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At least 883 records · Page 49

Western Eisila Regio, Venus - Radar properties of volcanic deposits

The 1988 Arecibo Observatory dual-polarization radar images are presented for Western Eisila Regio, Venus. The polarization information and Pioneer-Venus Orbiter reflectivity and altimetry data are analyzed for volcanic deposits on two 400-500 km radius constructs, Sif and Gula Montes. Many of the large effusive deposits studied appear to require superposed flows or multiple vents to explain the observed progression of roughness along their length. High Fresnel reflectivity material may be present along the summit region of Gula Mons and in an embayed tessera-like region to the N. Radar-dark units on the flanks of Sif Mons are inferred to be pyroclastic deposits, but radar-dark features near the summits of both edifices are more consistent with very smooth lava flows. Higher spatial resolution Magellan data will be useful in testing these predictions.

Campbell, Bruce A.↗

Generation of macro- and microplastic databases by high-throughput FTIR analysis with microplate readers

Abstract FTIR spectral identification is today’s gold standard analytical procedure for plastic pollution material characterization. High-throughput FTIR techniques have been advanced for small microplastics (10–500 µm) but less so for large microplastics (500–5 mm) and macroplastics (> 5 mm). These larger plastics are typically analyzed using ATR, which is highly manual and can sometimes destroy particles of interest. Furthermore, spectral libraries are often inadequate due to the limited variety of reference materials and spectral collection modes, resulting from expensive spectral data collection. We advance a new high-throughput technique to remedy these problems using FTIR microplate readers for measuring large particles (> 500 µm). We created a new reference database of over 6000 spectra for transmission, ATR, and reflection spectral collection modes with over 600 plastic, organic, and mineral reference materials relevant to plastic pollution research. We also streamline future analysis in microplate readers by creating a new particle holder for transmission measurements using off-the-shelf parts and fabricating a nonplastic 96-well microplate for storing particles. We determined that particles should be presented to microplate readers as thin as possible due to thick particles causing poor-quality spectra and identifications. We validated the new database using Open Specy and demonstrated that additional transmission and reflection spectra reference data were needed in spectral libraries. Graphical abstract

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Post-flight characterization of optical system samples, thermal control samples, and detectors from LDEF experiment M0003, sub-experiments 6 and 13

Flight samples and control samples of optical and thermal control coatings have been measured for hemispheric reflectance and transmission. Data was recorded for wavelengths from .25 microns to 18 microns. The samples were exposed directly to the orbital environment, but were on the trailing edge of the LDEF satellite. Preliminary analysis shows no significant change in the reflectance or transmission values of most of the samples. Post-flight tests of avalanche photodiodes have yielded results. The tests consist of measuring the following detector parameters: breakdown voltage for set values of reverse current, responsivity vs. bias voltage, noise equivalent power, and uniformity of photoresponse. The avalanche photodiodes were mounted on the leading edge of the LDEF satellite, but were shielded from the outside by a silver-coated teflon foil cover. Small puncture holes are present in the foil, probably caused by impact of particles in orbit. For most of the detectors, there has been no significant change in noise or response.

Randall R Hodgson↗

Leaf reflectance, leaf transmittance and sky irradiance, at four sites in Panama, 2022

Paired leaf reflectance and transmittance data measured in Panama, at the Parque Natural Metropolitano (PNM), on Barro Colorado Island (BCI), at the San Lorenzo canopy crane site (SLZ), and in Gamboa, Panama from January to April 2022. Measurements were made on leaves from 57 different tree, shrub and liana species, from sunlit canopy and understory locations. Bark reflectance was also measured on the trunks of common tree species at the PNM and SLZ sites. Also included are irradiance measurements and leaf area index (LAI) from eight vertical profiles at PNM. The aim of these data was to refine our understanding of vertical trait and environmental variation in tropical forests, and to improve models which can predict leaf traits from leaf contact spectral measurements. All spectral data and metadata are presented in .csv files and complete instrument output are included in .zip folders. Protocol details are provided as pdf documents. In addition to spectral data described here, some of these samples were also used for measurement of leaf gas exchange, carbon and nitrogen content, and leaf mass per unit leaf area (LMA) these data can be cross linked using the unique sample ID and are provided in separate related data packages.

54 ENVIRONMENTAL SCIENCES↗

Custom NEON AOP reflectance mosaics and maps of shade masks, canopy water content

This mosaic of visible to shortwave infrared (VSWIR) data was derived from the assignable asset NEON AOP radiance data that was collected by LBNL’s Watershed Function SFA during the summer of 2018 (DOI: 10.15485/1617204). This atmospheric correction was completed to take into account site-specific terrain variability in the 334 km2 survey area centered around Crested Butte, CO. The atmospheric correction was completed using ACORN atmospheric correction software executed on 200 x 200 pixel kernels rather than line by line in order to capture local flight altitude conditions. Manual cloud delineation removed any small shaded areas that occurred within the data collection areas. Mosaics were developed based on preference for days that were in close timing proximity to the coincident ground campaign and with mosaicing criteria that minimized the angle between the sun and the sensor to retrieve the most consistent reflectance (min_phase_refl_tiled). Finally, we generated shade masks based on the geometry between the sun angle at time of flight, the ground surface, and the sensor. Here we provide the orthomosaiced estimated reflectance data (min_phase_refl_tiled.tif), canopy water content (wtrl), estimated atmospheric water vapor (wtrv), the observational data (obs) for this particular mosaic, the estimated visibility (vis), shade masks derived from the digital surface elevation model (shade) and the digital terrain model (shade_tch) added to the canopy height model (DOI: 10.15485/1617203), and a wavelength metadata file. Each image file is provided as a GeoTiff with internal tiling and LZW compression. These data can also be found on Google Earth Engine for extraction, download, and analysis of smaller extents (Google Earth Engine data is linked in external link table).

2018 NEON and 2025 CHESS Campaigns↗

Calibration and evaluation of AVIRIS data: Cripple Creek in October 1987

Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data were obtained over Cripple Creek and Canon City Colorado on October 19, 1987 at local noon. Multiple ground calibration sites were measured within both areas with a field spectrometer and samples were returned to the laboratory for more detailed spectral characterization. The data were used to calibrate the AVIRIS data to ground reflectance. Once calibrated, selected spectra in the image were extracted and examined, and the signal to noise performance was computed. Images of band depth selected to be diagnostic of the presence of certain minerals and vegetation were computed. The AVIRIS data were extremely noisy, but images showing the presence of goethite, kaolinite and lodgepole pine trees agree with ground checks of the area.

Clark, Roger N.↗

Rotational and reflectional equivariant convolutional neural network for data-limited applications: Multiphase flow demonstration

This article deals with approximating steady-state particle-resolved fluid flow around a fixed particle of interest under the influence of randomly distributed stationary particles in a dispersed multiphase setup using convolutional neural network (CNN). The considered problem involves rotational symmetry about the mean velocity (streamwise) direction. Thus, this work enforces this symmetry using SE(3)-equivariant, special Euclidean group of dimension 3, CNN architecture, which is translation and three-dimensional rotation equivariant. This study mainly explores the generalization capabilities and benefits of a SE(3)-equivariant network. Accurate synthetic flow fields for Reynolds number and particle volume fraction combinations spanning over a range of [86.22, 172.96] and [0.11, 0.45], respectively, are produced with careful application of symmetry-aware data-driven approach.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Upper tropospheric dynamics as reflected in Nimbus-4 THIR 6.7 micron data

In order to determine if a quantifiable relationship exists between the 6.7 micron radiometric patterns observed by the Nimbus-4 temperature-humidity infrared radiometer (THIR) and tropospheric dynamics, a 10-level diagnostic model is employed. The model is used to show the spatial and temporal relationships existing between radiometrically observed water vapor patterns and conventionally derived water vapor patterns, and to examine the upper and middle tropospheric water vapor budget and associated dynamics in order to assess the causes behind the spatially- and temporally-varying water vapor radiometric patterns. A particular situation involving a confluent trough located to the lee of the Rockies over the Central United States is examined.

Rodgers, E. B.↗

Upper tropospheric dynamics as reflected in Nimbus 4 THIR 6.7-micron data

An investigation was conducted of the spatial and temporal relationships existing between the radiometrically observed water vapor patterns in cloud free areas and the conventionally derived water vapor patterns. The upper and middle tropospheric water vapor budget and the associated dynamics were examined to obtain a basis for a more definite evaluation of the significance of the Nimbus 4 radiometric 6.7-micrometer observations for the study of tropospheric dynamics in cloud free areas. A large-amplitude trough situated to the lee of the Rocky Mountains over the central U.S. between April 30 and May 1, 1970, was selected for the investigation because it best illustrated large upper tropospheric dynamic variations.

Rodgers, E. B.↗

Analysis of AIS radiometry with emphasis on determination of atmospheric properties and surface reflectance

Airborne Imaging Spectrometer data from Mono Lake, California, were studied in order to establish spectral radiance of test areas under solar illumination. The objective is to provide a method of atmospheric correction for major absorbers from the spectrometer data themselves. Crucial to the analysis is radiometric calibration of the instrument. Good agreement is found between calculated and measured radiances for uniform surface targets (beaches), but simulations of atmospheric properties with LOWTRAN lead to unreasonably low values of atmospheric precipitable water. Absorptions from carbon dioxide are not detected in the AIS data, but are strongly present in the LOWTRAN model. The apparent low contrast of all atmospheric absorption bands leads to a study of contamination from overlapping spectral orders in the AIS data. The suspected contamination is shown unambiguously to be present beyond approximately 1500 nm and consists of an extra radiance term including atmospheric bands from the delta/2 wavelength interval. A rigorous removal of the unwanted spectral contamination does not seem possible for any data taken in the rock mode. Rough estimates for tree-mode observations might be pieced together is a suitable after-the-fact radiometric claibration of the instrument can be formulated.

Conel, J. E.↗

Optical Constants of Mars Candidate Materials used to Model Laboratory Reflectance Spectra of Mixtures

Data obtained at visible and nearinfrared wavelengths by OMEGA on MarsExpress and CRISM on MRO provide definitive evidence for the presence of phyllosilicates and other hydrated phases on Mars. A diverse range of both Fe/Mg-OH and Al- OH-bearing phyllosilicates were identified including the smectites nontronite, saponite, and montmorillonite. To constrain the abundances of these phyllosilicates, spectral analyses of mixtures are needed. We report on our effort to enable the quantitative evaluation of the abundance of hydrated-hydroxylated silicates when they are contained in mixtures. Here we focus on two component mixtures of the hydrated/ hydroxylated silicates, saponite and montmorillonite (Mg- and Al-rich smectites) with each other and with two analogs for other Martian materials; pyroxene (enstatite) and palagonitic soil (an alteration product of basaltic glass, hereafter referred to as palagonite). We prepared three size separates of each end-member for study: 20-45, 63-90, and 125-150 micron. Here we focus upon mixtures of the 63-90 m size fractions.

MarsExpress and CRISM↗

Mesoscale variability of free tropospheric humidity near San Nicolas Island during FIRE

Humidity variability at the top of the marine boundary layer (MBL) and in the free troposphere was examined using a variety of measurements taken on and around San Nicolas Island (SNI) during the FIRE IFO in July, 1987. Doppler wind profiler reflectivity recorded at two minute time resolution has provided the most continuous record and detail of small scale humidity fluctuations. Rawinsonde data were available from both an island site and the research vessel Point Sur. The information extractable from these sources is somewhat limited due to the frequency of launches (3 to 4/day at SNI and 6/day on the Point Sur). Some additional data were available from instrumented aircraft although scheduling flights in the neighborhood of the island was difficult due to restrictions on the air space. Other relevant data were collected at SNI near the radar and rawinsonde launch sites. A continuous record of cloud base altitude was logged by a ceilometer. Doppler acoustic sounder (sodar) reflectivity data provided a good record of inversion height. The sodar also monitored turbulent temperature fluctuations in the MBL. A small ground station recorded hourly averages of solar irradiance and downward longwave irradiance. The analysis in progress of the various data sets for two adjacent two day periods from 11 July to 14 July is described. The earlier period was chosen because the marine inversion was unusually high and there was increased frequency of rawinsonde launches at SNI. The later period was chosen because of the significant descent with time of an elevated inversion indicated by the radar data. Throughout the four day period, but especially in the first half, the turbulent humidity structure calculated from Doppler radar reflectivity shows excellent agreement with humidity profiles evaluated from rawinsonde data.

White, A. B.↗

Goniometric and Polarized Imaging Spectroscopic Lab Measurements of Spacecraft Materials

To better characterize the spectral response of common spacecraft materials, the following laboratory measurements are presented to support the Space Situational Awareness community in the analysis of remotely sensed observational data. Of interest is classifying material reflective properties using directional reflectance spectroscopy and spatially resolved polarized imaging spectroscopy, allowing laboratory data to be applicable to ground-based optical telescope observations. The team acquired a typical CubeSat solar panel and a sample of multi-layer insulation (MLI) commonly used on spacecraft for initial measurements. The directional spectral data were collected at the Goniometer of the Rochester Institute of Technology (GRIT) laboratory with a lab and field goniometer incorporating two AnalyticalSpectral Device (ASD) spectrometers, a small Lab sphere integrating sphere also paired with an ASD spectrometer, and a Headwall micro-Hyperspec E-Series imaging spectrometer with an adjustable linear polarizer. The goniometer measures spectral bi-directional reflectance factor (BRF) data over a broad range from 350−2500 nm at 1 nm spacing with 3 nm spectral resolution in the visible and near infrared and 8 nm in the shortwave infrared. With the same spectral capabilities, the integrating sphere measures hemispherical-directional reflectance (HDR) in a 45◦-nadir configuration. The Headwall imager covers a spectral range from 400−1000 nm with 1.6 nm spectral resolution.Our initial BRF measurements show interference effects for both materials typically observed with thin films and high infrared reflectivity. In contrast, the interference effects are not present in the HDR measurements of the MLI likely due to the interference effects being averaged out over the reflecting hemisphere. Spatially resolved polarization ratio maps show variability across the materials due to the varying surface structure. We outline a plan for expanding our analysis to a broader range of materials to characterize their directional reflectance spectroscopy.

Chris H. Lee↗

Probabilistic Seismic Hazard Assessment for Azerbaijan

Probabilistic Seismic Hazard Assessments (PSHA) underpin the determination of seismic loads in most contemporary seismic provisions of building codes around the world. Modern building codes are migrating towards using the entire uniform hazard spectrum at a range of vibration periods (typically up to 4 s or 10 s) rather than a single peak value such as peak ground acceleration (PGA), thus requiring a larger range of PSHA outputs. The hazard maps in the current version of the building code of Azerbaijan (2011) are in terms of intensity and peak ground acceleration. Recognizing the need for an up-to-date seismic hazard assessment in the country, Seismic Cooperation Program (SCP) under the Lawrence Livermore National Laboratory (LLNL) undertook, in coordination with the Republican Seismic Survey Center of the Azerbaijan National Academy of Sciences and the Azerbaijan Scientific Research Institute of Construction and Architecture, a PSHA study that reflects new seismic data recorded locally and recent research conducted nationally and regionally since the last update to the building code. The PSHA framework for this project was designed to help develop a new earthquake catalogue, to incorporate a novel characterization of ground motions that specifically reflects the attenuation characteristics in the eastern Caucasus, and to generate hazard information in a form that is useful for an update of the current building code or the development of a new building code for Azerbaijan. The project also aimed to provide training and support for the local seismologists and engineers related to the seismic hazard models, probabilistic seismic hazard results and their use towards changes in the building code.

58 GEOSCIENCES↗

Sea Surface Salinity Reemergence in an Updated North Atlantic In Situ Salinity Dataset

Monthly sea surface salinity (SSS) fields are constructed from observations, using objective mapping on a 1° x 1° grid in the Atlantic between 30°S and 50°N in the 1970-2016 period in an update of the dataset of Reverdin et al. Data coverage is heterogeneous, with increased density in 2002 when Argo floats become available, high density along Voluntary Observing Ship lines, and low density south of 10°S. Using lag correlation, the seasonal reemergence of SSS anomalies is investigated between 20° and 50°N in 5° x 5° boxes during the 1993-2016 period, both locally and remotely following the displacements of the deep mixed-layer waters estimated from virtual float trajectories derived from the daily AVISO surface geostrophic currents. Although SSS data are noisy, local SSS reemergence is detected in about half of the boxes, notably in the northeast and southeast, while little reemergence is seen in the central and part of the eastern subtropical gyre. In the same period, sea surface temperature (SST) reemergence is found only slightly more frequently, reflecting the short data duration. However, taking geostrophic advection into account degrades the detection of remote SSS and even SST reemergence. When anomalies are averaged over broader areas, robust evidence of a second and third SSS reemergence peak is found in the northeastern and southeastern parts of the domain, indicating long cold-season persistence of large-scale SSS anomalies, while only a first SST reemergence is seen. Finally, an oceanic reanalysis is used to confirm that the correlation analysis indeed reflects the reemergence of subsurface salinity anomalies.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of the photochemical reflectance index in AVIRIS imagery

In this paper, we evaluate the potential for extracting the 'photochemical reflectance index' (PRI; previously called the 'physiological reflectance index') from AVIRIS data. This index, which is derived from narrow-band reflectance at 531 and 570 nm, has proven to be a useful indicator of photosynthetic function at the leaf and canopy scales. At the leaf level, PRI varies with photosynthetic capacity, radiation-use efficiency, and vegetation type (unpublished data). This finding is consistent with the hypothesis that vegetation types exhibiting chronically reduced photosynthesis during periods of stress (e.g. drought-tolerant evergreens) invest proportionally more in photoprotective processes than vegetation with high photosynthetic capacity (e.g. crops or deciduous perennials). Vertical transects in tropical and boreal forest canopies have indicated declines in PRI associated with downregulation of photosynthesis at the canopy tops under sunny, dry midday conditions (unpublished data). This reduced PRI in upper canopy levels provides a further basis for examining this signal with the 'view from above' afforded by aircraft overflights. Although many factors could confound interpretation of a subtle physiological signal at the landscape scale, we conducted a preliminary examination of PRI extracted from existing, AVIRIS imagery of Stanford University's Jasper Ridge Biological Preserve obtained on the June 2nd, 1992, overflight. The goal was to use the hyperspectral capabilities of AVIRIS to evaluate the potential of this index for obtaining useful physiological data at the landscape scale. The expectation based on leaf- and canopy-level studies was that regions containing vegetation of reduced photosynthetic capacity (e.g. chaparral or evergreen woodland) would exhibit lower PRI values than regions of high capacity (e.g. deciduous woodland).

Gamon, John A.↗

Laboratory Reflectance Spectra of 160 Minerals, 0.4 to 2.5 Micrometers

This reports provides reflectance spectra of 160 minerals in both digital and printed form. In order to demonstrate the effect of particle size on reflectance, the spectral data for 135 of the minerals are presented at three different grain sizes. These are 125-500 microns, 45-125 microns and less than 45 microns. Ancillary information is provided with each mineral spectrum, which includes the mineral name, minerology, supplier, sampling locality and our designated sample number. The purity of every mineral sample was evaluated by X-ray diffraction (XRD). The composition of certain minerals known to deviate strongly from idealized end-member compositions was determined by electron microprobe analysis. The compositional information obtained by microbe analysis and accessory minerals identified by XRD are noted with the ancillary information. In addition, the spectrum acquired from the coarsest grain size available for each sample was processed with a feature-finding algorithm to quantify the characteristics of the spectral absorption features. All the reflectance spectra presented here are provided in digital form on IBM-compatible 3.5" diskettes. Also included on diskette is a program for displaying the spectral data and searching for spectral features that runs on an IBM-compatible PC with standard VCA graphics.

reflectance spectra↗