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CROCUS Weather Data at University of Illinois - Chicago Tower

Vaisala WXT sensor is an all-in-one weather instrument that provides 6 of the most important weather parameters: barometric pressure, temperature, relative humidity, rainfall, wind speed and direction. Temperature, pressure, relative humidity, and rainfall are sampled at 1 second frequency, while wind speed/direction is measured at ten per second (10Hz) frequency. These measurements are useful for looking at characterizing local weather, identifying unique weather events, and studying local turbulence, especially given the high temporal resolution of the wind measurements. These measurements are collected at the University of Illinois in Chicago, Illinois, on the meteorological tower near the greenhouse on campus. Data is available in the netCDF data format, we encourage data users review documentation through Project Pythia to understand how to work with netCDF data https://foundations.projectpythia.org/core/data-formats/netcdf-cf.html. File naming convention includes the project (CROCUS), location (UIC), data level (raw, a1), date (year, month, day), and hour (0000).

54 ENVIRONMENTAL SCIENCES↗

Data from: “Bald Cypress (Taxodium distichum) Knees Are Methane Sources Controlled by Geomorphology, Climate, and Hydrologic Extremes”

This dataset is associated with the manuscript “Bald Cypress (Taxodium distichum) Knees Are Methane Sources Controlled by Geomorphology, Climate, and Hydrologic Extremes”. Bald cypress “knees” (aboveground woody roots) have been shown to contribute to wetland methane (CH4) efflux, with large variation within and between studies. To explain this variation, we investigated spatial (i.e., across knee surface, within sites, between sites) and temporal dynamics of CH4 fluxes from knees. Methane fluxes were collected from September 2022 to August 2024 at three locations in western Kentucky, USA, within the Mississippi Alluvial Valley: a main channel (semi-permanently flooded), side channel (seasonally flooded), and reservoir edge (artificially flooded). Knee CH4 fluxes (“Ross_et_al_Knee_Flux_Data.csv”) were measured from multiple heights on knees (20, 40, and 60 cm) of various sizes (knee straight height ranged from 24 to 93 cm) using a LiCOR LI-7810 CH4/CO2/H2O Trace Gas Analyzer. The dataset also includes environmental variables collected with each knee measurement, including water level adjusted for knee-to-knee elevational differences, subsurface and air temperature, and humidity. Soil CH4 fluxes (“Ross_et_al_Soil_Flux_Data.csv”) were also collected adjacent to knees (starting in April 2023) when water levels didn’t overtop soil collars, using a LiCOR Smart Chamber and calculated in SoilFluxPro software. The soil flux dataset includes associated variables collected by the Smart Chamber. Three separate files (“*_Water_Level.csv”) are included for water level and subsurface temperature data collected at each site using HOBO U20L barometric pressure loggers. Each file type (knee flux, soil flux, water level) has an associated data dictionary (“*_dd.csv”). For specifics on methodology used and calculations, see the associated manuscript. The R script includes code used for figures and analyses reported in the manuscript.

54 ENVIRONMENTAL SCIENCES↗

Hourly gap-filled meteorological data from PIE LTER measurements (2004-2023) used as drivers to run ELM PFLOTRAN simulations

This dataset contains continuous gap-filled precipitation, solar radiation, photosynthetically active radiation (PAR), air temperature, relative humidity, wind speed, and barometric pressure data recorded primarily at the Marshview Farm weather station within the Plum Island Long Term Ecosystems Research (PIE LTER) in Newbury Massachusetts (MA) from 2004 to 2023. We compiled the data set from published annual data packages in 15min resolution available on DataOne. Gaps were filled using different statistical techniques or available observations from the vicinity, e.g. the US-PLo and the US-PHM Ameriflux sites, also located within the PIE LTER. Flags are included in this dataset to indicate the origin of each data point. Metadata files ELMPFLOTRAN_met_dd.csv and ELMPFLOTRAN_met_flmd.csv contain more information on site locations, gap filling protocols, data variables, flags, and QA/QC methods. The data set was used in the spin up and simulations of a land surface model coupled to a biogeochemical reaction network (ELM PFLOTRAN) assessing impacts of hydrology and salinity input on methane fluxes in 2022 and 2023 (Sulman et al., 2024).

54 ENVIRONMENTAL SCIENCES↗

Post-fire time series of sensor and geochemistry sample data from surface water, groundwater, precipitation, soil, and vegetation across Oak Creek watershed, Washington

This dataset supports a broader study examining wildfire impacts on hydrologic connectivity across 5 sites within the Oak Creek watershed and the resulting biogeochemical impacts. Stream sites were selected using the Advanced Terrestrial Simulator (ATS) hydrologic model to identify locations with varying groundwater contributions and hydrologic responses across different burn severity scenarios. The Retreat Fire burned from July 23 to August 2 in 2024, affecting the five study sites at varying burn severities. Each site is equipped with YSI EXO2 sondes logging sub-hourly throughout the year, and grab samples are collected approximately every six weeks. YSI sondes are used to measure temporally resolved proxies for groundwater inputs (specific conductivity) and organic matter (fluorescent dissolved organic matter; fDOM) along with basic water quality and depth. Grab samples of surface water, groundwater, and precipitation are analyzed for water stable isotopes and conductivity to understand endmembers for hydrologic mixing Grab samples of surface water, groundwater, soil water, and litter/vegetation/soil leachates are analyzed for organic matter composition measured by Fourier-Transform Ion Cyclotron Resonance Mass Spectrometry (FTICR-MS) to understand organic matter dynamics. Game camera photos are provided in a separate data package available at https://data.ess-dive.lbl.gov/datasets/doi:10.15485/3018598. Future versions of this dataset will include time series data from YSI EXO2 sondes (fDOM, dissolved oxygen, temperature, depth, specific conductance, turbidity, pH), BaroTROLL sensors (air temperature and barometric pressure), rain gauges (precipitation), and data from the soil and vegetation samples. Because this study is ongoing, this data package will be updated regularly to include newly collected data and the additional data types. For details on how to navigate data packages generated by this project, see https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. In addition to a readme, this data package also includes a file-level metadata (FLMD) file that describes each file and a data dictionary (DD) that describes all column/row headers and variable definitions. This dataset is comprised of (1) a folder of field photos; (2) a folder of surface water sample data; (3) a folder of raw Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) data; (4) a data checks report; (5) file-level metadata; (6) data dictionary; (7) field metadata; (8) readme; (9) international generic sample number (IGSN) mapping file; and (10) field protocols. The sample data subfolder contains (1) dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC) data and averages; (2) total dissolved nitrogen data and averages; (3) stable water isotopes and averages; (4) methods codes; (5) FTICR-MS methods; and (15) a subfolder of 9.4 Tesla (9.4T) FTICR-MS data. This folder contains the processed data and three subfolders, one containing the .xml files, one containing the water CoreMS output files, and the other containing instructions and scripts for processing the files in CoreMS (https://github.com/EMSL-Computing/CoreMS). All files are .csv, .pdf, .R, .xml, .d, .html, .Rmd, .py, .cal, .json, .jpg, .jpeg, .png, .mov, or .mp4.

Biogeochemistry↗

Soil and groundwater environmental sensor data, Wax Lake Delta, Louisiana, March 2023 - March 2024

This study evaluates how environmental parameters that integrate biogeochemical processes vary with water table fluctuations in the freshwater Wax Lake Delta (WLD) in Louisiana, U.S.A. This data package contains seven *.csv files and one Excel file that compiles all the data from the individual .csv files. This dataset reports high frequency (15-min) observations of water level, soil redox potential, specific conductance, and pH made for one year along elevation transects located on the older, proximal (OT) and younger, distal (YT) ends of a deltaic island. Water depth relative to the ground surface (cm; HOBO U20L-04; error ± 0.4 cm), water pH and temperature (HOBO MX2501), and specific conductance and temperature (HOBO U24-001) sensors were installed in March 2023. Water depth was corrected for barometric pressure recorded by a separate logger secured to a platform above the highest water level. Soil redox probes (SWAP ORP-40-4-B) were also installed in March 2023. Each probe had four Pt sensors (2 mm width) placed at 10 cm, 20 cm, 30 cm, and 40 cm below the ground surface. Redox data were referenced to an external Ag0/AgCl (3M KCl) reference probe placed in saturated ground and recorded on CR1000X dataloggers (Campbell Scientific) powered by solar panels. A second reference probe was positioned near the primary reference probe for backup and data correction. The tops of the soil redox probes and soil moisture probes were flush with the soil surface so that sensors are reported at their indicated depths below ground surface. Here, we report data collected between 15 March 2023 to 15 March 2024 for all sensors, with some differences due to exact dates of sensor placement or data gaps associated with sensor malfunction. For example, water depth at OT4 was not recorded between March to November 2023. Data flags indicate whether a value is valid (1) or was excluded from data analysis in the associated manuscript (-1).

EARTH SCIENCE > LAND SURFACE > SOILS↗

CROCUS Weather Data at Northwestern University Rooftop

This dataset is from the Department of Energy Office of Science funded project, Community Research on Urban and Climate Science (CROCUS) (https://crocus-urban.org/). Vaisala WXT sensor is an all-in-one weather instrument that provides 6 of the most important weather parameters: barometric pressure, temperature, relative humidity, rainfall, wind speed and direction. Temperature, pressure, relative humidity, and rainfall are sampled at 1 second frequency, while wind speed/direction is measured at ten per second (10Hz) frequency. These measurements are useful for looking at characterizing local weather, identifying unique weather events, and studying local turbulence, especially given the high temporal resolution of the wind measurements. Datasets are stored in the netCDF data format, and we we encourage users to make use the associated toolkits available from Unidata (https://www.unidata.ucar.edu/software/netcdf/), Project Pythia (https://foundations.projectpythia.org/core/data-formats/netcdf-cf.html), and our “Instrument Cookbooks” (https://crocus-urban.github.io/instrument-cookbooks) for more information on how to process the metadata-rich datasets.

EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC TEMPERATU↗

PA-BCI Meteorological dataset 1985-2018

This data package contains a QA/QC-ed meteorological time series dataset from 1985 to 2018, including relative humidity, temperature, solar radiation, rainfall, wind speed, and barometric pressure at Barro Colorado Island (PA-BCI) in Panama. The data were collected at the elevations of 42 m and 48 m at the BCI Lutz station, except for rainfall that was collected at the BCI Clearing station at the elevation of 1 m. Individual time series datasets were collected using electro-mechanical (electronic sensors, data loggers, chart recorders, etc.). The rainfall dataset was collected using the tipping bucket method, and the data could have been underestimated by 13-17% (likely the large values). The data is included as a single CSV file.

54 ENVIRONMENTAL SCIENCES↗

Monitoring Potential Transport of Radioactive Contaminants in Shallow Ephemeral Channels: FY2019

Desert Research Institute (DRI) conducted a field assessment of the potential for contaminated soil to be transported from the Smoky Site Contamination Area (CA) because of storm runoff. This activity supported U.S. Department of Energy (DOE) Environmental Management Nevada Program (EM NV) efforts to establish post-closure monitoring plans for the Smoky Site Soils Corrective Action Unit (CAU) 550. The work was intended to confirm the likely mechanism of transport and determine the meteorological conditions that might cause the movement of contaminated soils, as well as determine the particle size fraction most closely associated with transported radionuclide-contaminated soils. These data will facilitate the design of the appropriate post-closure monitoring program. In 2011, DRI installed a meteorological monitoring station on the west side of the Smoky Site CA and a hydrologic (runoff) monitoring station within the CA, near the east side. The meteorological station collected air temperature, wind speed, wind direction, relative humidity, precipitation, solar radiation, barometric pressure, soil temperature, and soil water content data. The maximum, minimum, and average or total values (as appropriate) for each of these parameters were recorded for each 10-minute interval. The maximum, minimum, and average water depth in the flume installed at the hydrologic station were also recorded for each 10-minute interval. This report presents the data collected from these stations during fiscal year (FY) 2019. During the FY2019 reporting period, the warmest months were June, July, and August and the coldest were December and February. The highest monthly solar radiation (i.e., sunshine) values were recorded in June, July, and August, whereas December through February had the lowest solar radiation values. Monthly mean wind speeds were highest in the spring (April) and early summer (June). Winds were predominantly from the north, except in February, July, August, and September when winds were mostly from the west. The monthly average relative humidity ranged from 17 percent to approximately 60 percent. Humidity was lowest in the summer and highest in the winter. Monthly total precipitation ranged from 0.0 during August and September to 2.22 inches (in) (56.39 millimeters [mm]) in February. Total precipitation for FY2019 was 7.83 in (198.88 mm). During the reporting period, a single, nonzero, flow event was recorded at the flume. This occurred over two days between March 6 and 7, 2019, in response to 1.16 in (29.46 mm) of precipitation falling within 9.3 hours on March 6, 2019. This event produced a peak water depth of 0.39 in (0.99 centimeters [cm]) in the flume, and runoff was measured for approximately 23.5 hours. However, the maximum recorded flow depth was less than the limit for flow discharge and velocity that can be calculated for the six-inch (15 cm) throat of a Parshall flume. The runoff event produced insufficient flow velocities through the natural channel to cause local erosion and transport of bedload materials. No bedload samples were collected for radiological analysis. Observing meteorological and environmental conditions that lead to storm runoff will help identify the parameters and threshold conditions that should be incorporated into post-closure monitoring plans for this and similar Soils CAU sites. Routine monitoring of meteorological and hydrologic parameters at the Smoky Site CA has been discontinued at the request of EM NV, effective at the conclusion of FY2019. Environmental data acquisition was completed and the meteorological and runoff monitoring stations were removed from the Smoky Site on October 15, 2019.

54 ENVIRONMENTAL SCIENCES↗

General Analysis of Data Collected from DOE Lidar Buoy Deployments Off Virginia and New Jersey

Pacific Northwest National Laboratory (PNNL) operates two AXYS WindSentinel lidar buoys for the U.S. Department of Energy’s Wind Energy Technologies. The purpose of these buoys is to collect hub-height winds and supporting meteorological and oceanographic information to facilitate the development of offshore wind energy in the U.S. In general, each buoy is deployed for a year or more at a given location in order to capture at least a full annual cycle of weather conditions. The initial deployment for one buoy was off the coast of Virginia beginning in 2015, and the other buoy was first deployed off the coast of New Jersey beginning in 2016. Over the last two years, PNNL has had an opportunity to analyze the data collected during these first two deployments. This report describes a substantial analysis of data collected by the two lidar buoys operated off the coasts of Virginia and New Jersey. The centerpiece instrument for each buoy as deployed off Virginia and New Jersey is a lidar system, which is designed to measure the horizontal wind vector from approximately 40 m to 200 m above the sea surface with vertical resolution of 40 m. Since the initial deployments, the original lidars have been replaced with more powerful Leosphere 866 v2 systems. The analyses in this report will apply to the original Vindicator systems. In addition to the wind profiles from the lidars, the buoys collect near-surface measurements of wind speed and direction, air temperature, relative humidity, barometric pressure, and solar irradiance. Oceanographic variables measured include the two-dimensional wave spectrum, water temperature and conductivity, and ocean current vectors to a depth of 90 m. An assessment of overall data recovery and a basic analysis of the data collected was provided in a previous report This report substantially extends that analysis. The various sections describe the development and application of an inertial measurement unit (IMU) data recovery scheme for the New Jersey deployment; a climatological analysis of winds at hub height and at the surface together with thermodynamic variables measured at the surface for the full deployment periods; an analysis of oceanographic observations describe sea state; the development of a refinement for NOAA’s WaveWatch III model to allow its application to near-shore areas; a basic climatology of ocean currents observed from the buoys; an analysis of observed winds in the framework of Monin-Obukhov Similarity Theory; and the development and evaluation of techniques to extract turbulence intensity and turbulence kinetic energy from the lidars. The analyses contained in this report provide a great deal of new information about offshore conditions on the U.S. East Coast. In addition, the experience gained will inform both configurations and analysis of data from future deployments of these lidar buoy systems.

17 WIND ENERGY↗

NNSS Soils Monitoring: Plutonium Valley (CAU 366) FY2019

Desert Research Institute (DRI) conducted a field assessment of the potential for radionuclide-contaminated soil to be transported from the Plutonium Valley Dispersion Sites Contamination Area (CA) because of both wind and storm water runoff. This activity supported U.S. Department of Energy (DOE) Environmental Management Nevada Program (EM NV) efforts to establish post-closure monitoring plans for the Plutonium Valley Dispersion Sites Corrective Action Unit (CAU) 366. The DRI task was intended to identify the likely mechanism(s) of transport and determine the meteorological conditions that might cause the movement of radionuclide-contaminated soils. The emphasis of the work was on collecting sediment transported by channelized storm runoff and measuring airborne dust concentrations and associated wind conditions. These data will facilitate an appropriate post-closure monitoring program. In 2011, DRI installed meteorological monitoring stations north and south of the Plutonium Valley CA—known as Pu Valley North and Pu Valley South, respectively—as well as a fluvial sediment sampling station within the CA. Since installation, temperature, wind speed, wind direction, relative humidity, precipitation, solar radiation, barometric pressure, soil temperature, volumetric soil moisture content, and airborne particulate concentrations have been collected at both meteorological stations. The maximum, minimum, and average or total (as appropriate) for each of these parameters were recorded for each 10-minute interval. The sediment sampling station included an automatically activated sampling pump with collection bottles for suspended sediment, which was activated when sufficient flow was present in the channel, and passive traps for bedload material that was transported down the channel during runoff events. This report presents data collected from these stations during fiscal year (FY) 2019. During the FY2019 (October 1, 2018, through September 30, 2019) reporting period, the warmest month was July and the coldest month was February. Monthly total solar radiation was highest in June or July (depending on the station) and lowest in December. Monthly mean wind speeds were highest during February. At the Pu Valley North station, winds were commonly northerly, northwesterly, and southerly. At the Pu Valley South station, the wind direction was more variable and winds frequently came from most directions, excluding westerly and northwesterly winds. Winds above 15.0 miles per hour (mph) (24.1 kilometers per hour [km/hr]) were frequently southerly at both stations, and less-frequent strong winds were northerly (at the Pu Valley South station) or northwesterly (at the Pu Valley North station). Monthly average relative humidity ranged from 18 percent in August to 62 percent in January and February. Monthly total precipitation ranged from zero at both stations in September to 2.23 inches (in) (56.6 millimeters [mm]) during February at the Pu Valley South station and 2.09 in (53.1 mm) during March at the Pu Valley North station. From October 1, 2018, through September 30, 2019, the total precipitation was 8.23 in (209 mm) and 8.15 in (207 mm) at the Pu Valley South and Pu Valley North stations, respectively. The largest daily precipitation totals of 1.46 in (37.1 mm) and 1.14 in (29.0 mm) occurred at the Pu Valley South and Pu Valley North stations, respectively, on March 6, 2019. However, the ISCO autosampler was not activated during any storm event in FY2019 because the channel water depth measurements were insufficient for suspended sediment sample collection. Additionally, because no significant flow through the channel was indicated, no bedload samples were collected. Light breezes of 0.0 mph to 5.0 mph (0.0 km/hr to 8.0 km/hr) occurred most frequently (approximately 55 percent to 57 percent of the time). The frequency of occurrence diminished exponentially as the wind speed increased such that winds in excess of 25.0 mph (40.2 km/hr) occurred less than 0.01 percent of the time. Winds in excess of 15.0 mph (24.1 km/hr) were most commonly southerly, which is likely controlled by the topography of the valley because topographic highs define the east and west sides of the valley and converge toward the north.The concentrations of PM2.5 (particulate matter with an aerodynamic diameter ≤2.5 micrometers [μm]) and PM10 (particulate matter with an aerodynamic diameter ≤10 μm) in the air generally increase as wind speed increases. However, the particle profiler at the Pu Valley South station regularly malfunctioned, which resulted in poor data quality and a limited period of record within FY2019. Therefore, discussion of the annual dust observations is mostly limited to the Pu Valley North station. At the Pu Valley North station, significant increases in windblown dust concentrations were observed when wind speeds exceeded 15.0 mph (24.1 km/hr), especially during southerly winds. When all wind speeds were considered, high dust concentrations at the Pu Valley North station were frequently associated with northerly, northwesterly, or southerly winds. The majority of PM10 transport at the Pu Valley North station occurred when winds were blowing northerly and northwesterly because of the high frequency of winds up to 15.0 mph (24.1 km/hr). The ratio of PM10 to PM2.5 is a qualitative indicator of the proximity of dust sources to the observation point and the values of the PM10 to PM2.5 ratio tend to be higher nearer to the source. The PM10 to PM2.5 ratio increased from 1.2 to 2.8 with higher wind speeds at the Pu Valley North station. This increase suggests that some locally sourced PM10 was present in the air when local winds exceeded 15.0 mph (24.1 km/hr). Local dust suspension is interpreted during major dust events when peaks in the PM10 to PM2.5 ratio occur simultaneously with the maximum wind speed and the peak PM10 concentration. Analysis of the five major dust events in FY2019 revealed that northerly winds were dominant in three events and southerly winds were dominant in two events. Local suspension of dust within Plutonium Valley is suspected to have occurred during two of the five major events (April 9, 2019, and September 28 to 29, 2019), and a nonlocal source of dust is presumed for the three other major dust events (October 14, 2018; May 16, 2019; and September 2, 2019). The three suspected regional dust transport events exhibited winds that typically did not exceed the 15.0 mph (24.1 km/hr) wind speed threshold for local dust transport and featured PM10 to PM2.5 ratios that indicate large-scale regional dust transport. Similar event characteristics (e.g., wind speed and PM10 concentration) were observed at air monitoring stations approximately 70 mi (113 km) to the northwest within the Tonopah Test Range (TTR). Therefore, these three regional events may not reflect transport from the Plutonium Valley CA. Routine monitoring of meteorological and hydrologic parameters at Plutonium Valley has been discontinued at the request of EM NV, effective at the conclusion of FY2019. Environmental data acquisition has been completed, and both Pu Valley North and Pu Valley South meteorological stations within Plutonium Valley as well as the ISCO autosampler station within the CA were removed on October 14, 2019.

54 ENVIRONMENTAL SCIENCES↗

2022 MB3a Infrasound Sensor Type Approval Evaluation

Sandia National Laboratories has tested and evaluated an updated version of the MB3a infrasound sensor, designed by CEA and manufactured by SeismoWave. The purpose of this infrasound sensor evaluation is to measure the performance characteristics in such areas as power consumption, sensitivity, full scale, self-noise, dynamic range, response, passband, sensitivity variation due to changes in barometric pressure and temperature, and sensitivity to acceleration. The MB3a infrasound sensors are being evaluated for use in the International Monitoring System (IMS) of the Preparatory Commission to the Comprehensive Nuclear-Test-Ban Treaty Organization (CTBTO).

47 OTHER INSTRUMENTATION↗

2022 Chaparral 64S Infrasound Sensor Type Approval Evaluation

Sandia National Laboratories has tested and evaluated a new version of the Chaparral 64S infrasound sensor, designed and manufactured by Chaparral Physics. The purpose of this infrasound sensor evaluation is to measure the performance characteristics in such areas as power consumption, sensitivity, full scale, self-noise, dynamic range, response, passband, sensitivity variation due to changes in barometric pressure and temperature, and sensitivity to acceleration. The Chaparral 64S infrasound sensors are being evaluated for use in the International Monitoring System (IMS) of the Preparatory Commission to the Comprehensive Nuclear-Test-Ban Treaty Organization (CTBTO).

47 OTHER INSTRUMENTATION↗

Identifying Controlling Variables Related to Mercury Vapor Concentrations in Legacy Facilities: SRNL Technology Development For D&D

A suite of sensor packages has been installed in the Alpha-4 facility at Y-12 and preliminary data analysis to isolate the controlling variables has been performed after two months of data collection. In line with the conceptual model presented in Section 2.0, the preliminary analysis has demonstrated that temperature, barometric pressure, and relative humidity are the key controlling variables for mercury vapor releases within the building. The data analysis will continue to explore these controlling variables across the next several months to capture a more complete picture of the annual change in meteorological conditions at Y-12.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Robust In-Situ Strain Measurements to Monitor CO 2 Storage

The goal of this project was to develop and demonstrate robust instrumentation to monitor the in-situ strain tensor in order to improve the reliability and security of CO 2 storage in geologic formations. We met the original goals of the project and the major overarching accomplishment is the advancement of strain tensor monitoring from an intriguing concept to a commercially available technology with a solid foundation of novel instruments supported by theoretical analyses and validation experiments. The main accomplishments of the project are summarized below. We designed, built and evaluated nine new optical fiber strainmeters and tiltmeters using Michelson interferometers to measure deformation with ultra-high resolution at both shallow and deep point locations in the subsurface. These are the robust strainmeters that motivated the title of the project. We designed, built and evaluated a novel method of measuring distributed strain in optical fibers with nanostrain resolution, and cm-scale location, and sampling into the seismic band. The new method is called Coherence-length-gated Microwave Photonics Interfereometry (CMPI). CMPI technology has advantages over existing commercial DAS and DSS methods. We developed and demonstrated capabilities to deploy instruments in the field and used them to measure strain caused by ambient signals like barometric pressure and tides, as well as induced signals like surface loading and pore pressure changes from pumping tests. We deployed a working strainmeter at 1,700 ft depth, slightly above an active reservoir. This is to our knowledge the greatest depth a strainmeter has been deployed and the techniques we used can readily be extended to greater depths. Optical fiber borehole tensor strainmeter techology was advanced from a TRL 4 at the start, to a TRL of 7 at the conclusion of the project. The project included advances in simulations and theoretical analyses. We developed and demonstrated a computational workflow that uses machine learning to reduce the computational requirements and make it practical to use Bayesian inversion to solve large numerical poroelastic analyses needed to interpret strain tensor field data. We evaluated the strain tensor fields and time series that would be caused by leaks of CO 2 or other fluids from reservoirs. These simulations demonstrated that signals from leaks could be measured with instruments developed for the project, opening a potentially new method for ensuring storage security. We showed that strains in caprock can be used to estimate pressure in a reservoir. This avoids the need to drill monitoring wells into the reservoir, and it expands the capabilities of monitoring in the caprock. The project includes a derivation and application of a novel analytical solution to the strains in the vicinity of a pressurized poroelastic inclusion. This solution explains field data measured during injeciton tests at the North Avant Field, and it will simplify future interpretation of strain tensor data. The project included a broad range of experiments, and of the most significant is the characterization of the strain tensor at an array three strainmeters during six injection tests at the North Avant Field, Oklahoma. This demonstrated repeatability of the strain signal measured by the new instruments developed for the project, and it showed similarities between the strain signal at shallow depths and pressure in the underlying reservoir. We also demonstrated that useful strain data can be measured at reservoir depths. This confirms that strain tensor data can be measured throughout the caprock over a reservoir. The project demonstrated the feasibility of using the strain tensor and distributed strain measured in caprock during a variety of different well tests where the pumping rate was constant, sinusoidal and positive, or a periodic square wave with zero net rate. This further strengthens the validity of using strain data to characterize reservoirs and aquifers. We also demonstrated that strain caused be fluctuations of air pressure and water pressure in the vadose zone can be measured and interpreted, suggesting that high resolution distributed strain measurements hold promise for monitoring the vadose zone. The project partially supported nine graduate students in the Environmental Engineering, Hydrogeology, Electrical Engineering programs at Clemson University. The research was described in nine journal papers, 23 talks and conference abstracts. Additional journal papers are in preparation. A new company called Tensora was started to provide strainmeter technology for commercial applications.

01 COAL, LIGNITE, AND PEAT↗

Field Results from New Tensor Borehole Optical Fiber Strainmeter Installations in Oklahoma and Utah

The time evolving strain field contains a wealth of information that can be used to interpret subsurface behavior. For example, injecting or removing fluids from reservoirs or aquifers causes deformation that can be used as a diagnostic signal in some cases, while it can interfere with geodetic interpretations in other cases. We've previously demonstrated the feasibility of measuring the strain tensor at a depth of 30m caused by injection into a reservoir at 530m. The observed strain signals were interpreted using four independent analytic and numerical methods that resulted in estimates of the poroelastic properties and geometry of the reservoir that was consistent with data from well logs. However, studies like these are only possible if these deformations can be reliably measured. Years of lab and field work has culminated in the development of a novel borehole strainmeter capable of resolving multiple components of strain using embedded optical fibers configured as Michelson interferometers. It features four horizontal gauges separated by 45° to resolve the horizontal strain tensor as well as a vertical strain gauge and a sixth null component for state-of-health monitoring. The downhole sensing package also includes an open pipe through its center for grout circulation during single-trip deployments and a fully welded stainless steel exterior for robustness and longevity. These instruments have a resolution of 2x10-13 strain that can easily measure the solid earth tides. Preliminary data are available from four strainmeters in shale at our Oklahoma site and four in compacted sand and gravel in Utah. These are deployed from 40-60m, except one of the strainmeters in Oklahoma is deployed at 500m. The data include strains from the initial grout curing, comparisons to predicted earth tide models and in-situ calibration results, barometric pressure admittances and spectral analyses as well as signals from underground injections and surface waves from teleseismic events. Preliminary analyses indicate behavior consistent with other strainmeter deployments, and comparison to data from a Gladwin strainmeter at the Oklahoma site validate the performance of the new design. Analyses from a suite of six well tests at the Oklahoma site show for the first time how the strain tensor field varies with location during well testing.

DeWolf, Scott↗

Identifying Controlling Variables for Mercury Vapors in Alpha-4 at Y-12: Two Year Data Collection Update

Multiple sensor packages were deployed at Alpha-4 by SRNL, in collaboration with United Cleanup Oak Ridge LLC (UCOR), to monitor mercury vapor concentrations and meteorological parameters. These sensors collected data, inside and outside of the legacy-use facility, for approximately two years. Though data gaps still exist, particularly in colder months, several controlling variables were identified that govern mercury vapor concentrations within Alpha-4. Temperature, barometric pressure gradients, humidity, and wind speed have been identified as controlling variables. A strong positive correlation was seen between mercury vapor concentrations and temperature which generally followed diurnal fluctuations. Temperatures below approximately 10 degrees Celsius did not show any spikes above the PEL, indicating more work can be performed at any time during the winter months – more data should be collected to confirm consistency in this finding. Additionally, spikes in mercury vapor concentrations above that of the permissible exposure limit (PEL; 100 µg/m 3 ) occurred primarily in late afternoon or evening/overnight hours (between 3 PM and 6 AM), which suggests D&D operations might be best scheduled during morning or daytime hours prior to the late afternoon. However, a limited number of spikes did occur outside of the identified window, although this may be attributed to disturbances in air flow and mercury vapor release from work activities performed inside of the Alpha-4 building. The analysis conducted allows for a strong predictive capability for estimating mercury vapor concentrations based upon accurate meteorological parameters. Still, additional data collection, particularly in the winter months, could help to strengthen the predictive power and validate the identified data trends. Further, increased temporal resolution could also help to better characterize the incipient stages of the increases and decreases in the mercury vapor concentration. Continued monitoring support by SRNL at Y-12 is underway at Alpha-4 to further close remaining data gaps and support deactivation and decommissioning work. Within a collaborative effort with UCOR, the SRNL team is collecting mercury vapor data to study the efficacy of a novel mercury suppressant, FerroBlack® which was recently deployed at Alpha-4. In addition, modifications to the current monitoring setup to increase measurement resolution is also being investigated.

54 ENVIRONMENTAL SCIENCES↗