Search NASA⌕ Search

SEARCH · Search NASA

Results for “Aggregate structure”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Heat and moisture flow in concrete as a function of temperature

Due to temperature, reactors in operation cause heat and moisture flows in the thick walled prestressed pressure vessels. These flows were studied in three beams of concrete made with crushed limestone aggregate, and in three beams made of crushed gravel/sand aggregate. The flow phenomena were related to the structural development of the concrete by determining the amount of non-evaporatable water, the total porosity, and the pore size distribution. Local temperature and moisture conditions also influenced the technical properties. Compressive strength, changes in length due to shrinkage and contraction, thermal expansion, and thermal conductivity were determined.

Hundt, J.↗
NASA NTRS1981

Terrestrial evolution of polymerization of amino acids - Heat to ATP

Sets of amino acids containing sufficient trifunctional monomer are thermally polymerized at temperatures such as 65 deg; the amino acids order themselves. Various polymers have diverse catalytic activities. The polymers aggregate, in aqueous solution, to cell-like structures having those activities plus emergent properties, e.g. proliferatability. Polyamino acids containing sufficient lysine catalyze conversion of free amino acids, by ATP, to small peptides and a high molecular weight fraction. The lysine-rich proteinoid is active in solution, within suspensions of cell-like particles, or in other particles composed of lysine-rich proteinoid and homopolyribonucleotide. Selectivities are observed. An archaic polyamino acid prelude to coded protein synthesis is indicated.

Fox, S. W.↗
NASA NTRS1989

Stereological characterization of dry alpine snow for microwave remote sensing

A persistent problem in investigations of electromagnetic properties of snow, from reflectance at visible wavelengths to emission and backscattering in the microwave, has been the proper characterization of the snow's physical properties. It is suggested that the granular and laminar structure of snow can be measured in its aggregated state by stereology performed on sections prepared from snow specimens, and that these kinds of measurements can be incorporated into models of the electromagnetic properties. With careful sampling, anisotropy in the snow microstructure at various scales can be quantified. It is shown how stereological parameters can be averaged over orientation and optical depth for radiative transfer modeling.

Davis, Robert E.↗
NASA NTRS1996

Soot Precursor Material: Visualization Via Simultaneous LIF-LII and Characterization Via TEM

Simultaneous combined laser-induced fluorescence and laser-induced incandescence (LIF-LII) images are presented for both a normal and inverse diffusion flame. The excitation wavelength dependence distinguishes the LIF and LII signals in images from the normal diffusion flame while the temporal decay distinguishes the signals in images of the inverse diffusion flame. Each flame presents a minimum in the combined LIF-LII intensity in a region separating the fuel pyrolysis and soot containing regions. Opacity, geometric in definition, and extent of crystallinity measured through both bright and dark field Transmission Electron Microscopy (TEM) characterizes the thermophoretically sampled material from within this minimal LIF-LII intensity region. TEM analysis reveals rather different soot processes occurring within the normal and inverse diffusion flame. In the normal diffusion flame, rapid chemical and physical coalescence of PAHs results in initial formation of soot precursor particles that are highly crystalline and evolve toward fully formed soot. In the inverse diffusion flame, rapid coalescence of pyrolysis products occurs, producing tarlike, globular structures equivalent in size to fully formed soot aggregates but with markedly less crystallinity than normal-appearing soot. These different material properties are interpreted as reflecting different relative rates of chemical and physical coalescence of fuel pyrolysis products versus carbonization. Significantly, these TEM images support qualitative photophysical arguments suggesting that, in general, this 'dark' region observed in the LIF-LII images demarcates a transitional region in which a fundamental change in the material the material chemical/physical properties occurs between solid carbonaceous soot and condensed or gaseous molecular growth material.

VanderWal, Randall L.↗
NASA NTRS1999

Effective Forces Between Colloidal Particles

Colloidal suspensions have proven to be excellent model systems for the study of condensed matter and its phase behavior. Many of the properties of colloidal suspensions can be investigated with a systematic variation of the characteristics of the systems and, in addition, the energy, length and time scales associated with them allow for experimental probing of otherwise inaccessible regimes. The latter property also makes colloidal systems vulnerable to external influences such as gravity. Experiments performed in micro-ravity by Chaikin and Russell have been invaluable in extracting the true behavior of the systems without an external field. Weitz and Pusey intend to use mixtures of colloidal particles with additives such as polymers to induce aggregation and form weak, tenuous, highly disordered fractal structures that would be stable in the absence of gravitational forces. When dispersed in a polarizable medium, colloidal particles can ionize, emitting counterions into the solution. The standard interaction potential in these charged colloidal suspensions was first obtained by Derjaguin, Landau, Verwey and Overbeek. The DLVO potential is obtained in the mean-field linearized Poisson-Boltzmann approximation and thus has limited applicability. For more precise calculations, we have used ab initio density functional theory. In our model, colloidal particles are charged hard spheres, the counterions are described by a continuum density field and the solvent is treated as a homogeneous medium with a specified dielectric constant. We calculate the effective forces between charged colloidal particles by integrating over the solvent and counterion degrees of freedom, taking into account the direct interactions between the particles as well as particle-counterion, counterion-counterion Coulomb, counterion entropic and correlation contributions. We obtain the effective interaction potential between charged colloidal particles in different configurations. We evaluate two- and three-body forces in the bulk as well as study the influence of soft walls. We qualitatively explain the effects of the walls on the forces and demonstrate that many-body effects are negligible in our system. With adjustments in the parameters, the DLVO pair-potential can describe the results quantitatively. Besides electrostatic interactions, entropic depletion effects that arise from (hard-core) exclusion play an important role in determining the behavior of multi-component colloidal suspensions. A standard theory for depletion forces is due to Asakura and Oosawa and is based on the ideal gas approximation. To go beyond this approximation, we have studied entropic forces in molecular dynamics simulations of systems of hard spheres (the effects of the solvent have been ignored). The effective depletion forces for these systems can be found either from equilibrium distribution functions or from direct momentum transfer calculations. Our results obtained by either method show qualitative differences from the Asakura-Oosawa forces, indicating a longer range, higher value at contact and most importantly a more complicated structure, comprising of several maxima and minima. Our calculations include the determination of effective forces between two spheres, a hard sphere and a wall, and the behavior of a hard sphere near a step-edge and a corner. We also demonstrate that such entropic forces do not necessarily satisfy pairwise additivity.

Tehver, Riina↗
NASA NTRS2003

Nanophase and Composite Optical Materials

This talk will focus on accomplishments, current developments, and future directions of our work on composite optical materials for microgravity science and space exploration. This research spans the order parameter from quasi-fractal structures such as sol-gels and other aggregated or porous media, to statistically random cluster media such as metal colloids, to highly ordered materials such as layered media and photonic bandgap materials. The common focus is on flexible materials that can be used to produce composite or artificial materials with superior optical properties that could not be achieved with homogeneous materials. Applications of this work to NASA exploration goals such as terraforming, biosensors, solar sails, solar cells, and vehicle health monitoring, will be discussed.

Source record↗
NASA NTRS2015

Noise Measurements of High Aspect Ratio Distributed Exhaust Systems

This paper covers far-field acoustic measurements of a family of rectangular nozzles with aspect ratio 8, in the high subsonic flow regime. Several variations of nozzle geometry, commonly proposed for embedded exhaust systems, are explored, including bevels, slants, single broad chevrons and notches, and internal septae. Far-field acoustic results, presented previously for the simple rectangular nozzle, showed that increasing aspect ratio increases the high frequency noise, especially directed in the plane containing the minor axis of the nozzle. Detailed changes to the nozzle geometry generally made little difference in the noise, and the differences were greatest at low speed. Having an extended lip on one broad side ('bevel') did produce up to 3dB more noise in all directions, while extending the lip on the narrow side ('slant') produced up to 2dB more noise, primarily on the side with the extension. Adding a single, non-intrusive chevron, made no significant change to the noise, while inverting the chevron ('notch') produced up to 2dB increase in the noise. Having internal walls ('septae') within the nozzle, such as would be required for structural support or when multiple fan ducts are aggregated, reduced the noise of the rectangular jet, but could produce a highly directional shedding tone from the septae trailing edges. Finally, a nozzle with both septae and a beveled nozzle, representative of the exhaust system envisioned for a distributed propulsion aircraft with a common rectangular duct, produced almost as much noise as the beveled nozzle, with the septae not contributing much reduction in noise.

Noise↗
NASA NTRS2015

Noise Measurements of High Aspect Ratio Distributed Exhaust Systems

This paper covers far-field acoustic measurements of a family of rectangular nozzles with aspect ratio 8, in the high subsonic flow regime. Several variations of nozzle geometry, commonly found in embedded exhaust systems, are explored, including bevels, slants, single broad chevrons and notches, and internal septae. Far-field acoustic results, presented previously for the simple rectangular nozzle, showed that increasing aspect ratio increases the high frequency noise, especially directed in the plane containing the minor axis of the nozzle. Detailed changes to the nozzle geometry generally made little difference in the noise, and the differences were greatest at low speed. Having an extended lip on one broad side (bevel) did produce up to 3 decibels more noise in all directions, while extending the lip on the narrow side (slant) produced up to 2 decibels more noise, primarily on the side with the extension. Adding a single, non-intrusive chevron, made no significant change to the noise, while inverting the chevron (notch) produced up to 2decibels increase in the noise. Having internal walls (septae) within the nozzle, such as would be required for structural support or when multiple fan ducts are aggregated, reduced the noise of the rectangular jet, but could produce a highly directional shedding tone from the septae trailing edges. Finally, a nozzle with both septae and a beveled nozzle, representative of the exhaust system envisioned for a distributed electric propulsion aircraft with a common rectangular duct, produced almost as much noise as the beveled nozzle, with the septae not contributing much reduction in noise.

Noise↗
NASA NTRS1994

Salt-induced aggregation of lysozyme: Implications for crystal growth

Crystallization of proteins is a prerequisite for structural analysis by x-ray crystallography. While improvements in protein crystals have been obtained in microgravity onboard the U.S. Space Shuttle, attempts to improve the crystal growth process both on the ground and in space have been limited by our lack of understanding of the mechanisms involved. Almost all proteins are crystallized with the aid of a precipitating agent. Many of the common precipitating agents are inorganic salts. An understanding of the role of salts on the aggregation of protein monomers is the key to the elucidation of the mechanisms involved in protein crystallization. In order for crystallization to occur individual molecules must self-associate into aggregates. Detection and characterization of aggregates in supersaturated protein solutions is the first step in understanding salt-induced crystallization.

Wilson, Lori J.↗
NASA NTRS1986

Rapid fluctuations in solar flares

Study of rapid fluctuations in the emission of radiation from solar flares provides a promising approach for probing the magneto-plasma structure and plasma processes that are responsible for a flare. It is proposed that elementary flare bursts in X-ray and microwave emission may be attributed to fine structure of the coronal magnetic field, related to the aggregation of photospheric magnetic field into magnetic knots. Fluctuations that occur on a subsecond time-scale may be due to magnetic islands that develop in current sheets during magnetic reconnection. The impulsive phase may sometimes represent the superposition of a large number of the elementary energy-release processes responsible for elementary flare bursts. If so, the challenge of trying to explain the properties of the impulsive phase in terms of the properties of the elementary processes must be faced. Magnetic field configurations that might produce solar flares are divided into a number of categories, depending on: whether or not there is a filament; whether there is no current sheet, a closed current sheet, or an open current sheet; and whether the filament erupts into the corona, or is ejected completely from the Sun's atmosphere. Analysis of the properties of these possible configurations is compared with different types of flares, and to Bai's subdivision of gamma-ray/proton events.

Sturrock, Peter A.↗
NASA NTRS1991

Sintering of two phase lamellar microstructures

The effect of an inert phase on neck growth rates during sintering of lamellar structures is described. Sintering diagrams are constructed for an aggregate of two-phase Cu spheres with lamellar microstructure containing an inert phase. It is shown that the regions corresponding to lattice diffusion domination shrink due to the inert phase presence. As the dispersion becomes finer, the alterations in the map become substantial.

Courtney, T. H.↗
NASA NTRS1997

Colloids and Nucleation

The objectives of the work funded under this grant were to develop a microphotographic technique and use it to monitor the nucleation and growth of crystals of hard colloidal spheres. Special attention is given to the possible need for microgravity studies in future experiments. A number of persons have been involved in this work. A masters student, Keith Davis, began the project and developed a sheet illumination apparatus and an image processing system for detection and analysis. His work on a segmentation program for image processing was sufficient for his master's research and has been published. A post doctoral student Bernie Olivier and a graduate student Yueming He, who originally suggested the sheet illumination, were funded by another source but along with Keith made photographic series of several samples (that had been made by Keith Davis). Data extraction has been done by Keith, Bernie, Yueming and two undergraduates employed on the grant. Results are published in Langmuir. These results describe the sheet lighting technique as one which illuminates not only the Bragg scattering crystal, but all the crystals. Thus, accurate crystal counts can be made for nucleation rate measurements. The strange crystal length scale reduction, observed in small angle light scattering (SALS) studies, following the initial nucleation and growth period, has been observed directly. The Bragg scattering (and dark) crystal size decreases in the crossover region. This could be an effect due to gravitational forces or due to over- compression of the crystal during growth. Direct observations indicate a complex morphology for the resulting hard sphere crystals. The crystal edges are fairly sharp but the crystals have a large degree of internal structure. This structure is a result of (unstable) growth and not aggregation. As yet unpublished work compares growth exponents data with data obtained by SALS. The nucleation rate density is determined over a broad volume fraction range (0.505 to 0.575) and compared to classical nucleation rate calculations. The experimental nucleation rate density varies with volume fraction more slowly than expected theoretically. Gravity may influence nucleation because crystal nuclei are more dense than the surrounding fluid and may be gravitationally convected. The largest observed crystal size was near volume fraction 0.52. Near the freezing point, crystals should grow to large size because nuclei are sparse and there is plenty of room to grow without contacting other crystals. Near melting the opposite is true, with crystals growing into one another shortly after nucleation. The maximum crystal size seen near 0.52 volume fraction suggests that gravitational stresses are limiting crystal growth near freezing.

Ackerson, Bruce↗
NASA NTRS1998

New AFM Techniques for Investigating Molecular Growth Mechanisms of Protein Crystals

Atomic Force Microscopy (AFM) has emerged as a powerful technique for investigating protein crystal growth. Earlier AFM studies were among the first to demonstrate that these crystals grew by dislocation and 2D nucleation growth mechanisms [1]. These investigations were restricted to the micron range where only surface features, such as dislocation hillocks and 2D islands are visible. Most AFM instruments can scan at higher resolutions and have the potential to resolve individual protein molecules at nanometer ranges. Such scans are essential for determining the molecular packing arrangements on crystal faces and for probing the growth process at the molecular level. However, at this resolution the AFM tip influences the image produced, with the resulting image being a convolution of the tip shape and the surface morphology [2]. In most studies this problem is resolved by deconvoluting the image to obtain the true surface morphology. Although deconvolution routines work reasonably well for simple one- dimensional shapes, for complex surfaces this approach does not produce accurate results. In this study we devised a new approach which takes advantage of the precise molecular order of crystal surfaces, combined with the knowledge of individual molecular shapes from the crystallographic data of the protein and the AFM tip shape. This information is used to construct expected theoretical AFM images by convoluting the tip shape with the constructed crystal surface shape for a given surface packing arrangement. By comparing the images from actual AFM scans with the constructed ones for different possible surface packing arrangements, the correct packing arrangement can be conclusively determined. This approach was used in this study to determine the correct one from two possible packing arrangements on (I 10) faces of tetragonal lysozyme crystals. Another novel AFM technique was also devised to measure the dimension of individual growth units of the crystal faces. Measuring these units was not attempted before and most studies have assumed that the growth unit consisted of individual protein molecules. The linescan mode of AFM instruments allows the crystal surface to be scanned along a single line. By scanning across a growth step an image showing the motion of the step is obtained. Normally such an image shows a straight line for continuous and constant step velocity. In this study by increasing the scan rate and by decreasing the step velocity (by decreasing the supersaturation), we were able to capture images of individual growth events, shown by jump discontinuities in the step line. By suitable integration of the image the growth unit dimension in the scanned direction can be obtained. Since multiple units can be involved in the growth process it is necessary to collect a statistically relevant sample before drawing conclusions about the growth mechanism. This technique was successfully employed to obtain the dimensions of growth units for the (110) face, showing that they consisted of various aggregates corresponding to the 43 helices in the crystal structure.

Li, Huayu↗
NASA NTRS1996

Method for Producing Non-Neoplastic, Three Dimensional, Mammalian Tissue and Cell Aggregates Under Microgravity Culture Conditions and the Products Produced Therefrom

Normal mammalian tissue and the culturing process has been developed for the three groups of organ, structural, and blood tissue. The cells are grown in vitro under microgravity culture conditions and form three dimensional cells aggregates with normal cell function. The microgravity culture conditions may be microgravity or simulated microgravity created in a horizontal rotating wall culture vessel.

Goodwin, Thomas J.↗
NASA NTRS2002

Characteristics of Vertical Profiles of Reflectivity and Doppler Derived From TRMM Field Campaigns

The TRMM Precipitation Radar (PR) measures the vertical profile of reflectivity from which the surface rain rate is estimated after attenuation corrections in the 2A21 algorithm. Characteristics of the vertical reflectivity profile is important for various reasons ranging from scientific to instrument algorithms. It is well known that different types of precipitation such as stratiform or convection, have different heating profiles. The vertical profile of reflectivity can provide information on precipitation classification. The vertical reflectivity structure also provides information on precipitation processes such as growth and aggregation. In terms of TRMM algorithms, an independent estimate of the vertical profiles are also extremely important since the PR returns can be attenuated in the rain layer near the surface. Corrections for attenuation are required in the lowest few kilometers, necessitating some assumptions about the rain size distributions and the reflectivity profile below the lowest measurement unaffected by the surface return. Furthermore, some assumptions about the vertical reflectivity profile are required for Ground Validation (GV) radars, since their lowest scan may be 1 or more kilometers above the surface. Statistics on the vertical reflectivity and Doppler structure are presented from the ER-2 Doppler Radar (EDOP) which participated in several TRMM field campaigns (TEFLUN-A, TEFLUN-B, and LBA) and CAMEX-3. The ER-2 aircraft overflew diverse precipitation types during these campaigns. EDOP is an X-band (9.6 GHz) radar for which returns are less attenuated than at the TRMM PR frequency. The EDOP profiles are first corrected for attenuation using the SRT method. The data from all the ER-2 campaigns are then classified by type (convection, stratiform, and other) and then statistics were performed on the vertical reflectivity and Doppler profiles in the form of CFAD's. These CFADs are compared and discussed. The computed CFAD's indicate significant differences as a function of precipitation type and location (hurricane versus non-hurricane, Brazil versus Florida). The implications of these profiles will be discussed.

Starr, David OC.↗
NASA NTRS1961

Semi-Annual Report: October 15, 1961

Investigations are proposed involving an experimental and theoretical program designed to investigate various properties of the structure of helium both in its atomic form and in the aggregates of the liquid and solid states. The key to the possibilities of performing the experiments lies in the relatively weak electric fields existing in liquid and solid helium and the possibility of producing external fields almost comparable with the internal fields. It is proposed to examine a) the melting pressure curve for helium as a function of electric field b) the dielectric constant of helium as a function of pressure and electric field c) in future, the effect of electric fields on the lambda transition. From the results of these experiments one would expect to be able to gather at least corroborative evidence on a) the crystal structure of solid helium on b) the effect of the Van der Waal interaction of the electric polarizability of helium, c) the possibility of producing helium molecules d) the effective volume available to helium atoms in the liquid and possibly e) the effect of particle interactions on the Bose-Einstein condensation.

HELIUM↗
NASA NTRS1983

The use of satellite observations of the ocean surface in commercial fishing operations

Commercial fishermen are interested in the safety of their crews, boats, and gear, and in making the best catch for their time and money. Rising fuel costs, increased competition from foreign fisheries, improved knowledge about fish habits and the new 200 mile economic zone have all had an impact on the U.S. fishing industry. As a consequence, the modern fisherman, more than ever, requires reliable and timely information about the marine environment. This paper describes an experimental program to utilize satellite observations of the ocean surface, in conjunction with conventional observations and products, to prepare special fisheries aids charts for daily radio facsimile broadcasts to commercial fishermen. These special fisheries products aggregate a broad set of ocean observations, including ocean color structure, to depict oceanographic conditions of importance to commercial fishing tactics. Results to date have shown that improved safety at sea and decreased fuel costs can be achieved through the applied use of these special fisheries charts.

Montgomery, D. R.↗
NASA NTRS1990

The role of data management in discipline-independent data visualization

The common data format (CDF) is described in terms of its support applications for the database management of visualization systems. The CDF is a self-describing data abstraction technique for the storage and manipulation of multidimensional data that are based on block structures. The discipline-independent approach is designed to manage, manipulate, archive, display, and analyze data, and can be applied to heterogeneous equipment communicating different data structures over networks. An improved CDF version incorporates a hyperplane access allowing random aggregate access to subdimensional blocks within a multidimensional variable. The visualization pipeline is also discussed, which controls the flow of data and permits the visualization of different classes of data representation techniques. The system is found to accommodate a large variety of scientific data structures and large disk-based data sets.

Treinish, Lloyd A.↗