight into the role of radiative energy loss as well as charm quark recombination in the hadronisation mechanisms.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1989

The winds of high luminosity late-type bright stars

The occurrence and characteristics of the Fe II line asymmetries were studied to determine the radial dependence of the wind velocity for each star. The dependence of the Fe II profiles on spectral type and luminosity class and thus the variation of the velocity fields with stellar type was also investigated. This allows the generality of the results reported for alpha Ori by Carpenter (1984b) to be judged. In addition, new atomic data was used along with observations of the C II (UV 0.01) multiplet to estimate N(sub e) in the stellar winds. Measures of relative Fe II fluxes can be used in a probability-of-escape model to determine the opacity and hydrogen column density versus height in the chromosphere of each star. Finally, analysis of the fluorescent Fe II lines (pumped by Ly alpha) near 2507 A will yield estimates of the intrinsic stellar Ly alpha flux that cannot be measured directly because of interstellar and circumstellar absorption. One important goal of the effort was to acquire high resolution spectra of the whole 2300 to 3200 A region of 13 luminous K and M stars as a data base that will be enormously valuable in planning observations with the Hubble Space Telescope High Resolution Spectrograph. It is also proposed to follow up the recent discovery of significant variations in the Fe II chromospheric emission line profiles from the M-giant Gamma Cru for the purpose of determining the underlying cause of the variations.

Stencel, Robert E.↗
NASA NTRS1990

A rough-surface thermophysical model for airless planets

A model for determining diurnal temperatures in spherical-section depressions and which encompasses both subsurface heat-flow and direct and scattered sunlight effects is presently applied to the disk-integrated thermal emission of a rough planetary surface with nonzero thermal inertia. Attention is given to the variation with roughness and thermal inertia of the beaming parameter eta, which characterizes zero-phase thermal emission by comparison with a smooth, nonrotating body and is almost independent of albedo for a given surface roughness. The thermal phase curve of Ceres is noted to be well matched by the model features of (1) prograde rotation, (2) 44-deg rms surface slope, and (3) a thermal inertia that is 30 percent of the lunar value.

Spencer, John R.↗
DOE OSTI2022

Hanford Waste Treatment Plant LAB Facility Stack Effluent Monitoring: Sampling Probe Location Qualification Evaluation

The Waste Treatment Plant laboratory (LAB) facility stack monitor locations were qualified using scale model stacks to mitigate the risk of identifying that sampling locations do not meet the qualification criteria on the full-scale stack. As required by the American National Standards Institute/Health Physics Society (ANSI/HPS) N13.1-1999 standard, the scale model and its sampling location were geometrically similar to the actual stack and the Reynolds numbers for both the actual and model stacks were >10,000. An additional criterion is that the product of the hydraulic diameter and mean velocity (DV) of the full-scale stack must be between 1/6 DV and 6 DV of the scale model stack tests. Verification tests of the LAB stacks were performed at normal operating conditions. The minimum 1/6 DV value, along with the maximum 6 DV value from the scale model testing determines the range of conditions for which the full-scale stack may be operated and remain in compliance with the stack verification criterion. Based on these DV values, the corresponding stack flow rates for each of the LAB stacks are 625 to 47,237 scfm for LB-C2, 1,704 to 103,131 scfm for LB-S1, and 467 to 18,088 scfm for LB-S2. The remaining criteria for the stack verification to be considered valid involve the flow angle and velocity uniformity results. First, the flow angle at the full-scale stack must be =20°. Second, the velocity uniformity at the full-scale stack must be =20% coefficient of variance (COV). Finally, the velocity uniformity results for the actual and scale model stack tests must agree within 5% COV. These criteria were met through the full-scale stack tests at the LAB facility. Flow angle results were primarily less than 10 degrees, except for the LB-C2 Fan A results, which were an average of 17.6 degrees; all flow angle results were within the =20° criterion. The velocity uniformity results for each test condition averaged between 1.5 and 3.5% COV, which were all within the range of the target %COV values from the scale model tests. Based on these stack verification test results, the three LAB filtered exhaust stack sampling locations meet the qualification criteria provided in the ANSI/HPS N13.1-1999 standard for all fan operating configurations. This includes single-fan as well as dual-fan operations for LB-C2, each of the dual-fan operating conditions for LB-S1, and each single-fan operating condition for LB-S2. Further changes to the system configuration or operating conditions that are outside the bounds described in this report may require additional tests or analyses to determine compliance with the standard.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

GLAD-M35: a joint P and S global tomographic model with uncertainty quantification

We present our third and final generation joint P and S global adjoint tomography (GLAD) model, GLAD-M35, and quantify its uncertainty based on a low-rank approximation of the inverse Hessian. Starting from our second-generation model, GLAD-M25, we added 680 new earthquakes to the database for a total of 2160 events. New P-wave categories are included to compensate for the imbalance between P- and S-wave measurements, and we enhanced the window selection algorithm to include more major-arc phases, providing better constraints on the structure of the deep mantle and more than doubling the number of measurement windows to 40 million. Two stages of a Broyden–Fletcher–Goldfarb–Shanno (BFGS) quasi-Newton inversion were performed, each comprising five iterations. With this BFGS update history, we determine the model’s standard deviation and resolution length through randomized singular value decomposition.

58 GEOSCIENCES↗
DOE OSTI2022

Constrained model calibration of grain structure dependent spall dynamics in shock-loaded tantalum

Here, we perform a gas gun experiment by shock loading tantalum samples of varying grain structures to assess the suitability of a numerical model for simulating spall behavior. The observed differences in spall strength, as well spallation and re-compression history, are not captured in uncalibrated hydrodynamic simulations. An optimization is performed on the Johnson spall model to determine the best parameters that fit the observed trends. Linear stability analysis is employed to motivate bounds on those parameters. Herein, optimized simulations agree well with the experimental results, reproducing pullback depth and recompression timescales across the different samples tested. Further, the observed pullback time of the single crystal sample was found to imply, via the stability analysis, a percolation threshold in good agreement with the theoretical value for a body centered cubic lattice. Therefore, the combined linear stability and percolation analysis shows promise and may be applied to other materials with diverse microstructures. Collectively, the findings demonstrate that the model is suitable for reproducing spall-induced free surface behavior across various microstructures, but also points to caution in using model coefficients for uncalibrated microstructures.

58 GEOSCIENCES↗
DOE OSTI2020

Assessment of Precipitating Marine Stratocumulus Clouds in the E3SMv1 Atmosphere Model: A Case Study from the ARM MAGIC Field Campaign

This paper presents a process-oriented evaluation of precipitating stratocumulus and its transition to cumulus in version 1 of the Energy Exascale Earth System Model (E3SMv1) using comprehensive case-study observations from a field campaign of the Atmospheric Radiation Measurement program (ARM). The E3SMv1 single-column model (SCM) of the marine boundary layer and its low clouds and precipitation are compared to observations including subcloud drizzle retrievals from a combination of Doppler radar and lidar backscatter measurements. Additionally, the SCM is also compared to a large-eddy simulation (LES) of the same case. The combination of advanced remote sensing observations and LES is a powerful framework to evaluate the physical parameterizations of large-scale models. Given the observed large-scale environment, the E3SMv1 SCM realistically represents the evolution of clouds and boundary layer structure during the stratocumulus-to-cumulus transition. The model well simulates the liquid water path and its diurnal cycle in the stratocumulus period as well as the two-layer vertical thermodynamic structure and lower cloud fraction in the transition period. E3SMv1’s success in simulating the cloud in the stratocumulus period permitted examination of its precipitation processes. Here problems were identified with E3SMv1 producing an unrealistically small subcloud precipitation fraction, an unrealistic double peak in the vertical profiles of precipitation mass, and drizzle that evaporates too close to the surface. Further model diagnostics determined that these unrealistic characteristics resulted from an overly long microphysics time step and an unrealistic parameterization of the precipitation fraction. These results imply that careful consideration of these issues is needed in order to better simulate precipitation processes in marine stratocumulus.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Hanford Waste Treatment Plant Low Activity Waste Facility Stack Effluent Monitoring - Sampling Probe Location Qualification Evaluation

The Hanford Tank Waste Treatment and Immobilization Plant low activity waste (LAW) facility stack monitor locations were qualified using scale model stacks to mitigate the risk of identifying that sampling locations do not meet the qualification criteria on the full-scale stack. As required by the American National Standards Institute/Health Physics Society (ANSI/HPS) N13.1-1999 standard, the scale model and its sampling location were geometrically similar to the actual stack and the Reynolds numbers for both the actual and model stacks were >10,000. An additional criterion is that the product of the hydraulic diameter and mean velocity (DV) of the full-scale stack must be between 1/6 DV and 6 DV of the scale model stack tests. Verification tests of the LAW stacks were performed at normal operating conditions. The minimum 1/6 DV value, along with the maximum 6 DV value from the scale model testing determines the range of conditions for which the full-scale stack may be operated and remain in compliance with the stack verification criterion. Based on these DV values, the corresponding stack flow rates for each of the LAW stacks are 815–55,758 scfm for LV-S1, 980–112,078 scfm for LV-S2, 264–22,901 scfm for LV-S3, and 981–79,832 scfm for LV-C2. The remaining criteria for the stack verification to be considered valid involve the flow angle and velocity uniformity results. First, the flow angle at the full-scale stack must be =20°. Second, the velocity uniformity at the full-scale stack must be =20% coefficient of variance (COV). Finally, the velocity uniformity results for the actual and scale model stack tests must agree within 5% COV. These criteria were met through the full-scale stack tests at the LAW facility. Flow angle results were primarily less than 10°, except for one LV-S2 Fan A result, which was 13.2°; all flow angle results were within the =20° criterion. The velocity uniformity results for each test condition ranged between 1.5 COV and 9.2% COV, which were all within the range of the target % COV values from the scale model tests. Based on these stack verification test results, the four LAW filtered exhaust stack sampling locations meet the qualification criteria provided in the ANSI/HPS N13.1-1999 standard for all fan operating configurations. This includes single-fan operating conditions for LV-S1 and LV-S2, dual-fan operations for LV-S3 at both the continuous air monitor and record sampler locations, and both the single-fan as well as the dual-fan operations for LV-C2. Further changes to the system configuration or operating conditions that are outside the bounds described in this report may require additional tests or analyses to determine compliance with the standard.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1996

Methyl bromide: ocean sources, ocean sinks, and climate sensitivity

The oceans play an important role in the geochemical cycle of methyl bromide (CH3Br), the major carrier of O3-destroying bromine to the stratosphere. The quantity of CH3Br produced annually in seawater is comparable to the amount entering the atmosphere each year from natural and anthropogenic sources. The production mechanism is unknown but may be biological. Most of this CH3Br is consumed in situ by hydrolysis or reaction with chloride. The size of the fraction which escapes to the atmosphere is poorly constrained; measurements in seawater and the atmosphere have been used to justify both a large oceanic CH3Br flux to the atmosphere and a small net ocean sink. Since the consumption reactions are extremely temperature-sensitive, small temperature variations have large effects on the CH3Br concentration in seawater, and therefore on the exchange between the atmosphere and the ocean. The net CH3Br flux is also sensitive to variations in the rate of CH3Br production. We have quantified these effects using a simple steady state mass balance model. When CH3Br production rates are linearly scaled with seawater chlorophyll content, this model reproduces the latitudinal variations in marine CH3Br concentrations observed in the east Pacific Ocean by Singh et al. [1983] and by Lobert et al. [1995]. The apparent correlation of CH3Br production with primary production explains the discrepancies between the two observational studies, strengthening recent suggestions that the open ocean is a small net sink for atmospheric CH3Br, rather than a large net source. The Southern Ocean is implicated as a possible large net source of CH3Br to the atmosphere. Since our model indicates that both the direction and magnitude of CH3Br exchange between the atmosphere and ocean are extremely sensitive to temperature and marine productivity, and since the rate of CH3Br production in the oceans is comparable to the rate at which this compound is introduced to the atmosphere, even small perturbations to temperature or productivity can modify atmospheric CH3Br. Therefore atmospheric CH3Br should be sensitive to climate conditions. Our modeling indicates that climate-induced CH3Br variations can be larger than those resulting from small (+/- 25%) changes in the anthropogenic source, assuming that this source comprises less than half of all inputs. Future measurements of marine CH3Br, temperature, and primary production should be combined with such models to determine the relationship between marine biological activity and CH3Br production. Better understanding of the biological term is especially important to assess the importance of non-anthropogenic sources to stratospheric ozone loss and the sensitivity of these sources to global climate change.

NASA Discipline Exobiology↗
NASA NTRS2001

Numerical Simulations of the Slingatron

The slingatron mass accelerator is described for several track configurations (shapes), and numerical simulations of this accelerating mass traversing a given track configuration are presented. The sled is modeled as a point mass that interacts with the slingatron track using both a conventional and a new empirical velocity dependent friction law. The closed loop circular slingatron was found to produce high maximum sled velocities provided the gyration angular speed is always increasing. In contrast several spiral shaped slingatron tracks reveal that high maximum sled velocities are obtainable with the gyration speed held constant. In fact, a slingatron constructed out of semi-circles is shown capable of generating high velocity sleds in such a way that no initial sled injection is necessary. Choosing the proper initial gyration phase with an empirically determined friction model allows the mass sled to gain ever-increasing velocities when placed in a semi-circle slingatron. The sled bearing pressure and its total acceleration are examined and presented.

Cooper, Gene R.↗
DOE OSTI2021

Classification and computation of extreme events in turbulent combustion

In the design of practical combustion systems, ensuring safety and reliability is an important requirement. For instance, reliably avoiding lean blowout, flame flashback or inlet unstart is critical for ensuring safe operation. Currently, the science of predicting such events is based on prior experience, limited modeling or diagnostic tools and purely statistical approaches. Even though computational and experimental tools for studying combustion devices have vastly advanced in the last three decades, the analysis of such failure events has not been pursued widely. While the use of data for model development and calibration is being widely accepted, the extension to failure events introduces numerous challenges. In particular, the focus here is on so-called data-poor problems, where the cost of generating data is extremely high and is not easily amenable to existing computational and experimental approaches. Data-poor problems are particularly relevant when related to extreme events (also called anomalous events) that can lead to catastrophic failure of the system. It is argued that transient events that describe such failure can have different causal mechanisms. To develop the scientific inference process, a classification of such problems is used to determine specific modeling paths as well as computational tools needed. Research opportunities in the emerging field of extreme event prediction are highlighted in order to identify critical and immediate needs.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2020

Comparative Study of Hydrology and Icemelt in Three Nepal River Basins Using the Glacio-Hydrological Degree-Day Model (GDM) and Observations From the Advanced Scatterometer (ASCAT)

An assessment of the water supply and its seasonal and annual changes over the century in the High Mountain Asia (HMA) region is of increasing interest due to its potential impact on one-sixth of the global population. In order to understand the changing hydrology and snow and ice melt, we used remotely sensed Advanced Scatterometer (ASCAT) observations of glacier melt (GM) and a distributed and gridded Glacio-hydrological Degree-day Model (GDM) in three river basins: Tamor, Trishuli and Marsyangdi. The GDM-estimated contribution of snowmelt, icemelt, rainfall and baseflow in river flows is found to be most accurate in the Trishuli River basin, with Nash-Sutcliffe efficiency (NSE) between the estimated and observed discharges of 0.81 and volume differences of -0.5%, and reasonably accurate in the Tamor River basin, with NSE of 0.69 and volume difference of -7.51%. Similarly, NSE of 0.81 and volume difference of 4.64% in Marsyangdi River basin. We find strong similarities in the timing of glacier melting using the GDM and from observations from the ASCAT GM, determining the seasonal start of glacier melting to within 6 days on average. In all basins ASCAT GM observes melting at higher elevations relative to GDM, average of 5,328 m a.s.l. Systematic differences in glacier melting area determined by modeling and satellite observations indicate ASCAT may have suboptimal resolution, view geometry and/or polarimetry for delineating glacier melting at the process-scale in complex topography, especially in the ablation zone. This is the first step in examining the remote sensing products that could potentially be incorporated into hydrologic models to increase the accuracy of the hydrologic flow as well as the ability to estimate river discharge in other basins with limited data.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2014

HEMCO v1.0: A Versatile, ESMF-Compliant Component for Calculating Emissions in Atmospheric Models

We describe the Harvard-NASA Emission Component version 1.0 (HEMCO), a stand-alone software component for computing emissions in global atmospheric models. HEMCO determines emissions from different sources, regions, and species on a user-defined grid and can combine, overlay, and update a set of data inventories and scale factors, as specified by the user through the HEMCO configuration file. New emission inventories at any spatial and temporal resolution are readily added to HEMCO and can be accessed by the user without any preprocessing of the data files or modification of the source code. Emissions that depend on dynamic source types and local environmental variables such as wind speed or surface temperature are calculated in separate HEMCO extensions. HEMCO is fully compliant with the Earth System Modeling Framework (ESMF) environment. It is highly portable and can be deployed in a new model environment with only few adjustments at the top-level interface. So far, we have implemented HEMCO in the NASA Goddard Earth Observing System (GEOS-5) Earth system model (ESM) and in the GEOS-Chem chemical transport model (CTM). By providing a widely applicable framework for specifying constituent emissions, HEMCO is designed to ease sensitivity studies and model comparisons, as well as inverse modeling in which emissions are adjusted iteratively. The HEMCO code, extensions, and the full set of emissions data files used in GEOS-Chem are available at http: //wiki.geos-chem.org/HEMCO.

GEOS-5↗
NASA NTRS2009

Modeling the Strahl in the Solar Wind Using CLUSTER/PEACE Electron Distribution Functions

We present a study of kinetic properties of the strahl electron velocity distribution functions (VDF's) in the solar wind. These are used to investigate the pitch-angle scattering and stability of the population to interactions with electromagnetic (whistler) fluctuations. The study is based on high time resolution data from the Cluster/PEACE electron spectrometer. Our study focuses on the mechanisms that control and regulate the pitch-angle and stability of strahl electrons in the solar wind; mechanisms that are not yet well understood. Various parameters are investigated such as the strahl-electron density, temperature anisotropy, and electron heat-flux. The goal is to check whether the strahl electrons are constrained by some instability (e.g., the whistler instability), or are maintained by other types of processes. The electron heat-flux and temperature anisotropy are determined by modeling the 3D-VDFs to a spectral spherical harmonic model from which the moments are obtained directly from the spectral coefficients.

Vinas, Adolfo F.↗
NASA NTRS2004

An Efficient End-To-End Model for the Kepler Photometer

The Kepler Mission is designed to characterize the frequency of Earth-sized planets in the habitable zones of solar-like stars in the solar galactic neighborhood by observing >100,000 main-sequence stars in a >100 square degree field of view (FOV) and seeking evidence of transiting planets. As part of the system engineering effort, we have developed an End-To-End Model (ETEM) of the photometer to better characterize the expected performance of the instrument and to guide us in making design trades. This model incorporates engineering information such as the point spread function, time histories of pointing offsets, operating temperature, quantization noise, the effects of shutterless readout, and read noise. Astrophysical parameters, such as a realistic distribution of stars vs. magnitude for the chosen FOV, zodiacal light, and cosmic ray events are also included. For a given set of design and operating parameters, ETEM generates pixel time series for all pixels of interest for a single CCD channel of the photometer. These time series are then processed to form light curves for the target stars and the impact of various noise sources on the combined differential photometric precision can be determined. This model is of particular value when investigating the effects of noise sources that cannot be easily subjected to direct analysis, such as residual pointing offsets, thermal drift or cosmic ray effects. This version of ETEM features extremely efficient computation times relative to the previous version while maintaining a high degree of fidelity with respect to the realism of the relevant phenomena.

performance modeling↗
DOE OSTI2025

Cloud processing of dimethyl sulfide (DMS) oxidation products limits sulfur dioxide (SO 2 ) and carbonyl sulfide (OCS) production in the eastern North Atlantic marine boundary layer

Dimethyl sulfide (DMS) is the major sulfur species emitted from the ocean. The gas-phase oxidation of DMS by hydroxyl radicals proceeds through the stable, soluble intermediate hydroperoxymethyl thioformate (HPMTF), eventually forming carbonyl sulfide (OCS) and sulfur dioxide (SO 2 ). Recent work has shown that HPMTF is efficiently lost to marine boundary layer (MBL) clouds, thus arresting OCS and SO 2 production and their contributions to new-particle formation and growth events. To date, no long-term field studies exist to assess the extent to which frequent cloud processing impacts the fate of HPMTF. Here, we present 6 weeks of measurements of the cloud fraction and the marine sulfur species methanethiol, DMS, and HPMTF made at the Atmospheric Radiation Measurement (ARM) research facility on Graciosa Island, Azores, Portugal. Using an observationally constrained chemical box model, we determine that cloud loss is the dominant sink of HPMTF in this region of the MBL during the study, accounting for 79 %–91 % of HPMTF loss on average. When accounting for HPMTF uptake to clouds, we calculate campaign average reductions in DMS-derived MBL SO 2 and OCS of 52 %–60 % and 80 %–92 % for the study period. Using yearly measurements of the site- and satellite-measured 3D cloud fraction and DMS climatology, we infer that HPMTF cloud loss is the dominant sink of HPMTF in the eastern North Atlantic during all seasons and occurs on timescales faster than what is prescribed in global chemical transport models. Accurately resolving this rapid loss of HPMTF to clouds has important implications for constraining drivers of MBL new-particle formation.

54 ENVIRONMENTAL SCIENCES↗