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At least 883 records · Page 49

Extraction of Thermal Performance Values from Samples in the Lunar Dust Adhesion Bell Jar

A simulation chamber has been developed to test the performance of thermal control surfaces under dusty lunar conditions. The lunar dust adhesion bell jar (LDAB) is a diffusion pumped vacuum chamber (10-8 Torr) built to test material samples less than about 7 cm in diameter. The LDAB has the following lunar dust stimulant processing capabilities: heating and cooling while stirring in order to degas and remove absorbed water; RF air-plasma for activating the dust and for organic contaminant removal; RF H/He-plasma to simulate solar wind; dust sieving system for controlling particle sizes; and a controlled means of introducing the activated dust to the samples under study. The LDAB is also fitted with an in situ Xe arc lamp solar simulator, and a cold box that can reach 30 K. Samples of thermal control surfaces (2.5 cm diameter) are introduced into the chamber for calorimetric evaluation using thermocouple instrumentation. The object of this paper is to present a thermal model of the samples under test conditions, and to outline the procedure to extract the absorptance, emittance, and thermal efficiency from the pristine and sub-monolayer dust covered samples

Gaier, James R.↗

Extraction of Thermal Performance Values from Samples in the Lunar Dust Adhesion Bell Jar

A simulation chamber has been developed to test the performance of thermal control surfaces under dusty lunar conditions. The lunar dust adhesion bell jar (LDAB) is a diffusion pumped vacuum chamber (10(exp -8) Torr) built to test material samples less than about 7 cm in diameter. The LDAB has the following lunar dust simulant processing capabilities: heating and cooling while stirring in order to degas and remove adsorbed water; RF air-plasma for activating the dust and for organic contaminant removal; RF H/He-plasma to simulate solar wind; dust sieving system for controlling particle sizes; and a controlled means of introducing the activated dust to the samples under study. The LDAB is also fitted with an in situ Xe arc lamp solar simulator, and a cold box that can reach 30 K. Samples of thermal control surfaces (2.5 cm diameter) are introduced into the chamber for calorimetric evaluation using thermocouple instrumentation. The object of this paper is to present a thermal model of the samples under test conditions and to outline the procedure to extract the absorptance, emittance, and thermal efficiency from the pristine and sub-monolayer dust covered samples.

Gaier, James R.↗

Advanced Curation Activities at NASA: Implications for Astrobiological Studies of Future Sample Collections

The Astromaterials Acquisition and Curation Office (henceforth referred to herein as NASA Curation Office) at NASA Johnson Space Center (JSC) is responsible for curating all of NASA's extraterrestrial samples. Under the governing document, NASA Policy Directive (NPD) 7100.10F JSC is charged with curation of all extraterrestrial material under NASA control, including future NASA missions. The Directive goes on to define Curation as including documentation, preservation, preparation, and distribution of samples for re-search, education, and public outreach. Here we briefly describe NASA's astromaterials collections and our ongoing efforts related to enhancing the utility of our current collections as well as our efforts to prepare for future sample return missions. We collectively refer to these efforts as advanced curation.

McCubbin, F. M.↗

Advanced Curation Activities at NASA: Preparing to Receive, Process, and Distribute Samples Returned from Future Missions

The Astromaterials Acquisition and Curation Office (henceforth referred to herein as NASA Curation Office) at NASA Johnson Space Center (JSC) is responsible for curating all of NASA's extraterrestrial samples. Under the governing document, NASA Policy Directive (NPD) 7100.10F JSC is charged with curation of all extraterrestrial material under NASA control, including future NASA missions. The Directive goes on to define Curation as including documentation, preservation, preparation, and distribution of samples for research, education, and public outreach. Here we briefly describe NASA's astromaterials collections and our ongoing efforts related to enhancing the utility of our current collections as well as our efforts to prepare for future sample return missions. We collectively refer to these efforts as advanced curation.

McCubbin, Francis M.↗

Digital Autoradiography as a novel complementary technique for the investigation of radioactive contamination in nuclear facilities under dismantlement

The detection (location and quantification) of nuclear facilities to be dismantled possible contamination with low-range particles emitters ({sup 3}H, other low-energy β emitters, a emitters) remains a tedious and expensive task. Indeed, usual remote counters show a too low sensitivity to these non-penetrating radiations, while conventional wipe tests are irrelevant for fixed radioactivity evaluation. The only method to accurately measure activity levels consists in sampling and running advanced laboratory analyses (spectroscopy, liquid scintillation counting, pyrolysis...). Such measurements generally induce sample preparation, waste production (destructive analyses, solvents), nuclear material transportation, long durations, and significant labor mobilization. Therefore, the search for the limitation of their number and cost easily conflicts with the necessity to perform a dense screening for sampling (to maximize the representativeness of the samples), in installations of thousands of square meters (floors, wells, ceilings), plus furniture, pipes, and other wastes. To overcome this contradiction, Digital Autoradiography (D. A.) was re-routed from bio molecular research to radiological mapping of nuclear installations under dismantling and to waste and sample analysis. After in-situ exposure to the possibly-contaminated areas to investigate, commercial reusable radiosensitive phosphor screens (of a few 100 cm{sup 2}) were scanned in the proper laboratory device and sharp quantitative images of the radioactivity could be obtained. The implementation of geostatistical tools in the data processing software enabled the exhaustive characterization of concrete floors at a rate of 2 weeks / 100 m{sup 2}, at lowest costs. Various samples such as drilled cores, or tank and wood pieces, were also successfully evaluated with this method, for decisive results. Thanks to the accurate location of potential contamination spots, this approach ensures relevant and representative sampling for further laboratory analyses and should be inserted in the range of common tools used in dismantling. (authors)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Impact on quality activities of measurement systems meeting an L:1 rule

This study considers the impact of a measurement system that meets an L:1 rule on various quality activities. These activities include inspection, acceptance sampling, and control charting. A measurement system that meets a 10:1 rule performs much better than one that meets a 4:1 rule. R code is provided so that the practitioner is able to evaluate these activities to his or her particular situation.

97 MATHEMATICS AND COMPUTING↗

Preparation of novel BiVO4 nanofibers and their excellent adsorptive properties

Highlights: • Monoclinic BiVO{sub 4} nanofibers were obtained by two-step synthesis method. • BiVO{sub 4} nanofibers possessed highly effective adsorptive properties. • BiVO{sub 4} nanofibers showed higher specific surface area. • EG and NaOH promoted the formation of BiVO{sub 4} nanofibers. - Abstract: The novel BiVO{sub 4} nanofibers were firstly obtained by two-step synthesis method. Characterized by X-ray diffractometer (XRD) and scanning electron microscopy (SEM), the samples were shown to be nanofibers with monoclinic phase. The ethylene glycol (EG) and NaOH solution played an important role on their formation. Taking rhodamine B (RhB) as the removal object, the nanofibers exhibited the enhanced adsorptive activity compared with other samples. It may be due to the increase of the specific surface area, the acidic surface property of the BiVO{sub 4} nanofibers and the nature of the RhB dye. The formation mechanism of the special morphology was investigated and proposed. It is expected to provide some guidance for designing and preparing other materials for removal of organic pollutants.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

M558 radioactive tracer diffusion

This experiment was performed in Skylab 3 with two objectives in mind. First, the experimental self-diffusion coefficients for liquid zinc were to be determined in a convection-free environment. Secondly the reduction in convective mixing in earth gravity by going into the zero-gravity environment of space was to be estimated. The experiment was designed to utilize high temperatures and linear thermal gradients provided by the M518 Multipurpose Electric Furnace, and the radioactivity of zinc-65 of 245-day half-life to investigate self-diffusion in liquid zinc. The distribution of zinc-65 tracer, after melting, maintaining at soak temperature for 1 hour of soak time and then resolidifying, was obtained by sample sectioning. The concentration of activity of each section (microcurie-gram) was plotted against positions along the sample axial and radial position. Experimental data and theoretical results from solution of Fick's law of diffusion in one dimensional were compared. Samples tested on earth showed very rapid diffusion. Diffusion coefficient in unit gravity was 50 times the zero-gravity diffusion coefficient of Skylab.

Ukanwa, A. O.↗

Circular dichroism in the presence of resonant Mie scatterers

Unpolarised light propagation is considered in a circularly dichroic medium with optically isotropic Mie-particles. The degree of passed radiation polarisation is calculated under the assumption that multiple scattering in such a system occurs in the spatial diffusion regime. It is shown that introducing Mie particles into a homogeneous sample with natural optical activity can noticeably enhance the observed circular dichroism, namely, increase a difference between the intensities of right- and left-handed polarised light passed through the medium. If the first Kerker condition is fulfilled for Mie particles, then the effect can be almost ten times stronger as compared to the case of a homogeneous sample. (radiation scattering)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

A census of gas outflows in type 2 active galactic nuclei

We perform a census of ionized gas outflows using a sample of ∼23,000 type 2 active galactic nuclei (AGNs) out to z ∼ 0.1. By measuring the velocity offset of narrow emission lines, i.e., [O III] λ5007 and Hα, with respect to the systemic velocity measured from the stellar absorption lines, we find that 47% of AGNs display an [O III] line-of-sight velocity offset ≥ 20 km s{sup –1}. The fraction of the [O III] velocity offset in type 2 AGNs is comparable to that in type 1 AGNs after considering the projection effect. AGNs with a large [O III] velocity offset preferentially have a high Eddington ratio, implying that the detected velocity offsets are related to black hole activity. The distribution of the host galaxy inclination is clearly different between the AGNs with blueshifted [O III] and the AGNs with redshifted [O III], supporting the combined model of the biconical outflow and dust obscuration. In addition, for ∼3% of AGNs, [O III] and Hα show comparable large velocity offsets, indicating a more complex gas kinematics than decelerating outflows in a stratified narrow-line region.

79 ASTRONOMY AND ASTROPHYSICS↗

Preparation and electrocatalytic activity of tungsten carbide and titania nanocomposite

Graphical abstract: The electrocatalytic activity of tungsten carbide and titania nanocomposite is related to the structure, crystal phase and chemical components of the nanocomposite, and is also affected by the property of electrolyte. A synergistic effect exists between tungsten carbide and titania of the composite. Highlights: {yields} Electrocatalytic activity of tungsten carbide and titania nanocomposite with core-shell structure. {yields} Activity is related to the structure, crystal phase and chemical component of the nanocomposite. {yields} The property of electrolyte affects the electrocatalytic activity. {yields} A synergistic effect exists between tungsten carbide and titania of the composite. -- Abstract: Tungsten carbide and titania nanocomposite was prepared by combining a reduced-carbonized approach with a mechanochemical approach. The samples were characterized by X-ray diffraction, transmission electron microscope under scanning mode and X-ray energy dispersion spectrum. The results show that the crystal phases of the samples are composed of anatase, rutile, nonstoichiometry titanium oxide, monotungsten carbide, bitungsten carbide and nonstoichiometry tungsten carbide, and they can be controlled by adjusting the parameters of the reduced-carbonized approach; tungsten carbide particles decorate on the surface of titania support, the diameter of tungsten carbide particle is smaller than 20 nm and that of titania is around 100 nm; the chemical components of the samples are Ti, O, W and C. The electrocatalytic activity of the samples was measured by a cyclic voltammetry with three electrodes. The results indicate that the electrocatalytic activities of the samples are related to their crystal phases and the property of electrolyte in aqueous solution. A synergistic effect between titania and tungsten carbide is reported for the first time.

36 MATERIALS SCIENCE↗

HEMISPHERIC HELICITY TREND FOR SOLAR CYCLE 24

Using vector magnetograms obtained with the Spectro-polarimeter (SP) on board Hinode satellite, we studied two helicity parameters (local twist and current helicity) of 64 active regions that occurred in the descending phase of solar cycle 23 and the ascending phase of solar cycle 24. Our analysis gives the following results. (1) The 34 active regions of the solar cycle 24 follow the so-called hemispheric helicity rule, whereas the 30 active regions of the solar cycle 23 do not. (2) When combining all 64 active regions as one sample, they follow the hemispheric helicity sign rule as in most other observations. (3) Despite the so-far most accurate measurement of vector magnetic field given by SP/Hinode, the rule is still weak with large scatters. (4) The data show evidence of different helicity signs between strong and weak fields, confirming previous result from a large sample of ground-based observations. (5) With two example sunspots we show that the helicity parameters change sign from the inner umbra to the outer penumbra, where the sign of penumbra agrees with the sign of the active region as a whole. From these results, we speculate that both the {Sigma}-effect (turbulent convection) and the dynamo have contributed in the generation of helicity, whereas in both cases turbulence in the convection zone has played a significant role.

79 ASTRONOMY AND ASTROPHYSICS↗

Rietveld refinement and dielectric relaxation of a new rare earth based double perovskite oxide: BaPrCoNbO{sub 6}

A new rare earth based double perovskite oxide barium praseodymium cobalt niobate, BaPrCoNbO{sub 6} (BPCN) is synthesized by solid-state reaction technique. Rietveld analysis of X-ray diffraction (XRD) data shows that the compound crystallizes in a perovskite like tetragonal structure which belongs to the I4/mmm space group with lattice parameters a=b=5.6828(9) Å, c=8.063(2) Å. Structural analysis reveals 1:1 ordered arrangement for the Co{sup 2+} and Nb{sup 5+} cations over the six-coordinate B-sites of BPCN. The superlattice line (1 0 1) at 2θ=19.10° arising from the alternate ordering of Co{sup 2+} and Nb{sup 5+} sites is observed in the XRD pattern which confirms the presence of cation ordering in BPCN. Fourier transform infrared spectrum shows two phonon modes of the sample due to the antisymmetric NbO{sub 6} stretching vibration. The relaxation dynamics of the conductive process in BPCN is investigated in the temperature range 303 to 503 K and in the frequency range 100 Hz to 1 MHz using impedance spectroscopy. The relaxation mechanism of the sample in the framework of electric modulus formalism is modeled by Davidson–Cole model (DCM). The values of α (distribution of relaxation time) for the DCM varies from 0.1 to 0.3 which suggests the asymmetric distribution of relaxation time for BPCN. The activation energy of the sample, calculated from both conductivity and modulus spectra, are found to be almost the same ∼0.4 eV, which indicates that the conduction mechanism for BPCN is polaron hopping. The scaling behaviour of the imaginary part of electric modulus suggests that the relaxation follows the same mechanism at various temperatures. - Graphical abstract: Rietveld refinement plot for BPCN. Inset shows the schematic presentation of the BPCN tetragonal unit cell. The Co{sup 2+} atoms are located at the centers of the CoO{sub 6} (blue) octahedra. The Nb{sup 5+} atoms are located at the centers of the NbO{sub 6} (green) octahedra. Display Omitted - Highlights: • BaPrCoNbO{sub 6} is synthesized for the first time. • Rietveld refinement of XRD data confirms tetragonal phase. • XRD confirms the presence of cation ordering in BaPrCoNbO{sub 6}. • The activation energy is ∼0.4 eV. • The conduction mechanism for BPCN is due to polaron hopping.

36 MATERIALS SCIENCE↗

Frequent ultraviolet brightenings observed in a solar active region with solar maximum mission

Observations of the temporal behavior of ultraviolet emission from bright points within an active region of the sun are reported. Frequent and rapid brightenings in Si IV and O IV line emission are seen. The observations suggest that intermittent heating events of modest amplitude are occurring at many sites within an active region. By selecting the brightest site at any given time within an active region and then sampling its behavior in detail within a 120 s interval, it is found that about two-thirds of the samples show variations of the Si IV line intensity. The brightenings typically last about 40-60 s; intensity increases of about 20-100 percent are frequently observed. The results suggest that heating due to magnetic field reconnection within an active region is proceeding almost stochastically. Events involving only a modest release of energy occur the most frequently.

Porter, J. G.↗

Patterns of bird and bat migration along Lake Michigan and Lake Huron coastal areas

Wind energy is becoming a more important and common source of renewable energy. Coastal areas produce high winds and as a result more wind farms are being established along coastlines. These same coastal areas are also potentially migration corridors, as birds and bats avoid the risks of crossing open water (e.g. encountering inclement weather or predators without adequate cover in close proximity). Bats and birds that migrate along shorelines developed with wind turbines are at risk for turbine collisions and related fatalities (i.e., barotrauma). We examined the fall migration of bats and night flying birds at 5 sites along the Great Lakes shorelines. After standardizing habitat types, we specifically compared species use at 5 shoreline plots versus 5 plots 3 miles inland. We used an acoustic-radar sampling system between sunset and sunrise to capture species flight patterns, bird calls, and echolocative activity of bats. The radar sampling unit covered a 2-km radius, whereas the volume recorded by the acoustic unit varied by the frequency of the call. Our results showed that the flight activity of both bats and birds was highest at inland sites consistently across all sites. Acoustic activity of both bats and birds decreased over the fall migration period. Our data did not support the alternative hypothesis that the shoreline provides more intensely used fall migration corridors than inland areas for bats and night migrant birds. Our data suggest that shoreline areas may be less important as a travel corridor to bats and night-flying birds than more inland areas. Further studies should be conducted to determine if this pattern is consistent among temporal and spatial variables and consistent for further offshore. Future conservation efforts may need to critically consider inland areas in efforts to reduce risk from wind turbine fatalities. By learning the migratory habits of bats and birds, specifically whether they are using the coastline, inland pathways, or offshore routes, wind energy developers can significantly reduce negative impacts to bats and birds by siting wind turbines in non-migratory areas.

17 WIND ENERGY↗

Updated Radiological Inventory of G1 Reactor Thanks to a Strengthened Data Processing - 17271

The radiological inventory of G1 reactor is under refinement and consolidation. This reactor, located at the CEA Marcoule center in France, presents an issue for Chlorine-36 as graphite was used as moderator. The improvement of the 3D physical description and a better understanding of historical events enable the computation of activation levels thanks to a numerical model. These results are compared to old samples and more recent ones to quantify nuclide activity levels as well as their spatial distributions. In particular a spatial and statistical correction of sample bias leads to an update of the radiological inventory with an expected reduction of average activity levels. Another part of the work consists in identifying missing pieces of information and still uncertain parts of the reactor (sample analysis of activated concrete for instance) to reinforce the radiological inventory of G1 reactor. This will be the basis of future investigation works. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

LADEE UVS (UltraViolet Visible Spectrometer) and the Search for Lunar Exospheric Dust: A Detailed Spectral Analysis

The Lunar Atmosphere and Dust Environment Explorer (LADEE) executed science observations in lunar orbit spanning 2013-Oct-16- 2014-04-18 UT. LADEE's Ultraviolet/Visible Spectrometer (UVS) studies the composition and temporal variations of the tenuous lunar exosphere and dust environment, utilizing two sets of optics: a limb-viewing telescope, and a solar-viewer. The limb-viewing telescope observes illuminated dust and emitting gas species while the Sun is just behind the lunar limb. The solar viewer, with its diffuser, allows UVS to also stare directly at the solar disk as it approaches the limb, sampling progressively lower exosphere altitudes. Solar viewer "Occultation" activities occur at the lunar sunrise limb, as the LADEE spacecraft passes into the lunar night side, facing the Sun (the spacecraft orbit is near-equatorial retrograde). A loss of transmission of sunlight occurs by the occultation of dust grains along the line-of-sight. So-called "Inertial Limb" activities have the limb-viewing telescope pointed at the lit exosphere just after the Sun has set. Inertial Limb activities follow a similar progression of diminishing sampling altitudes but hold the solar elongation angle constant so the zodiacal light contribution remains constant while seeking to observe the weak lunar horizon glow. On the dark side of the moon, "Sodium Tail" activities pointed the limb-viewing telescope in the direction of the Moon's sodium tail (similar to anti-sunward), during different lunar phases. Of the UVS data sets, these show the largest excess of scattered blue light, indicative of the presence of small (approximately 100 nm) dust grains in the tail. Correlations are sought between dust in the sodium tail and meteor streams and magnetotail crossings to investigate impact- versus electrostatic-lofting. Once lofted, nanoparticles can become charged and picked up by the solar wind. The LADEE UVS Occultation, Inertial Limb, and Sodium Tail spectral datasets provide evidence of a lunar dust exosphere.

LADEE↗

Personal PM2.5 exposure among wildland firefighters working at prescribed forest burns in southeastern United States.

This study investigated occupational exposure to wood and vegetative smoke in a group of 28 forest firefighters at prescribed forest burns in a southeastern U.S. forest during the winters of 2003-2005. During burn activities, 203 individual person-day PM{sub 2.5} and 149 individual person-day CO samples were collected; during non-burn activities, 37 person-day PM{sub 2.5} samples were collected as controls. Time-activity diaries and post-work shift questionnaires were administered to identify factors influencing smoke exposure and to determine how accurately the firefighters qualitative assessment estimated their personal level of smoke exposure with discrete responses: 'none' or 'very little,' 'low,' 'moderate,' 'high,' and 'very high.' An average of 6.7 firefighters were monitored per burn, with samples collected on 30 burn days and 7 non-burn days. Size of burn plots ranged from 1-2745 acres (avg = 687.8). Duration of work shift ranged from 6.8-19.4 hr (avg = 10.3 hr) on burn days. Concentration of PM{sub 2.5} ranged from 5.9-2673 {mu}g/m{sup 3} on burn days. Geometric mean PM{sub 2.5} exposure was 280 {mu}g/m{sup 3} (95% CL = 140, 557 {mu}g/m{sup 3}, n = 177) for burn day samples, and 16 {mu}g/m{sup 3} (95% CL = 10, 26 {mu}g/m{sup 3}, n = 35) on non-burn days. Average measured PM{sub 2.5} differed across levels of the firefighters categorical self-assessments of exposure (p < 0.0001): none to very little = 120 {mu}g/m{sup 3} (95% CL = 71, 203 {mu}g/m{sup 3}) and high to very high = 664 {mu}g/m{sup 3} (95% CL = 373, 1185 {mu}g/m{sup 3}); p < 0.0001 on burn days. Time-weighted average PM{sub 2.5} and personal CO averaged over the run times of PM{sub 2.5} pumps were correlated (correlation coefficient estimate, r = 0.79; CLs: 0.72, 0.85). Overall occupational exposures to particulate matter were low, but results indicate that exposure could exceed the ACGIH{reg_sign}-recommended threshold limit value of 3 mg/m{sup 3} for respirable particulate matter in a few extreme situations. Self-assessed exposure levels agreed with measured concentrations of PM{sub 2.5}. Correlation analysis shows that either PM{sub 2.5} or CO could be used as a surrogate measure of exposure to woodsmoke at prescribed burns.

09 BIOMASS FUELS↗