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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Meeting sustainable aviation fuel policy targets through first generation corn biorefineries

This paper investigates options to produce low carbon and renewable aviation fuel through existing commercial first generation biorefineries, which could be strategic given the rapid growth of the electric vehicle market for personal mobility. We evaluate the environmental impact of retrofitting a first generation biorefinery to produce aviation fuel through chemical process simulation. The analysis investigates the potential for reducing greenhouse gas (GHG) emissions and displacing fossil fuel (petroleum-based jet kerosene) in the aviation fuel industry through using corn feedstocks in dry grind biorefineries to convert sugars to 1,4-dimethylcyclooctane (DMCO), which qualifies as renewable jet-A fuel blend and is infrastructure compatible. Further, the average life cycle GHG emissions for a baseline case and a scenario with carbon capture and storage (CCS) of fermentative CO 2 are 36 and 5g CO 2 e/MJ DMCO, respectively. Investment in CCS at the biorefinery and adoption of crop best management practices on farms are essential for mitigating the risks of induced land use change GHG emissions for existing corn biorefineries. DMCO as a low-carbon aviation fuel could be a strategic fuel product for retrofitting existing corn dry grind facilities. For aviation fuel supply, corn dry grind facilities could displace about 12% of jet fuel demand in the near term, which would meet sustainable aviation fuel policy targets. We conclude that corn-to-DMCO shows promise for near-term low-carbon fuel markets in the aviation industry and as a bridge to developing biomass-based jet fuel in the future.

09 BIOMASS FUELS↗

Unraveling the multi-step crystallization mechanism of polytetrafluoroethylene, modified polytetrafluoroethylene, and their nanocomposites with boron nitride nanobarbs: Experimental insights and theoretical analysis

The non-isothermal crystallization behavior and kinetics of polytetrafluoroethylene (PTFE) composites with boron nitride nanobarb (BNNB), a new generation nanostructure with unique surface morphology and mechanical “barbs” have been analyzed, understanding these properties is essential for their high-end applications as thermal interface materials (TIM) for microwave, 5G and microelectronic devices. The analysis of the crystallization parameters includes crystallization onset, peak and end temperatures, crystallization half-life and overall crystallinity of PTFE, modified PTFE and their BNNB composites. The results were further analyzed using theoretical models such as the combined Avrami-Ozawa model. It was found that BNNB supports crystallization in the modified PTFE but shows minimal effect on the crystallization of PTFE. Due to the limitation of the classical theoretical models used above in fully characterizing the multi-step crystallization process of PTFE, an in-depth analysis using the model-free advanced isoconversional computation was used to characterize the PTFE crystallization based on the evolution of activation energy with fractional crystallinity and for the first time with temperature. Three kinetic regions were identified in the crystallization mechanism. Here, this study investigated the molecular organization and microstructural evolution of PTFE, modified PTFE and their composites during non-isothermal crystallization using advanced X-ray scattering measurements. An insight into the changes undergone by the material's microstructural units including crystallite size and morphology, lamellar thickness and lamellar interfacial layer thickness, and crystallographic phase dynamics during non-isothermal cooling from the melt, was provided here in this work. The effect of copolymer modification of PTFE and the inclusion of pristine and functionalized BNNB (a thermally conductive and electrically insulating ceramic) are both new investigations that provide valuable knowledge for the development of materials with strong matrix-nanofiller interaction and guidance for optimizing sintering and cooling cycles, two key steps in PTFE processing that largely affect the material microstructural features. Overall, the result of the three-part investigation demonstrates that BNNB supports crystallization in the modified PTFE up to 20 wt% concentration and at low and high cooling rates typically used in the industrial processing of PTFE.

36 MATERIALS SCIENCE↗

Defending Weapons Inspections from the Effects of Disinformation

The intentional spread of disinformation is not a new challenge for the scientific world. We have seen it perpetuate the idea of a flat earth, convince communities that vaccines are more dangerous than helpful, and even suggest a connection between the “5G” communication infrastructure and COVID-19. Nor is disinformation a new phenomenon in the weapons inspection arena. Weapons inspectors themselves are often forced to sift through alternative narratives of events and inconsistent reporting, and they regularly see their credibility and conclusions questioned in the face of government politics or public biases. But certain recent disinformation campaigns have become so overwhelmingly comprehensive and effective that they constitute a new kind of threat. By preventing accountability for clear violations of international law, these campaigns have created a challenge to the survival of arms control treaties themselves. If weapons inspectors cannot regain the trust of the international community in the face of this challenge, it will be increasingly difficult to ensure compliance with arms control and disarmament treaties going forward. In this essay, I will briefly discuss one of the most comprehensive disinformation efforts of the past decade: the disinformation campaign used to prevent accountability for Syria's repeated use of chemical weapons. After this discussion, I will propose one possible approach to help protect the credibility of disarmament experts and weapons inspectors in the face of pervasive disinformation. This approach will require a concerted effort to connect and support compliance experts and to understand and explain their expertise across cultural, political, national, economic, and religious divides.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Lattice and electronic structure of ScN observed by angle-resolved photoemission spectroscopy measurements

Scandium nitride (ScN) has recently attracted much attention for its potential applications in thermoelectric energy conversion, as a semiconductor in epitaxial metal/semiconductor superlattices, as a substrate for GaN growth, and alloying it with AlN for 5G technology. This study was undertaken to better understand its stoichiometry and electronic structure. ScN (100) single crystals 2 mm thick were grown on a single crystal tungsten (100) substrate by a physical vapor transport method over a temperature range of 1900–2000 °C and a pressure of 20 Torr. The core level spectra of Sc 2p 3/2,1/2 and N 1s were obtained by x-ray photoelectron spectroscopy (XPS). The XPS core levels were shifted by 1.1 eV toward higher values as the [Sc]:[N] ratio varied from 1.4 at 1900 °C to ~1.0 at 2000 °C due to the higher binding energies in stoichiometric ScN. Angle-resolved photoemission spectroscopy measurements confirmed that ScN has an indirect bandgap of ~1.2 eV.

42 ENGINEERING↗

Printed graphene and its composite with copper for electromagnetic interference shielding applications

Abstract Advances in mobile electronics and telecommunication systems along with 5G technologies have been escalating the electromagnetic interference (EMI) problem in recent years. Graphene-based material systems such as pristine graphene, graphene-polymer composites and other graphene-containing candidates have been shown to provide adequate EMI shielding performance. Besides achieving the needed shielding effectiveness (SE), the method of applying the candidate shielding material onto the object in need of protection is of enormous importance due to considerations of ease of application, reduced logistics and infrastructure, rapid prototyping and throughput, versatility to handle both rigid and flexible substrates and cost. Printing readily meets all these criteria and here we demonstrate plasma jet printing of thin films of graphene and its composite with copper to meet the EMI shielding needs. SE over 30 dB is achieved, which represents blocking over 99.9% of the incoming radiation. Graphene and its composite with copper yield higher green index compared to pure copper shields, implying reduced reflection of incoming electromagnetic waves to help reduce secondary pollution.

Materials Science↗

Design of Muon Campus full flow purifier for varying operational conditions and horizontal shipping

Constant ingress of impurities in Muon Campus g-2 experiment at Fermilab has resulted in reduction of efficiency of cryogenic expanders and occasional undesired downtime to flush the impurities. Due to insufficiency of current 0.06 kg/s mobile purifier, a full flow purifier is designed to be used in Muon Campus which purifies 0.24 kg/s of Helium throughput of 4 compressors through charcoal bed at 80 K and returns ambient Helium back to the system. The purifier is designed to be operated near liquid Nitrogen temperature during cold operations and up to 400 K during regeneration. Both warm and cold operational range of the purifier has required use of appropriate clearances in design due to expansion and contraction. The vessel of around 5.5 m height which is designed to be operated vertically is to be shipped horizontally. The asymmetrical position of heavy stainless steel heat exchanger in the purifier support frame and 5g vertical load design consideration for shipping has required use of shipping supports and heat exchanger rotational stops to comply with design requirements. FEA of purifier system is performed in cold, warm and shipping cases to verify that the purifier satisfies the design requirements.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Information Carried by Electromagnetic Radiation Launched from Accelerated Polarization Currents

We show experimentally that a continuous, linear, dielectric antenna in which a superluminal polarization-current distribution accelerates can be used to transmit a broadband signal that is reproduced in a comprehensible form at a chosen target distance and angle. The requirement for this exact correspondence between broadcast and received signals is that each moving point in the polarization-current distribution approaches the target at the speed of light at all times during its transit along the antenna. This results in a one-to-one correspondence between the time at which each point on the moving polarization current enters the antenna and the time at which all of the radiation emitted by this particular point during its transit through the antenna arrives simultaneously at the target. This has the effect of reproducing the desired time dependence of the original broadcast signal. For other observer-detector positions, the time dependence of the signal is scrambled, due to the nontrivial relationship between emission (retarded) time and reception time. This technique represents a contrast to conventional radio transmission methods; in most examples of the latter, signals are broadcast with little or no directivity, selectivity of reception being achieved through the use of narrow frequency bands. In place of this, the current paper uses a spread of frequencies to transmit information to a particular location; the signal is weaker and has a scrambled time dependence elsewhere. Here, we point out the possible relevance of this mechanism to 5G neighborhood networks and pulsar astronomy.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Sentinel

Network intrusion detection systems (NIDS) are commonplace in network security but they frequently employ algorithms that are computational demanding requiring hardware and software with significant power requirements. Two examples of such resource-intensive algorithms used for network security are regular expression matching and broader signature pattern matching which are commonly used in deep packet inspection (DPI). Network security algorithms that have large power requirements may be a challenge for low-power internet-of-things (IoT) environments, which generally lack the power resources to implement complex security measures like computationally expensive DPI at the edge. Furthermore, IoT environments incorporating 5G standalone networks have network latency constraints beyond just power that make DPI at the edge even more difficult. Programmable logic is ideally suited for machine learning inference for DPI because of its deep instruction level parallelism and single-cycle memory access. Machine learning approaches for DPI have been explored before using the programmable logic of field programmable gate arrays (FPGA) as a potential solution for NIDS approaches that would be power-suitable for IoT. However, those previous programmable logic NIDS approaches utilize either a supervised or unsupervised learning model. Sentinel utilizes the ensemble of these two machine learning approaches known as a semi-supervised approach which has shown promise in NIDS implementations. Sentinel provides a programmable logic implementation of a semi-supervised approach for DPI which operates at much lower power and latency than a GPU implementation with negligible loss of accuracy due to quantization through a logistic regressor.

Anderson, MatthewW [Idaho National Laboratory (INL↗

Idaho National Laboratory Quality Of Service Dataset

The code is designed to run tests to generate and collect data from a Wi-Fi network using OPENWRT or a simulated a 5G network using Open5gs and UERANSIM. The tests simulate the network performing downloads or uploads of various files with a varying number of concurrent users. The tests use tcpdump to collect the network traffic but only stores the summarized data. The summarized datasets will be included.

Krome, Cameron [Idaho National Laboratory (INL), I↗

A holistic cyber-physical security protocol for authenticating the provenance and integrity of structural health monitoring imagery data

Modern infrastructure systems, such as bridges, dams, power generation stations, and buildings increasingly have an intrinsic cyber-physical nature to them. Infrastructure now commonly, includes actuators, network connections, sensors, control systems, and computational resources. It is of increasing concern that modern infrastructure is vulnerable to cyber-attacks that can damage both the cyber and physical nature of the infrastructure. To date, the physical and cyber health of infrastructure has been considered separately. However, the increasing concerns associated with the cyber-physical security of infrastructure coupled with the emergence of 5G networks made using components that are not universally considered trustworthy, and the emergence of techniques for creating deepfakes and adversarial examples suggests the time has come to begin considering cyber health and structural health with a more holistic approach. In this work, a protocol is developed for ensuring the imagery data captured by a structural health monitoring system can be unambiguously attributed to legitimate sensors associated with the structural health monitoring system. A computer vision approach based on the idea of mutual information is then presented to detect damage in an image. This work presents the protocol for authenticating the provenance of imager data and demonstrates that this protocol does not have overly adverse effects when used with the mutual information-based technique for detecting damage in the resulting imagery data.

Jung, HweeKwon↗

Active and tunable nanophotonic metamaterials

Abstract Metamaterials enable subwavelength tailoring of light–matter interactions, driving fundamental discoveries which fuel novel applications in areas ranging from compressed sensing to quantum engineering. Importantly, the metallic and dielectric resonators from which static metamaterials are comprised present an open architecture amenable to materials integration. Thus, incorporating responsive materials such as semiconductors, liquid crystals, phase-change materials, or quantum materials (e.g., superconductors, 2D materials, etc.) imbue metamaterials with dynamic properties, facilitating the development of active and tunable devices harboring enhanced or even entirely novel electromagnetic functionality. Ultimately, active control derives from the ability to craft the local electromagnetic fields; accomplished using a host of external stimuli to modify the electronic or optical properties of the responsive materials embedded into the active regions of the subwavelength resonators. We provide a broad overview of this frontier area of metamaterials research, introducing fundamental concepts and presenting control strategies that include electronic, optical, mechanical, thermal, and magnetic stimuli. The examples presented range from microwave to visible wavelengths, utilizing a wide range of materials to realize spatial light modulators, effective nonlinear media, on-demand optics, and polarimetric imaging as but a few examples. Often, active and tunable nanophotonic metamaterials yield an emergent electromagnetic response that is more than the sum of the parts, providing reconfigurable or real-time control of the amplitude, phase, wavevector, polarization, and frequency of light. The examples to date are impressive, setting the stage for future advances that are likely to impact holography, beyond 5G communications, imaging, and quantum sensing and transduction.

36 MATERIALS SCIENCE↗

Digital Twin Network (DTN): Concepts, Architecture, and Key Technologies

With the commercial deployment of 5G and the migration of internet from IPv4 to IPv6, the new development of the network technology has highly attracted the attention of the industry. The intelligentization of network is believed as the trend of the new generation of network development. The network provides the foundation for the information transmission in the digital society, and the digitalization of the network itself is the prerequisite for the intelligent development. Facing the goal of the new generation of digital and intelligent network, this paper introduces the new concept of "digital twin network (DTN)", designs the system architecture, and analyzes the key technologies of DTN. By investigating the challenges of DTN, this paper points out the future development direction of digital twin network.

digital twin network↗

Learning from learning machines: improving the predictive power of energy-water-land nexus models with insights from complex measured and simulated data

Focal Area(s): Insights gleaned from complex data (observed and simulated) using AI; Predictive modeling through the use of AI techniques and AI-derived model components, including physics- and knowledge-informed models; Energy-water-land nexus and integrated energy systems – models of MultiSector dynamics. Science Challenge: Scientific communities are in need of tools for the computational integration of physics-based models, experimental data, and empirical/observational studies across a broad range of temporal and spatial scales to explore and meet EESSD grand challenges. We require AI algorithms for the discovery of process-drivers in the Earth-energy-human system and to link them with complex measured and simulated data. We aim to understand the energy-water-land nexus, particularly under extreme forcing scenarios and rare events, leveraging scale-aware AI process models, including probabilistic uncertainties, and benefiting from the emerging 5G-enabled landscape-scale sensing and edge computing capabilities. These models are needed to identify instabilities and tipping points that manifest extreme system behaviors with consequences for integrated energy systems and the environment. This work requires fundamental advances in uncertainty quantification, in particular, to identify and model unlikely but catastrophic outliers. Specifically, we need models that are interpretable to domain scientists and, essentially, explainable to public and private stake holders.

54 ENVIRONMENTAL SCIENCES↗

Multisensor Agile Adaptive Sampling of Convective Storms Driven by Real-time Analytics

Convective storms vertically transport water vapor and condensate from Earth’s surface to the upper troposphere. Life on Earth is fundamentally linked to this transport which determines the hydrological cycle, and the intensity of severe weather responsible for the destruction of life and property. Despite advances in high-resolution modeling and better observational capabilities, the scientific community continues to be confronted with knowledge gaps about convective storms that limit our predictive capabilities. The ongoing developments in the high-resolution Energy Exascale Earth System Model (E3SM), large eddy simulations, and AI-based analytics to evaluate uncertainties are expected to provide a comprehensive framework for new scientific discovery. The model-experiment (MODEX) approach suggests that the aforementioned advancements in model development and AI-based inference techniques should be complemented by similar advancements in the experimental (observational) side so that the former does not outstrip the ability of the latter to provide meaningful constraints. What are the recent advancements in observations that will provide the necessary leap forward in improving our predictive capabilities? To address this question, we propose a new experimental paradigm called Multisensor Agile Adaptive Sampling (MAAS) that capitalizes on advancements in communications (5G), computational resources (edge/fog computing), sensor capabilities, and machine learning (ML) and AI techniques (Kollias et al., 2020). The MAAS framework allows for the collection of higher spatiotemporal resolution and quality observations of convective storms than is traditionally possible. The MAAS framework is scalable and applicable to atmospheric observatories such as those operated by the Department of Energy (DoE) Atmospheric Radiation Measurement (ARM) facility.

54 ENVIRONMENTAL SCIENCES↗

Blue Rock CropSpanPV - Low Cost Racking for Agricultural Solar Photovoltaics

In this work, a total of four solar panel layouts, applied to Agrivoltaics, are investigated. This study presents two hypotheses: 1. Prefabrication - Lower total cost can be achieved by constructing a pre-assembled, pre-wired solar array in a factory, with automation, then rapidly deploying it in the field. 2. Tension Structures - Using tension structures in a way to suspend an overhead solar array also reduces costs when compared to conventional support methods. Designs are presented for frames to hold the panels. Configurations are advanced to connect the frames into arrays. Supports and foundations to hold the arrays in the desired layout are calculated, selected and presented. Cost models are prepared for the four layouts, which include definition of the business enterprise, the manufacturing operation, and the required facility for production at scale. Cost models include, detail material and task/labor take-offs for both manufacturing and installation. Comparisons with conventional system adapted to Agrivoltaics reveal that the two hypotheses do not hold true. A prefabricated array requires additional material that is not needed in the base system and the cost of this additional material is not outweighed by the cost savings of reduced field installation. The cost of wire rope for a tension structure does result in an economy of material, however, the cost of end connections and tensioning devices adds significantly to the cost of the overall tension structure. Foundation loads with tension structures, especially the large wind uplift seen with a fixed tilt solar array, impose significant constraints and high costs. The following conclusions are recommended for further consideration: 1. Best Case Agrivoltaic Configuration - The best value/lowest cost configuration for agrivoltaics is the installation of solar panels mounted on a single axis tracker in either a 2-in-portrait or 2-in landscape arrangement. This is useful for grazing lands and for staple crops which require high light levels. These applications represent the vast majority of the potential agrivoltaic market. Important elements in this configuration are the specific geometric layout coordinated with the various field operations and a control system linked between the farm equipment and single axis tracker. The control system is to monitor location and orientation, then actively tilt the solar panels or brake the field equipment to provide clearance and avoid collisions. 2. Long Span Applications - The use of tension structures for an overhead fixed tilt array is beneficial where long spans are a necessity, especially where the base support in the project location has consolidated rock near the surface or some other solid structure. One application is spanning wide irrigation canals. Another may be as an installation at the top deck of parking structures. 3. Direct Ground Mount Configuration – Having skids at the base of a pre-fabricated array that extend when the array is deployed, could be a successful design. This could be a useful strategy for dense, flat, ground-mount configurations like that employed by a couple of successful commercial operations (5G Maverick and Erthos). Arrays would be orientated north and south, deployed very low on prepared grade. Arrays would be aligned closely next to each other and anchored with small ground screws or simply with ballast. This same product arrangement could be very useful for rapid deployment and set-up of solar arrays for temporary deployments, disaster response and the military operations

14 SOLAR ENERGY↗

Integration and commissioning plan of Full Flow Purifier at Muon Campus

The Full Flow Purifier for Fermilab’s Muon Campus uses a charcoal bed surrounded by a liquid nitrogen jacket to purify up to 240 g/s of helium gas. Fabrication by Ability Engineering Technology Inc. has been completed and the purifier delivered to Fermilab. It is the largest purifier to be used at Fermilab based on both capacity and size. A previous paper discussed the design of purifier for various operational conditions and horizontal shipping. The purifier is designed to withstand 5g force in vertical and 2g force in lateral and longitudinal directions. Transportation experience from vendor to Fermilab and within site is discussed. Integration of the purifier involved design and fabrication of a liquid nitrogen transfer line, regeneration system, and helium piping to connect it to Muon Campus cryogenic system. It also involved establishing electrical, instrumentation and controls connections to the system. Integration of the purifier is discussed in detail. The purifier is to be commissioned using up to 4 MYCOM helium compressors to supply helium and liquid nitrogen supplied by a 15,000 -gallon tank. Actual effectiveness of the 3-stream heat exchanger is to be estimated based on measured temperatures and flow rate. Impurity levels shall be monitored at inlet and outlet of the purifier. Theoretical adsorption capacity of the purifier is calculated based on the measured temperatures and flowrates and is compared to actual adsorption capacity over time.

Subedi, Jeewan [Fermilab]↗

Design of a shipping fixture for a compact cryomodule hermetic assembly

Two conduction-cooled 915 MHz superconducting radio frequency hermetic assemblies must be safely transported from the Jefferson Lab in Newport News, VA to General Atomics in San Diego, CA for perfor-mance testing in a custom horizontal test cryostat. One hermetic assembly consists of a 2-cell 915 MHz cavity, a coaxial fundamental power coupler, and the warm-to-cold transition beam tubes. The second hermetic assembly consists of a 2-cell 915 MHz cavity only. The assemblies will be transported on a flatbed air-ride trailer over the approximate 4000 km distance. Design requirements included adequate attenuation of 4g vertical axis, 5g beamline axis, and 1.5g lateral axis shock events. The isolation system was designed using helical wire-rope isolators with modal and transient finite element analysis performed in Ansys. Results show shock attenuation of a 10 ms half-sine pulse input to < 1g in the vertical axis, < 1.5g in the beam-line axis, and < 0.5g in the lateral axis for both assem-blies at the specified design loads and all structural stresses are kept below the material yield limits. Addi-tionally, the natural frequencies of both isolation sys-tems adequately attenuate the fundamental modes of the critical structures.

Accelerator Physics↗