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At least 91 records · Page 5

Radar images of Mars

VLA radar-reflected flux-density mappings have yielded full disk images of Mars which reveal near-surface features, including a region in the Tharsis volcano area that displayed no echo to the very low level of the radar-system noise. This feature is interpreted as a deposit of dust or ash whose density is less than about 0.5 g/cu cm; it must be several meters thick, and may be much deeper. The most strongly reflecting geological feature was the south polar ice cap, which is interpretable as arising from nearly-pure CO2 or H2O ice, with less than 2 vol pct Martian dust. Only one anomalous reflecting feature was identified outside the Tharsis region.

Muhleman, Duane O.↗

Potential Mars Surveyor 2001 Landing Sites Near Apollinaris Patera

Landing sites near Apollinaris Patera are proposed for the Mars Surveyor 2001 lander/rover mission. Regions near the base of Apollinaris Patera provide a unique opportunity within the proposed -15(beta)o 30(beta) latitude belt to sample outcrop lithologies ranging from highland Noachian basement rocks, to Hesperian aged lava flows, channel and flood plain materials, to Amazonian volcanic, ash flow, and channel deposits. Pristine impact craters exhibiting lobate ejecta blankets are found both on the volcano itself and on the surrounding terrain implying a ground water rich environment well into the Amazonian. Therefore its formation likely induced long-lived volcanic-hydrothermal systems, a high priority target for the mission.

Gulick, Virginia C.↗

Potential Mars Surveyor 2001 Landing Sites Near Apollinaris Patera

Landing sites near Apollinaris Patera are proposed for the Mars Surveyor 2001 lander/rover mission. Regions near the base of Apollinaris Patera provide a unique opportunity within the proposed -15 deg to 30deg latitude belt to sample outcrop lithologies ranging from highland Noachian basement rocks, to Hesperian aged lava flows, channel and flood plain materials, to Amazonian volcanic, ash flow, and channel deposits. Pristine impact craters exhibiting lobate ejecta blankets are found both on the volcano itself and on the surrounding terrain implying a ground water rich environment well into the Amazonian. Therefore its formation likely induced long-lived volcanic-hydrothermal systems, a high priority target for the mission.

Gulick, Virginia C.↗

Widespread Layers in Arabia Terra: Implications for Martian Geologic History

Layered rocks in Arabia Terra have been the focus of several recent papers. Studies have focused on the layers found in crater basins located in the southwest portion of the region. However, Mars Orbiter Camera (MOC) images have identified layered deposits across the region. Terrestrial layered rocks are usually sedimentary, and often deposited in water. Thus extensive layered sequences in Arabia Terra may indicate locations of past, major depositional basins on Mars. Other mechanisms can also create layered rocks, or the appearance of layered rocks, including volcanism (both lava flows and ash falls), wind-blown deposits, and wave-cut terraces at shorelines. By identifying where in the region layers occur, and classifying the layers according to morphology and albedo, past depositional environments may be identified. Arabia Terra is characterized by heavily cratered Noachian plains, as well as a rise from -4000 m in the northwest to 4000 m in the southeast (Mars Orbital Laser Altimeter [MOLA] datum). This slope may have provided a constraint on sediment deposition and thus layer formation. While most of the region is Noachian in age, a significant percentage of the area is identified as Hesperian. Although the history of the Arabia Terra initially seems to be straightforward cratered plains with several younger units atop them analysis of high-resolution imagery may reveal a more complex history.

Venechuk, Elizabeth M.↗

Chronology and pyroclastic stratigraphy of the May 18, 1980, eruption of Mount St. Helens, Washington

The eruption of Mount St. Helens on May 18, 1980 can be subdivided into six phases: the paroxysmal phase I, the early Plinian phase II, the early ash flow phase III, the climactic phase IV, the late ash flow phase V, and phase VI, the activity of which consisted of a low-energy ash plume. These phases are correlated with stratigraphic subunits of ash-fall tephra and pyroclastic flow deposits. Sustained vertical discharge of phase II produced evolved dacite with high S/Cl ratios. Ash flow activity of phase III is attributed to decreases in gas content, indicated by reduced S/Cl ratios and increased clast density of the less evolved gray pumice. Climactic events are attributed to vent clearing and exhaustion of the evolved dacite.

Criswell, C. William↗

Coupled Hydrothermal Extraction and Ligand-Associated Swellable Glass Media Recovery of Rare Earth Elements from Coal Fly Ash (Final Report)

Wayne State University (WSU) researchers, in collaboration with the University of California-Los Angeles (UCLA) and Los Alamos National Laboratory (LANL), have successfully developed a new sorbent media used in a process that concentrated the rare earth content in a coal fly ash sample from southeast MI by >350×, resulting in >13 wt% REO powder. The project developed a new DTPA-associated media that was used to concentrate total REEs. This project demonstrated a coupled hydrothermal extraction and solid-liquid recovery process that produced REO powder from raw fly ash while nearly eliminating the use of organic solvents. The project successfully: 1) identified a commercially viable ash supply with >$2.5 M in REO value being deposited monthly, 2) hydrothermally extracted >77% of REEs in coal fly ash (20% more than acid alone), 3) developed a new sorbent media that was used to concentrate REEs, 4) and engineered a process that resulted in a >13 wt% REO powder. The media also demonstrates a selectivity for mid and heavy REEs over Ce and La and the potential for use in separating individual rare earth elements. An invention disclosure for the sorbent media has been filed with WSU and a patent application will be submitted in the near future. The project examined the potential to couple hydrothermal leaching of coal fly ash with the engineering of a custom ligand-associated media to provide an organic solvent-free method of extracting and recovering REEs. Fly ash feedstock was collected from Detroit area coal-fired power plants, characterized for REE content, and subjected to a bench-top batch hydrothermal leaching/dissolution process inside custom-build pressure reactors at Los Alamos National Laboratory (LANL). This process applied a dissolution technique previously developed to process spent nuclear fuel and other nuclear materials. The modified ash was acidified and the resulting leachate was enriched with REEs along with Ca, Al, and Si. Ligands known to be effective in lanthanide/actinide separation were evaluated based on a series of criteria such as selectivity and association to organosilica through hydrophobicity. Batch experiments were conducted to establish the best conditions (e.g., pH, eluent, etc.) and best ligand systems for the effective extraction of REEs from the alkaline feed solution obtained from the hydrothermal leaching process. Once the organosilica-ligand extraction media was developed for REE concentration, an acidic solution was used to back extract and concentrate the REEs into a heavily REE-laden strip solution. The REEs in the strip solution were precipitated with oxalate to produce rare earth oxides.

01 COAL, LIGNITE, AND PEAT↗

Variable features on Mars. VI - An unusual crater streak in Mesogaea

An unusual prominent dark streak located in Mesogaea (near 8 deg N, 191 deg W) is described. Its appearance is unlike that of most dark streaks on Mars, many of which have ragged outlines, are variable on short time-scales, and are presumed to be erosional. The Mesogaea streak has a tapered smooth outline, and no changes within it were observed. It is suggested that this streak is depositional and that the low-albedo material originated within the associated crater itself. The source area is identified with a compact low-albedo region on the crater floor. Two possible origins for the dark material are suggested:(1) deflation from a recently exposed and relatively unconsolidated subsurface deposit, and (2) production of ash by a volcanic vent.

Veverka, J.↗

The 1883 eruption of Krakatau

The 1883 eruption of Krakatau was a modest ignimbrite-forming event. The deposits are primarily coarse-grained dacitic, non-welded ignimbrite. Large explosions produced pyroclastic flows that entered the sea, generating destructive tsunami. Grain-size studies of the ignimbrite suggest that these explosions were not driven by magma-seawater interaction. The total bulk volume of pyroclastic deposits, including co-ignimbrite ash, is estimated to be 18-21 cu km.

Self, S.↗

Effusive silicic volcanism in the Central Andes: The Chao dacite and other young lavas of the Altiplano-Puna Volcanic Complex

The largest known Quaternary silicic lava body in the world is Cerro Chao in north Chile, a 14-km-long coulee with a volume of at least 26 cu km. It is the largest of a group of several closely similar dacitic lavas erupted during a recent (less than 100,000 year old) magmatic episode in the Altiplano-Puna Volcanic Complex (APVC; 21-24 deg S) of the Centra; Andean Volcanic Zone. The eruption of Chao proceeded in three phases. Phase 1 was explosive and produced approximately 1 cu km of coarse, nonwelded dacitic pumice deposits and later block and ash flows that form an apron in front of the main lava body. Phase 2 was dominantly effusive and erupted approximately 22.5 cu km of magma in the form of a composite coulee covering approximately 53 sq km with a 400-m-high flow front and a small cone of poorly expanded pumice around the vent. The lava is homogeneous with rare flow banding and vesicular tops and selvages. Ogives (flow ridges) reaching heights of 30 m form prominent features on its surface. Phase 3 produced a 6-km-long, 3-km-wide flow that emanated from a collapsed dome. Ogives are subdued, and the lava is glassier than that produced in previous phases. All the Chao products are crystal-rich high-K dacites and rhyodacites with phenocrysts of plagioclase, quartz, hornblende, biotite, sphene, rare snidine, and oxides. Phenocryst contents reach 40-60 vol % (vesicle free) in the main phase 2 lavas but are lower in the phase 1 (20-25%) and phase 3 (approximately 40%) lavas. Ovoid andesitic inclusions with vesicular interiors and chilled margins up to 10 cm are found in the later stages of phase 2 and compose up to 5% of the phase 3 lava. There is little evidence for preeruptive zonation of the magma body in composition, temperature (approximately 840 C), fO2 (19(exp -11), or water content, so we propose that eruption of the Chao complex was driven by intrusion of fresh, hot andesitic magma into a crystallizing and largely homogeneous body of dacitic magma. Morphological measurements suggest that the Chao lavas had internal plastic viscosities of 10(exp 10) to 10(exp 12) Pa s, apparent viscosities of 10(exp 9) Pa s, surface viscosities of 10(exp 15) to 10(exp 24) Pa s, and a yield strength of 8 x 10(exp 5) Pa. These estimates indicate that Chao would have exhibited largely similar rheological properties to other silicic lava extrusions, notwithstanding its high phenocryst content. We suggest that Chao's anomalous size is a function of both the relatively steep local slope (20 deg to 3 deg) and the available volume of magma. The eruption duration for Chao's emplacement is thought to have been about 100 to 150 years, with maximum effusion rates of about 25 cu m/s for short periods. Four other lavas in the vicinity with volumes of approximately 5 cu km closely resemble Chao and are probably comagnetic. The suite as a whole shares a petrologic and chemical similarity with the voluminous regional Tertiary to Pleistocene ignimbrites of the APVC and may be derived from a zone of silicic magmatism that is thought to have been active since the late Tertiary. Chao and the other young lavas may represent either the waning of this system or a new episode fueled by intrusions of mafic magma.

De Silva, S. L.↗

Wildfire smoke impacts lake ecosystems

Abstract Wildfire activity is increasing globally. The resulting smoke plumes can travel hundreds to thousands of kilometers, reflecting or scattering sunlight and depositing particles within ecosystems. Several key physical, chemical, and biological processes in lakes are controlled by factors affected by smoke. The spatial and temporal scales of lake exposure to smoke are extensive and under‐recognized. We introduce the concept of the lake smoke‐day, or the number of days any given lake is exposed to smoke in any given fire season, and quantify the total lake smoke‐day exposure in North America from 2019 to 2021. Because smoke can be transported at continental to intercontinental scales, even regions that may not typically experience direct burning of landscapes by wildfire are at risk of smoke exposure. We found that 99.3% of North America was covered by smoke, affecting a total of 1,333,687 lakes ≥10 ha. An incredible 98.9% of lakes experienced at least 10 smoke‐days a year, with 89.6% of lakes receiving over 30 lake smoke‐days, and lakes in some regions experiencing up to 4 months of cumulative smoke‐days. Herein we review the mechanisms through which smoke and ash can affect lakes by altering the amount and spectral composition of incoming solar radiation and depositing carbon, nutrients, or toxic compounds that could alter chemical conditions and impact biota. We develop a conceptual framework that synthesizes known and theoretical impacts of smoke on lakes to guide future research. Finally, we identify emerging research priorities that can help us better understand how lakes will be affected by smoke as wildfire activity increases due to climate change and other anthropogenic activities.

54 ENVIRONMENTAL SCIENCES↗

Diesel Particulate Filter Durability Performance Comparison Using Metals Doped B20 vs. Conventional Diesel Part II: Chemical and Microscopic Characterization of Aged DPFs

This project's objective was to generate experimental data to evaluate the impact of metals doped B20 on diesel particle filter (DPF) ash loading and performance compared to that of conventional petrodiesel. The effect of metals doped B20 vs. conventional diesel on a DPF was quantified in a laboratory controlled accelerated ash loading study. The ash loading was conducted on two DPFs - one using ULSD fuel and the other on B20 containing metals dopants equivalent to 4 ppm B100 total metals. Engine oil consumption and B20 metals levels were accelerated by a factor of 5, with DPFs loaded to 30 g/L of ash. Details of the ash loading experiment and on-engine DPF performance evaluations are presented in the companion paper (Part I). The DPFs were cleaned, and ash samples were taken from the cleaned material. X-ray Fluorescence (XRF), X-Ray Photoelectron Spectroscopy (XPS) and X-Ray Diffraction (XRD) were conducted on the ash samples. Core samples were taken from the cleaned DPF and were subjected to scanning electron microscope energy dispersive x-ray spectroscopy (SEM-EDS) and XRF analysis. A comparison of the data from the two DPFs is presented. The XRD and XPS analysis showed that the compounds present in the ash from the two DPFs were nearly identical, though differing in concentrations. CaSO4 was the biggest component of the ash from both DPFs. The metals doped B20 fuel resulted in ash with similar characteristics to that deposited by the lube oil and did not appear to have any deleterious physical effects on the DPF substrate (did not penetrate the substrate).

ADVANCED PROPULSION SYSTEMS,BIOMASS FUELS↗

On the geometric form of volcanoes - Comment

The model of Lacey et al. (1981) accounting for the geometric regularity and approximate cone shape of volcanoes is discussed. It is pointed out that, contrary to the model, volcano eruptions do not occur randomly in elevation and azimuth, but are commonly restricted to summit vents and a few well defined flank zones, so that the form of a volcano is determined by its vent locations and styles of eruption. Other false predictions of the model include the constancy of lava volumes at all vent elevations, the increase in volcano radius as the square root of time, a critical height for volcano growth, the influence of planetary gravity on volcano height and the negligible influence of ash falls and flows and erosional deposition. It is noted that the model of Shteynberg and Solov'yev, in which cone shape is related to stresses due to increasing cone height, may provide a better understanding of volcano morphology.

Wood, C. A.↗

On the colors of Jupiter's satellite Io - Irradiation of solid sulfur at 77 K

The colors of seven sulfur allotropes at 77 K have been investigated both before and after irradiation by a high-pressure mercury lamp. S8 is white at 77 K but turns intense yellow within a few minutes on irradiation through quartz or DURAN. On warming, the yellow species (presumably chain-like sulfur diradicals characterized by an absorption at 430 nm) decomposes near 260 K and polymeric sulfur (S-infinity) is formed; the sample color changes gradually to the very similar color of an S8-S-infinity mixture, resulting in no visually detectable color change with temperatures from 77 K to 260 K. This is consistent with the lack of posteclipse brightening on Io. Other sulfur forms also turn intense yellow (S7, S10), grayish yellow (S12, S20, S-infinity), or brownish yellow (S6) on irradiation at 77 K, and these colors also change to the normal colors of the starting materials on warming to 298 K. It is suggested that the yellowish features on Io are caused by the effect of solar radiation on elemental sulfur. The yellow color thus produced may subsequently be modified by deposits of SO2 frosts and volcanic ash.

Steudel, R.↗

Satellite‐Detected Ocean Ecosystem Response to Volcanic Eruptions in the Subarctic Northeast Pacific Ocean

Volcanic eruptions in the Aleutian Archipelago during the summer of 2008 deposited large quantities of iron‐laden ash to the subarctic North Pacific Ocean. The surface ocean ecosystem response has been previously characterized using limited in situ and autonomous field measurements and numerical modeling, but basin‐scale satellite remote sensing has been limited to a simple description of chlorophyll variability. Here, we show that the ecosystem response is a complex combination of phytoplankton biomass and physiology that can be described with satellite ocean color diagnostics such as the chlorophyll‐to‐carbon biomass ratio (Chl:Cphyto) and chlorophyll fluorescence yield. Together, these quantities outline a more complete picture of ecological responses spanning unique signals of iron stress (and relief from), photo acclimation, changes in phytoplankton growth rate, increases in biomass, and timescales of decay for these processes.

T.K. Westberry↗

Investigating Buried Ice at Askja Volcano, Northern Iceland using Ground Penetrating Radar: A Planetary Analog Perspective

Shallow subsurface ice deposits on Mars and the Moon have been identified as potential targets for in situ resource utilization by future crewed missions to the surfaces of these bodies. On Mars, such deposits have been identified through a variety of orbital measurements at the poles, mid-latitudes, and even preserved by volcanic ash near the Tharsis Montes. At some locations, massive ice deposits have been documented to be 100 m in thickness at depths as shallow as 1 m. On the Moon, the presence of thick, massive ice has not been confirmed; however, orbital observations indicate that the upper 1-2 m of regolith may contain a few weight percent in thermally favorable locations. Eruptions of the Askja Volcano in March, 1875 and November, 1961 deposited abundant pyroclasts, which blanketed and insulated fresh snowfall that later densified into massive ice and is preserved today. The pyroclasts consist of a buff colored pumice from the eruption in 1875 and basaltic lapilli and ash from the eruption in 1961. The largely unvegetated, unconsolidated nature of the pyroclasts and their stratigraphic relationships with shallow subsurface ice make them potentially analogous to some ice deposits within regolith and pyroclasts at the Moon and Mars. Ground penetrating radar(GPR) can be used by future human or robotic missions to identify water ice similarly preserved in the shallow subsurface of these bodies. Our team conducted over 66 GPR surveys inside and surrounding the Askja caldera in August 2019 at 200 and 400 MHz to map both the volcanic deposits and the subsurface ice deposits. We also used a hammer drill augur to take boreholes in order to confirm subsurface stratigraphy and the presence of ice down to 1-1.5 m and aerial surveys using a Mavic 2 Pro quadcopter at each site for additional context. We observed shallow ice deposits within pore spaces of the pyroclasts at depths of ~15-30 cm and pure ice deposits at varying depths (0.6-1 m) as thick as 2-3 m. We also plan to use the data to characterize the frequency-dependent attenuation of the radar signal as it travels through volcanoclastic material and ice in the subsurface. Our investigation of Askja as a planetary analog will provide insight into analytical methods that can be used to investigate subsurface water ice from surface operations at other terrestrial bodies.

Geophysics↗

Optimum concentration of fly ash nanoparticles to stabilize CO 2 foams for aquifer and soil remediation

Contamination caused by non-aqueous phase liquids (NAPLs) in aquifers and soil is an important challenge that requires effective remediation techniques. One potential approach is through the use of CO 2 foams to displace NAPLs from permeable media. CO 2 foams generated only by surfactants are not stable enough for the efficient removal of NAPLs contamination. This shortcoming may be alleviated via the use of nanoparticles (NPs)-surfactant mixtures as a stabilizing agent. This work focuses on the evaluation of the optimum concentration of fly ash nanoparticles for stabilizing CO 2 foam with the combined action of the surfactant. The performance of this foam is evaluated in remediating a contaminated 41 mm × 36 mm surrogate permeable medium in a microfluidic device. Mixtures of fly ash, a by-product of coal-burning power plants, and alpha-olefin sulfonate (AOS) and lauramidopropyl betaine (LAPB) surfactants are used to generate stable foams. The results show that a 1000 mg/L AOS-LAPB surfactant solution along with 1000 mg/L of fly ash NPs produces the best performance. Formation of deposits in the matrix is observed. These deposits, which are more prominent at higher NP concentrations, appear to adversely affect displacement, displacement efficiency and remediation of the medium. This study demonstrates that using fly ash nanoparticles and optimizing their concentration can effectively stabilize CO 2 foams and improve the displacement efficiency for aquifer and soil remediation.

54 ENVIRONMENTAL SCIENCES↗

Evaluating the state-of-the-art in remote volcanic eruption characterization Part II: Ulawun volcano, Papua New Guinea

Retrospective eruption characterization is valuable for advancing our understanding of volcanic systems and evaluating our observational capabilities, especially with remote technologies (defined here as a space-borne system or non-local, ground-based instrumentation which include regional and remote infrasound sensors). In June 2019, the open-system Ulawun volcano, Papua New Guinea, produced a VEI 4 eruption. We combined data from satellites (including Sentinel-2, TROPOMI, MODIS, Himawari-8), the International Monitoring System infrasound network, and GLD360 globally detected lightning with information from the local authorities and social media to characterize the pre-, syn- and post-eruptive behaviour. The Rabaul Volcano Observatory recorded ~24 h of seismicity and detected SO 2 emissions ~16 h before the visually-documented start of the Plinian phase on 26 June at 04:20 UTC. Infrasound and SO2 detections suggest the eruption started during the night on 24 June 2019 at 10:39 UTC ~38 h before ash detections with a gas-dominated jetting phase. Local reports and infrasound detections show that the second phase of the eruption started on 25 June 19:28 UTC with ~6 h of jetting. The first detected lightning occurred on 26 June 00:14 UTC, and ash emissions were first detected by Himawari-8 at 01:00 UTC. Post-eruptive satellite imagery indicates new flow deposits to the south and north of the edifice and ash fall to the west and southwest. In particular, regional infrasound data provided novel insight into eruption onset and syn-eruptive changes in intensity. We conclude that, while remote observations are sufficient for detection and tracking of syn-eruptive changes, key challenges in data latency, acquisition, and synthesis must be addressed to improve future near-real-time characterization of eruptions at minimally-monitored or unmonitored volcanoes.

58 GEOSCIENCES↗

Heterogeneous multiphase flow properties of volcanic rocks and implications for noble gas transport from underground nuclear explosions

Of interest to the Underground Nuclear Explosion Signatures Experiment are patterns and timing of explosion-generated noble gases that reach the land surface. The impact of potentially simultaneous flow of water and gas on noble gas transport in heterogeneous fractured rock is a current scientific knowledge gap. This article presents field and laboratory data to constrain and justify a triple continua conceptual model with multimodal multiphase fluid flow constitutive equations that represents host rock matrix, natural fractures, and induced fractures from past underground nuclear explosions (UNEs) at Aqueduct and Pahute Mesas, Nevada National Security Site, Nevada, USA. Capillary pressure from mercury intrusion and direct air–water measurements on volcanic tuff core samples exhibit extreme spatial heterogeneity (i.e., variation over multiple orders of magnitude). Petrographic observations indicate that heterogeneity derives from multimodal pore structures in ash-flow tuff components and post-depositional alteration processes. Comparisons of pre- and post-UNE samples reveal different pore size distributions that are due in part to microfractures. Capillary pressure relationships require a multimodal van Genuchten (VG) constitutive model to best fit the data. Relative permeability estimations based on unimodal VG fits to capillary pressure can be different from those based on bimodal VG fits, implying the choice of unimodal vs. bimodal fits may greatly affect flow and transport predictions of noble gas signatures. The range in measured capillary pressure and predicted relative permeability curves for a given lithology and between lithologies highlights the need for future modeling to consider spatially distributed properties.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗