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NASA NTRS1993

Earth Observing System (EOS) real-time onboard orbit determination

The paper describes the TDRSS Onboard Navigation System (TONS) selected by NASA/GSFC for the EOS-AM1 spacecraft as the baseline navigation system for real-time onboard orbit determination. Particular attention is given to the TONS algorithms and environmental models, the general design considerations, the algorithm implementation, and the required hardware. Results are presented of the covariance analysis for the nominal onboard and instrument requirements.

Folta, David C.↗

NASA NTRS1992

Synthesis, vapor growth, polymerization, and characterization of thin films of novel diacetylene derivatives of pyrrole. The use of computer modeling to predict chemical and optical properties of these diacetylenes and poly(diacetylenes)

In the present work two diacetylene derivatives of pyrrole which are predicted by semiempirical AM1 calculations to have very different properties, are synthesized; the polymerizability of these diacetylenes in the solid state is determined, and the results are compared to the computer predictions. Diacetylene 1 is novel in that the monomer is a liquid at room temperature; this may allow for the possibility of polymerization in the liquid state as well as the solid state. Thin poly(diacetylene) films are obtained from compound 1 by growing films of the monomer using vapor deposition and polymerizing with UV light; these films are then characterized. Interestingly, while the poly(diacetylene) from 1 does not possess good nonlinear optical properties, the monomer exhibits very good third-order effects (phase conjugation) in solution. Dilute acetone solutions of the monomer 1 give intensity-dependent refractive indices on the order of 10 exp -6 esu; these are 10 exp 6 times better than for CS2.

Paley, M. S.↗

NASA NTRS1997

Degradation of Perfluorinated Ether Lubricants on Pure Aluminum Surfaces: Semiempirical Quantum Chemical Modeling

The AM1 semiempirical quantum chemical method was used to model the interaction of perfluoroethers with aluminum surfaces. Perfluorodimethoxymethane and perfluorodimethyl ether were studied interacting with aluminum surfaces, which were modeled by a five-atom cluster and a nine-atom cluster. Interactions were studied for edge (high index) sites and top (low index) sites of the clusters. Both dissociative binding and nondissociative binding were found, with dissociative binding being stronger. The two different ethers bound and dissociated on the clusters in different ways: perfluorodimethoxymethane through its oxygen atoms, but perfluorodimethyl ether through its fluorine atoms. The acetal linkage of perfluorodimeth-oxymethane was the key structural feature of this molecule in its binding and dissociation on the aluminum surface models. The high-index sites of the clusters caused the dissociation of both ethers. These results are consistent with the experimental observation that perfluorinated ethers decompose in contact with sputtered aluminum surfaces.

Slaby, Scott M.↗

NASA NTRS1998

Theoretical Accuracy of Global Snow-Cover Mapping Using Satellite Data in the Earth Observing System (EOS) Era

Following the launch of the Earth Observing System first morning (EOS-AM1) satellite, daily, global snow-cover mapping will be performed automatically at a spatial resolution of 500 m, cloud-cover permitting, using Moderate Resolution Imaging Spectroradiometer (MODIS) data. A technique to calculate theoretical accuracy of the MODIS-derived snow maps is presented. Field studies demonstrate that under cloud-free conditions when snow cover is complete, snow-mapping errors are small (less than 1%) in all land covers studied except forests where errors are greater and more variable. The theoretical accuracy of MODIS snow-cover maps is largely determined by percent forest cover north of the snowline. Using the 17-class International Geosphere-Biosphere Program (IGBP) land-cover maps of North America and Eurasia, the Northern Hemisphere is classified into seven land-cover classes and water. Snow-mapping errors estimated for each of the seven land-cover classes are extrapolated to the entire Northern Hemisphere for areas north of the average continental snowline for each month. Average monthly errors for the Northern Hemisphere are expected to range from 5 - 10%, and the theoretical accuracy of the future global snow-cover maps is 92% or higher. Error estimates will be refined after the first full year that MODIS data are available.

Hall, D. K.↗

NASA NTRS1999

Remote Sensing of Forest Fires from Space

Forest fires, and fires used for deforestation and agriculture are sporadic. Some may last an hour others several days. It is difficult to find the fires or to estimate their effect on atmospheric pollution without an "eye in the sky" a satellite or an array of satellites that monitors them routinely from space. Since fires have a significant effect on the quality of air that we breath, on the surface vegetation, on clouds and precipitation and even on climate, NASA and other space agencies try to develop fire monitoring capability from space. Presently satellites were not designed to monitor fires. But the AVHRR and GOES satellites were used for fire monitoring. AVHRR is an orbiter that passes over the same area twice a day with detailed observations of fires from a distance of 800 km, GOES is a stationary satellite located above the equator, and observes the larger fires from a distance of 20,000 km. Field experiments, such as the "SCAR-B" experiment in Brazil conducted in 1995 by INPE, NASA and Universities of Sao Paulo, Washington and Wisconsin, were used to determine the ability of satellites to observe fires and the emitted pollution. They are the basis of a new system of satellites designed by NASA to observe fires and pollution, the Earth Observing System AM1 and PM1. NASA plans to use the information for four observations a day of the fires and the emitted smoke. The information can be used to determine the location of the fires, to distinguish between small and large fires and monitor their development. The satellites will measure the emitted smoke and with trajectory models can be used to predict the density and spread of the smoke.

Kaufman, Y.↗

NASA NTRS1999

Cloud Spatial Structure and 3D Radiative Transfer

Cloud radiative properties are sensitive to drop size and other parameters of cloud micro-structure, but also to cloud shape,spacing, and other parameters of cloud macro-structure, including internal fractal structure. New information on cloud structure is being derived from a variety of cloud radars, and ongoing field programs such as DoE/ARM. These programs are improving the measurement and modelling of physical and radiative properties of clouds. A parallel effort is underway to improve cloud remote sensing, especially from the new suite of EOS-AM1 instruments which will provide higher spectral, spatial resolution, and/or angular resolution. Key parameters for improving pixel-scale retrievals are cloud thickness and photon mean-free-path, which together determine the scale of "radiative smoothing" of cloud fluxes and radiances. This scale has been observed as a change in the spatial spectrum of Landsat cloud radiances, and was also recently found with the Goddard micropulse lidar, by searching for returns from directions nonparallel to the incident beam. "Offbeam" Lidar returns are now being used to estimate the cloud "radiative Green's function", G,which depends on cloud thickness and may be used to retrieve that important quantity. G is also being applied to improving simple IPA estimates of cloud radiative properties. This and other measurements of 3D transfer in clouds, coupled with Monte Carlo and other 3D transfer methods, are beginning to provide a better understanding of the dependence of radiation on cloud inhomogeneity, and to suggest new retrieval and parameterization algorithms which take account of cloud inhomogeneity.

Cahalan, Robert F.↗

NASA NTRS1997

Molecular Static Third-Order Polarizabilities of Carbon-Cage Fullerenes and their Correlation with Three Geometric Parameters: Group Order, Aromaticity, and Size

Calculations were performed on the valence contribution to the static molecular third-order polarizabilities (gamma) of thirty carbon-cage fullerenes (C60, C70, five isomers of C78, and twenty-three isomers of C84). The molecular structures were obtained from B3LYP/STO-3G calculations. The values of the tensor elements and an associated numerical uncertainty were obtained using the finite-field approach and polynomial expansions of orders four to eighteen of polarization versus static electric field data. The latter information was obtained from semiempirical calculations using the AM1 hamiltonian.

Moore, Craig E.↗

NASA NTRS1998

Molecular Static Third-Order Polarizabilities of Carbon-Cage Fullerene and Their Correlation with Three Geometric Properties: Symmetry, Aromaticity, and Size

The static third-order polarizabilities (gamma) of C60, C70, five isomers of C78 and two isomers of C84 were analyzed in terms of three properties, from a geometric point of view: symmetry, aromaticity and size. The polarizability values were based on the finite field approximation using a semiempirical Hamiltonian (AM1) and applied to molecular structures obtained from density functional theory calculations. Symmetry was characterized by the molecular group order. The selection of 6-member rings as aromatic was determined from an analysis of bond lengths. Maximum interatomic distance and surface area were the parameters considered with respect to size. Based on triple linear regression analysis, it was found that the static linear polarizability (alpha) and gamma in these molecules respond differently to geometrical properties: alpha depends almost exclusively on surface area while gamma is affected by a combination of number of aromatic rings, length and group order, in decreasing importance. In the case of alpha, valence electron contributions provide the same information as all-electron estimates. For gamma, the best correlation coefficients are obtained when all-electron estimates are used and when the dependent parameter is ln(gamma) instead of gamma.

Moore, C. E.↗

NASA NTRS1999

Cloud Spatial Structure and 3D Radiative Transfer

Cloud radiative properties are sensitive to drop size and other parameters of cloud micro-structure, but also to cloud shape,spacing, and other parameters of cloud macro-structure, including internal fractal structure. New information on cloud structure is being derived from a variety of cloud radars. Ongoing field programs such as Department of Energy's Atmospheric Radiation Measurement (DoE/ARM) are improving the measurement and modelling of physical and radiative properties of clouds. A parallel effort is underway to improve cloud remote sensing, especially from the new suite of EOS-AM1 instruments which will provide higher spectral, spatial resolution, and/or angular resolution. Key parameters for improving pixel-scale retrievals are cloud thickness and photon mean-free-path, which together determine the scale of "radiative smoothing" of cloud fluxes and radiances. This scale has been observed as a change in the spatial spectrum of Landsat cloud radiances, and was also recently found with the Goddard micropulse lidar, by searching for returns from directions nonparallel to the incident beam. "Offbeam" Lidar returns are now being used to estimate the cloud "radiative Green's function", G,which depends on cloud thickness and may be used to retrieve that important quantity. G is also being applied to improving simple IPA estimates of cloud radiative properties. This and other measurements of 3D transfer in clouds, coupled with Monte Carlo and other 3D transfer methods, are beginning to provide a better understanding of the dependence of adiation on cloud inhomogeneity, and to suggest new retrieval and parameterization algorithms which take account of cloud inhomogeneity. An international "Intercomparison of 3D Radiation Codes" or I3RC, program is beginning to coordinate and evaluate the variety of 3D radiative transfer methods now available, and to make them more widely available. Information is on the Web at: http://climate.qsfc.nasa.crov/I3RC. Input consists of selected cloud fields derived from data sources such as radar, microwave and satellite, and from models involved in the GEWEX Cloud Systems Studies. Output is selected radiative quantities that characterize the large- scale properties of the fields of radiative fluxes and heating. Several example cloud fields will be used to illustrate.

Cahalan, Robert F.↗

NASA NTRS1999

NASA/NOAA/AMS Earth Science Electronic Theater

Selections from the following very large Earth science observed & simulated datasets shown from: Historical: GOES-10 & AVHRR, SeaWIFS, TRMM, Meteosat, GMS, FY2, and ADEOS. and Simulated: EOS-AM1, Landsat 7, Astrovision, and 3D numerical storm model. Also highlights of the 1998 Hurricane & Severe Storm Seasons will be reviewed. A spectacular animations of La Nina season hurricanes: Bonnie, Georges, etc. 5000 frame 5-min GOES 10 continuous 28 day animation of the'98 Spring tornadic thunderstorm season and other special GOES test datasets will be shown.

Hasler, Fritz↗

NASA NTRS1998

Enabling High Performance Reconfigurable Ground Data Processing Systems

The deployment of high data rate instruments onboard satellites with direct broadcast capability demands the implementation of powerful ground data processing systems. Conversely, to enable the widespread usage of direct broadcast data and the generation of subsequent data products, low cost data processing systems must be available. Reconfigurable computers based on Field Programmable Gate Arrays (FPGA) enable the implementation of ground data processing systems that lead to higher performance and lower cost while keeping a high degree of programmability and maintainability. This paper presents the conceptualization of the MODIS Adaptive Level One Accelerator (ALOA), a prototype under construction at NASA's Goddard Space Flight Center. The ALOA is a computer workstation augmented by a reconfigurable computer. The system will calibrate and geographically locate data from the EOS-AM1 MODerate resolution Imaging Spectroradiometer (MODIS) instrument at near real-time data rates.

Hines, Tonjua M.↗

NASA NTRS1999

Aerosol Radiative Forcing of Climate Assessed Using Satellite Data and Ground Based Sun/Sky Radiometers

Aerosol and cloud impacts on the earth's climate become a recent hot topic in climate studies. Having near future earth observing satellites, EOS-AM1, ENVISAT (Environmental Satellite) and ADEOS-2 (Advanced Earth Observation Satellite-2), it will be a good timing to discuss how to obtain and use the microphysical parameters of aerosols and clouds for studying their climate impacts. Center for Climate System Research (CCSR) of the University of Tokyo invites you to 'Symposium on synergy between satellite- remote sensing and climate modeling in aerosol and cloud issues.' Here, we like to discuss the current and future issues in the remote sensing of aerosol and cloud microphysical parameters and their climate modeling studies. This workshop is also one of workshop series on aerosol remote sensing held in 1996, Washington D. C., and Meribel, France in 1999. It should be reminded that NASDA/ADEOS-1 & -2 Workshop will be held in the following week (Dec. 6-10, 1999), so that this opportunity will be a perfect period for you to attend two meetings for satellite remote sensing in Japan. A weekend in Kyoto, the old capital of Japan, will add a nice memory to your visiting Japan.

Kaufman, Yoram J.↗

NASA NTRS2000

Terra Flexible Blanket Solar Array Deployment, On-Orbit Performance and Future Applications

The Terra spacecraft (formerly identified as EOS AM1) is the flagship in a planned series of NASA/GSFC (Goddard Space Flight Center) Earth observing system satellites designed to provide information on the health of the Earth's land, oceans, air, ice, and life as a total ecological global system. It has been successfully performing its mission since a late-December 1999 launch into a 705 km polar orbit. The spacecraft is powered by a single wing, flexible blanket array using single junction (SJ) gallium arsenide/germanium (GaAs/Ge) solar cells sized to provide five year end-of-life (EOL) power of greater than 5000 watts at 127 volts. It is currently the highest voltage and power operational flexible blanket array with GaAs/Ge cells. This paper briefly describes the wing design as a basis for discussing the operation of the electronics and mechanisms used to achieve successful on-orbit deployment. Its orbital electrical performance to date will be presented and compared to analytical predictions based on ground qualification testing. The paper concludes with a brief section on future applications and performance trends using advanced multi-junction cells and weight-efficient mechanical components.

Kurland, Richard↗

NASA NTRS2000

Terra Flexible Blanket Solar Array Deployment, On-Orbit Performance and Future Applications

Kurland, Richard↗

NASA NTRS1998

Modeling of Branched (L, T and Y) Carbon Nanotubes

Models for connecting two or three carbon nanotubes (CNT) using topological defects (i.e., pentagons and heptagons) are presented for the characterization of experimentally observed L, T and Y CNT junctions. The effects of the separation and orientation of the topological defects on the structures and energetics of these junctions are investigated using the nonlocal density function theory (DFT) and semi-empirical molecular orbital (AM1) calculations, and the Brenner empirical potential molecular mechanics simulations. The potential applications of L, Y and T CNT junctions in nanoelectronic devices are also discussed.

Han, Jie↗

NASA NTRS2004

Validation and Analysis of SRTM and VCL Data Over Tropical Volcanoes

The focus of our investigation was on the application of digital topographic data in conducting first-order volcanological and structural studies of tropical volcanoes, focusing on the Java, the Philippines and the Galapagos Islands. Kilauea volcano, Hawaii, served as our test site for SRTM data validation. Volcanoes in humid tropical environments are frequently cloud covered, typically densely vegetated and erode rapidly, so that it was expected that new insights into the styles of eruption of these volcanoes could be obtained from analysis of topographic data. For instance, in certain parts of the world, such as Indonesia, even the regional structural context of volcanic centers is poorly known, and the distribution of volcanic products (e.g., lava flows, pyroclastic flows, and lahars) are not well mapped. SRTM and Vegetation Canopy Lidar (VCL) data were expected to provide new information on these volcanoes. Due to the cancellation of the VCL mission, we did not conduct any lidar studies during the duration of this project. Digital elevation models (DEMs) such as those collected by SRTM provide quantitative information about the time-integrated typical activity on a volcano and allow an assessment of the spatial and temporal contributions of various constructional and destructional processes to each volcano's present morphology. For basaltic volcanoes, P_c?w!m-d and Garbed (2000) have shown that gradual slopes (less than 5 deg.) occur where lava and tephra pond within calderas or in the saddles between adjacent volcanoes, as well as where lava deltas coalesce to form coastal plains. Vent concentration zones (axes of rift zones) have slopes ranging from 10 deg. to 12 deg. Differential vertical growth rates between vent concentration zones and adjacent mostly-lava flanks produce steep constructional slopes up to 40". The steepest slopes (locally approaching 90 deg.) are produced by fluvial erosion, caldera collapse, faulting, and catastrophic avalanches, all of which are usually identifiable. Due to the delay in the release of the SRTM data following the February 2000 flight, a significant part of our effort was devoted to the analog studies of the SRTM topographic data using topographic data from airborne interferometric radars. As part of the original SRTM Science Team, we proposed four study sites (Kilauea, Hawaii; Mt. Pinatubo, Philippines; Cerro Am1 and Femandina volcanoes, Galapagos Islands; and Tengger caldera, Java) where we could conduct detailed geologic studies to evaluate the uses of SRTM data for the analysis of lava flows, lahars, erosion of ash deposits, and an evaluation of the structural setting of the volcanoes. Only near the end of this project was one of these SRTM Science Team products (Luzon Island, the Philippines) released to the community, and we only had limited time to work on these data.

Mouginis-Mark, Peter J.↗

NASA NTRS2001

A semiempirical study of the optimized ground and excited state potential energy surfaces of retinal and its protonated Schiff base

The electronic ground and first excited states of retinal and its Schiff base are optimized for the first time using the semiempirical AM1 Hamiltonian. The barrier for rotation about the C(11)-C(12) double bond is characterized by variation of both the twist angle delta(C(10)-C(11)-C(12)-C(13)) and the bond length d(C(11)-C(12)). The potential energy surface is obtained by varying these two parameters. The calculated ground state rotational barrier is equal to 15.6 kcal/mol for retinal and 20.5 kcal/mol for its Schiff base. The all-trans conformation is more stable by 3.7 kcal/mol than the 11-cis geometry. For the first excited state, S(1,) the 90 degrees twisted geometry represents a saddle point for retinal with the rotational barrier of 14.6 kcal/mol. In contrast, this conformation is an energy minimum for the Schiff base. It can be easily reached at room temperature from the planar minima since it is separated from them by a barrier of only 0.6 kcal/mol. The 90 degrees minimum conformation is more stable than the all-trans by 8.6 kcal/mol. We are thus able to present a reaction path on the S(1) surface of the retinal Schiff base with an almost barrier-less geometrical relaxation into a twisted minimum geometry, as observed experimentally. The character of the ground and first excited singlet states underscores the need for the inclusion of double excitations in the calculations.

Retinaldehyde/chemistry↗

NASA NTRS2004

InGaAs/InP Monolithic Interconnected Modules (MIM) for Thermophotovoltaic Applications

There has been a traditional trade-off in thermophotovoltaic (TPV) energy conversion development between systems efficiency and power density. This trade-off originates from the use of front surface spectral controls such as selective emitters and various types of filters. A monolithic interconnected module (MIM) structure has been developed which allows for both high power densities and high system efficiencies. The MIM device consists of many individual indium gallium arsenide (InGaAs) devices series -connected on a single semi-insulating indium phosphide (InP) substrate. The MIMs are exposed to the entire emitter output, thereby maximizing output power density. An infrared (IR) reflector placed on the rear surface of the substrate returns the unused portion of the emitter output spectrum back to the emitter for recycling, thereby providing for high system efficiencies. Initial MIM development has focused on a 1 sq cm device consisting of eight series interconnected cells. MIM devices, produced from 0,74 eV InGAAs, have demonstrated V(sub infinity) = 3.23 volts, J(sub sc) = 70 mA/sq cm and a fill factor of 66% under flashlamp testing. Infrared (IR) reflectance measurement (less than 2 microns) of these devices indicate a reflectivity of less than 82%. MIM devices produced from 0.55 eV InGaAs have also been den=monstrated. In addition, conventional p/n InGaAs devices with record efficiencies (11.7% AM1) have been demonstrated.

Wilt, David M.↗