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At least 91 records · Page 5

Lean-Stratified Combustion System with Miller Cycle for Downsized Boosted Application - Part 2

Automotive manufacturers relentlessly explore engine technology combinations to achieve reduced fuel consumption under continued regulatory, societal and economic pressures. For example, technologies enabling advanced combustion modes, increased expansion to effective compression ratio and reduced parasitics continue to be developed and integrated within conventional and hybrid propulsion strategies across the industry. Here, a high-efficiency gasoline engine capable for use in conventional or hybrid electric vehicle platforms is highly desirable. This paper is the second of two papers describing the multi-cylinder integration of a technology package combining lean-stratified combustion with Miller cycle for downsized boosted applications. The first paper describes the design, analysis and single-cylinder testing conducted to down-select the combustion system deployed to the multi-cylinder engine. This paper defines a light-duty engine package capable of achieving a 35% fuel economy improvement at US Tier 3 emission standards over a naturally aspirated stoichiometric baseline vehicle. A multi-mode combustion system was developed enabling highly efficient lean-stratified operation at light-load and stoichiometric Miller-cycle operation at mid- to high-loads. A central direct-injection four-valve layout was designed with high-tumble ports and a bowl-in-piston capable of stable operation under highly dilute mixtures when properly matched to fuel spray characteristics, injection strategy, and a high-energy ignition system. Boost system layout and base engine architecture were selected to minimize parasitics and maximize after treatment effectiveness. A multi-cylinder engine was developed and calibrated over a steady-state map. Results fed vehicle simulations over the EPA city and highway test cycles to predict the fuel economy improvement and tailpipe emissions potential. Fuel economy improvements over the baseline vehicle were projected at 42% and 39% for active-urea and passive-ammonia SCR after treatment systems respectively. Controls complexity to achieve regulatory compliance and the cost of the lean after treatment system were identified as the primary challenges to commercial viability.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Boosted Dark Matter Search with the ICARUS Detector at the Gran Sasso Underground National Laboratory

The quest to discover dark matter is one of the most pressing topics in modern physics. Evidence of gravitational anomalies is present at different cosmological scales, spanning the stability and rotation of galaxies to the overall density profile of the entire observable Universe. Due to the discrepancy between the mass measured and the gravitational influence on the mass, if General Relativity is to correctly describe gravity at different scales, extra electromagnetically invisible matter termed dark matter must exist. In recent decades, many experiments have been performed to detect dark matter with masses that span many orders of magnitude, from Mass Compact Halo Objects (MACHOs) with masses several orders of magnitude that of our sun to very light particles on the order of $\sim\mu$eV. However, experiments have only been able to constrain the possible parameter space of dark matter models and, in general, probe dark matter models with single constituent dark matter like Weakly Interacting Massive Particles (WIMPs). In the Boosted Dark Matter (BDM) paradigm, there are four particles in the dark sector: $\chi_0$, $\chi_1$, $\chi_2$, and the dark photon $X$. WIMP-like properties are ascribed to $\chi_0$ to describe the physics of the gravitational anomalies, while relativistic components are assigned to $\chi_1$ and $\chi_2$. The inelastic boosted dark matter (iBDM) channel $\chi_1 e^-\rightarrow \chi_2 e^-\rightarrow \chi_1 Xe^-\rightarrow \chi_1 (e^+ e^- ) e^-$, where $\chi_2$ is an excited state of $\chi_1$, has a unique signature that is distinguishable from neutrino interactions, making neutrino experiments a viable search environment for BDM. Using data collected by the ICARUS collaboration with ICARUS T-600 Liquid Argon Time Projection Chamber (LArTPC) during its operation at the Gran Sasso Underground Laboratory (LNGS), the first-ever LArTPC dark matter search using the ICARUS detector is presented. With a total detector exposure of 0.13 kton$\cdot$year, a total of 4 iBDM candidate events were identified by several stages of data scanning. All were rejected due to defined selection criteria and a wire-by-wire $dE/dx$ evaluation, giving a null result. Exclusion plots at 90\%C.L. for the dark photon ($m_X$, $\epsilon$) parameter space for fixed ($m_0,m_1,m_2$) DM mass sets are presented, setting new limits on the dark photon visible decay parameter space.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Using Boosted Decision Trees to Select High Quality Measurements in the Mu2e Experiment at Fermilab

This thesis presents the implementation and evaluation of a Boosted Decision Tree (BDT) model to improve the selection of high-quality track measurements in the Mu2e experiment at Fermilab. The Mu2e experiment is a high-energy physics experiments seeking to observe a rare theoretical physics process known as Charged Lepton Flavor Violation. A significant challenge faced by the Mu2e experiment are so-called background events, which are events whose data mimics that of the rare physics process the experiment seeks to observe. Without a mechanism to reduce background, it would be impossible to know whether Charged Lepton Flavor Violation occurred or not. To this end, high-quality track measurements must be distinguished from low-quality track measurements. A track can be conceived of as the reconstructed path of a particle that traveled through the Mu2e detector. In addition to other data, data about such tracks is stored using a C++-based framework, specific to the domain of high-energy physics, known as ROOT. A boosted decision tree model was trained using ROOT’s Toolkit For Multivariate Analysis by leveraging variables ancillary to track quality. In evaluation, the BDT achieves a ROC-AUC of 0.927 in discriminating good-quality tracks from poor-quality tracks. Such a score is indicative of both strong discrimination and strong generalization. Subsequently, it is shown that applying a BDT-based quality cut to the distribution of particle momenta significantly enhances the signal-to-background distinction for signal electrons, paving the way for improved sensitivity to Charged Lepton Flavor Violation.

Mullany, Brendan T. [Drew U.] (ORCID:0009000818888↗

Differential $t\overline{t}$ cross-section measurements using boosted top quarks in the all-hadronic final state with 139 fb -1 of ATLAS data

Measurements of single-, double-, and triple-differential cross-sections are presented for boosted top-quark pair-production in 13 TeV proton–proton collisions recorded by the ATLAS detector at the LHC. The top quarks are observed through their hadronic decay and reconstructed as large-radius jets with the leading jet having transverse momentum (pT) greater than 500 GeV. The observed data are unfolded to remove detector effects. The particle-level cross-section, multiplied by the $t\overline{t}$ $\rightarrow$ $WWb$$\overline{b}$ branching fraction and measured in a fiducial phase space defined by requiring the leading and second-leading jets to have p T > 500 GeV and p T > 350 GeV, respectively, is 331 ± 3(stat.) ± 39(syst.) fb. This is approximately 20% lower than the prediction of ${398}^{+48}_{-49}$ fb by POWHEG+PYTHIA 8 with next-to-leading-order (NLO) accuracy but consistent within the theoretical uncertainties. Results are also presented at the parton level, where the effects of top-quark decay, parton showering, and hadronization are removed such that they can be compared with fixed-order next-to-next-to-leading-order (NNLO) calculations. The parton-level cross-section, measured in a fiducial phase space similar to that at particle level, is 1.94 ± 0.02(stat.) ± 0.25(syst.) pb. This agrees with the NNLO prediction of ${1.96}^{+0.02}_{-0.17}$ pb. Reasonable agreement with the differential cross-sections is found for most NLO models, while the NNLO calculations are generally in better agreement with the data. The differential cross-sections are interpreted using a Standard Model effective field-theory formalism and limits are set on Wilson coefficients of several four-fermion operators.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

An iterative bidirectional gradient boosting approach for CVR baseline estimation

Here this paper presents a novel Iterative Bidirectional Gradient Boosting Model (IBi-GBM) for estimating the baseline of Conservation Voltage Reduction (CVR) programs. In contrast to many existing methods, we treat CVR baseline estimation as a missing data retrieval problem. The approach involves dividing the load and its corresponding temperature profiles into three periods: pre-CVR, CVR, and post-CVR. To restore the missing load profile during the CVR period, the method employs a three-step process. First, a forward-pass GBM is executed using data from the pre-CVR period as inputs. Subsequently, a backward-pass GBM is applied using data from the post-CVR period. The two restored load profiles are reconciled, considering pre-calculated weights derived from forecasting accuracy, and only the leftmost and rightmost points are retained. The newly restored points are then included as inputs for the subsequent iteration. This iterative procedure continues until the original load data in the CVR period is fully restored. We develop IBi-GBM using actual smart meter and Supervisory Control and Data Acquisition (SCADA) data. Our results demonstrate that IBi-GBM exhibits robust performance across various data resolutions and in different seasons and outperforms existing methods by achieving a 1-2% reduction in normalized Root Mean Square Error (nRMSE).

42 ENGINEERING↗

Search for a massive scalar resonance decaying to a light scalar and a Higgs boson in the four b quarks final state with boosted topology

We search for new massive scalar particles X and Y through the resonant process X→YH→$b\bar{b}b\bar{b}$, where H is the standard model Higgs boson. Data from CERN LHC proton-proton collisions are used, collected at a centre-of-mass energy of 13 TeV in 2016–2018 and corresponding to an integrated luminosity of 138 fb -1 . The search is performed in mass ranges of 0.9–4 TeV for X and 60–600 GeV for Y, where both Y and H are reconstructed as Lorentz-boosted single large-area jets. The results are interpreted in the context of the next-to-minimal supersymmetric standard model and also in an extension of the standard model with two additional singlet scalar fields. The 95% confidence level upper limits for the production cross section vary between 0.1 and 150 fb depending on the X and Y masses, and represent a significant improvement over results from previous searches.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Modeling laser-wakefield accelerators using the time-averaged ponderomotive approximation in a Lorentz boosted frame

Future, high-fidelity simulations of multi-GeV-class laser Wakefield accelerators (LWFAs) will need to model the propagation of high-intensity laser drivers over meter-scale plasmas with high spatial and temporal resolutions, thus requiring high amounts of computational resources. Various techniques have been devised over the years to reduce the computational cost of such simulations, including the time-averaged ponderomotive approximation, and the use of the Lorentz boosted frame technique. In this paper we discuss the combination of these two computational techniques, highlighting the resulting significant reduction in the computational cost of LWFA simulations and the limitations of this approach. The combination of the two techniques can potentially become essential for the modeling of a multi-TeV, LWFA-based collider.

Laser Wakefield Acceleration↗

Novel Quadratic High Gain Boost Converter With Adaptive Soft-Switching Scheme and Reduced Conduction Loss

In this article, an improved soft-switching quadratic boost converter is proposed. Instead of inserting an additional active clamp or auxiliary zero-voltage transition circuit at the switching node, the proposed topology connects the high-voltage switching node to the input diode node by replacing one of the input diodes with a low-rated switch. The proposed topology can attain soft-switching condition for all the switches and input diode turns- off under zero-current switching (ZCS). The operation of input-side switch not only aids zero-voltage switching (ZVS) turn- on for the main switch but also helps in reducing the conduction loss. Also, the input-side switch operates under ZCS turn- on and ZVS turn- off , making it a loss economical solution. An adaptive timing scheme for driving the input switch is proposed, which can ensure soft-switching condition under varying gain and load range. The detailed operational modes, analysis, and design considerations of the proposed topology are presented. A 250 W hardware prototype is built to validate the performance of the proposed converter operating at 100 kHz switching frequency. Results with adaptive soft-switching scheme shows that the converter is modulated to achieve its best efficiency condition under various system conditions. Furthermore, a peak efficiency of 96.1% at 155 W and efficiencies above 95.75% over a wide load range are achieved using all Si devices.

14 SOLAR ENERGY↗

Boosting the H 2 –D 2 Exchange Activity of Dilute Nanoporous Ti–Cu Catalysts through Oxidation–Reduction Cycle–Induced Restructuring

The use of nanoporous metals as catalysts has attracted significant interest in recent years. Their high-curvature, nanoscale ligaments provide not only high surface area but also a high density of undercoordinated step edge and kink sites. However, their long-term stability, especially at higher temperatures, is often limited by thermal coarsening and the associated loss of surface area. Herein, it is demonstrated that the nanoscale morphology of nanoporous Cu can be regenerated by applying oxidation/reduction cycles at 250 °C. Specifically, the morphological evolution and H 2 dissociation activity of hierarchical nanoporous Cu catalysts doped with Ti during structural rearrangement triggered by oxidative and reductive atmospheres at elevated temperatures are studied. In addition to coarsening of the structure at elevated temperatures, oxidation at 400 °C causes an expansion of the ligaments. Further, subsequent reduction at 400 °C leads to the formation of particles and a drop in the H 2 dissociation activity compared the fresh catalyst. However, performing the redox cycle at 250 °C reverses coarsening and boosts the H 2 dissociation activity for the hydrogen–deuterium (H 2 –D 2 ) reaction. Herein, the possibility to reverse coarsening is demonstrated, thereby mitigating the loss of activity frequently observed in nanoporous catalysts.

36 MATERIALS SCIENCE↗

Boosting Piezoelectricity by 3D Printing PVDF‐MoS 2 Composite as a Conformal and High‐Sensitivity Piezoelectric Sensor

Abstract Additively manufactured flexible and high‐performance piezoelectric devices are highly desirable for sensing and energy harvesting of 3D conformal structures. Herein, the study reports a significantly enhanced piezoelectricity in polyvinylidene fluoride (PVDF) achieved through the in situ dipole alignment of PVDF within PVDF‐2D molybdenum disulfide (2D MoS 2 ) composite by 3D printing. The shear stress‐induced dipole poling of PVDF and 2D MoS 2 alignment are harnessed during 3D printing to boost piezoelectricity without requiring a post‐poling process. The results show a remarkable, more than the eight‐fold increment in the piezoelectric coefficient ( d 33 ) for 3D printed PVDF‐8wt.% MoS 2 composite over cast neat PVDF. The underlying mechanism of piezoelectric property enhancement is attributed to the increased volume fraction of β phase in PVDF, filler fraction, heterogeneous strain distribution around PVDF‐MoS 2 interfaces, and strain transfer to the nanofillers as confirmed by microstructural analysis and finite element simulation. These results provide a promising route to design and fabricate high‐performance 3D piezoelectric devices via 3D printing for next‐generation sensors and mechanical–electronic conformal devices.

2D MoS2↗

Insight Into Sulfur‐Containing Additive to Boost Anti‐Oxidation Ability of the Ether‐Based Electrolyte for Sodium‐Ion Full Batteries

Ether-based electrolytes are considered as promising candidates for sodium-ion batteries (SIBs) due to their high ionic conductivity and good compatibility with hard carbon (HC) anode. However, they suffer from poor anti-oxidative ability with unstable cathode electrolyte interface, inducing successive electrolyte decomposition and rapid capacity fading. Herein, the sulfur-containing additive (1,3-propanediol cyclic sulfate, PCS) is introduced to boost the stability of the electrode-electrolyte interface (EEI) in ether-based electrolyte. PCS largely participates in the inner Na + sheath, causing more diglyme (G2) molecules and fewer PF 6 - anions to occupy the inner Na + solvation sheath, avoiding the decomposition of G2 molecules at high operation voltage. Moreover, PCS is beneficial for simultaneously constructing thin and robust sulfur-containing EEI on both Prussian blue (PB) cathode and HC anode, maintaining the structural stability of PB and alleviating the dissolution of transition metals. These enable PB||HC pouch cells to deliver a capacity retention of 60.3% after 400 cycles, significantly higher than the 32.1% in PCS-free electrolytes. In conclusion, this work discloses the underlying mechanism of PCS to evoke the anti-oxidation ability of ether-based electrolyte and provides a promising method for realizing advanced sodium-ion full cells.

anti-oxidation ability↗

Boosting CO 2 Electrochemical Reduction with Atomically Precise Surface Modification on Gold Nanoclusters

Thiolate-protected gold nanoclusters (NCs) are promising catalytic materials for the electrochemical CO 2 reduction reaction (CO 2 RR). In this work an atomic level modification of a Au 23 NC is made by substituting two surface Au atoms with two Cd atoms, and it enhances the CO 2 RR selectivity to 90–95 % at the applied potential between -0.5 to -0.9 V, which is doubled compared to that of the undoped Au 23 . Additionally, the Cd-doped Au 19 Cd 2 exhibits the highest CO 2 RR activity (2200 mA mg -1 at -1.0 V vs. RHE) among the reported NCs. This synergetic effect between Au and Cd is remarkable. Density-functional theory calculations reveal that the exposure of a sulfur active site upon partial ligand removal provides an energetically feasible CO 2 RR pathway. The thermodynamic energy barrier for CO formation is 0.74 eV lower on Au 19 Cd 2 than on Au 23 . Here these results reveal that Cd doping can boost the CO 2 RR performance of Au NCs by modifying the surface geometry and electronic structure, which further changes the intermediate binding energy. This work offers insights into the surface doping mechanism of the CO 2 RR and bimetallic synergism.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Boosting the Oxygen Reduction Performance via Tuning the Synergy between Metal Core and Oxide Shell of Metal−Organic Frameworks‐Derived Co@CoO x

Abstract Co core@Co oxide shell (Co@CoO x ) catalysts represent a large family with promising oxygen reduction reaction (ORR) catalytic activity. However, inadequate understanding of Co@CoO x synergy prohibits further pursuit of catalytic performance enhancement. Herein, a Co zeolitic−imidazolate framework was converted into metallic Co, followed by controlled air treatment to form Co@CoO x . The composition and structure evolution as a function of air treatment temperature were studied thoroughly through conventional and synchrotron (both ex‐situ and in‐situ) characterizations, confirming the coexistence of CoO and Co 3 O 4 in the shell. The optimal catalyst showed an ORR half‐wave potential of 0.87 V (vs. RHE) in an alkaline half‐cell and delivered high discharge capacity in an aprotic Li−O 2 battery (7,124 mAh g Cat+C −1 ) and an aqueous Zn−air battery (694 mAh g Zn −1 ) with good performance retention after durability test. Modeling simulation and density functional theory calculation confirmed the charge donation from metal core to oxide shell and shed light on new insights of how metal@metal oxide synergy impacted the ORR via tuning the charge conductivity, oxygen affinity and intermediate transfer pathway. This work opens up a venue to boost ORR catalytic activity from an interfacial synergy perspective.

Wang, Hao↗

Self‐Standing Carbon Nanofibers@Carbon Felt Electrodes to Boost Electrolyzer Productivity: Application to the Electro‐Manufacturing of trans ‐3‐Hexenedioic Acid and Adipic Acid

The industrial implementation of electrosynthesis for chemical manufacturing remains constrained by the limited surface area of conventional electrodes. Herein, this challenge is addressed by designing a carbon nanofiber@carbon felt (CNF@CF) electrode platform that combines the high conductivity, flexibility, and ease of handling of commercial carbon felts (CF) with the large surface area and tunable surface chemistry of carbon nanofibers (CNFs). CNFs are deliberately grown onto the CF scaffold to form a sword-in-sheath structure, where entangled nanofibers wrap the felt macrofibers to provide excellent mechanical stability and electrical conductivity without binders. CNF@CF is evaluated both as an electrode and as a catalyst support for the electrochemical hydrogenation of cis,cis-muconic acid (ccMA), a biobased platform molecule key to the production of performance polyamides and renewable Nylon 6,6. As a noncatalytic electrode for the partial hydrogenation to trans-3-hexenedioic acid, CNF@CF achieves a threefold increase in both cumulative productivity and Faradaic efficiency (FE) compared to bare CF. A similar boost in catalytic activity and energy efficiency is observed using Pd/CNF@CF for the hydrogenation of ccMA to adipic acid. These results highlight the opportunities of the CNF@CF platform for electro-organic synthesis and sustainable chemical manufacturing.

electrochemical hydrogenation↗

Atomically Dispersed Silver Atoms Embedded in NiCo Layer Double Hydroxide Boost Oxygen Evolution Reaction

Abstract Bimetallic layered double hydroxides (LDHs) are promising catalysts for anodic oxygen evolution reaction (OER) in alkaline media. Despite good stability, NiCo LDH displays an unsatisfactory OER activity relative to the most robust NiFe LDH and CoFe LDH. Herein, a novel NiCo LDH electrocatalyst modified with single‐atom silver grown on carbon cloth (Ag SA ‐NiCo LDH/CC) that exhibits exceptional OER activity and stability in 1.0 m KOH is reported. The Ag SA ‐NiCo LDH/CC catalyst only requires a low overpotential of 192 mV to reach a current density of 10 mA cm −2 , obviously boosting the OER activity of NiCo LDH/CC (410 mV@10 mA cm −2 ). Inspiringly, Ag SA ‐NiCo LDH/CC can maintain its high activity for up to 500 h at a large current density of 100 mA cm −2 , exceeding most single‐atom OER catalysts. In situ Raman spectroscopy studies uncover that the in situ formed NiCoOOH during OER is the real active species. Hard X‐ray absorption spectrum (XAS) and density functional theory (DFT) calculations validate that single‐atom Ag occupying Ni site increases the chemical valence of Ni elements, and then weakens the adsorption of oxygen‐contained intermediates on Ni sites, fundamentally accounting for the enhanced OER performance.

Chemistry↗

Pacific Lamprey Translocations to the Snake River Boost Abundance of All Life Stages

Abstract The Pacific Lamprey Entosphenus tridentatus is an anadromous fish that has severely declined in the Snake River basin. In 2007, the Nez Perce Tribe initiated translocation of adults to this region from the main‐stem Columbia River and has continued the translocations to this day. These actions are aimed at restoring larval abundance along with holistic habitat improvements. We performed parentage and sibship analyses with 260 single‐nucleotide polymorphism loci to monitor productivity of translocated lamprey over a decade (2007–2018). These results provide the first direct evidence that translocations boosted larval abundance, increased juvenile production in the interior Columbia River (~3% in 2017 and 2018), and demonstrated successful migration to the Pacific Ocean. Per capita juvenile production from Snake River adult lamprey translocations out‐performed that of their volitionally migrating counterparts in the interior Columbia River, demonstrating that translocating adults to suitable habitats increased overall productivity. We projected that the translocations may eventually return enough adult offspring to the Columbia River to replace the annual take of adults for translocations, despite many adults likely returning to other basins. These translocations are also restoring Pacific Lamprey to historical areas where they had been nearly extirpated, which has impactful benefits both culturally and ecologically. Further, this study provided an unprecedented volume of data that has redefined key biological attributes, including timing of life stage transformation (average of 6.7‐year‐old juveniles), larval growth rates (~22 mm/year for the first 4 years), ocean duration (average of 5.1 years), dispersal (~3% of Snake River‐origin adults that return to the Columbia River will divert to the Willamette River), and life span (median age of postspawn adults was 12.9 years). We even quantified a new biological phenomenon of delayed spawning, which occurs at low rates (~9%) in nature. These data provide an opportunity to monitor ongoing translocation efforts and inform adaptive management to aid species recovery.

Hess, Jon E.↗

Search for boosted low-mass resonances decaying into hadrons produced in association with a photon in pp collisions at $ \sqrt{s}$ = 13 TeV with the ATLAS detector

Many extensions of the Standard Model, including those with dark matter particles, propose new mediator particles that decay into hadrons. This paper presents a search for such low mass narrow resonances decaying into hadrons using 140 fb −1 of proton-proton collision data recorded with the ATLAS detector at a centre-of-mass energy of 13 TeV. The resonances are searched for in the invariant mass spectrum of large-radius jets with two-pronged substructure that are recoiling against an energetic photon from initial state radiation, which is used as a trigger to circumvent limitations on the maximum data recording rate. This technique enables the search for boosted hadronically decaying resonances in the mass range 20–100 GeV hitherto unprobed by the ATLAS Collaboration. The observed data are found to agree with Standard Model predictions and 95% confidence level upper limits are set on the coupling of a hypothetical new spin-1 Z′ resonance with Standard Model quarks as a function of the assumed Z′-boson mass in the range between 20 and 200 GeV.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Boosted dark matter from primordial black holes produced in a first-order phase transition

During a cosmological first-order phase transition in a dark sector, fermion dark matter particles χ can form macroscopic Fermi balls that collapse to primordial black holes (PBHs) under certain conditions. The evaporation of the PBHs produces a boosted χ flux, which may be detectable if χ couples to visible matter. We consider the interaction of χ with electrons, and calculate signals of the dark matter flux in the XENON1T, XENONnT, Super-Kamiokande and Hyper-Kamiokande experiments. A correlated gravitational wave signal from the phase transition can be observed at THEIA and μAres. An amount of dark radiation measurable by CMB-S4 is an epiphenomenon of the phase transition.

79 ASTRONOMY AND ASTROPHYSICS↗