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NASA NTRS2005

Of Ashes and Atoms

This feature length DVD documentary, reviews the history of the Plum Brook Nuclear Reactor from the initial settlers of the area, through its use as a munitions facility during the second World War to the development of the nuclear facility and its use as one of the first nuclear test reactors built in the United States, and the only one built by NASA. It concludes with the beginning of the decommissioning of the facility. There is a brief review of the reactor design, and its workings. Through discussions with the NASA engineers and operators of the facility, the film reviews the work done to advance the knowledge of the effects of radiation, the properties of radiated materials, and the work to advance the state of the art in nuclear propulsion. The film shows footage of public tours, and shows actual footage of the facility in operation, and after its shutdown in 1973. The DVD was narrated by Kate Mulgrew, who leads the viewer through the history of the facility to its eventual ongoing decommissioning, and return to the state of pastoral uses.

Source record↗
NASA NTRSDate not supplied

Plasma Assisted Nutrient Recovery from Inedible Biomass via Ash Leaching

Sustaining a human presence on the Moon, Mars, or deep space will require closing loops on many life support systems. Some form of agriculture will be required because plants produce the vitamins, antioxidants, and essential oils in our diets that degrade over time in stored foods. In addition, they provide dietary fiber, revitalize air and purify water. It is estimated that 93 kg of plant nutrients are required to support one crew member per year. Growing plants will require recycling nutrients trapped in inedible plant stems, leaves and debris. We examined the effects of using thermal plasma and various carrier gases to breakdown inedible plant biomass and aid in nutrient recovery. Previous work demonstrated a thermally degrading environment such as a muffle furnace improved nutrient recovery from inedible biomass prior to an acid leaching process, however, a muffle furnace is an inefficient process. We tested the ability of a small scale, thermal plasma using carbon dioxide, nitrogen, or air as plasma carrier gases to degrade pelleted plant biomass. The gases were chosen to explore variations in recovery and potential chemical by-products. Plasma treated and untreated biomass was leached with different concentrations of acid to determine the extraction of nutrients (potassium, magnesium, calcium, and. phosphorus) for reuse in the crop production cycle. Results are presented showing the impact of plasma processing prior to acid leaching on recovery of plant nutrients.

Plasma↗
NASA NTRS2022

Plasma Assisted Nutrient Recovery from Inedible Biomass via Ash Leaching

Sustaining a human presence on the Moon, Mars, or deep space will require closing loops on many life support systems. Some form of agriculture will be required because plants produce the vitamins, antioxidants, and essential oils in our diets that degrade over time in stored foods. In addition, they provide dietary fiber, restore air, and purify water. Growing plants will require recycling nutrients trapped in inedible vegetation. Researchers at KSC have investigated the use of a thermal plasma with various carrier gases to thermally degrade inedible plant biomass for nutrient recovery. Previous work demonstrated a thermally degrading environment such as a muffle furnace improved nutrient recovery from inedible biomass prior to an acid leaching process. However, a muffle furnace is an inefficient process. We have explored the use of a small scale, thermal plasma for degradation of pellets to enhance the breakdown of plant stems, leaves, and debris to further close the nutrient loop. Plasma carrier gases such as carbon dioxide (CO2), nitrogen (N2), and air were used to explore variations in recovery and potential chemical by-products. Plasma processed inedible biomass was added to varying concentrations of acid solution for leaching of nutrients (e.g. potassium (K) , magnesium (Mg), calcium (Ca), and phosphorus (P)) for reuse in the crop production cycle. We also examined total N2 recovery. Results are presented showing the impact of plasma processing prior to acid leaching on recovery of plant nutrients.

Kenneth Engeling↗
NASA NTRS1996

Recycle of Inorganic Nutrients for Hydroponic Crop Production Following Incineration of Inedible Biomass

Recovery of resources from waste streams is essential for future implementation and reliance on a regenerative life support system. The major waste streams of concern are from human activities and plant wastes. Carbon, water and inorganics are the primary desired raw materials of interest. The goal of resource recovery is maintenance of product quality to insure support of reliable and predictable levels of life support function performance by the crop plant component. Further, these systems must be maintained over extended periods of time, requiring maintenance of nutrient solutions to avoid toxicity and deficiencies. Today, reagent grade nutrients are used to make nutrient solutions for hydroponic culture and these solutions are frequently changed during the life cycle or sometimes managed for only one crop life cycle. The focus of this study was to determine the suitability of the ash product following incineration of inedible biomass as a source of inorganic nutrients for hydroponic crop production. Inedible wheat biomass was incinerated and ash quality characterized. The incinerator ash was dissolved in adequate nitric acid to establish a consistent nitrogen concentration in all nutrient solution treatments. Four experimental nutrient treatments were included: control, ash only, ash supplemented to match control, and ash only quality formulated with reagent grade chemicals. When nutrient solutions are formulated using only ash following-incineration of inedible biomass, a balance in solution is established representing elemental retention following incineration and nutrient proportions present in the original biomass. The resulting solution is not identical to the control. This imbalance resulted in suppression of crop growth. When the ash is supplemented with nutrients to establish the same balance as in the control, growth is identical to the control. The ash appears to carry no phytotoxic materials. Growth in solution formulated with reagent grade chemicals but matching the quality of the ash only treatment resulted in growth similar to that of the ash only treatment. The ash product resulting from incineration of inedible biomass appears to be a suitable form for recycle of inorganic nutrients to crop production.

Bubenheim, David L.↗
NASA NTRS2023

The Calipso Version 4.5 Stratospheric Aerosol Subtyping Algorithm

The accurate classification of aerosol types injected into the stratosphere is important to properly characterize their chemical and radiative impacts within the Earth climate system. The updated stratospheric aerosol subtyping algorithm used in the version 4.5 (V4.5) release of the Cloud Aerosol Lidar with Orthogonal Polarization (CALIOP) level 2 data products now delivers more comprehensive and accurate classifications than its predecessor. The original algorithm identified four aerosol subtypes for layers detected above the tropopause: volcanic ash, smoke, sulfate/other, and polar stratospheric aerosol (PSA). In the revised algorithm, sulfates are separately identified as a distinct, homogeneous subtype, and the diffuse, weakly scattering layers previously assigned to the sulfate/other class are recategorized as a fifth “unclassified” subtype. By making two structural changes to the algorithm and revising two thresholds, the V4.5 algorithm improves the ability to discriminate between volcanic ash and smoke from pyrocumulonimbus injections, improves the fidelity of the sulfate subtype, and more accurately reflects the uncertainties inherent in the classification process. The 532 nm lidar ratio for volcanic ash was also revised to a value more consistent with the current state of knowledge. This paper briefly reviews the previous version of the algorithm (V4.1 and V4.2) then fully details the rationale and impact of the V4.5 changes on subtype classification frequency for specific events where the dominant aerosol type is known based on the literature. Classification accuracy is best for volcanic ash due to its characteristically high depolarization ratio. Smoke layers in the stratosphere are also classified with reasonable accuracy, though during the daytime a substantial fraction are misclassified as ash. It is also possible for mixtures of ash and sulfate to be misclassified as smoke. The V4.5 sulfate subtype accuracy is less than that for ash or smoke, with sulfates being misclassified as smoke about one-third of the time. However, because exceptionally tenuous layers are now assigned to the unclassified subtype and the revised algorithm levies more stringent criteria for identifying an aerosol as sulfate, it is more likely that layers labeled as this subtype are in fact sulfate compared to those assigned the sulfate/other classification in the previous data release.

Jason L Tackett↗
NASA NTRS1995

Incineration as a Method for Resource Recovery from Inedible Biomass in a Controlled Ecological Life Support System

Resource recovery from waste streams in a space habitat is essential to minimize the resupply burden and achieve self-sufficiency. In a Controlled Ecological Life Support System (CELSS) human wastes and inedible biomass will represent significant sources of secondary raw materials necessary for support of crop plant production (carbon, water, and inorganic plant nutrients). Incineration, pyrolysis, and water extraction have been investigated as candidate processes for recovery of these important resources from inedible biomass in a CELSS. During incineration CO2 is produced by oxidation of the organic components and this product can be directly utilized by plants. Water is concomitantly produced, requiring only a phase change for recovery. Recovery of inorganics is more difficult, requiring solubilization of the incinerator ash. The process of incineration followed by water solubilization of ash resulted in loss of 35% of the inorganics originally present in the biomass. Losses were attributed to volatilization (8%) and non-water-soluble ash (27%). All of the ash remaining following incineration could be solubilized with acid, with losses resulting from volatilization only. The recovery for individual elements varied. Elemental retention in the ash ranged from 100% of that present in the biomass for Ca, P, Mg, Na, and Si to 10% for Zn. The greatest water solubility was observed for potassium with recovery of approximately 77% of that present in the straw. Potassium represented 80% of the inorganic constituents in the wheat straw, and because of slightly greater solubility made up 86% of the water-soluble ash. Following incineration of inedible biomass from wheat, 65% of the inorganics originally present in the straw were recovered by water solubilization and 92% recovered by acid solubilization. Recovery of resources is more complex for pyrolysis and water extraction. Recovery of carbon, a resource of greater mass than the inorganic component of biomass, is more difficult following pyrolysis and water extraction of biomass. In both cases, additional processors would be required to provide products equivalent to those resulting from incineration alone. The carbon, water, and organic resources of inedible biomass are effectively separated and output in usable forms through incineration.

Bubenheim, David L.↗
NASA NTRS2011

In Situ Observations and Sampling of Volcanic Emissions with Unmanned Aircraft: A NASA/UCR Case Study at Turrialba Volcano, Costa Rica

Burgeoning new technology in the design and development of robotic aircraft-unmanned aerial vehicles (UAVs)-presents unprecedented opportunities for the volcanology community to observe, measure, and sample eruption plumes and drifting volcanic clouds in situ. While manned aircraft can sample dilute parts of such emissions, demonstrated hazards to air breathing, and most particularly turbine, engines preclude penetration of the zones of highest ash concentrations. Such areas within plumes are often of highest interest with respect to boundary conditions of applicable mass-loading retrieval models, as well as Lagrangian, Eulerian, and hybrid transport models used by hazard responders to predict plume trajectories, particularly in the context of airborne hazards. Before the 2010 Ejyafyallajokull eruption in Iceland, ICAO zero-ash-tolerance rules were typically followed, particularly for relatively uncrowded Pacific Rim airspace, and over North and South America, where often diversion of aircraft around ash plumes and clouds was practical. The 2010 eruption in Iceland radically changed the paradigm, in that critical airspace over continental Europe and the United Kingdom were summarily shut by local civil aviation authorities and EURO CONTROL. A strong desire emerged for better real-time knowledge of ash cloud characteristics, particularly ash concentrations, and especially for validation of orbital multispectral imaging. UAV platforms appear to provide a viable adjunct, if not a primary source, of such in situ data for volcanic plumes and drifting volcanic clouds from explosive eruptions, with prompt and comprehensive application to aviation safety and to the basic science of volcanology. Current work is underway in Costa Rica at Turrialba volcano by the authors, with the goal of developing and testing new small, economical UAV platforms, with miniaturized instrument payloads, within a volcanic plume. We are underway with bi-monthly deployments of tethered SO2-sondes and are in the planning stages for the deployment of the SIERRA UAV to our site in March 2013. We will be conducting in situ observations simultaneously with ASTER orbital multispectral TIR data acquisitions, in order to compare in situ measurements with estimates of SO2 mass loading and dispersion derived from ASTER data. Though small UAVs are now being considered for use in active volcanic areas for in situ sampling of emissions (e.g., efforts by our group, and by our colleagues at the INGV in Italy and the Applied Science University in Dusseldorf, Germany, and others in the United Kingdom and Iceland), and also for remote sensing, much more needs to be done in the way of instrument development, and in developing small UAVs for both low altitude (tropospheric) and high altitude (stratospheric) applications. In particular, the development of all weather and day/night operational flight capabilities in close proximity to hazardous topography is crucial to a truly responsive volcano in situ measurement system. Finally, it is imperative that national civil aviation authorities recognize the unique benefits of such platforms. It is important that authorities understand that severely restricting or not deploying such tools in airspace over restless volcanoes or within eruption plumes, ostensibly because of the perceived (small) risk that such unmanned aircraft pose to manned air operations, itself poses a bigger transcendental risk to proximal populations and particularly to the aviation community, itself.

Volcanic Ash Advisory Centers (VAACs)↗
NASA NTRS1974

Raw Liquid Waste Treatment System and Process

A raw sewage treatment process is disclosed in which substantially all the non-dissolved matter, suspended in the sewage water is first separated from the water, in which at least organic matter remains dissolved. The non-dissolved material is pyrolyzed to form an activated carbon and ash material without the addition of any conditioning agents. The activated carbon and ash material is added to the water from which the non-dissolved matter was removed. The activated carbon and ash material adsorbs the organic matter dissolved in the water and is thereafter supplied in a counter flow direction and combined with the incoming raw sewage to at least facilitate the separation of the non-dissolved settleable materials from the sewage water. Carbon and ash material together with the non-dissolved matter which was separated from the sewage water are pyrolyzed to form the activated carbon and ash material.

Humphrey, M. F.↗
NASA NTRS1982

The 18 May 1980 eruption of Mount St. Helens: The nature of the eruption, with an atmospheric perspective

Mount St. Helens erupted somewhat less than 0.5 cu km of magma (dense rock equivalent) on May 18, 1980. The May 18 event was usually violent. As much 35% of the volume of the airfall material fell outside of the 2.5 mm isopach, which encloses about 88,000 sq km. This extraordinary dispersive power was transmitted by an eruption column which reached heights of more than 20 km. There was a lateral blast (or surge) of unusually large dimensions associated with the onset of the eruption. The magma is dacitic in composition and had a low ( 500 ppm) sulfur content. Distal ashes contain much nonmagmatic (lithic) material, but smaller ( 50 microns m) particles are mostly finely divided magmatic dacite. The grain size distributions of the ash are multimodal, frequently with peaks at 90, 25, and 10 microns. The finer populations fell out faster than their terminal velocities as simple particles would suggest. It is inferred that large proportions of the fine ash fell out as composite particles. This condition greatly reduces the atmospheric burden of silicate particles. Some of the unusual aspects (violence, intense surges, multimodal grain size distributions, lithic content of the ashes) of the eruption may be due to its phreatomagmatic character. The hydrothermal system above the magma may have infiltrated the magma body at the onset of the eruption. An "overprint" of the geochemistry of this hydrothermal system on the geochemistry of the magmatic gas system is likely. One important feature is that reduced gas species may be much more abundant than in many eruptions. Another is that fine ash may form aggregates more readily.

Rose, W. I., Jr.↗
NASA NTRS1982

Time variations of aerosols in the stratosphere following Mount St. Helens eruptions

Samples of stratospheric aerosols collected with U-2 aircraft for several months following the first three major eruptions of Mount St. Helens were analyzed for ash and liquid acid content. Ash grain sizes and compositions vary depending on collection altitude, location within the drifting cloud, and days following their injection. s computers Size distributions of ash particles vary with altitude. Generally small particles are depleted more rapidly at low altitudes (12 km) than at higher altitudes (17-18 km). Although samples collected 1 day after the first eruption of May 18, 1980, were dry, flow marks on the aircraft indicated parts of the cloud contained heavy acid concentrations. Indeed, all other samples obtained within 1 to 4 days after later eruptions (May 25 and June 12, 1980) were covered with copious amounts of liquid acid. Proportions of liquid to ash varied considerably depending on sampling location and cloud age. Because the acid-coated ash globules were large, they rapidly fell from the stratosphere until, by late June 1980, only a residue of acid droplets remained. Size distributions and concentrations of these droplets varied considerably.

Farlow, N. H.↗
NASA NTRS1987

Chronology and pyroclastic stratigraphy of the May 18, 1980, eruption of Mount St. Helens, Washington

The eruption of Mount St. Helens on May 18, 1980 can be subdivided into six phases: the paroxysmal phase I, the early Plinian phase II, the early ash flow phase III, the climactic phase IV, the late ash flow phase V, and phase VI, the activity of which consisted of a low-energy ash plume. These phases are correlated with stratigraphic subunits of ash-fall tephra and pyroclastic flow deposits. Sustained vertical discharge of phase II produced evolved dacite with high S/Cl ratios. Ash flow activity of phase III is attributed to decreases in gas content, indicated by reduced S/Cl ratios and increased clast density of the less evolved gray pumice. Climactic events are attributed to vent clearing and exhaustion of the evolved dacite.

Criswell, C. William↗