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At least 91 records · Page 5

Revisiting two thiophosphate compounds constituting d 0 transition metal HfP 2 S 6 and d 10 transition metal α-Ag 4 P 2 S 6 as multifunctional materials for combining second harmonic generation response and photocurrent response

Two acentric thiophosphate compounds, HfP 2 S 6 and α-Ag 4 P 2 S 6 , are revisited and studied as infrared nonlinear optical materials. HfP 2 S 6 and α-Ag 4 P 2 S 6 were structurally characterized without any property measurements. Here, in this work, HfP 2 S 6 and α-Ag 4 P 2 S 6 were synthesized via high temperature salt flux reactions. Low-temperature polymorph acentric α-Ag 4 P 2 S 6 was purified and grown as mm-sized crystals with the aid of AgBr flux. The AgBr flux was revealed to play an important role in stabilizing the acentric α-Ag 4 P 2 S 6 . The acentric α-Ag 4 P 2 S 6 transforms to centrosymmetric β-Ag 4 P 2 S 6 at 850(5) K, which is revealed by differential scanning calorimetry (DSC) analysis and powder X-ray diffraction experiments. HfP 2 S 6 and α-Ag 4 P 2 S 6 are discovered by UV-vis spectrum measurements as indirect bandgap semiconductors with bandgaps of 2.2(1) eV and 2.5(1) eV, respectively, which is supported by DFT calculations and TB-LMTO-ASA calculations. The bonding pictures of α-Ag 4 P 2 S 6 were studied by crystal orbital Hamilton population calculations (COHP) coupled with electron localization function (ELF) analysis. DFT calculations predict that HfP 2 S 6 and α-Ag 4 P 2 S 6 would exhibit different optical performances regardless of being constructed from identical [P 2 S 6 ] motifs. HfP 2 S 6 exhibits a low second harmonic generation (SHG) response, ~0.21 × AGS (for the sample of particle size of 25 μm). α-Ag 4 P 2 S 6 possesses moderate SHG response, ~0.61 × AGS (for the sample of particle size of 225 μm) coupled with a high laser damage threshold (LDT) of ~3.2 × AGS. Characteristics of high ambient stability, moderate bandgap and SHG response, type-I phase-matching capability, and high LDT together with the easy growth of large crystals make α-Ag 4 P 2 S 6 attractive for future infrared nonlinear optical applications. Photocurrent measurements found that α-Ag 4 P 2 S 6 and β-Ag 4 P 2 S 6 have high photocurrent response, 165 nA cm -2 and 135 nA cm -2 , respectively. α-Ag 4 P 2 S 6 is a new multifunctional material of the ternary Ag–P–S system, which combines nonlinear optical (NLO) properties and photocurrent response.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Verification of Subcritical Limits in ANSI/ANS-8.1-2014

The first edition of the current American National Standards Institute (ANSI)/American Nuclear Society (ANS) standard ANSI/ANS-8.1-2014, “Nuclear Criticality Safety in Operations with Fissionable Materials Outside Reactors,” was published in 1964 as ASA N6.1-1964, “Safety Standard for Operations with Fissionable Materials Outside Reactors.” In 1969, that standard was revised as ANSI N16.1-1969, “Nuclear Criticality Safety in Operations with Fissionable Materials Outside Reactors.” ANSI N16.1-1969 includes a variety of subcritical limits (SCLs) for uniform aqueous solutions and metals containing fissile nuclides of 233 U, 235 U, and 239 Pu. Furthermore, SCLs are also included for uranium-water lattices. In the 1983 version of ANSI/ANS-8.1 (a revision of ANSI N16.1-1975), the suite of SCLs in the standard was expanded to include 235 U enrichment limits for homogeneous uranium-water mixtures and dry/damp oxides, uniform aqueous solutions of low-enriched uranium, and uniform aqueous mixtures of Pu(NO 3 ) 4 containing 240Pu in addition to the SCLs included in ANSI N16.1-1969. The SCLs have changed little in subsequent revisions (ANSI/ANS-8.1-1998 and ANSI/ANS-8.1-2014). The ANSI/ANS-8.1-2014 standard is currently being revised to include new SCLs (uranium metal and compounds with enrichments up to 20 wt% 235 U) and possible updates to the current SCLs already in the standard, although these new/updated SCLs will not be available to the nuclear criticality safety (NCS) community for a number of years. The original bases for these SCLs were documented in papers in journals such as Nuclear Science and Engineering and in ANS meeting transactions; however, these bases are ambiguous enough that sites and regulators in the United States have not widely endorsed them for safety purposes. Overall, the purpose of this paper is to present the results of a comparison study for the SCLs in the ANSI/ANS-8.1-2014 standard using modern codes (SCALE and MCNP) and cross sections (ENDF/B-VIII.0) to provide some assurance about their quality (bias and bias uncertainty) for use in NCS applications and for consideration by the ANS-8.1 Working Group as a reference for future revisions.

42 ENGINEERING↗

Reanalysis of c-type RR Lyrae variable BE Dor, period modulations and possible mechanism

ABSTRACT We reanalysed the c-type RR Lyrae star BE Dor (MACHO 5.4644.8, OGLE-LMC-RRLYR-06002) that had been discovered to show cyclic period changes. The photometric data of several sky surveys (DASCH, MACHO, OGLE, ASAS-SN, and TESS) were used for analyses. The O − C diagram and pulsation period obtained from Fourier analysis show significant period modulations in BE Dor. However, different from the previous viewpoint, the changes are quasi-periodic and abrupt. Therefore, the light-traveltime effect caused by the companion motion cannot explain the changes. Noting a same subtype star KIC 9453114 with similar phenomena has a high macroturbulent velocity, and the degree of O − C changes seem to be positively correlated with these velocities, we consider that the mechanism leading to period modulation should be caused by the interaction between turbulent convection and magnetic field activity in the ionization zone, i.e. the viewpoint of Stothers. It may not explain the general Blazhko effect but should explain such period modulations in BE Dor and those other c-type RR Lyrae stars. We hope our discoveries and viewpoints can provide some information and inspiration for relevant research.

Li, L-J↗

The ‘Giraffe’: discovery of a stripped red giant in an interacting binary with an ∼2 M ⊙ lower giant

We report the discovery of a stripped giant + lower giant Algol-type binary, 2M04123153+6738486 (2M0412), identified during a search for non-interacting compact object – star binaries. 2M0412 is an evolved ( T eff, giant ≃ 4000 K), luminous ( L giant ≃ 150 L ⊙ ) red giant in a circular P = 81.2 d binary. 2M0412 is a known variable star previously classified as a semiregular variable. The cross-correlation functions of follow-up Keck/HIRES and LBT/Potsdam Echelle Polarimetric and Spectroscopic Instrument (PEPSI) spectra show an radial velocity variable second component with implied mass ratio q = M giant / M comp ≃ 0.20 ± 0.01. The All-Sky Automated Survey for SuperNovae (ASAS-SN), Asteroid Terrestrial-impact Last Alert System (ATLAS), Transiting Exoplanet Survey Telescope ( TESS ), and Zwicky Transient Facility (ZTF) light curves show that the giant is a Roche lobe filling ellipsoidal variable with an inclination of 49.4 ± 0.3°, and a giant mass of M giant = 0.38 ± 0.01 M ⊙ for a distance of ≃ 3.7 kpc. The mass of the giant indicates that its envelope has been partially stripped. The giant companion on the lower red giant branch has a mass of M comp = 1.91 ± 0.03 M ⊙ with T eff, comp ≃ 5000 K, L comp ≃ 60 L ⊙ , and R comp ≃ 11 R ⊙ . The lower giant contributes ${\sim }35{{\ \rm per\ cent}}$ of the flux in the V band. We also identify an orbital phase dependent, broad $\rm H\,\alpha$ emission line which could indicate ongoing accretion from the stripped red giant on to the companion.

(stars:) binaries: spectroscopic↗

Statistical estimates of the binary properties of rotational variables

ABSTRACT We present a model to estimate the average primary masses, companion mass ranges, the inclination limit for recognizing a rotational variable, and the primary mass spreads for populations of binary stars. The model fits a population’s binary mass function distribution and allows for a probability that some mass functions are incorrectly estimated. Using tests with synthetic data, we assess the model’s sensitivity to each parameter, finding that we are most sensitive to the average primary mass and the minimum companion mass, with less sensitivity to the inclination limit and little to no sensitivity to the primary mass spread. We apply the model to five populations of binary spotted rotational variables identified in ASAS-SN, computing their binary mass functions using RV data from APOGEE. Their average primary mass estimates are consistent with our expectations based on their CMD locations ($\sim 0.75 \, {\rm M}_{\odot }$ for lower main sequence primaries and $\sim 0.9$–$1.2 \, {\rm M}_{\odot }$ for RS CVn and sub-subgiants). Their companion mass range estimates allow companion masses down to $M_2/M_1\simeq 0.1$, although the main sequence population may have a higher minimum mass fraction ($\sim 0.4$). We see weak evidence of an inclination limit $\gtrsim 50^{\circ }$ for the main sequence and sub-subgiant groups and no evidence of an inclination limit in the other groups. No groups show strong evidence for a preferred primary mass spread. We conclude by demonstrating that the approach will provide significantly better estimates of the primary mass and the minimum mass ratio and reasonable sensitivity to the inclination limit with 10 times as many systems.

Phillips, Anya (ORCID:000900051914974X)↗

Synthesis, structural characterization, and electronic structure of the novel Zintl phase Ba 2 ZnP 2

The novel Zintl phase dibarium zinc diphosphide (Ba 2 ZnP 2 ) was synthesized for the first time. This was accom­plished using the Pb flux technique, which allowed for the growth of crystals of adequate size for structural determination via single-crystal X-ray diffraction methods. The Ba 2 ZnP 2 com­pound was determined to crystallize in a body-centered ortho­rhom­bic space group, Ibam (No. 72). Formally, this crystallographic arrangement belongs to the K 2 SiP 2 structure type. Therefore, the structure can be best described as infinite [ZnP 2 ] 4– polyanionic chains with divalent Ba 2+ cations located between the chains. All valence electrons are partitioned, which conforms to the Zintl–Klemm concept and suggests that Ba 2 ZnP 2 is a valence-precise com­position. In conclusion, the electronic band structure of this new com­pound, com­puted with the aid of the TB–LMTO–ASA code, shows that Ba 2 ZnP 2 is an intrinsic semiconductor with a band gap of ca 0.6 eV.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Conduct of Operations and Nuclear Criticality Safety Standards

Since the beginning of the nuclear age in 1943, there have been 22 criticality accidents in process facilities worldwide in which fissionable materials were processed by hand for various purposes. Of these 22 process criticality accidents, 16 involved faulty or flawed conduct of operations. Most of these process accidents (17 of 22) occurred before 1970, mostly due to the implementation of formal conduct of operations—such as the use of operating procedures and training—and the use of consensus standards for nuclear criticality safety (NCS). Obviously, the nuclear facilities applied lessons learned from their accident history, and the rate of criticality accidents was significantly reduced as a result. Over the years, it has been emphasized in NCS training courses and other venues in the United States that the consensus standards, such as ASA N6.1-1964, were the key contributors to this reduction in accidents. The formality of operations required to implement and apply the standards at a facility is also a crucial prerequisite that must be sufficiently robust to ensure NCS. This prerequisite is crucial to success fully implement the NCS consensus and other safety standards at a site.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

TIC 168789840: A Sextuply Eclipsing Sextuple Star System

We report the discovery of a sextuply eclipsing sextuple star system from TESS data, TIC 168789840, also known as TYC 7037-89-1, the first known sextuple system consisting of three eclipsing binaries. The target was observed in Sectors 4 and 5 during Cycle 1, with lightcurves extracted from TESS Full Frame Image data. It was also previously observed by the WASP survey and ASAS-SN. The system consists of three gravitationally bound eclipsing binaries in a hierarchical structure of an inner quadruple system with an outer binary subsystem. Follow-up observations from several different observatories were conducted as a means of determining additional parameters. The system was resolved by speckle interferometry with a 0.″42 separation between the inner quadruple and outer binary, inferring an estimated outer period of ∼2 kyr. It was determined that the fainter of the two resolved components is an 8.217 day eclipsing binary, which orbits the inner quadruple that contains two eclipsing binaries with periods of 1.570 days and 1.306 days. Markov Chain Monte Carlo (MCMC) analysis of the stellar parameters has shown that the three binaries of TIC 168789840 are “triplets,” as each binary is quite similar to the others in terms of mass, radius, and T {sub eff}. As a consequence of its rare composition, structure, and orientation, this object can provide important new insight into the formation, dynamics, and evolution of multiple star systems. Future observations could reveal if the intermediate and outer orbital planes are all aligned with the planes of the three inner eclipsing binaries.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

2M17091769+3127589: A Mass-transfer Binary with an Extreme Mass Ratio

We present the orbital solution of a peculiar double-lined spectroscopic and eclipsing binary system, 2M17091769+3127589. This solution was obtained by a simultaneous fit of both APOGEE radial velocities and TESS and ASAS-SN light curves to determine masses and radii. This system consists of an M=0.256{sub -0.006}{sup +0.010} M {sub ⊙}, R=3.961{sub -0.032}{sup +0.049} R {sub ⊙} red giant and a hotter M=1.518{sub -0.031}{sup +0.057} M {sub ⊙}, R=2.608{sub -0.321}{sup +0.034} R {sub ⊙} subgiant. Modeling with the MESA evolutionary codes indicates that the system likely formed 5.26 Gyrs ago, with a M = 1.2 M {sub ⊙} primary that is now the system’s red giant and a M = 1.11 M {sub ⊙} secondary that is now a more massive subgiant. Due to Roche-lobe overflow as the primary ascends the red giant branch, the more evolved “primary” (i.e., originally the more massive star of the pair) is now only one sixth as massive as the “secondary.” Such a difference between the initial and the current mass ratio is one of the most extreme detected so far. Evolutionary modeling suggests the system is still engaged in mass transfer, at a rate of M-dot ~10{sup -9} M {sub ⊙}/yr, and it provides an example of a less evolved precursor to some of the systems that consist of white dwarfs and blue stragglers.

47 OTHER INSTRUMENTATION↗

The Rise and Fall of ASASSN-18pg: Following a TDE from Early to Late Times

Here, we present nearly 500 days of observations of the tidal disruption event (TDE) ASASSN-18pg, spanning from 54 days before peak light to 441 days after peak light. Our data set includes X-ray, UV, and optical photometry, optical spectroscopy, radio observations, and the first published spectropolarimetric observations of a TDE. ASASSN-18pg was discovered on 2018 July 11 by the All-Sky Automated Survey for Supernovae (ASAS-SN) at a distance of $\textit{d}$ = 78.6 Mpc; with a peak UV magnitude of $\textit{m}$ ≃ 14, it is both one of the nearest and brightest TDEs discovered to-date. The photometric data allow us to track both the rise to peak and the long-term evolution of the TDE. ASASSN-18pg peaked at a luminosity of $\textit{L}$ ≃ 2.4 × 10 44 erg s -1 , and its late-time evolution is shallower than a flux ∝$\textit{t}^{–5/3}$ power-law model, similar to what has been seen in other TDEs. ASASSN-18pg exhibited Balmer lines and spectroscopic features consistent with Bowen fluorescence prior to peak, which remained detectable for roughly 225 days after peak. Analysis of the two-component Hα profile indicates that, if they are the result of reprocessing of emission from the accretion disk, the different spectroscopic lines may be coming from regions between ~10 and ~60 lt-days from the black hole. No X-ray emission is detected from the TDE, and there is no evidence of a jet or strong outflow detected in the radio. Our spectropolarimetric observations indicate that the projected emission region is likely not significantly aspherical, with the projected emission region having an axis ratio of ≳0.65.

79 ASTRONOMY AND ASTROPHYSICS↗

Early-time Light Curves of Type Ia Supernovae Observed with TESS

We present the early-time light curves of Type Ia supernovae (SNe Ia) observed in the first six sectors of Transiting Exoplanet Survey Satellite (TESS) data. Ten of these SNe were discovered by ASAS-SN, seven by ATLAS, six by ZTF, and one by Gaia. For nine of these objects with sufficient dynamic range (>3.0 mag from detection to peak), we fit power-law models and searched for signatures of companion stars. We found a diversity of early-time light-curve shapes, although most of our sources are consistent with fireball models where the flux increases as ∝t 2 . Three SNe displayed a flatter rise with flux ∝t. We did not find any obvious evidence for additional structures, such as multiple power-law components, in the early rising light curves. For assumptions about the SN properties and the observer viewing angle (ejecta mass of 1.4 M⊙, expansion velocity of 10 4 km s –1 , opacity of 0.2 cm 2 g –1 , and viewing angle of 45°) and a further assumption that any companion stars would be in Roche lobe overflow, it is possible to place upper limits on the radii of any companion stars. Six of the nine SNe had complete coverage of the early-time light curves, and we placed upper limits on the radii of companion stars of ≲32 R ⊙ for these SNe, ≲20 R ⊙ for five of the six, and ≲4 R ⊙ for two of the six. The small sample size did not allow us to put limits on the occurrence rate of companion stars in the progenitors of SNe Ia. However, we expect that TESS observed enough SNe in its two-year primary mission (26 sectors) to either detect the signature of a large companion (R > 20 R ⊙ ) or constrain the occurrence rate of such systems, at least for the fiducial SN properties adopted here. Here, we also show that TESS is capable of detecting emission from a 1 R ⊙ companion for an SN Ia within 50 Mpc and has a reasonable chance of doing so after about six years.

79 ASTRONOMY AND ASTROPHYSICS↗

The Curious Case of ASASSN-20hx: A Slowly Evolving, UV- and X-Ray-Luminous, Ambiguous Nuclear Transient

Abstract We present observations of ASASSN-20hx, a nearby ambiguous nuclear transient (ANT) discovered in NGC 6297 by the All-Sky Automated Survey for Supernovae (ASAS-SN). We observed ASASSN-20hx from −30 to 275 days relative to the peak UV/optical emission using high-cadence, multiwavelength spectroscopy and photometry. From Transiting Exoplanet Survey Satellite data, we determine that the ANT began to brighten on 2020 June 22.8 with a linear rise in flux for at least the first week. ASASSN-20hx peaked in the UV/optical 30 days later on 2020 July 22.8 (MJD = 59052.8) at a bolometric luminosity of L = (3.15 ± 0.04) × 10 43 erg s −1 . The subsequent decline is slower than any TDE observed to date and consistent with many other ANTs. Compared to an archival X-ray detection, the X-ray luminosity of ASASSN-20hx increased by an order of magnitude to L x ∼ 1.5 × 10 42 erg s −1 and then slowly declined over time. The X-ray emission is well fit by a power law with a photon index of Γ ∼ 2.3–2.6. Both the optical and near-infrared spectra of ASASSN-20hx lack emission lines, unusual for any known class of nuclear transient. While ASASSN-20hx has some characteristics seen in both tidal disruption events and active galactic nuclei, it cannot be definitively classified with current data.

79 ASTRONOMY AND ASTROPHYSICS↗

Metallicity of Galactic RR Lyrae from Optical and Infrared Light Curves. II. Period–Fourier–Metallicity Relations for First Overtone RR Lyrae

We present new period-$\phi$ 31 -[Fe/H] relations for first-overtone RRL stars (RRc), calibrated over a broad range of metallicities (–2.5 ≲ [Fe/H] ≲ 0.0) using the largest currently available set of Galactic halo field RRL with homogeneous spectroscopic metallicities. Our relations are defined in the optical (ASAS-SN V band) and, inaugurally, in the infrared (WISE W1 and W2 bands). Our V-band relation can reproduce individual RRc spectroscopic metallicities with a dispersion of 0.30 dex over the entire metallicity range of our calibrator sample (an rms smaller than what we found for other relations in literature including nonlinear terms). Our infrared relation has a similar dispersion in the low- and intermediate-metallicity range ([Fe/H] ≲ –0.5), but tends to underestimate the [Fe/H] abundance around solar metallicity. We tested our relations by measuring both the metallicity of the Sculptor dSph and a sample of Galactic globular clusters, rich in both RRc and RRab stars. The average metallicity we obtain for the combined RRL sample in each cluster is within ±0.08 dex of their spectroscopic metallicities. The infrared and optical relations presented in this work will enable deriving reliable photometric RRL metallicities in conditions where spectroscopic measurements are not feasible; e.g., in distant galaxies or reddened regions (observed with upcoming Extremely Large Telescopes and the James Webb Space Telescope), or in the large sample of new RRL that will be discovered in large-area time-domain photometric surveys (such as the LSST and the Roman space telescope).

79 ASTRONOMY AND ASTROPHYSICS↗

Investigating the Nature of the Luminous Ambiguous Nuclear Transient ASASSN-17jz

Abstract We present observations of the extremely luminous but ambiguous nuclear transient (ANT) ASASSN-17jz, spanning roughly 1200 days of the object’s evolution. ASASSN-17jz was discovered by the All-Sky Automated Survey for Supernovae (ASAS-SN) in the galaxy SDSS J171955.84+414049.4 on UT 2017 July 27 at a redshift of z = 0.1641. The transient peaked at an absolute B -band magnitude of M B ,peak = −22.81, corresponding to a bolometric luminosity of L bol,peak = 8.3 × 10 44 erg s −1 , and exhibited late-time ultraviolet emission that was still ongoing in our latest observations. Integrating the full light curve gives a total emitted energy of E tot = (1.36 ±0.08) × 10 52 erg, with (0.80 ± 0.02) × 10 52 erg of this emitted within 200 days of peak light. This late-time ultraviolet emission is accompanied by increasing X-ray emission that becomes softer as it brightens. ASASSN-17jz exhibited a large number of spectral emission lines most commonly seen in active galactic nuclei (AGNs) with little evidence of evolution. It also showed transient Balmer features, which became fainter and broader over time, and are still being detected >1000 days after peak brightness. We consider various physical scenarios for the origin of the transient, including supernovae (SNe), tidal disruption events, AGN outbursts, and ANTs. We find that the most likely explanation is that ASASSN-17jz was a SN IIn occurring in or near the disk of an existing AGN, and that the late-time emission is caused by the AGN transitioning to a more active state.

79 ASTRONOMY AND ASTROPHYSICS↗

The Milky Way Revealed by Variable Stars. I. Sample Selection of RR Lyrae Stars and Evidence for Merger History

In order to study the Milky Way, RR Lyrae (RRL) variable stars identified by Gaia, ASAS-SN, and ZTF sky survey projects have been analyzed as tracers in this work. Photometric and spectroscopic information of 3417 RRLs including proper motions, radial velocity, and metallcity are obtained from observational data of Gaia, LAMOST, GALAH, APOGEE, and RAVE. Precise distances of RRLs with typical uncertainties less than 3% are derived by using a recent comprehensive period–luminosity–metallicity relation. Our results from kinematical and chemical analysis provide important clues for the assembly history of the Milky Way, especially for the Gaia–Sausage ancient merger. The kinematical and chemical trends found in this work are consistent with those of recent simulations that indicated that the Gaia–Sausage merger had a dual origin in the Galactic thick disk and halo. As recent similar works have found, the halo RRL sample in this work contains a subset of radially biased orbits besides a more isotropic component. This higher orbital anisotropy component amounts to β ≃ 0.8, and it contributes between 42% and 83% of the halo RRLs at 4 < R( kpc) < 20.

79 ASTRONOMY AND ASTROPHYSICS↗

Comparison of MX-857 versus MX-641 chemistries for type 2485 film

Tests were conducted to evaluate Kodak MX-857 and MX-641 chemistry systems for use with film Type 2485 to be used in the dim light experiments on Apollo 16. The test program objectives were to: (1) retain a minimum ASA speed of at least 4000; (2) maintain a base-plus-fog level of 0.21 density units or less; and (3) minimize the granularity but do not exceed the granularity level of the Apollo 15 imagery. Test results on the Versamat processor indicate that the use of MX-857 chemistry is preferred over MX-641 chemistry in satisfying the stated test objectives.

Bourque, P. F.↗

Film type SO-168 radiation study

Investigations were performed to determine optimum exposure and processing procedures necessary to partially offset the effect of radiation to which film type SO-168 will be exposed during the Skylab Mission. This task became necessary when it was determined that original predictions of 2 to 3 RADS of radiation to which the film will be exposed were too low, and that levels as high as 3.5 to 4.0 RADS may be incurred, thus reducing image quality below an acceptable level. Tests results show that forced processing of type SO-168 film tended to reduce the density range to an unusable level, and that processing to a lower ASA value would provide greater image quality for the user.

Pierce, W. N.↗