Search NASA⌕ Search

SEARCH · Search NASA

Results for “Amine Sorbents”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS2011

Bench-Scale Trace Contaminant Testing of SA9T at Ambient and Reduced Pressure Conditions

A principal concern for air revitalization technology in a closed loop system is the capability to control carbon dioxide (CO2) and humidity (H2O). An amine based sorbent technology, SA9T, has been evaluated for use in this application and several programs are evaluating it for use in both cabin and space suit applications. While the CO2 and H2O performance of the sorbent has been tested extensively, the question of how trace contaminants impact performance requires further evaluation. This paper presents experimental results of bench-scale SA9T testing that was performed under a variety of test conditions and with several different trace contaminants. Tests were conducted to determine if the capacity of the SA9T media to sufficiently remove CO2 and H2O is compromised after exposure to a fully saturated trace contaminant at ambient conditions. Tests also were conducted to evaluate the performance of SA9T at ambient conditions in a continuous 30-day test with a mixed trace contaminant stream. In addition, testing also evaluated the impact of CO2 and H2O removal performance at suit loop pressures (29.6 KPa/4.3 psia) during cyclic operation with a constant inlet contaminant load.

Broerman, Craig↗
NASA NTRSDate not supplied

Literature Review of Microwave Regeneration of CO2 Capture Sorbent Materials

Utilizing liquid amines for air revitalization applications has been of continued interest for many decades. They have the advantage of being regenerable sorbents with long lifetimes and a high acuteness for carbon dioxide. While their usage on Earth for flue gas and submarines has been explored for some time now, they are still being researched for use in microgravity environments. To succeed in a microgravity environment, such as usage on the International Space Station, an air revitalization system that is reliant on liquid amines as its sorbent must have a low Equivalent System Mass (ESM), among many other performance parameters. One way of optimizing this ESM number is through bringing down the systems power consumption with the use of microwave heating of the liquid sorbent. Microwave heating allows the liquid sorbent to be heated in a much more efficient way when compared to conventional types of heating techniques, such as convection or conduction. This paper will explore the physical mechanisms behind microwave heating, and how it could potentially be applied to a liquid amine carbon capture system, laying out any concerns and future constraints that a system designer may encounter.

Tiago Faria Costa↗
DOE OSTI2024

Assessment of Amine-Based CO2BOLs for Direct Air Capture

Direct air capture (DAC) technologies extract CO 2 from the atmosphere for CO 2 storage, or utilization. Capturing CO 2 from the air is the most expensive application of carbon capture because CO 2 in the atmosphere is very dilute. There are limited number of CO 2 capture technologies for DAC application. This project aims at developing an energy efficient technology for DAC, leveraging two PNNL’s chemistries (solid and liquid CO 2 capture). Three CO 2 capture sorbents consisting of amine based CO 2 BOLs immobilized in mesoporous silica were designed, synthesized, and tested. These sorbents had ~ 19-23 wt.% amine loadings which is lower than typical amine-based silica sorbents. The surface area and pore volumes of these solid supported CO 2 BOLs are lower compared to those of the pristine silica support. The CO 2 capture performance of these materials was significantly lower than the typical silica supported amines due to low amine loading and higher molecular weight with low amine density. These results show that immobilize CO 2 BOLs in silica are not viable materials for removing CO 2 from ambient air. This project also designed, synthesized at tested liquid solvents for DAC application. Solvent properties that is vapor pressure, CO 2 uptake capacity, kinetics, and viscosity for three novel solvents were evaluated. The CO 2 uptake capacity for one of the most promising amine-based solvent BEPBEGDA was the highest at 13.2 wt% corresponding to 97 mol%. The vapor pressure of the BEPBEGDA solvents were very low at 80 °C compared to other solvents making them suitable for DAC application. The effect of humidity on the CO 2 capture performance of these solvents was evaluated which shows that presence of moisture doesn’t have a negative effect on the CO 2 uptake performance but makes it slightly better. The performances of these solvents were slightly below that of the 0.1M NaOH solution tested under similar conditions. Despite of the slightly lower CO 2 uptake, it is expected that these liquid solvents will have lower regeneration temperature and minimum evaporative losses due their low vapor pressure. Future work will focus on optimization of the liquid solvents for DAC application to improve both CO 2 capture efficiency and capacity without viscosity and vapor pressure increase. Testing of these solvents under DAC conditions using a gas liquid contactor that mimic industrial applications is needed. Solvent cost projection, techno-economic analysis and life cycle analysis are required to evaluate economic viability of this technology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Challenges in Product Selectivity for Electrocatalytic Reduction of Amine-Captured CO 2 : Implications for Reactive Carbon Capture

CO 2 is a potential feedstock for carbon-based fuels or materials, but is only available in dilute streams. Integrated processes for CO 2 capture and conversion directly valorize the CO 2 captured by sorbent materials, skipping the energetically expensive sorbent regeneration step. Amines are the most heavily studied liquid-phase sorbent materials for CO 2 capture from dilute streams. Amines react with CO 2 in a 2:1 ratio to form the corresponding ammonium carbamate. Ammonium carbamate [NH 4 ][H 2 NCO 2 ] was tested as the substrate using the highly selective and robust CO 2 -to-formate reduction electrocatalyst [( tBu POCOP)Ir(H)(NCCH 3 ) 2 ], where ( tBu POCOP) is the tridentate pincer ligand 2,6-bis(di tert -butyl-phosphonito). When ammonium carbamate was used as the substrate instead of CO 2 , only hydrogen was produced. An equivalent electrolysis with ammonium hexafluorophosphate with CO 2 also resulted in primarily hydrogen. Methyl carbamate and urea were also tested as substrates as proxies for carbamate that do not contain an equivalent of ammonium, and there was also negligible reduction to carbon-based products. These results indicate that the loss of selectivity observed for aminecaptured CO 2 , or ammonium carbamate, is likely due to the generation of the acidic ammonium equivalent as well as the greater challenge of reducing carbamate compared to CO 2 . This study illustrates that catalysts with high selectivity for concentrated CO 2 can favor hydrogen evolution and loss of carbon-based products when amine-captured CO 2 is used instead.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRSDate not supplied

Ammonia-Removal Efficiency By Full-Scale Carbon-Based Trace-Contaminant Sorbent Monoliths Integrated With the Rapid-Cycle Amine (RCA) Swing Bed

Results are presented on full-scale performance testing of vacuum-regenerable, carbon based sorbent monoliths for trace-contaminant (TC) removal integrated with the Rapid-Cycle Amine (RCA) swing bed for use in the Portable Life Support System (PLSS) during Extravehicular Activities (EVAs). The current state-of-art in TC-control technology involves the use of a packed bed of acid-impregnated granular charcoal, which is difficult to regenerate. The carbon-based sorbent under development in this project can be regenerated by exposure to vacuum at room temperature. Data on cyclic sorption-desorption of ammonia, which is a major TC of concern, were collected in a simulated PLSS ventilation loop which involved the RCA placed upstream of the Trace Contaminant Control System (TCCS). Results of testing involving pressure-swing operation of the integrated TCCS/RCA system indicate ammonia-removal efficiency exceeding 80% throughout multiple sorption-desorption cycles. This paper presents an overview of the TCCS research, the favorable results obtained, and provides insight into future work needed to further the technology development.

Marek A Wójtowicz↗
NASA NTRS2006

Development Status of Amine-based, Combined Humidity, CO2, and Trace Contaminant Control System for CEV

Under a NASA-sponsored technology development project, a multi-disciplinary team consisting of industry, academia, and government organizations lead by Hamilton Sundstrand is developing an amine-based humidity and CO2 removal process and prototype equipment for Vision for Space Exploration (VSE) applications. Originally this project sought to research enhanced amine formulations and incorporate a trace contaminant control capability into the sorbent. In October 2005, NASA re-directed the project team to accelerate the delivery of hardware by approximately one year and emphasize deployment on board the Crew Exploration Vehicle (CEV) as the near-term developmental goal. Preliminary performance requirements were defined based on nominal and off-nominal conditions and the design effort was initiated using the baseline amine sorbent, SA9T. As part of the original project effort, basic sorbent development was continued with the University of Connecticut and dynamic equilibrium trace contaminant adsorption characteristics were evaluated by NASA. This paper summarizes the University sorbent research effort, the basic trace contaminant loading characteristics of the SA9T sorbent, design support testing, and the status of the full-scale system hardware design and manufacturing effort.

Smith, Fred↗
DOE OSTI2026

Direct Air Capture Using Trapped Small Amines in Hierarchical Nanoporous Capsules on Porous Electrospun Fibers (Final Technical Report)

This report summarizes the carbon capture research and development conducted by The State University of New York at Buffalo (UB) and GTI Energy (GTI) for award “DE-FE0031969: Direct Air Capture Using Trapped Small Amines in Hierarchical Nanoporous Capsules on Porous Electrospun Fibers” sponsored by the U.S. Department of Energy (DOE). The objective of this project is to develop an innovative sorbent structure of trapped small amines in HNC embedded in PEF for DAC. This involves tailoring both sorbent and PEF materials to achieve a compact system for DAC with high capacity for CO 2 at concentrations typically available in air and at near ambient conditions. An innovative sorbent structure of trapped small amines in hierarchical nanoporous capsules (HNC) embedded in porous electrospun fibers (PEF) was developed for direct air capture (DAC). This involves tailoring both sorbent and PEF materials to achieve a compact system for DAC with high capacity for CO 2 at concentrations typically available in air and at near ambient conditions. An interfacial polymerization process was developed, which utilized loaded amines inside mesoporous silica and trimesoyl chloride (TMC) dissolved in organic solvents as the precursors, to generate a polyamide (PA) coating layer on mesoporous silica and thus trap amines. Reaction conditions, including TMC concentration, organic solvents, reaction time, etc., for interfacial polymerization were optimized to effectively trap loaded amines, and cyclic heating-cooling operation was conducted to evaluate the coating quality. Larger pore volume mesoporous silica was also synthesized to increase amine loading and thus increase CO 2 capacity. The optimized sorbent material exhibited CO 2 capacity as high as 4.88 mmol/g under humid DAC conditions and negligible loss (<1%) during 10 cyclic heating-cooling operations. The optimized PA-coated sorbent also showed fast adsorption and desorption kinetics, with <20% t1/2 increase compared to uncoated sorbent. PEF fabrication conditions, including organic solvents for dissolving core and shell polymers, voltage, distance from the nozzle to the collection panel, etc. were adjusted to better incorporate HNC. After incorporating the optimized sorbent material into PEF, the structured sorbent had a CO 2 capacity of approximately 4.0 mmol/g under humid DAC conditions, with capacity loss of 0.17% per cycle and t1/2 increase less than 10%. A techno-economic analysis (TEA) for the process design for a DAC system based on our developed sorbent structure of trapped small amines in HNC embedded in PEF was conducted. The process design included process description and major equipment sizing and energy and mass balances in addition to scale-up research results and estimated capture cost. Aspen Adsorption Simulator was used to fit the experimentally measured breakthrough curves and extract equilibrium and kinetic data of the optimized sorbent. Our results indicated that for a DAC plant with CO 2 productivity of 3,000 tonne/year, the levelized cost of CO 2 capture was $\$$612/tonne, with the largest contribution of 44.33% from the fixed operation cost. Increasing CO 2 productivity, while maintaining similar fixed operation cost, is expected to significantly reduce the CO 2 capture cost. A sensitivity study was also conducted to understand the influence of total plant cost, sorbent cost, CO 2 concentration in the feed, sorbent mat lifetime, sorbent regeneration electricity, and adsorption blower pressure drop on the levelized cost of CO 2 capture, revealing a capture cost range of $\$$520-870/tonne.

36 MATERIALS SCIENCE↗
NASA NTRS2020

NASA Exploration Systems & Habitation (X-Hab)Academic Innovation Challenge 2020: Microgravity Gas/Liquid Separator for the CO2 Revitalization System Final Report

This report outlines the efforts of UNT X-Hab Team on a project titled, Microgravity Gas/Liquid Separator for the CO2 Revitalization System. The project is executed as a senior design project during academic year 2019-2020. The X-Hab 2020 Academic Innovation Challenge has selected eleven senior design teams from colleges across the US to demonstrate working prototypes for exploration systems and habitation. UNT has been tasked with the creation of a gas-liquid separator for an air revitalization system. Air revitalization technology has been used to support spaceflight by removing CO2 from enclosed systems in order to maintain breathable air. Solid sorbents such as zeolites or lithium hydroxide have been used in the past for these systems but are difficult to handle in microgravity environments and require a large amount of energy. This challenge aims to demonstrate vortex phase separator (VPS) technology for removing H2O from a CO2 stream. However, VPS technology also has the capability of using liquid sorbents for removing CO2 from an air stream. Further research could be done on liquid sorbents, such as liquid amine, in use with VPS systems. This would potentially be an alternative technology in replacing use of solid sorbents in CO2 removal systems. In 2019, NASA proposed a design that uses a gas/liquid contactor to allow for efficient contact between the two fluid phase. This was integrated into an overall CO2 removal system. The subsystems for gas-liquid separation and storage in NASA’s previous models for CO2 removal system could be replaced with a VPS. Innovative vortex separator technology is expected to allow for high throughput flow and highly efficient CO2 removal compared to other gas-liquid separation technologies. VPS relies on centripetal driven buoyancy forces to form a gas-liquid vortex within a fixed, right circular cylinder. The gas stream enters the separator through a tangential nozzle and breaks into very small bubbles (<<1 mm) resulting in a very large contact surface area for interaction with the liquid stream via energy and mass exchange. VPS technology can handle mismatches in inlet and outlet flow rates and system volume changes through the range of liquid thickness held in the separator (i.e., buffering and accumulating capability), and requires low pressure differences (<5-10 in H2O in most cases) for operation. The X-Hab 2020 team leverages these characteristics to investigate VPS technology as an alternative CO2 removal technology.

Alyssa Sarvadi↗
DOE OSTI2023

Development of Advanced Solid Sorbents for Direct Air Capture (Final Report)

RTI International is partnering with Creare, and Mohammed VI Polytechnic University (UM6P) successfully met all major technical objectives as outlined below: Identified one MOF adsorbent for DAC; Identified one amine-P-dendrimer adsorbent for DAC; Performed Computational fluid dynamics simulations of the MOF and amine-P-dendrimer adsorbents and validate them with experimental data; Selected one adsorbent for DAC; Demonstrated the scale-up of selected candidate and perform cost review; Performed a preliminary process design; Performed technology maturation plan and environmental health and safety risk assessment. After a thorough comparison between both adsorbents (MOFs and P-dendrimers) and based on their technical merits, the amine-based P-dendrimers sorbent was selected as the best performing adsorbent for DAC. In fact, the amine-based P-dendrimers have demonstrated superior performance over the MOF sorbents under relevant DAC conditions. The selected sorbent has been used in subsequent projects (DE-FE0032099 and DE-AR0001412) and has demonstrated similar superior performance with no loss of activity after long-term sorption-desorption testing (e.g., 100 cycles). This sorbent has demonstrated a very high and stable sorption performance, excellent kinetics, and fast regeneration at 80 °C, specifically at 75% relative humidity (RH). The incorporation of RTI’s high-performance, high-durability amine-based P-dendrimers sorbent and Creare’s hybrid additive manufacturing (H-AM) technology that will produce high performance, compact heat and mass exchange structures at low cost using methods, will lead to a contactor that is optimized for wind-driven operation. This contactor technology provides a technically viable pathway for reducing the cost of DAC to <$100/tonne of CO 2 .

36 MATERIALS SCIENCE↗
DOE OSTI2026

Bench-Scale Development of Promoted High-Capacity Structured Sorbents (Final Technical Report)

The project objective was to develop high-capacity structured sorbent capable of achieving low CO 2 removal from air. The sorbent framework consists of an amine-functionalized onto hydrophobic polymer backbone with an added promoter. The functionalized amine provides high CO 2 capacity and adsorption rates and the polymer backbone to reduce water uptake. For the sorbent development, multiple functionalized amines and promoters were assessed to select a candidate that achieved high CO 2 capacity, high adsorption rate, and high stability. A sorbent-coated filter design was selected as the structured sorbent, which provides high sorbent loading capacity and contains an electrically conductive nonwoven filter substrate that can be Joule-heated to provide efficient utilization of available electricity for sorbent regeneration. A commercial partner operated a pilot filter manufacturing line to produce the filter panels coated with the developed sorbent. A 1 kg CO 2 /day bench unit was designed and fabricated to test the structured filter sorbent. The key achievements from the structured sorbent development activity were demonstrating that existing filter industrial-scale processes can be used for manufacturing Susteon’s structured sorbent and completing a proof-of-concept demonstration of the commercially manufactured structured sorbent filters for CO 2 capture from air with direct, Joule-heated regeneration. A techno-economic assessment with sensitivity analysis was conducted on a 100,000 TPY facility with 85% operating capacity. Through sorbent optimization and process design improvements, it is estimated that the cost of capture was reduced from $\$$349/tCO 2 to $\$$241/tCO 2 . The TEA projects further reductions to $165/tCO 2 through enhancements in CO 2 adsorption rate and sorbent capacity and reducing manufacturing and scale up risks. A life cycle analysis was conducted on the same 100,000 TPY facility and confirmed that the facility’s electricity demand drives its greenhouse gas impact. It was determined that electricity supplied through the current grid mix would result in net-positive CO 2 emissions and that achieving net-negative emissions is only possible by powering the system with renewable electricity or fossil fuel sources equipped with carbon capture and sequestration.

36 MATERIALS SCIENCE↗
DOE OSTI2023

High-Performance CO 2 Capture from Air by Harnessing the Power of CaO- and Superbase-Ionic-Liquid-Engineered Sorbents

Direct air capture (DAC) of CO 2 by solid porous materials represents an attractive “negative emission” technology. However, state-of-the-art sorbents based on supported amines still suffer from unsolved high energy consumption and stability issues. For this work, taking clues from the CO 2 interaction with superbase-derived ionic liquids (SILs), high-performance and tunable sorbents in DAC of CO 2 was developed by harnessing the power of CaO- and SIL-engineered sorbents. Deploying mesoporous silica as the substrate, a thin CaO layer was first introduced to consume the surface-OH groups, and then active sites with different basicities (e. g., triazolate and imidazolate) were introduced as a uniformly distributed thin layer. The as-obtained sorbents displayed high CO 2 uptake capacity via volumetric (at 0.4 mbar) and breakthrough test (400 ppm CO 2 source), rapid interaction kinetics, facile CO 2 releasing, and stable sorption/desorption cycles. Operando diffuse reflectance infrared Fourier transformation spectroscopy (DRIFTS) analysis under simulated air atmosphere and solid-state NMR under 13 CO 2 atmosphere demonstrated the critical roles of the SIL species in low-concentration CO 2 capture. The fundamental insights obtained in this work provide guidance on the development of high-performance sorbents in DAC of CO 2 by leveraging the combined advantages of porous solid scaffolds and the unique features of CO 2 -philic ionic liquids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2010

Trace Contaminant Testing with the Orion Atmosphere Revitalization Technology

Every spacecraft atmosphere contains trace contaminants resulting from offgassing by cabin materials and human passengers. An amine-based carbon dioxide (CO2) and water vapor sorbent in pressure-swing regenerable beds has been developed by Hamilton Sundstrand and baselined for the Orion Atmosphere Revitalization System (ARS). Part of the risk mitigation effort for this new technology is the study of how atmospheric trace contaminants will affect and be affected by the technology. One particular area of concern is ammonia, which, in addition to the normal spacecraft sources, can also be offgassed by the amine-based sorbent. In the spring of 2009, tests were performed at Johnson Space Center (JSC) with typical cabin atmosphere levels of five of the most common trace gases, most of which had not yet been tested with this technology. A subscale sample of the sorbent was exposed to each of the chemicals mixed into a stream of moist, CO2-laden air, and the CO2 adsorption capacity of the sorbent was compared before and after the exposure. After these typical-concentration chemicals were proven to have negligible effect on the subscale sample, tests proceeded on a full-scale test article in a sealed chamber with a suite of eleven contaminants. To isolate the effects of various test rig components, several extended-duration tests were run: without injection or scrubbing, with injection and without scrubbing, with injection of both contaminants and metabolic CO2 and water vapor loads and scrubbing by both the test article and dedicated trace contaminant filters, and with the same injections and scrubbing by only the test article. The high-level results of both the subscale and full-scale tests are examined in this paper.

Button, Amy B.↗
NASA NTRS2009

Trace Contaminant Testing with the Orion Atmosphere Revitalization Technology

Every spacecraft atmosphere contains trace contaminants resulting from offgassing by cabin materials and human passengers. An amine-based carbon dioxide (CO2) and water vapor sorbent in pressure-swing regenerable beds has been developed by Hamilton Sundstrand and baselined for the Orion Atmosphere Revitalization System (ARS). Part of the risk mitigation effort for this new technology is the study of how atmospheric trace contaminants will affect and be affected by the technology. One particular area of concern is ammonia, which, in addition to the normal spacecraft sources, can also be off-gassed by the amine-based sorbent. In the first half of 2009, tests were performed with typical cabin atmosphere levels of five of the most common trace gases, most of which had not yet been tested with this technology. A subscale sample of the sorbent was exposed to each of the chemicals mixed into a stream of moist, CO2-laden air, and the CO2 adsorption capacity of the sorbent was compared before and after the exposure. After these typical-concentration chemicals were proven to have negligible effect on the subscale sample, tests proceeded on a full-scale test article in a sealed chamber with a suite of eleven contaminants. To isolate the effects of various test rig components, several extended-duration tests were run: without injection or scrubbing, with injection and without scrubbing, with injection and scrubbing by both the test article and dedicated trace contaminant filters, and with injection and scrubbing by only the test article. The high-level results of both the subscale and full-scale tests are examined in this paper.

Button, Amy Lin↗
DOE OSTI2025

Photoreactive Capture and Conversion of Dilute Carbon Dioxide into Synthetic Natural Gas

This study introduces a photoreactive system that integrates the capture of dilute CO 2 streams with their catalytic conversion to synthetic natural gas (CH 4 ), utilizing a Ru nanoparticle (NP)-doped TiO 2 composite loaded with linear polyethylenimine (L-PEI) and enhanced with plasmonic titanium nitride (TiN). This light-driven approach mitigates challenges that have plagued traditional thermal reactive carbon capture (RCC) methods, such as CO 2 slip and amine degradation. We demonstrate that L-PEI enables stable CO 2 capture and conversion, achieving ~70% conversion of captured CO 2 to CH 4 across multiple reaction cycles using nonflammable forming gas (~5% H 2 ) as the reductant. In contrast, branched PEI (B-PEI)-loaded composites exhibited significant catalyst deactivation after several RCC cycles. Scanning transmission electron microscopy (STEM) imaging confirms that significant sintering of the Ru NPs occur in the B-PEI sample under RCC conditions, whereas their size remains stable in more rigid L-PEI composites. Technoeconomic analysis (TEA) estimates that CH 4 production using this system could cost less than $\$$5/kg based on current electrocatalytic H 2 prices. These results represent one of the most promising demonstrations of amine-based RCC employing dilute CO 2 sources to date.

36 MATERIALS SCIENCE↗
NASA NTRS2005

International Space Station Carbon Dioxide Removal Assembly (ISS CDRA) Concepts and Advancements

An important aspect of air revitalization for life support in spacecraft is the removal of carbon dioxide from cabin air. Several types of carbon dioxide removal systems are in use in spacecraft life support. These systems rely on various removal techniques that employ different architectures and media for scrubbing CO2, such as permeable membranes, liquid amine, adsorbents, and absorbents. Sorbent systems have been used since the first manned missions. The current state of key technology is the existing International Space Station (ISS) Carbon Dioxide Removal Assembly (CDRA), a system that selectively removes carbon dioxide from the cabin atmosphere. The CDRA system was launched aboard UF-2 in February 2001 and resides in the U.S. Destiny Laboratory module. During the past four years, the CDRA system has operated with varying degrees of success. There have been several approaches to troubleshooting the CDRA system aimed at developing work-around solutions that would minimize the impact on astronaut time required to implement interim solutions. The paper discusses some of the short-term fixes applied to promote hardware life and restore functionality, as well as long-term plans and solutions for improving operability and reliability. The CDRA is a critical piece of life support equipment in the air revitalization system of the ISS, and is demonstrated technology that may ultimately prove well-suited for use in lunar or Mars base, and Mars transit life support applications.

ElSherif, Dina↗
DOE OSTI2020

Regenerative adsorbents of modified amines on solid supports

The invention relates to regenerative, solid sorbents for adsorbing carbon dioxide from a gas mixture, including air, with the sorbent including a modified polyamine and a solid support. The modified polyamine is the reaction product of an amine and an epoxide. The sorbent provides structural integrity, as well as high selectivity and increased capacity for efficiently capturing carbon dioxide from gas mixtures, including the air. The sorbent is regenerative, and can be used through multiple cycles of adsorption-desorption.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Regenerative adsorbents of modified amines on solid supports

The invention relates to regenerative, solid sorbents for adsorbing carbon dioxide from a gas mixture, including air, with the sorbent including a modified polyamine and a solid support. The modified polyamine is the reaction product of an amine and an epoxide. The sorbent provides structural integrity, as well as high selectivity and increased capacity for efficiently capturing carbon dioxide from gas mixtures, including the air. The sorbent is regenerative, and can be used through multiple cycles of adsorption-desorption.

Goeppert, Alain↗